Preliminary Chemical Analysis and Biological Testing of Materials from the HRI Catalytic Two-stage Liquefaction (CTSL) Process

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Book Synopsis Preliminary Chemical Analysis and Biological Testing of Materials from the HRI Catalytic Two-stage Liquefaction (CTSL) Process by : D. W. Later

Download or read book Preliminary Chemical Analysis and Biological Testing of Materials from the HRI Catalytic Two-stage Liquefaction (CTSL) Process written by D. W. Later and published by . This book was released on 1985 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Preliminary Chemical Analysis and Biological Testing of Materials from the HRI Catalytic Two-stage Liquefaction (CTSL) Process

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Book Synopsis Preliminary Chemical Analysis and Biological Testing of Materials from the HRI Catalytic Two-stage Liquefaction (CTSL) Process by : D. W. Later

Download or read book Preliminary Chemical Analysis and Biological Testing of Materials from the HRI Catalytic Two-stage Liquefaction (CTSL) Process written by D. W. Later and published by . This book was released on 1985 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Energy Research Abstracts

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ISBN 13 :
Total Pages : 1200 pages
Book Rating : 4.3/5 (129 download)

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Download or read book Energy Research Abstracts written by and published by . This book was released on 1986 with total page 1200 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Fossil Energy Update

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Total Pages : 980 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis Fossil Energy Update by :

Download or read book Fossil Energy Update written by and published by . This book was released on 1985 with total page 980 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Biological Testing and Chemical Analysis of Process Materials from an Integrated Two Stage Coal Liquefaction

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Book Synopsis Biological Testing and Chemical Analysis of Process Materials from an Integrated Two Stage Coal Liquefaction by :

Download or read book Biological Testing and Chemical Analysis of Process Materials from an Integrated Two Stage Coal Liquefaction written by and published by . This book was released on 1983 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Samples for chemical characterization and biological testing were obtained from ITSL runs 3LCF7, 3LCF8 and 3LCF9. Chemical analysis of these materials showed that SCT products were composed of fewer compounds than analogous materials from Solvent Refined Coal (SRC) processes. Major components in the SCT materials were three-, four-, five- and six-ring neutral polycyclic aromatic hydrocarbons (PAH). Methyl(C1) and C2 homologs of these compounds were present in relatively low concentrations, compared to their non-alkylated homologs. Organic nitrogen was primarily in the form of tertiary polycyclic aromatic nitrogen heterocycles and carbazoles. Little or no amino PAH (APAH) or cyano PAH were detected in samples taken during normal PDU operations, however, mutagenic APAH were produced during off-normal operation. Microbial mutagenicity appeared to be due mainly to the presence of APAH which were probably formed in the LC finer due to failure of the catalyst to promote deamination following carbon-nitrogen bond scission of nitrogen-containing hydroaromatics. This failure was observed for the off-normal runs where it was likely that the catalyst had been deactivated. Carcinogenic activity of ITSL materials as assessed by (tumors per animal) in the initiation/promotion mouse skin painting assay was slightly reduced for materials produced with good catalyst under normal operation compared to those collected during recycle of the LC Finer feed. Initiation activity of the latter samples did not appear to be significantly different from that of other coal derived materials with comparable boiling ranges. The observed initiation activity was not unexpected, considering analytical data which showed the presence of four-, five- and six-ring PAH in ITSL materials.

Coal Abstracts

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Total Pages : 542 pages
Book Rating : 4.F/5 ( download)

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Download or read book Coal Abstracts written by and published by . This book was released on 1985 with total page 542 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Government reports annual index

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Total Pages : 1384 pages
Book Rating : 4.3/5 (129 download)

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Book Synopsis Government reports annual index by :

Download or read book Government reports annual index written by and published by . This book was released on 199? with total page 1384 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Catalytic Two-Stage Liquefaction (CTSL{trademark}) Process Bench Studies and PDU Scale-up with Sub-bituminous Coal. Final Report

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Total Pages : 622 pages
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Book Synopsis Catalytic Two-Stage Liquefaction (CTSL{trademark}) Process Bench Studies and PDU Scale-up with Sub-bituminous Coal. Final Report by :

Download or read book Catalytic Two-Stage Liquefaction (CTSL{trademark}) Process Bench Studies and PDU Scale-up with Sub-bituminous Coal. Final Report written by and published by . This book was released on 1993 with total page 622 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reported are the details and results of Laboratory and Bench-Scale experiments using sub-bituminous coal conducted at Hydrocarbon Research, Inc., under DOE Contract No. DE-AC22-88PC88818 during the period October 1, 1988 to December 31, 1992. The work described is primarily concerned with testing of the baseline Catalytic Two-Stage Liquefaction (CTSL{trademark}) process with comparisons with other two stage process configurations, catalyst evaluations and unit operations such as solid separation, pretreatments, on-line hydrotreating, and an examination of new concepts. In the overall program, three coals were evaluated, bituminous Illinois No. 6, Burning Star and sub-bituminous Wyoming Black Thunder and New Mexico McKinley Mine seams. The results from a total of 16 bench-scale runs are reported and analyzed in detail. The runs (experiments) concern process variables, variable reactor volumes, catalysts (both supported, dispersed and rejuvenated), coal cleaned by agglomeration, hot slurry treatments, reactor sequence, on-line hydrotreating, dispersed catalyst with pretreatment reactors and CO2/coal effects. The tests involving the Wyoming and New Mexico Coals are reported herein, and the tests involving the Illinois coal are described in Topical Report No. 2. On a laboratory scale, microautoclave tests evaluating coal, start-up oils, catalysts, thermal treatment, CO2 addition and sulfur compound effects were conducted and reported in Topical Report No. 3. Other microautoclave tests are described in the Bench Run sections to which they refer such as: rejuvenated catalyst, coker liquids and cleaned coals. The microautoclave tests conducted for modelling the CTSL{trademark} process are described in the CTSL{trademark} Modelling section of Topical Report No. 3 under this contract.

Close-coupled Catalytic Two-Stage Liquefaction (CTSL{trademark}) Process Bench Studies. Final Report, [October 1, 1988--July 31, 1993].

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Total Pages : 402 pages
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Book Synopsis Close-coupled Catalytic Two-Stage Liquefaction (CTSL{trademark}) Process Bench Studies. Final Report, [October 1, 1988--July 31, 1993]. by :

Download or read book Close-coupled Catalytic Two-Stage Liquefaction (CTSL{trademark}) Process Bench Studies. Final Report, [October 1, 1988--July 31, 1993]. written by and published by . This book was released on 1993 with total page 402 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the final report of a four year and ten month contract starting on October 1, 1988 to July 31, 1993 with the US Department of Energy to study and improve Close-Coupled Catalytic Two-Stage Direct Liquefaction of coal by producing high yields of distillate with improved quality at lower capital and production costs in comparison to existing technologies. Laboratory, Bench and PDU scale studies on sub-bituminous and bituminous coals are summarized and referenced in this volume. Details are presented in the three topical reports of this contract; CTSL Process Bench Studies and PDU Scale-Up with Sub-Bituminous Coal-DE-88818-TOP-1, CTSL Process Bench Studies with Bituminous Coal-DE-88818-TOP-2, and CTSL Process Laboratory Scale Studies, Modelling and Technical Assessment-DE-88818-TOP-3. Results are summarized on experiments and studies covering several process configurations, cleaned coals, solid separation methods, additives and catalysts both dispersed and supported. Laboratory microautoclave scale experiments, economic analysis and modelling studies are also included along with the PDU-Scale-Up of the CTSL processing of sub-bituminous Black Thunder Mine Wyoming coal. During this DOE/HRI effort, high distillate yields were maintained at higher throughput rates while quality was markedly improved using on-line hydrotreating and cleaned coals. Solid separations options of filtration and delayed coking were evaluated on a Bench-Scale with filtration successfully scaled to a PDU demonstration. Directions for future direct coal liquefaction related work are outlined herein based on the results from this and previous programs.

Catalytic Two-Stage Liquefaction (CTSL) Process Bench Studies with Bituminous Coal

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Book Synopsis Catalytic Two-Stage Liquefaction (CTSL) Process Bench Studies with Bituminous Coal by :

Download or read book Catalytic Two-Stage Liquefaction (CTSL) Process Bench Studies with Bituminous Coal written by and published by . This book was released on 1993 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Close-coupled Catalytic Two-Stage Liquefaction (CTSLtrademark) Process Bench Studies

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Book Synopsis Close-coupled Catalytic Two-Stage Liquefaction (CTSLtrademark) Process Bench Studies by :

Download or read book Close-coupled Catalytic Two-Stage Liquefaction (CTSLtrademark) Process Bench Studies written by and published by . This book was released on 1993 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Catalytic Two-Stage Liquefaction (CTSLtrademark) Process: Laboratory Scale Studies Modelling and Technical Assessment, Final Topical Report

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Book Synopsis Catalytic Two-Stage Liquefaction (CTSLtrademark) Process: Laboratory Scale Studies Modelling and Technical Assessment, Final Topical Report by :

Download or read book Catalytic Two-Stage Liquefaction (CTSLtrademark) Process: Laboratory Scale Studies Modelling and Technical Assessment, Final Topical Report written by and published by . This book was released on 1993 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Government Reports Annual Index: Keyword A-L

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ISBN 13 :
Total Pages : 1164 pages
Book Rating : 4.:/5 (319 download)

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Book Synopsis Government Reports Annual Index: Keyword A-L by :

Download or read book Government Reports Annual Index: Keyword A-L written by and published by . This book was released on 1986 with total page 1164 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Catalytic Two-Stage Liquefaction (CTSL) Process Bench Studies with Bituminous Coal. Final Report, [October 1, 1988--December 31, 1992].

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Total Pages : 223 pages
Book Rating : 4.:/5 (685 download)

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Book Synopsis Catalytic Two-Stage Liquefaction (CTSL) Process Bench Studies with Bituminous Coal. Final Report, [October 1, 1988--December 31, 1992]. by :

Download or read book Catalytic Two-Stage Liquefaction (CTSL) Process Bench Studies with Bituminous Coal. Final Report, [October 1, 1988--December 31, 1992]. written by and published by . This book was released on 1993 with total page 223 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reported herein are the details and results of Laboratory and Bench-Scale experiments using bituminous coal concluded at Hydrocarbon Research, Inc., under DOE contract during the period October 1, 1988 to December 31, 1992. The work described is primarily concerned with the application of coal cleaning methods and solids separation methods to the Catalytic Two-Stage Liquefaction (CTSL) Process. Additionally a predispersed catalyst was evaluated in a thermal/catalytic configuration, and an alternative nickel molybdenum catalyst was evaluated for the CTSL process. Three coals were evaluated in this program: Bituminous Illinois No. 6 Burning Star and Sub-bituminous Wyoming Black Thunder and New Mexico McKinley Mine seams. The results from a total of 16 bench-scale runs are reported and analyzed in detail. The tests involving the Illinois coal are reported herein, and the tests involving the Wyoming and New Mexico coals are described in Topical Report No. 1. On the laboratory scale, microautoclave tests evaluating coal, start-up oils, catalysts, thermal treatment, CO2 addition and sulfur compound effects are reported in Topical Report No. 3. Other microautoclave tests, such as tests on rejuvenated catalyst, coker liquids, and cleaned coals, are described in the Bench Run sections to which they refer. The microautoclave tests conducted for modelling the CTSL process are described in the CTSL Modelling section of Topical Report No. 3 under this contract.

Chemical Analysis and Biological Testing of Materials from the EDS Coal Liquefaction Process

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Download or read book Chemical Analysis and Biological Testing of Materials from the EDS Coal Liquefaction Process written by and published by . This book was released on 1984 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Representative process materials were obtained from the EDS pilot plant for chemical and biological analyses. These materials were characterized for biological activity and chemical composition using a microbial mutagenicity assay and chromatographic and mass spectrometric analytical techniques. The two highest boiling distillation cuts, as well as process solvent (PS) obtained from the bottoms recycle mode operation, were tested for initiation of mouse skin tumorigenicity. All three materials were active; the crude 800/sup 0 +/F cut was substantially more potent than the crude bottoms recycle PS or 750 to 800°F distillate cut. Results from chemical analyses showed the EDS materials, in general, to be more highly alkylated and have higher hydroaromatic content than analogous SRC II process materials (no in-line process hydrogenation) used for comparison. In the microbial mutagenicity assays the N-PAC fractions showed greater activity than did the aliphatic hydrocarbon, hydroxy-PAH, or PAH fractions, although mutagenicity was detected in certain PAH fractions by a modified version of the standard microbial mutagenicity assay. Mutagenic activities for the EDS materials were lower, overall, than those for the corresponding materials from the SRC II process. The EDS materials produced under different operational modes had distinguishable differences in both their chemical constituency and biological activity. The primary differences between the EDS materials studied here and their SRC II counterparts used for comparison are most likely attributable to the incorporation of catalytic hydrogenation in the EDS process. 27 references, 28 figures, 27 tables.

Catalytic Two-Stage Liquefaction (CTSL[trademark] Process: Laboratory Scale Studies Modelling and Technical Assessment. Final Report, [October 1, 1988--June 30, 1993].

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Book Synopsis Catalytic Two-Stage Liquefaction (CTSL[trademark] Process: Laboratory Scale Studies Modelling and Technical Assessment. Final Report, [October 1, 1988--June 30, 1993]. by :

Download or read book Catalytic Two-Stage Liquefaction (CTSL[trademark] Process: Laboratory Scale Studies Modelling and Technical Assessment. Final Report, [October 1, 1988--June 30, 1993]. written by and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Reported herein are the details and results of Laboratory-Scale experiments using sub-bituminous and bituminous coal concluded at Hydrocarbon Research, Inc., under DOE Contract No. AC22-88PCB8818 during the period October 1, 1988 to June 30, 1993. The work described in this report is primarily concerned with tests on a Laboratory Scale primarily using microautoclaves. Experiments were conducted evaluating coal, solvents, start-up oils, catalysts, thermal treatments, C0[sub 2] addition and sulfur compound effects. Other microautoclave tests are included in the companion topical reports for this contract, DE-88818-TOP-01 & 02 on Sub-Bituminous and Bituminous Bench-Scale and PDU activities. In addition to the Laboratory Scale Studies, kinetic data and modelling results from Bench-Scale and Microautoclave tests are interpreted and presented along with some economic updates and sensitivity studies.

Government Reports Announcements & Index

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ISBN 13 :
Total Pages : 1176 pages
Book Rating : 4.:/5 (334 download)

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Download or read book Government Reports Announcements & Index written by and published by . This book was released on 1986-07 with total page 1176 pages. Available in PDF, EPUB and Kindle. Book excerpt: