Theoretical Studies of Chemical Bonding in Early Transition Metal Clusters, Dinuclear Complexes and an Organometallic Polymer

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ISBN 13 :
Total Pages : 228 pages
Book Rating : 4.:/5 (64 download)

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Book Synopsis Theoretical Studies of Chemical Bonding in Early Transition Metal Clusters, Dinuclear Complexes and an Organometallic Polymer by : Kimberly Anne Lawler

Download or read book Theoretical Studies of Chemical Bonding in Early Transition Metal Clusters, Dinuclear Complexes and an Organometallic Polymer written by Kimberly Anne Lawler and published by . This book was released on 1994 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Clusters – Contemporary Insight in Structure and Bonding

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Publisher : Springer
ISBN 13 : 3319522965
Total Pages : 386 pages
Book Rating : 4.3/5 (195 download)

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Book Synopsis Clusters – Contemporary Insight in Structure and Bonding by : Stefanie Dehnen

Download or read book Clusters – Contemporary Insight in Structure and Bonding written by Stefanie Dehnen and published by Springer. This book was released on 2017-03-23 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience.

Metal-Metal Bonds and Clusters in Chemistry and Catalysis

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Publisher : Springer Science & Business Media
ISBN 13 : 1489924922
Total Pages : 344 pages
Book Rating : 4.4/5 (899 download)

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Book Synopsis Metal-Metal Bonds and Clusters in Chemistry and Catalysis by : John P. Fackler Jr.

Download or read book Metal-Metal Bonds and Clusters in Chemistry and Catalysis written by John P. Fackler Jr. and published by Springer Science & Business Media. This book was released on 2013-11-22 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book contains a series of papers and abstracts from the 7th Industry-University Cooperative Chemistry Program symposium held in the spring of 1989 at Texas A&M University. The symposium was larger than previous IUCCP symposia since it also celebrated the 25 years that had elapsed since the initial discovery by F. A. Cotton and his co-workers of the existence of metal-metal quadruple bonds. Cotton's discovery demonstrated that multiple bonding in inorganic systems is not governed by the same constraints observed in organic chemistry regarding s and p orbital involvement. The d orbitals are involved in the multiple bonding description. The quadruple bond involves considerable d orbital overlap between adjacent metal centers. Part I of this series of papers focuses upon the impact of this discovery and describes further contributions to the development of the field. Multiple metal-metal bonding now is known to permeate broad areas of transition metal chemistry. The understanding of metal-metal bonding that developed as a result of the discovery of multiple metal-metal bonding awakened a new chemistry involving metal clusters. Clusters were defined by Cotton to be species containing metal-metal bonding. Clusters in catalysis therefore seemed a logical grouping of papers in this symposium. Clusters play an every increasing role in the control of chemical reactions. Part II of this book describes some of the interesting new developments in this field. In Part III the papers examine the role clusters play in describing and understanding solid state materials.

Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces

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Publisher : Springer Science & Business Media
ISBN 13 : 9401128227
Total Pages : 428 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces by : Dennis R. Salahub

Download or read book Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces written by Dennis R. Salahub and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-ligand interactions are currently being studied in different fields, from a variety of points of view, and recent progress has been substantial. Whole new classes of compounds and reactions have been found; an arsenal of physical methods has been developed; mechanistic detail can be ascertained to an increasingly minute degree; and the theory is being developed to handle systems of ever-growing complexity. As usual, such multidisciplinarity leads to great opportunities, coupled with great problems of communication between specialists. It is in its promotion of interactions across these fields that Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces makes its timely contribution: the tools, both theoretical and experimental, are highly developed, and fundamental questions remain unanswered. The most fundamental of these concerns the nature of the microscopic interactions between metal atoms (clusters, surfaces) and ligands (atoms, molecules, absorbates, reagents, products) and the changes in these interactions during physical and chemical transformation. In Metal-Ligand Interactions, leading experts discuss the following, vital aspects: ab initio theory, semi-empirical theory, density functional theory, complexes and clusters, surfaces, and catalysis.

Early Transition Metal Clusters with pi-Donor Ligands

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Publisher : Wiley-VCH
ISBN 13 : 9780471186069
Total Pages : 0 pages
Book Rating : 4.1/5 (86 download)

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Book Synopsis Early Transition Metal Clusters with pi-Donor Ligands by : M. H. Chisholm

Download or read book Early Transition Metal Clusters with pi-Donor Ligands written by M. H. Chisholm and published by Wiley-VCH. This book was released on 1996-12-17 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The discovery and evolution of oranometallic cluster chemistry is a major event in the development of inorganic chemistry. This is the second volume in the series 'The Chemistry of Metal Clusters' edited by Du Shriver, Herb Kaesz, and Richard Adams. This volume focuses on the chemistry of the early transition elements in their lower and middle oxidation states, i.e., halide, sulfide, oxide, phosphate, alkoxide, and related o-donor ligands. The key feature linking all these complexes in metal-metal bonding is the presence of pi-donor ligands.

Metal Dihydrogen and σ-Bond Complexes

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Publisher : Springer Science & Business Media
ISBN 13 : 0306475979
Total Pages : 479 pages
Book Rating : 4.3/5 (64 download)

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Book Synopsis Metal Dihydrogen and σ-Bond Complexes by : Gregory J. Kubas

Download or read book Metal Dihydrogen and σ-Bond Complexes written by Gregory J. Kubas and published by Springer Science & Business Media. This book was released on 2006-04-18 with total page 479 pages. Available in PDF, EPUB and Kindle. Book excerpt: According to R.H. Crabtree, Metal Dihydrogen and sigma-Bond Complexes is described as `the definitive account of twentieth-century work in the area of sigma complexation'. It covers not only Kubas' discovery of dihydrogen coordination and the study of its structure and general properties but also discusses both the theoretical beliefs and experimental results of bonding and activation of dihydrogen on metal centers and the coordination and activation of C-H, B-H, X-H, and X-Y bonds, giving an overview of `one of the hottest areas in chemistry'.

Rings, Clusters, and Polymers of Main Group and Transition Elements

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Publisher : Elsevier Publishing Company
ISBN 13 :
Total Pages : 568 pages
Book Rating : 4.:/5 (44 download)

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Book Synopsis Rings, Clusters, and Polymers of Main Group and Transition Elements by : H. W. Roesky

Download or read book Rings, Clusters, and Polymers of Main Group and Transition Elements written by H. W. Roesky and published by Elsevier Publishing Company. This book was released on 1989 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of rings, clusters and polymers is becoming an important branch of inorganic and organometallic chemistry. Although inorganic rings have been known for more than 150 years, they have only been structurally characterized within the last fifty years. Inorganic and organometallic clusters and polymers have recently become the subject of intense interest and study because of their unusual properties and their potential for applications in the areas of catalysis, electronics and ceramics. Transition metal clusters have been examined as models for heterogeneous catalysts. Both rings and clusters might function as potential building blocks for extended solid state systems. In comparison with organic polymers, however, general and versatile methods for the synthesis of inorganic and organometallic polymers are not readily available. In particular, the preparation of polymers containing transition metal atoms in the polymer backbone is a challenge to inorganic chemistry. This book describes the rapid development which has taken place in this field.

Molecular Metal-Metal Bonds

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Publisher : John Wiley & Sons
ISBN 13 : 3527673385
Total Pages : 592 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Molecular Metal-Metal Bonds by : Stephen T. Liddle

Download or read book Molecular Metal-Metal Bonds written by Stephen T. Liddle and published by John Wiley & Sons. This book was released on 2016-03-16 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: Systematically covering all the latest developments in the field, this is a comprehensive and handy introduction to metal-metal bonding. The chapters follow a uniform, coherent structure for a clear overview, allowing readers easy access to the information. The text covers such topics as synthesis, properties, structures, notable features, reactivity and examples of applications of the most important compounds in each group with metal-metal bonding throughout the periodic table. With its general remarks at the beginning of each chapter, this is a must-have reference for all molecular inorganic chemists, including PhD students and postdocs, as well as more experienced researchers.

Cluster Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 3642859267
Total Pages : 310 pages
Book Rating : 4.6/5 (428 download)

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Book Synopsis Cluster Chemistry by : Guillermo Gonzalez-Moraga

Download or read book Cluster Chemistry written by Guillermo Gonzalez-Moraga and published by Springer Science & Business Media. This book was released on 2013-11-09 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.

The Chemistry of Metal Cluster Complexes

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Publisher : Wiley-VCH
ISBN 13 :
Total Pages : 456 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis The Chemistry of Metal Cluster Complexes by : Duward F. Shriver

Download or read book The Chemistry of Metal Cluster Complexes written by Duward F. Shriver and published by Wiley-VCH. This book was released on 1990 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: Seven chapters summarize the current status of organometallic cluster chemistry from the viewpoints of synthesis, structure and bonding, ligand substitution reactions, ligand transformations, polyhedral rearrangement, cluster fragmentation reactions, and metal clusters as homogeneous catalysts. An eighth provides an extensive bibliography of reviews for the period from 1965 to 1988. Annotation copyrighted by Book News, Inc., Portland, OR

Metal-Ligand Interactions

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Publisher : Springer
ISBN 13 :
Total Pages : 574 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Metal-Ligand Interactions by : N. Russo

Download or read book Metal-Ligand Interactions written by N. Russo and published by Springer. This book was released on 1996 with total page 574 pages. Available in PDF, EPUB and Kindle. Book excerpt: A sequel to the June 1991 NATO ASI on "Metal-Ligand Interactions: From Atoms to Clusters to Surfaces," the present September 1994 ASI focused more on reactivity and its structural dependence. Hence, it emphasized experimental determinations of structure and dynamics supported by the theoretical and computational approaches needed to establish the concepts and guide the experiments. These proceedings are based on the lectures presented in the areas of clusters, inorganic complexes, surfaces, catalysis, ab initio theory, density functional theory, semiempirical methods, and dynamics. Annotation copyright by Book News, Inc., Portland, OR

The Synergy Between Dynamics and Reactivity at Clusters and Surfaces

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Publisher : Springer Science & Business Media
ISBN 13 : 9401101337
Total Pages : 365 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis The Synergy Between Dynamics and Reactivity at Clusters and Surfaces by : L.J. Farrugia

Download or read book The Synergy Between Dynamics and Reactivity at Clusters and Surfaces written by L.J. Farrugia and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 365 pages. Available in PDF, EPUB and Kindle. Book excerpt: The analogy between the chemistry of molecular transition metal clusters and the processes of chemisorption and catalysis at metal surfaces (the Cluster Surface analogy) has for a number of years provided an interplay between experimental and theoretical inorganic and physical chemists. This collaborative approach has born fruit in the use of well defined modes of metal-ligand bonding in discrete molecular clusters, models for metal-ligand binding on surfaces. Some of the key topics discussed in The Synergy between Dynamics and Reactivity at Clusters and Surfaces are: (1) Mechanisms of the fluxional behaviour in clusters in the liquid phase and the connections with diffusion processes on extended surfaces. The role of metal-metal bond breaking in diffusion. (2) Analogies in the structure of chemisorbed species and related ligands on metallic clusters. (3) Analogies between benzene surface chemistry on extended metal surfaces and on metal surfaces in molecular cluster compounds with particular reference to structural distortions. (4) The role of mobile precursors for dissociation of chemisorption on extended metals and on clusters. Are there analogies in the ligand attachment during cluster compound synthesis? (5) The role of defect sites on metal surfaces in catalyzing chemical reactions and the connection to the special bonding properties of sites on metal clusters having lowest metal-metal coordination. (6) The size of metal clusters needed to mimic surface phenomena on bulk metal surfaces. Different sites needed for different phenomena.

Metal-Metal Bonding

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Publisher : Springer
ISBN 13 : 3642052436
Total Pages : 316 pages
Book Rating : 4.6/5 (42 download)

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Book Synopsis Metal-Metal Bonding by : Gerard Parkin

Download or read book Metal-Metal Bonding written by Gerard Parkin and published by Springer. This book was released on 2010-03-10 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: John Berry: Metal-Metal Bonds in Chains of Three or More Metal Atoms: From Homometallic to Heterometallic Chains.- Malcolm Chisholm: Electronically Coupled MM Quadruple Bonded Complexes of Molybdenum and Tungsten.- Philip Power: Transition Metal Complexes Stabilized by Bulky Terphenyl Ligands: Applications to Metal–Metal Bonded Compounds.- Gerard Parkin: Metal–Metal Bonding in Bridging Hydride and Alkyl Compounds.- Roland Fischer and Gernot Frenking: Structure and Bonding of Metal Rich Coordination Compounds Containing Low Valent Ga(I) and Zn(I) Ligands.- Mike Hill: Homocatenation of Metal and Metalloid Main Group Elements.- Constandinos A. Tsipis: Aromaticity/Antiaromaticity in "Bare" and ‘‘Ligand-Stabilized’’ Rings of Metal Atoms.- Alexander Boldyrev: All-Transition Metal Aromaticity and Antiaromaticity.

Theoretical Studies of Ligand-bridged Transition-metal Dinuclear Organometallic Compounds and the Synthesis and Structure Determination of Bis(n-cyclopentadienyl)bis(benzoato)titanium(IV)

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Publisher :
ISBN 13 :
Total Pages : 524 pages
Book Rating : 4.E/5 ( download)

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Book Synopsis Theoretical Studies of Ligand-bridged Transition-metal Dinuclear Organometallic Compounds and the Synthesis and Structure Determination of Bis(n-cyclopentadienyl)bis(benzoato)titanium(IV) by : David Maurice Hoffman

Download or read book Theoretical Studies of Ligand-bridged Transition-metal Dinuclear Organometallic Compounds and the Synthesis and Structure Determination of Bis(n-cyclopentadienyl)bis(benzoato)titanium(IV) written by David Maurice Hoffman and published by . This book was released on 1982 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Theoretical Studies of the Bonding in Some Organotransition Metal Fragments and Clusters

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Publisher :
ISBN 13 :
Total Pages : 480 pages
Book Rating : 4.:/5 (89 download)

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Book Synopsis Theoretical Studies of the Bonding in Some Organotransition Metal Fragments and Clusters by : Albert Brownlee Rives

Download or read book Theoretical Studies of the Bonding in Some Organotransition Metal Fragments and Clusters written by Albert Brownlee Rives and published by . This book was released on 1981 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt:

C-X Bond Formation

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Publisher : Springer
ISBN 13 : 3642120733
Total Pages : 198 pages
Book Rating : 4.6/5 (421 download)

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Book Synopsis C-X Bond Formation by : Arkadi Vigalok

Download or read book C-X Bond Formation written by Arkadi Vigalok and published by Springer. This book was released on 2010-06-30 with total page 198 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contents: Kilian Muñiz: Transition Metal Catalyzed Electrophilic Halogenation of C-H bonds in alpha-Position to Carbonyl Groups; Arkadi Vigalok * and Ariela W Kaspi: Late Transition Metal-Mediated Formation of Carbon-Halogen Bonds; Paul Bichler and Jennifer A. Love*: Organometallic Approaches to Carbon-Sulfur Bond Formation; David S. Glueck: Recent Advances in Metal-Catalyzed C-P Bond Formation; Andrei N. Vedernikov: C-O Reductive Elimination from High Valent Pt and Pd Centers; Lukas Hintermann: Recent Developments in Metal-Catalyzed Additions of Oxygen Nucleophiles to Alkenes and Alkynes; Moris S. Eisen: Catalytic C-N, C-O and C-S bond formation promoted by organoactinide complexes.

American Doctoral Dissertations

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Publisher :
ISBN 13 :
Total Pages : 872 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis American Doctoral Dissertations by :

Download or read book American Doctoral Dissertations written by and published by . This book was released on 1996 with total page 872 pages. Available in PDF, EPUB and Kindle. Book excerpt: