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Metal Metal Bonds And Clusters In Chemistry And Catalysis
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Book Synopsis Metal-Metal Bonds and Clusters in Chemistry and Catalysis by : John P. Fackler Jr.
Download or read book Metal-Metal Bonds and Clusters in Chemistry and Catalysis written by John P. Fackler Jr. and published by Springer Science & Business Media. This book was released on 2013-11-22 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book contains a series of papers and abstracts from the 7th Industry-University Cooperative Chemistry Program symposium held in the spring of 1989 at Texas A&M University. The symposium was larger than previous IUCCP symposia since it also celebrated the 25 years that had elapsed since the initial discovery by F. A. Cotton and his co-workers of the existence of metal-metal quadruple bonds. Cotton's discovery demonstrated that multiple bonding in inorganic systems is not governed by the same constraints observed in organic chemistry regarding s and p orbital involvement. The d orbitals are involved in the multiple bonding description. The quadruple bond involves considerable d orbital overlap between adjacent metal centers. Part I of this series of papers focuses upon the impact of this discovery and describes further contributions to the development of the field. Multiple metal-metal bonding now is known to permeate broad areas of transition metal chemistry. The understanding of metal-metal bonding that developed as a result of the discovery of multiple metal-metal bonding awakened a new chemistry involving metal clusters. Clusters were defined by Cotton to be species containing metal-metal bonding. Clusters in catalysis therefore seemed a logical grouping of papers in this symposium. Clusters play an every increasing role in the control of chemical reactions. Part II of this book describes some of the interesting new developments in this field. In Part III the papers examine the role clusters play in describing and understanding solid state materials.
Book Synopsis Metal-metal bonds and clusters in chemistry and catalysis by : Barbie Navr
Download or read book Metal-metal bonds and clusters in chemistry and catalysis written by Barbie Navr and published by . This book was released on 2020 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Metal Clusters in Chemistry by : Pierre Braunstein
Download or read book Metal Clusters in Chemistry written by Pierre Braunstein and published by Wiley-VCH. This book was released on 2000-01-11 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal cluster chemistry is at the cutting edge between molecular and solid-state chemistry and has therefore had a great impact on the researchers working on organic, coordination, and solid-state chemistry, catalysis, physics, and materials science. The development of new sophisticated synthetic techniques has led to enormous progress in the synthesis of this diverse class of compounds. The number of clusters is growing rapidly, since the possible variations in the metal and ligand sphere are numerous. Modern bonding theories, such as the isolobal principle, have allowed a better understanding of the structures and properties of metal clusters, and thus paved the way for the usage of these versatile materials. Catalysis and nanomaterials are just two of the very promising application-oriented fields. Seventy six contributions, written by world experts in this research field, provide extensive coverage of different aspects of cluster chemistry, ranging from synthesis, structure determination, and dynamics to applications. Up-to-date information, including an impressive collection of structural data and illustrations, extensive coverage of the most important publications of the last decade, and many more features make this three-volume set a complete single-source guide for all researchers working in the area of cluster chemistry.
Book Synopsis Transition Metal Carbonyl Cluster Chemistry by : Paul J. Dyson
Download or read book Transition Metal Carbonyl Cluster Chemistry written by Paul J. Dyson and published by CRC Press. This book was released on 2018-10-03 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.
Book Synopsis Metal Clusters in Catalysis by : Bruce C. Gates
Download or read book Metal Clusters in Catalysis written by Bruce C. Gates and published by Elsevier Publishing Company. This book was released on 1986 with total page 684 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research on metal clusters (compounds with metal-metal bonds) has undergone explosive growth and the subject is now perhaps one of the hottest'' topics in organometallic chemistry. The prospect of catalytic applications has motivated a large part of the research mentioned in this book - the long term goal being to exploit the unique properties of metal clusters to prepare catalysts with new activities and selectivities. This is the first book to address the role of metal clusters in catalysis. The coverage is up-to-date and is particularly comprehensive, ranging from molecular chemistry of clusters (synthesis, structure, thermochemistry, reactivity, and homogeneous catalysis) to supported clusters (molecular analogues on polymers, and metal oxides and metals in zeolite cages). Preparation by methods of organometallic surface chemistry and metal atom chemistry and characterization of surface structures by physical methods are highlighted. Concepts unifying metal cluster chemistry and the chemistry of metal surfaces are elucidated. Of particular value to the user will be the cluster and subject indexes. The cluster index is organized in alphabetical order according to the metal.
Book Synopsis The Chemistry of Metal Cluster Complexes by : Duward F. Shriver
Download or read book The Chemistry of Metal Cluster Complexes written by Duward F. Shriver and published by Wiley-VCH. This book was released on 1990 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: Seven chapters summarize the current status of organometallic cluster chemistry from the viewpoints of synthesis, structure and bonding, ligand substitution reactions, ligand transformations, polyhedral rearrangement, cluster fragmentation reactions, and metal clusters as homogeneous catalysts. An eighth provides an extensive bibliography of reviews for the period from 1965 to 1988. Annotation copyrighted by Book News, Inc., Portland, OR
Book Synopsis Metal Clusters and Their Reactivity by : Zhixun Luo
Download or read book Metal Clusters and Their Reactivity written by Zhixun Luo and published by Springer Nature. This book was released on 2020-10-31 with total page 267 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book discusses current techniques and instrumentation for cluster chemistry. It addresses both the experimental and theoretical aspects of gas-phase metal cluster reactivities, especially those pertaining to pollution removal, energetic reactions and corrosion and anticorrosion. These metal cluster systems have attracted enormous interest as they display a completely new class of physical, chemical, electronic, magnetic and catalytic properties. As these properties change with size and composition, it can thus be understood how their nature evolves from atoms to bulk solids. The book offers readers a basic understanding of the structural chemistry and reactivity of metal clusters in both gas-phase and wet chemistry. Further, the lessons they learn here regarding metal cluster chemistry will prepare researchers for the study of condensed phase dynamics that pertain to wet chemical synthesis, soft-landing deposition and cluster assembly.
Author :Guillermo Gonzalez-Moraga Publisher :Springer Science & Business Media ISBN 13 :3642859267 Total Pages :310 pages Book Rating :4.6/5 (428 download)
Book Synopsis Cluster Chemistry by : Guillermo Gonzalez-Moraga
Download or read book Cluster Chemistry written by Guillermo Gonzalez-Moraga and published by Springer Science & Business Media. This book was released on 2013-11-09 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.
Book Synopsis Metal Clusters in Chemistry by : Sir Jack Lewis
Download or read book Metal Clusters in Chemistry written by Sir Jack Lewis and published by . This book was released on 1983 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Metal Clusters by : Martin Moskovits
Download or read book Metal Clusters written by Martin Moskovits and published by Wiley-Interscience. This book was released on 1986 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt: Offering broad coverage of metal clusters and their applications, particularly those active in catalysis, this book looks at the current state of the art in metal cluster research, applications to physical chemistry, inorganic and organometallic synthesis, heterogeneous and homogeneous catalysis, and spectroscopy. It includes both physical and theoretical techniques currently used to study metal clusters.
Book Synopsis Transition Metal Clusters by : Brian Frederick Gilbert Johnson
Download or read book Transition Metal Clusters written by Brian Frederick Gilbert Johnson and published by John Wiley & Sons. This book was released on 1980 with total page 702 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Synergy Between Dynamics and Reactivity at Clusters and Surfaces by : L.J. Farrugia
Download or read book The Synergy Between Dynamics and Reactivity at Clusters and Surfaces written by L.J. Farrugia and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 365 pages. Available in PDF, EPUB and Kindle. Book excerpt: The analogy between the chemistry of molecular transition metal clusters and the processes of chemisorption and catalysis at metal surfaces (the Cluster Surface analogy) has for a number of years provided an interplay between experimental and theoretical inorganic and physical chemists. This collaborative approach has born fruit in the use of well defined modes of metal-ligand bonding in discrete molecular clusters, models for metal-ligand binding on surfaces. Some of the key topics discussed in The Synergy between Dynamics and Reactivity at Clusters and Surfaces are: (1) Mechanisms of the fluxional behaviour in clusters in the liquid phase and the connections with diffusion processes on extended surfaces. The role of metal-metal bond breaking in diffusion. (2) Analogies in the structure of chemisorbed species and related ligands on metallic clusters. (3) Analogies between benzene surface chemistry on extended metal surfaces and on metal surfaces in molecular cluster compounds with particular reference to structural distortions. (4) The role of mobile precursors for dissociation of chemisorption on extended metals and on clusters. Are there analogies in the ligand attachment during cluster compound synthesis? (5) The role of defect sites on metal surfaces in catalyzing chemical reactions and the connection to the special bonding properties of sites on metal clusters having lowest metal-metal coordination. (6) The size of metal clusters needed to mimic surface phenomena on bulk metal surfaces. Different sites needed for different phenomena.
Book Synopsis Molecular Metal-Metal Bonds by : Stephen T. Liddle
Download or read book Molecular Metal-Metal Bonds written by Stephen T. Liddle and published by John Wiley & Sons. This book was released on 2016-03-16 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: Systematically covering all the latest developments in the field, this is a comprehensive and handy introduction to metal-metal bonding. The chapters follow a uniform, coherent structure for a clear overview, allowing readers easy access to the information. The text covers such topics as synthesis, properties, structures, notable features, reactivity and examples of applications of the most important compounds in each group with metal-metal bonding throughout the periodic table. With its general remarks at the beginning of each chapter, this is a must-have reference for all molecular inorganic chemists, including PhD students and postdocs, as well as more experienced researchers.
Book Synopsis Introduction to Cluster Chemistry by : D. M. P. Mingos
Download or read book Introduction to Cluster Chemistry written by D. M. P. Mingos and published by . This book was released on 1990 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Organometallic Bonding and Reactivity by : J.M. Brown
Download or read book Organometallic Bonding and Reactivity written by J.M. Brown and published by Springer. This book was released on 2003-07-01 with total page 195 pages. Available in PDF, EPUB and Kindle. Book excerpt: The making and breaking of carbon-metal bonds is fundamental to all the processes of organometallic chemistry and metal mediated homogeneous or heterogeneous catalysis. The ever expanding scope of highly specific stoichiometric and catalytic transformations or organic substrates involving metals requires a thorough physical and theoretical understanding of fundamental principles of organometallic structure and reactivity. Diffraction experiments form the basis of tailoring the molecular architecture of organometallic compounds for specific functions. Mass spectrometric techniques possess the power to provide direct information on the energetics of transient species generated in the gas-phase. Computational chemistry with ab initio or density functional methods make a reliable numerical assessment of structures and (relative) energies increasingly feasible. Embedding methods, combining quantum chemistry with force field of semiempirical MO treatments, quantum dynamic studies and the computational modelling of solvent effects extend the utility of the basic methods. This volume in the series Topics in Organometallic Chemistry presents a survey by renowned experts of important experimental and theoretical developments to elucidate basic aspects of bonding, energetics, reaction mechanisms, molecular geometries and solid-state structures of organometallic compounds. Written by authors with frontier research expertise in their fields, both experimental and quantum chemical techniques, methodologies, results and interpretations are detailed in a manner suitable for the non-specialist, who seeks state-of-the-art information in the respective field.
Book Synopsis Heteronuclear Metal-Metal Bonds by : R.D. Adams
Download or read book Heteronuclear Metal-Metal Bonds written by R.D. Adams and published by Elsevier. This book was released on 2004-09-16 with total page 458 pages. Available in PDF, EPUB and Kindle. Book excerpt: The number of organometallic compounds containing heteronuclear metal-metal bonds has grown tremendously in the last ten years. Also known as cluster compounds, these compounds have been found to exhibit a rich diversity of molecular structures and reactivities. Descriptions of the structures and transformations of the complexes are central features. Separate chapters have been prepared for compounds containing bonds between transition metals and the metals of the copper and zinc subgroups. Unlike COMC, this volume contains an entire chapter devoted to studies of heteronuclear metal compounds in catalysis.
Book Synopsis Organometallic Chemistry and Catalysis by : Didier Astruc
Download or read book Organometallic Chemistry and Catalysis written by Didier Astruc and published by Springer Science & Business Media. This book was released on 2007-08-02 with total page 598 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the book. Beginners in inorganic, organic and organometallic chemistry, as well as advanced scholars and chemists from academia and industry will find much value in this title.
