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Synthesis Reactivity And Mechanistic Studies On Oxo Imido And Alkylidine Complexes Of The Early Transition Metals
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Book Synopsis Synthesis, Reactivity and Mechanistic Studies on Oxo, Imido and Alkylidine Complexes of the Early Transition Metals by : Jonathan Paul Mitchell
Download or read book Synthesis, Reactivity and Mechanistic Studies on Oxo, Imido and Alkylidine Complexes of the Early Transition Metals written by Jonathan Paul Mitchell and published by . This book was released on 1992 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, reactivity and mechanistic studies on oxo, imido and alkylidene complexes of the early transition metals by : Jonathan Paul Mitchell
Download or read book Synthesis, reactivity and mechanistic studies on oxo, imido and alkylidene complexes of the early transition metals written by Jonathan Paul Mitchell and published by . This book was released on 1992 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactivity of Imido and Oxo Complexes of Transition Metals by :
Download or read book Synthesis and Reactivity of Imido and Oxo Complexes of Transition Metals written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Refer to the Full-Text, p.16-18.
Book Synopsis Organic Synthesis Using Transition Metals by : Roderick Bates
Download or read book Organic Synthesis Using Transition Metals written by Roderick Bates and published by John Wiley & Sons. This book was released on 2012-04-30 with total page 469 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metals open up new opportunities for synthesis, because their means of bonding and their reaction mechanisms differ from those of the elements of the s and p blocks. In the last two decades the subject has mushroomed - established reactions are seeing both technical improvements and increasing numbers of applications, and new reactions are being developed. The practicality of the subject is demonstrated by the large number of publications coming from the process development laboratories of pharmaceutical companies, and its importance is underlined by the fact that three Nobel prizes have been awarded for discoveries in this field in the 21st Century already. Organic Synthesis Using Transition Metals, 2nd Edition considers the ways in which transition metals, as catalysts and reagents, can be used in organic synthesis, both for pharmaceutical compounds and for natural products. It concentrates on the bond-forming reactions that set transition metal chemistry apart from "classical" organic chemistry. Each chapter is extensively referenced and provides a convenient point of entry to the research literature. Topics covered include: introduction to transition metals in organic synthesis coupling reactions C-H activation carbonylative coupling reactions alkene and alkyne insertion reactions electrophilic alkene and alkyne complexes reactions of alkyne complexes carbene complexes h3- or p-allyl -allyl complexes diene, dienyl and arene complexes cycloaddition and cycloisomerisation reactions For this second edition the text has been extensively revised and expanded to reflect the significant improvements and advances in the field since the first edition, as well as the large number of new transition metal-catalysed processes that have come to prominence in the last 10 years – for example the extraordinary progress in coupling reactions using “designer” ligands, catalysis using gold complexes, new opportunities arising from metathesis chemistry, and C-H activation – without neglecting the well established chemistry of metals such as palladium. Organic Synthesis Using Transition Metals, 2nd Edition will find a place on the bookshelves of advanced undergraduates and postgraduates working in organic synthesis, catalysis, medicinal chemistry and drug discovery. It is also useful for practising researchers who want to refresh and enhance their knowledge of the field.
Book Synopsis Synthesis, Reactivity and Structural Studies of Early Transition Metal Alkyl and Alkylidene Complexes in PI-Loaded Environments (PHD). by : Paula Marie Briggs
Download or read book Synthesis, Reactivity and Structural Studies of Early Transition Metal Alkyl and Alkylidene Complexes in PI-Loaded Environments (PHD). written by Paula Marie Briggs and published by . This book was released on 1998 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactivity Studies on Oxo and Sulphido Compounds of Early Transition Metals by : Alan Shaw
Download or read book Synthesis and Reactivity Studies on Oxo and Sulphido Compounds of Early Transition Metals written by Alan Shaw and published by . This book was released on 1989 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Index to Theses with Abstracts Accepted for Higher Degrees by the Universities of Great Britain and Ireland and the Council for National Academic Awards by :
Download or read book Index to Theses with Abstracts Accepted for Higher Degrees by the Universities of Great Britain and Ireland and the Council for National Academic Awards written by and published by . This book was released on 1994 with total page 1036 pages. Available in PDF, EPUB and Kindle. Book excerpt: Theses on any subject submitted by the academic libraries in the UK and Ireland.
Book Synopsis Synthesis and Reactivity Studies Om Oxo and Sulphido Compounds of Early Transition Metals by : A. Shaw
Download or read book Synthesis and Reactivity Studies Om Oxo and Sulphido Compounds of Early Transition Metals written by A. Shaw and published by . This book was released on 1989 with total page 273 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis British Reports, Translations and Theses by : British Library. Document Supply Centre
Download or read book British Reports, Translations and Theses written by British Library. Document Supply Centre and published by . This book was released on 1994 with total page 706 pages. Available in PDF, EPUB and Kindle. Book excerpt: Issue for Mar. 1981 contains index for Jan.-Mar. 1981 in microfiche form.
Book Synopsis Late Transition Metal. Mu.-oxo And. Mu.-imido Complexes by :
Download or read book Late Transition Metal. Mu.-oxo And. Mu.-imido Complexes written by and published by . This book was released on 1990 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt: The synthesis and reactions of late-transition-metal oxo and imido complexes was explored. The deprotonation of platinum(II) hydroxo complexes yielded new oxo complexes. Attempted deprotonation of Cp*Rh(III) hydroxo complexes did not give oxo complexes but complex mixtures probably resulting from reduction of the Rh(III) center. The reaction of Na/Hg with (Cp*RhCl2)2 gave the very reactive Rh(II) dimer, (Cp*RhCl)2. Rhodium(I) imido complexes with the bis(dimethylphosphino)methane ligand were prepared and found to be similar to the previously prepared bis(diphenylphosphino)methane complexes. Attempts to prepare bis(diphenylphosphino)methylamine, bis(diphenylphosphino)phenylamine, PMe{sub e} and NO analogues were not successful. Attempts to prepare Cp*Rh(III) imido complexes resulted in amido complexes and reduction. Rhodium (III) tris(3.5-dimethylpyrazoyl)borate analogues are reduction resistant but have not yet yielded imido complexes. The first imido complexes of Au were prepared by treating a Au oxo complex with amines or isocyanates. Dimeric Cp*Rh dioxygen and nitrosobenzene complexes were prepared by insertion into the Rh-Rh bond of (Cp*RhCl)2. The dioxygen complex activates a C-H bond of the Cp* ligand on treatment with PMe3. Imido and oxo complexes nitrene and oxygen atom transfer product in reactions with CO. A novel electrophilic ring addition was observed with sterically protected aryl imido complexes. 15 refs.
Book Synopsis Transition Metals in the Synthesis of Complex Organic Molecules by : Louis S. Hegedus
Download or read book Transition Metals in the Synthesis of Complex Organic Molecules written by Louis S. Hegedus and published by University Science Books. This book was released on 1994 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt: A text for use in a one-semester course for upper-level students familiar with basic organic chemistry, or as a survey course for practicing organic chemists. Chapters 1 and 2 present a brief overview of the formalisms and mechanisms required to understand the processes discussed in chapters 3-10, which deal with the application of transition metal organometallic chemistry to organic synthesis with specific attention to applications with complex molecules. Updates and expands chapters 13-20 of Principles and Applications of Organotransition Metal Chemistry, 2nd ed. (1987). Published by University Science Books, 20 Edgehill Rd., Mill Valley, CA 94941. Annotation copyright by Book News, Inc., Portland, OR
Book Synopsis Synthetic and Mechanistic Studies of a Vanadium-catalyzed Enantioselective Oxidation of Di-tert-butyl-disulfide by : Suzanne Amy Blum
Download or read book Synthetic and Mechanistic Studies of a Vanadium-catalyzed Enantioselective Oxidation of Di-tert-butyl-disulfide written by Suzanne Amy Blum and published by . This book was released on 2004 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Transition metal Organometallics In Organic Synthesis by : Howard Alper
Download or read book Transition metal Organometallics In Organic Synthesis written by Howard Alper and published by Elsevier. This book was released on 2012-12-02 with total page 271 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition Metal Organometallics in Organic Synthesis: Volume I reviews the literature in the field of organic synthesis with a focus on the most effective synthetic transformations. The text covers topics such as the general considerations in organic synthesis, C-C and C-X bond formations, and the isomerization and reorganization reactions of olefins. Also covered are topics such as displacement reactions with transition metal complexes, electrophilic reactions of organopalladium complexes, carbonylation reactions, and metal-carbene complexes — its structure, spectra, bonding, and direct synthesis. The book is recommended as a reference for chemists and inorganic chemists who would like to learn the applications of organometallic complexes as reagents and catalysts.
Book Synopsis Synthesis and Reactivity of Dinitrogen, Oxo, and Nitrido Complexes of First Row Transition Metals Supported by Hydrotris(pyrazolyl)borate Ligands by : Daniel Clayton Cummins
Download or read book Synthesis and Reactivity of Dinitrogen, Oxo, and Nitrido Complexes of First Row Transition Metals Supported by Hydrotris(pyrazolyl)borate Ligands written by Daniel Clayton Cummins and published by . This book was released on 2018 with total page 281 pages. Available in PDF, EPUB and Kindle. Book excerpt: When 9 is reacted with single oxygen atom transfer reagents the novel bridging oxo complex in the form of [TpFc,MeFe] 2(μ2-η1:η1-O) (16) is produced. 16 is only the second instance of such a FeII-O-FeII compound to have been isolated and structurally characterized. In the effort to produce additional chalcogenide compounds the complexes TpFc,MeFeOCPh3 (13) and TpFc,MeFeSCPh3 (14) were produced by salt metathesis with 3. The reaction of 14 with KH in the presence of 18-crown-6 to produce a bridging sulfide, [Tp Fc,MeFe]2(μ2-η1:η 1-S) (15). Attempts to produce imide compounds to act as isoelectronic models for terminal oxo compounds by reacting organic azides with 9 and 10 resulted in the production of tetrazene complex TpFc,MeCoN4Bn2 (17), as well as metallated azides TpFc,MeFeN3 (20) and TpFc,MeCoN3 (21).
Book Synopsis Synthesis, Reactivity and Mechanistic Studies on Oxo, Alkoxo and Tertiary Phosphine Derivatives of Niobium and Tantalum by : Terence Phillip Kee
Download or read book Synthesis, Reactivity and Mechanistic Studies on Oxo, Alkoxo and Tertiary Phosphine Derivatives of Niobium and Tantalum written by Terence Phillip Kee and published by . This book was released on 1989 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis New Pathways for Organic Synthesis by : H.M. Colquhoun
Download or read book New Pathways for Organic Synthesis written by H.M. Colquhoun and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 459 pages. Available in PDF, EPUB and Kindle. Book excerpt: The continually growing contribution of transition metal chemistry to synthetic organic chemistry is, of course, widely recognized. Equally well known is the difficulty in keeping up-to-date with the multifarious reactions and procedures that seem to be spawned at an ever-increasing rate. These can certainly be summarized on the basis of reviews under the headings of the individual transition metals. More useful to the bench organic chemist, however, would be the opposite type of concordance based on the structural type of the desired synthetic product. This is the approach taken in the present monograph, which presents for each structural entity a conspectus of the transition metal-mediated processes that can be employed in its production. The resulting comparative survey should be a great help in devising the optimum synthetic approach for a particular goal. It is presented from an essentially practical viewpoint, with detailed direc tions interspersed in the Houben-Weyl style. The wide scope of the volume should certainly encourage synthetic organic chemists to utilize fully the range and versatility of these transition metal-mediated processes. This will certainly be a well-thumbed reference book! R. A. RAPHAEL Cambridge University v Preface In recent years an enormous amount of work has been done on the catalysis of organic reactions by various transition metal species and on the organic reactivity of organo-transition-metal compounds.
Book Synopsis Synthesis and Reactivity of Early Transition Metal Complexes by : LeGrande Mancel Slaughter (III)
Download or read book Synthesis and Reactivity of Early Transition Metal Complexes written by LeGrande Mancel Slaughter (III) and published by . This book was released on 2000 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt:
