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Transition Metal Catalyzed Reactions Of Carbon And Heteroatom Bridge Bicyclic Alkenes
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Author :University of Guelph. Department of Chemistry and Biochemistry Publisher : ISBN 13 :9780494365366 Total Pages :147 pages Book Rating :4.3/5 (653 download)
Book Synopsis Transition Metal-catalyzed Reactions of Carbon and Heteroatom Bridge Bicyclic Alkenes by : University of Guelph. Department of Chemistry and Biochemistry
Download or read book Transition Metal-catalyzed Reactions of Carbon and Heteroatom Bridge Bicyclic Alkenes written by University of Guelph. Department of Chemistry and Biochemistry and published by . This book was released on 2007 with total page 147 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Catalyzed Carbon-Heteroatom Bond Formation by : Andrei K. Yudin
Download or read book Catalyzed Carbon-Heteroatom Bond Formation written by Andrei K. Yudin and published by John Wiley & Sons. This book was released on 2010-12-01 with total page 541 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by an experienced editor widely acclaimed within the scientific community, this book covers everything fromo9xygen to nitrogen functionalities. From the contents: Palladium-Catalyzed Syntheses of Five-Member Saturated Heterocyclic and of Aromatic Heterodynes Palladium-Catalysis for Oxidative 1, 2-Difunctionalization of Alkenes Rhodium-Catalyzed Amination of C-H-Bonds Carbon-Heteroatom Bond Formation by RH(I)-Catalyzed Ring-Opening Reactions Transition Metal-Catalyzed Synthesis of Lactones and of Monocyclic and Fused Five-Membered Aromatic heterocycles the Formation of Carbon-Sulfur and Carbon-Selenium bonds by Substitution and Addition reactions catalyzed by Transition Metal Complexes New Reactions of Copper Acetylides Gold Catalyzed Addition of Nitrogen, Sulfur and Oxygen Nucleophiles to C-C Multiple Bonds. The result is an indispensable source of information for the Strategic Planning of the Synthetic routes for organic, catalytic and medicinal chemists, as well as chemists in industry.
Book Synopsis Heterocycles from Transition Metal Catalysis by : András Kotschy
Download or read book Heterocycles from Transition Metal Catalysis written by András Kotschy and published by Springer Science & Business Media. This book was released on 2005-09-30 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Heterocycles from Transition Metal Catalysis: Formation and Functionalization" provides a concise summary of the prominent role of late transition metal (palladium, nickel, copper) catalysed processes in the synthesis and functionalization of heterocyclic systems. It gives an introduction to catalytic transformations, an overview of the most important reaction types, and presents synthetically useful catalytic processes classified by the target system and the type of transformation. The book provides a representative selection of transition metal catalysed reactions transformations that are relevant in heterocyclic chemistry. In this way, the authors present a useful resource for members of the academic community looking for a textbook as well as industrial chemists in search of a reference book. This book will be an invaluable resource for synthetic chemists, medicinal chemists, and those more generally interested in applied catalysis.
Book Synopsis Cleavage of Carbon-Carbon Single Bonds by Transition Metals by : Masahiro Murakami
Download or read book Cleavage of Carbon-Carbon Single Bonds by Transition Metals written by Masahiro Murakami and published by John Wiley & Sons. This book was released on 2015-12-21 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Edited by leading experts and pioneers in the field, this is the first up-to-date book on this hot topic. The authors provide synthetic chemists with different methods to activate carbon-carbon sigma bonds in organic molecules promoted by transition metal complexes. They explain the basic principles and strategies for carbon-carbon bond cleavage and highlight recently developed synthetic protocols based on this methodology. In so doing, they cover cleavage of C-C bonds in strained molecules, reactions involving elimination of carbon dioxide and ketones, reactions via retroallylation, and cleavage of C-C bonds of ketones and nitriles. The result is an excellent information source for researchers in academia and industry working in the field of synthetic organic chemistry, while equally serving as supplementary reading for advanced courses in organometallic chemistry and catalysis.
Book Synopsis Homogeneous Transition Metal Catalyzed Reactions by : William R. Moser
Download or read book Homogeneous Transition Metal Catalyzed Reactions written by William R. Moser and published by . This book was released on 1992 with total page 650 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Earth-Abundant Transition Metal Catalyzed Reactions by :
Download or read book Earth-Abundant Transition Metal Catalyzed Reactions written by and published by Elsevier. This book was released on 2024-09-09 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: Earth-Abundant Transition Metal Catalyzed Reactions, Volume 74 in the Advances in Catalysis series, highlights new advances in the field, with this new volume presenting interesting chapters. Each chapter is written by an international board of authors. Chapters in this new release include in Chiral Iron Complexes for Asymmetric Catalysis, Recent advances in Ni-catalyzed Functionalization of Strong C-O and C-H Bonds, Low-valent Molecular Cobalt Complexes for Reductive Chemistry, Iron-catalyzed group-transfer reactions with hypervalent iodine reagents, and Iron Porphyrins for Mediating Atom Efficient C–C Bond Formations. - Provides the authority and expertise of leading contributors from an international board of authors - Presents the latest release in Advances in Catalysis serials - Updated release includes the latest information in the field
Book Synopsis Rhodium-Catalyzed Asymmetric Ring Opening of Oxabicyclic Alkenes and Palladium-Catalyzed Carbon-Halogen Bond Forming Reactions by : Christine Le
Download or read book Rhodium-Catalyzed Asymmetric Ring Opening of Oxabicyclic Alkenes and Palladium-Catalyzed Carbon-Halogen Bond Forming Reactions written by Christine Le and published by . This book was released on 2017 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atom-economical addition reactions to unsaturated carbonâ carbon bonds represent a powerful class of transformations in organic chemistry, since a great deal of molecular complexity can be generated from simple starting materials. Highly regio- and stereoselective processes have been made possible through the use of transition metal catalysts, alongside specialized ancillary ligands and in combination with rational substrate design. One area of research in the Lautens group involves the transition metal catalyzed asymmetric ring opening (ARO) of strained alkenes, which provides access to enantioenriched carbocyclic frameworks. Although a variety of coupling partners have been applied in this transformation, the use of soft carbon nucleophiles remains limited in scope. The first chapter describes a rhodium(I)-catalyzed ARO of meso-oxabicyclic alkenes using silyl enol ethers and ketene acetals. In analogy to the Mukaiyama aldol reaction, a novel silyl migration occurs, enabling an in situ protection of the chiral alcohols obtained. Developing new reactivity from Heck-type carbopalladation processes represents another research interest in the Lautens group. Oxidative addition into a carbonâ halogen bond constitutes the first step of nearly all palladium(0)-catalyzed cross-couplings. Conversely, reductive elimination from palladium(II) to yield an organohalide product represents a rare and often thermodynamically unfavoured process. The next two chapters address challenges in the synthesis of vinyl halides using palladium(0) catalysis via the intramolecular carbohalogenation and chlorocarbamoylation of alkynes. During our investigations, we discovered that the steric bulk of both the substrate and the phosphine ligand play an important role in promoting the desired reactivity. Mechanistic insight has been gained through combined experimental and computational studies, which implicate a palladium-catalyzed stereoisomerization in both of these transformations. Under certain conditions, we demonstrate that highly stereoselective trans-additions to alkynes can be achieved, which illustrates that specific substrate/catalyst combinations can override the inherent cis-selectivity in carbometallations. In the fourth chapter, a formal palladium(II)-catalyzed alkyne chlorocarbamoylation reaction is presented, which provides access to medicinally relevant methylene oxindole scaffolds. In contrast to the analogous protocol using palladium(0) catalysts, the reaction is initiated by an alkyne chloropalladation step, followed by intramolecular cross-coupling with a carbamoyl chloride. Experimental and computational studies provide insight into the mechanism of this reaction.
Book Synopsis N-Heterocyclic Carbenes in Transition Metal Catalysis by : Frank Glorius
Download or read book N-Heterocyclic Carbenes in Transition Metal Catalysis written by Frank Glorius and published by Springer. This book was released on 2007-02-05 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes.
Book Synopsis Transition Metal Catalyzed Carbonylative Synthesis of Heterocycles by : Xiao-Feng Wu
Download or read book Transition Metal Catalyzed Carbonylative Synthesis of Heterocycles written by Xiao-Feng Wu and published by Springer. This book was released on 2015-12-14 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field. All chapters from Topics in Heterocyclic Chemistry are published Online First with an individual DOI. In references, Topics in Heterocyclic Chemistry is abbreviated as Top Heterocycl Chem and cited as a journal.
Book Synopsis Part I, Transition Metal-catalyzed Reactions of Carbon Tetrachloride with Alkenes ; Part II, Generation of a Perphosphate Intermediate in the Decomposition of Triphenyl Phosphite Ozonide by : Douglas S. McBain
Download or read book Part I, Transition Metal-catalyzed Reactions of Carbon Tetrachloride with Alkenes ; Part II, Generation of a Perphosphate Intermediate in the Decomposition of Triphenyl Phosphite Ozonide written by Douglas S. McBain and published by . This book was released on 1984 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Transition Metal-Catalyzed Carbene Transformations by : Jianbo Wang
Download or read book Transition Metal-Catalyzed Carbene Transformations written by Jianbo Wang and published by John Wiley & Sons. This book was released on 2022-05-16 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents an up-to-date overview of the rapidly growing field of carbene transformations Carbene transformations have had an enormous impact on catalysis and organometallic chemistry. With the growth of transition metal-catalyzed carbene transformations in recent decades, carbene transformations are today an important compound class in organic synthesis as well as in the pharmaceutical and agrochemical industries. Edited by leading experts in the field, Transition Metal-Catalyzed Carbene Transformations is a thorough summary of the most recent advances in the rapidly expanding research area. This authoritative volume covers different reaction types such as ring forming reactions and rearrangement reactions, details their conditions and properties, and provides readers with accurate information on a wide range of carbene reactions. Twelve in-depth chapters address topics including carbene C-H bond insertion in alkane functionalization, the application of engineered enzymes in asymmetric carbene transfer, progress in transition-metal-catalyzed cross-coupling using carbene precursors, and more. Throughout the text, the authors highlight novel catalytic systems, transformations, and applications of transition-metal-catalyzed carbene transfer. Highlights the dynamic nature of the field of transition-metal-catalyzed carbene transformations Summarizes the catalytic radical approach for selective carbene cyclopropanation, high enantioselectivity in X-H insertions, and bio-inspired carbene transformations Introduces chiral N,N'-dioxide and chiral guanidine-based catalysts and different transformations with gold catalysis Discusses approaches in cycloaddition reactions with metal carbenes and polymerization with carbene transformations Outlines multicomponent reactions through gem-difunctionalization and transition-metal-catalyzed cross-coupling using carbene precursors Transition Metal-Catalyzed Carbene Transformations is essential reading for all chemists involved in organometallics, including organic and inorganic chemists, catalytic chemists, and chemists working in industry.
Book Synopsis Transition Metal Catalysed Reactions by : International Union of Pure and Applied Chemistry
Download or read book Transition Metal Catalysed Reactions written by International Union of Pure and Applied Chemistry and published by . This book was released on 1999 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Oxidative Cross-Coupling Reactions by : Aiwen Lei
Download or read book Oxidative Cross-Coupling Reactions written by Aiwen Lei and published by John Wiley & Sons. This book was released on 2016-08-12 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first handbook on this emerging field provides a comprehensive overview of transition metal-catalyzed coupling reactions in the presence of an oxidant. Following an introduction to the general concept and mechanism of this reaction class, the team of authors presents chapters on C-C cross-coupling reactions using organometallic partners, C-Heteroatom bond forming reactions via oxidative couplings, and C-H couplings via C-H activation. The text also covers such groundbreaking topics as recent achievements in the fields of C-C and C-X bond formation reactions as well as C-H activation involving oxidative couplings. With its novel and concise approach towards important building blocks in organic chemistry and its focus on synthetic applications, this handbook is of great interest to all synthetic chemists in academia and industry alike.
Book Synopsis Transition Metal Catalyzed Ring-opening Reactions of Unsymmetrical Oxabicyclic Alkenes by : Raheem Mohammed Abdul
Download or read book Transition Metal Catalyzed Ring-opening Reactions of Unsymmetrical Oxabicyclic Alkenes written by Raheem Mohammed Abdul and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Transition Metal-catalyzed Carbon-carbon/Carbon-heteroatom Bond Formation Reactions Utilizing Strained Ring Systems by :
Download or read book Transition Metal-catalyzed Carbon-carbon/Carbon-heteroatom Bond Formation Reactions Utilizing Strained Ring Systems written by and published by . This book was released on 2002 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: PhD.
Book Synopsis Transition Metals in the Synthesis of Complex Organic Molecules by : Louis S. Hegedus
Download or read book Transition Metals in the Synthesis of Complex Organic Molecules written by Louis S. Hegedus and published by . This book was released on 2010 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt: The third edition of Transition Metals in the Synthesis of Complex Organic Molecules is a comprehensive revision and significant expansion of the second edition. The clear and systematic approach to the formation, manipulation, and reactivity of organometallic complexes has been maintained. The book is divided into 10 chapters starting with general formalisms, electron counting, and basic principles of organometallic reaction mechanisms. The organic chemistry of transition metals is then presented by class of metal complex, with many examples of applications in the synthesis of complex natural products and pharmaceuticals. The book is ideal for advanced undergraduate and graduate students as well as all practicing synthetic organic chemists. It is written for organic chemists and offers an easy entry into the field of organotransition metal chemistry without requiring a background in inorganic chemistry.
Book Synopsis Homogeneous Transition-metal Catalysis by : Christopher Masters
Download or read book Homogeneous Transition-metal Catalysis written by Christopher Masters and published by Springer. This book was released on 1981 with total page 298 pages. Available in PDF, EPUB and Kindle. Book excerpt: Soluble catalysts are used extensively in many branches of chemistry and are indeed a vital constituent of many natural processes. They find wide application throughout the chemical industry where they assist in the production of several million tonnes of chemicals each year. Since homogeneous systems, especially those incorporating transition metals, often function effectively under milder conditions than their heterogeneous counterparts, they are becoming increasingly important at a time when the chemical industry in particular, and society in general, is seeking ways of conserving energy and of making the best possible use of available resources. My principal objective in· writing this book is to engender sufficient enthusiasm for, and knowledge of, the subject in the reader that he or she will be encouraged to begin, or continue, to make their own contribution to advancing our knowledge of homogeneous catalysis. After attempting to acquaint the reader with some of the ground rules I have tried to describe the .present scope, and the future potential, of this fascinating field of chemistry by drawing both on academic and on industrial data sources. This approach stems from a personal conviction that future progress could be considerably hastened by a more meaningful dialogue between chemists working both in industrial and in academic research institutions. Wherever possible, examples of the commercial application of homogeneous catalyst systems have been included and no attempt has been made in any way to disguise the many unresolved questions and exciting challenges which still pervade this rapidly developing area.
