Organosilicon Chemistry Ii

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Organosilicon Compounds

Author : Vladimir Ya Lee
Publisher : Academic Press
ISBN 13 : 0128019913
Total Pages : 758 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Organosilicon Compounds by : Vladimir Ya Lee

Download or read book Organosilicon Compounds written by Vladimir Ya Lee and published by Academic Press. This book was released on 2017-08-22 with total page 758 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds' structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. - Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry - Covers important breakthroughs in the field, along with the historically significant achievements of the past - Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) - Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology

Organosilicon Chemistry

Author : Stephan Pawlenko
Publisher : Walter de Gruyter
ISBN 13 : 3110862387
Total Pages : 201 pages
Book Rating : 4.1/5 (18 download)

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Book Synopsis Organosilicon Chemistry by : Stephan Pawlenko

Download or read book Organosilicon Chemistry written by Stephan Pawlenko and published by Walter de Gruyter. This book was released on 2011-06-01 with total page 201 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organosilicon Chemistry V

Author : Norbert Auner
Publisher : Wiley-VCH
ISBN 13 : 9783527306701
Total Pages : 0 pages
Book Rating : 4.3/5 (67 download)

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Book Synopsis Organosilicon Chemistry V by : Norbert Auner

Download or read book Organosilicon Chemistry V written by Norbert Auner and published by Wiley-VCH. This book was released on 2003-12-09 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Never Change a winning team. The fifth volume in this renowned series retains the established and successful concept: Leading experts from academia and industry present a comprehensive and detailed overview of the latest results in organosilicon chemistry. Synthesis and characterization of new organosilicon compounds Applications in polymer and materials science Summary of the latest research results The result is a unique collection of first-hand information, vital for every expert working in this field. From the contents: Reactions of Silicon Atoms- An Access to Unusual Molecules New Reactions of Stable Silylenes Synthesis and Chemistry of Some Bridged Silicocations Synthesis of a Highly Enantiomerically Enriched Silyllithium Compound Experimental Determination of the Inversion Barriers of Oligosily Anions SiO and SiOSiN Chains, Rings, and Cages Novel Cyclic and Polycyclic Chalcogenides of Silicon Organosilicon Compounds in Medicine and Cosmetics Organosilicon Chemistry and Nanoscience Sustainable Silicon Production The Role of Silanes in Filled and Crosslinked Polymers Catalytic Hydrosilylation of Fatty Compounds Novel Routes fro the Preparation of Nanoporous Silica Particles Aluminosiloxanes as Molecular Models for Aluminosilicates

Silicon in Organic Synthesis

Author : Ernest W. Colvin
Publisher : Butterworth-Heinemann
ISBN 13 : 148314223X
Total Pages : 361 pages
Book Rating : 4.4/5 (831 download)

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Book Synopsis Silicon in Organic Synthesis by : Ernest W. Colvin

Download or read book Silicon in Organic Synthesis written by Ernest W. Colvin and published by Butterworth-Heinemann. This book was released on 2013-10-22 with total page 361 pages. Available in PDF, EPUB and Kindle. Book excerpt: Silicon in Organic Synthesis provides an introduction to the organic chemistry of silicon. This book places particular emphasis on the concept of silicon as a "ferryman, mediating the transformation of one wholly organic molecule into another. The book begins by reviewing the discovery and development of organosilicon compounds. This is followed by separate chapters on the physical properties of organosilicon compounds; the preparation of a-metallated organosilanes, which play a key role in preparative organosilicon chemistry; migration/rearrangement reactions of silicon; the preparation and chemistry of vinylsilanes, allylsilanes, arylsilanes, and organosilyl metallic compounds. Subsequent chapters cover the synthesis of compounds such as alkene, alkynylsilanes, allenylsilanes, silylketenes, alkyl silyl ethers, acyloxysilanes, and silyl enol ethers. This book aims to serve as a timely introduction to organic chemistry for students and practitioners of synthetic organic chemistry, as well as provide a source of useful information and possibly of new ideas to those already experienced in the area.

Coordination Chemistry of Silicon

Author : Prof. Dr. Shigeyoshi Inoue
Publisher : MDPI
ISBN 13 : 3038976385
Total Pages : 228 pages
Book Rating : 4.0/5 (389 download)

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Book Synopsis Coordination Chemistry of Silicon by : Prof. Dr. Shigeyoshi Inoue

Download or read book Coordination Chemistry of Silicon written by Prof. Dr. Shigeyoshi Inoue and published by MDPI. This book was released on 2019-03-04 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist’s viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds.

Silicon in Organic, Organometallic, and Polymer Chemistry

Author : Michael A. Brook
Publisher : Wiley-Interscience
ISBN 13 : 9780471196587
Total Pages : 704 pages
Book Rating : 4.1/5 (965 download)

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Book Synopsis Silicon in Organic, Organometallic, and Polymer Chemistry by : Michael A. Brook

Download or read book Silicon in Organic, Organometallic, and Polymer Chemistry written by Michael A. Brook and published by Wiley-Interscience. This book was released on 1999-12-28 with total page 704 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive, up-to-date reference to synthetic applications of organosilicon chemistry Organic, organometallic, and polymer chemistry as well as materials science all utilize silicon in various forms, yet there is little cross-fertilization of ideas and applications among the disciplines. This book presents a much-needed overview of silicon chemistry, allowing fundamental and applied scientists to take full advantage of progress made within and outside their primary fields of expertise. With an emphasis on the preparation and reactivity of silicon compounds in organic, organometallic, and polymer chemistry, the author examines a broad range of useful topics-from mechanisms to syntheses of and syntheses using different organofunctional silanes. Numerous schemes as well as up-to-date examples from academia and industry will help readers to solve current synthetic problems and explore ideas for future research. Clear, concise coverage includes: * The mechanistic basis for the development of new silicon-based reactions * Formation and cleavage of silane reagents and functional siliconheteroatom compounds * Silicones, silica, polysilanes, and other silicon-containing polymers * Properties of molecules containing silicon, including bioactivity * Methods for the preparation of Si-C compounds * Silicon in organic synthesis * An extensive functional group index for easy access to functional group transformations

Organosilicon Materials

Author : Grish Chandra
Publisher :
ISBN 13 : 9783662148211
Total Pages : 348 pages
Book Rating : 4.1/5 (482 download)

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Book Synopsis Organosilicon Materials by : Grish Chandra

Download or read book Organosilicon Materials written by Grish Chandra and published by . This book was released on 2014-01-15 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organosilicon Chemistry: 2

Author : Sam Stuart
Publisher : Elsevier
ISBN 13 : 1483284824
Total Pages : 257 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Organosilicon Chemistry: 2 by : Sam Stuart

Download or read book Organosilicon Chemistry: 2 written by Sam Stuart and published by Elsevier. This book was released on 2013-09-03 with total page 257 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organosilicon Chemistry: 2 provides information pertinent to the fundamental aspects of organosilicon chemistry. This book discusses the organosilicon substituents in anionic rearrangements as well as examines the production of tetrakis allene from a large number of aliphatic and aromatic polyhalogenated compounds. Organized into 14 chapters, this book begins with an overview of the use of organosilyl groups as migrating substituents. This text then examines the development in the chemistry of organosilicon cyclic compounds. Other chapters consider the evidence supporting the intermediacy of silylenes and the general picture of the chemistry of organosilylenes. This book discusses as well the two major approaches for the silylation of polyhalogenated compounds, including the direct reaction of polyhalogenated compounds and the metalation or halogen-metal exchange between the halogenated aromatic compounds and organolithium reagents. The final chapter deals with the importance of hydrosilation. This book is a valuable resource for chemists, scientists, and research workers.

Chemistry and Technology of Silicones

Author : Walter Noll
Publisher : Elsevier
ISBN 13 : 0323141404
Total Pages : 716 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Chemistry and Technology of Silicones by : Walter Noll

Download or read book Chemistry and Technology of Silicones written by Walter Noll and published by Elsevier. This book was released on 2012-12-02 with total page 716 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemistry and Technology of Silicones retains the nature of a monograph despite its expanded scope, giving the reader in condensed form not only a wide-ranging but also a thorough review of this rapidly growing field. In contrast to some other monographs on organosilicon compounds that have appeared in the interim, the silicones occupy in this edition the central position, and the technological part of the work is entirely devoted to them. This book comprises 12 chapters, and begins with a general discussion of the chemistry and molecular structure of the silicones. The following chapters then discuss preparation of silanes with nonfunctional organic substituents; monomeric organosilicon compounds RnSiX4-n; and organosilanes with organofunctional groups. Other chapters cover preparation of polyorganosiloxanes; the polymeric organosiloxanes; other organosilicon polymers; production of technical silicone products from polyorganosiloxanes; properties of technical products; applications of technical silicone products in various branches of industry; esters of silicic acid; and analytical methods. This book will be of interest to practitioners in the fields of molecular chemistry.

Organosilicon Derivatives of Phosphorus and Sulfur

Author : S. Borisov
Publisher : Springer
ISBN 13 :
Total Pages : 368 pages
Book Rating : 4.:/5 (44 download)

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Book Synopsis Organosilicon Derivatives of Phosphorus and Sulfur by : S. Borisov

Download or read book Organosilicon Derivatives of Phosphorus and Sulfur written by S. Borisov and published by Springer. This book was released on 1971 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt: One of the characteristics of the development of chemical science in the middle of the present century is the vigorous proƯ gress of the "third chemistry," which is often named now the chemistry of heteroorganic compounds. Then in the last decade, among specialists in this field there has been a marked increase in interest in heteroatomic organic derivatives of silicon, i. e., heteroorganic silicon compounds. However, until recently this new class of chemical substances, which is extremely interesting theoretically and practically, has been without a single specialized monograph which systematizes and generalizes all progress in the heteroorganic chemistry of silicon. The first attempt in this direction was our book "Heteroorganic Compounds of Silicon" [42 (F), 17 (S) *], which appeared at the end of 1966 and was published as an English translation in the USA in 1969. However, as follows from its subtitle "Derivatives of Inorganic Elements," this monoƯ graph could not cover the whole broad field of the chemistry of heteroorganic compounds of silicon. The main reason for this was above all the abundance and variety of original investigations of organosilicon derivatives of inorganic elements, which was unƯ expected even to the authors themselves. As a result of this the planned length of the book compelled us to omit the sections on organosilicon compounds of phosphorus and sulfur, which had alƯ ready been prepared for publication.

Advances in Organometallic Chemistry

Author :
Publisher : Academic Press
ISBN 13 : 0080580084
Total Pages : 347 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Advances in Organometallic Chemistry by :

Download or read book Advances in Organometallic Chemistry written by and published by Academic Press. This book was released on 1968 with total page 347 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Organometallic Chemistry

Ionic and Organometallic-Catalyzed Organosilane Reductions

Author : Gerald L. Larson
Publisher : John Wiley & Sons
ISBN 13 : 0470572671
Total Pages : 768 pages
Book Rating : 4.4/5 (75 download)

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Book Synopsis Ionic and Organometallic-Catalyzed Organosilane Reductions by : Gerald L. Larson

Download or read book Ionic and Organometallic-Catalyzed Organosilane Reductions written by Gerald L. Larson and published by John Wiley & Sons. This book was released on 2009-11-19 with total page 768 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ionic and Organometallic-Catalyzed Organosilane Reductions provides an up-to-date, comprehensive review of reductions with organosilanes. Both ionic and catalyst-mediated reaction types are included, with appropriate reference to reaction mechanisms where they have been elucidated. The text also provides a wide variety of organic functional group reductions by organosilicon hydrides, and includes a substantial discussion of asymmetric reductions. All known examples have been compiled in thirty-four easily scanned, comprehensive tables compiled from 809 original articles. This is a must-have reference book for all synthetic organic chemists working in academic and industrial laboratories.

Organosilicon Chemistry III

Author : Norbert Auner
Publisher : John Wiley & Sons
ISBN 13 : 3527620745
Total Pages : 742 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Organosilicon Chemistry III by : Norbert Auner

Download or read book Organosilicon Chemistry III written by Norbert Auner and published by John Wiley & Sons. This book was released on 2008-08-29 with total page 742 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organosilicon Chemistry at its best ...((kursiv)) Like its two hugely successful predecessors, the third volume again presents the latest developments in a rapidly developing field of industsrial and academic research. The contributions from approx. 80 internationally renowned experts and researchers in this fascinating part of the rapidly growing field of main group chemistry describe current trends in organosilicon chemistry and provide summaries of the latest (1997!) knowledge in this area. To facilitate access to the ongoing research this volume is split into two parts, each with a comprehensive introduction: Part 1: Fascinating Organosilicon Compounds Part 2: Silicon Based Materials

Organic Chemistry

Author : Jonathan Clayden
Publisher : Oxford University Press
ISBN 13 : 0199270295
Total Pages : 1261 pages
Book Rating : 4.1/5 (992 download)

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Book Synopsis Organic Chemistry by : Jonathan Clayden

Download or read book Organic Chemistry written by Jonathan Clayden and published by Oxford University Press. This book was released on 2012-03-15 with total page 1261 pages. Available in PDF, EPUB and Kindle. Book excerpt: A first- and second-year undergraduate organic chemistry textbook, specifically geared to British and European courses and those offered in better schools in North America, this text emphasises throughout clarity and understanding.

Silicon Based Polymers

Author : François Ganachaud
Publisher : Springer Science & Business Media
ISBN 13 : 1402085281
Total Pages : 285 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Silicon Based Polymers by : François Ganachaud

Download or read book Silicon Based Polymers written by François Ganachaud and published by Springer Science & Business Media. This book was released on 2008-08-09 with total page 285 pages. Available in PDF, EPUB and Kindle. Book excerpt: Silicon Based Polymers presents highlights in advanced research and technological innovations using macromolecular organosilicon compounds and systems, as presented in the 2007 ISPO congress. Silicon-containing materials and polymers are used all over the world and in a variety of industries, domestic products and high technology applications. Among them, silicones are certainly the most well–known, however there are still new properties discovered and preparative processes developed all the time, therefore adding to their potential. Less known, but in preparation for the future, are other silicon containing-polymers which are now close to maturity and in fact some are already available like polysilsesquioxanes and polysilanes. All these silicon based materials can adopt very different structures like chains, dendrimers, hyperbranched and networks, physical and chemical gels. The result is a vast array of materials with applications in various areas such as optics, electronics, ionic electrolytes, liquid crystals, biomaterials, ceramics and concrete, paints and coatings ... all needed to face the environmental, energetical and technological issues of today. Some industrial aspects of the applications of these materials will also be presented.

Hydrosilylation

Author : Bogdan Marciniec
Publisher : Springer Science & Business Media
ISBN 13 : 1402081723
Total Pages : 424 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Hydrosilylation by : Bogdan Marciniec

Download or read book Hydrosilylation written by Bogdan Marciniec and published by Springer Science & Business Media. This book was released on 2008-11-09 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: For fifty years, Hydrosilylation has been one of the most fundamental and elegant methods for the laboratory and industrial synthesis of organosilicon and silicon related compounds. Despite the intensive research and continued interest generated by organosilicon compounds, no comprehensive book incorporating its various aspects has been published this century. The aim of this book is to comprehensively review the advances of hydrosilylation processes since 1990. The survey of the literature published over the last two decades enables the authors to discuss the most recent aspects of hydrosilylation advances (catalytic and synthetic) and to elucidate the reaction mechanism for the given catalyst used and the reaction utilization. New catalytic pathways under optimum conditions necessary for efficient synthesis of organosilicon compounds are presented. This monograph shows the extensive development in the application of hydrosilylation in organic and asymmetric syntheses and in polymer and material science.

Efficient Methods for Preparing Silicon Compounds

Author : Herbert W Roesky
Publisher : Academic Press
ISBN 13 : 0128035684
Total Pages : 540 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Efficient Methods for Preparing Silicon Compounds by : Herbert W Roesky

Download or read book Efficient Methods for Preparing Silicon Compounds written by Herbert W Roesky and published by Academic Press. This book was released on 2016-05-12 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Efficient Methods for Preparing Silicon Compounds is a unique and valuable handbook for chemists and students involved in advanced studies of preparative chemistry in academia and industry. Organized by the various coordination numbers (from two to six) of the central silicon atom of the reported compounds, this book provides researchers with a handy and immediate reference for any compound or properties needed in the area. Edited by a renowned expert in the field, each chapter explores a different type of compound, thoroughly illustrated with useful schemes and supplemented by additional references. Knowledgeable contributors report on a broad range of compounds on which they have published and which are already used on a broad scale or have the potential to be used in the very near future to develop a new field of research or application in silicon chemistry. - Includes contributions and edits from leading experts in the field - Includes detailed chemical schemes and useful references for each preparative method - Organized by the coordination numbers of the central silicon atom for each compound for easy navigation - Serves as a go-to primer for researchers in novel compositions of silicon matter