Stereoselective Synthesis of Cyclometalated Iridium(III) Complexes: Characterization and Photophysical Properties

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Book Synopsis Stereoselective Synthesis of Cyclometalated Iridium(III) Complexes: Characterization and Photophysical Properties by :

Download or read book Stereoselective Synthesis of Cyclometalated Iridium(III) Complexes: Characterization and Photophysical Properties written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The stereoselective synthesis of a highly luminescent neutral Ir(III) complex comprising two bidentate chiral, cyclometalating phenylpyridine derivatives, and one acetylacetonate as ligands is described. The final complex and some intermediates were characterized by X-ray structural analysis, NMR-, CD-, and CPL-spectroscopy.

The Synthesis and Photophysical Studies of Cyclometalated Iridium(III) Complexes

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ISBN 13 :
Total Pages : 208 pages
Book Rating : 4.:/5 (912 download)

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Book Synopsis The Synthesis and Photophysical Studies of Cyclometalated Iridium(III) Complexes by :

Download or read book The Synthesis and Photophysical Studies of Cyclometalated Iridium(III) Complexes written by and published by . This book was released on 2003 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis and the Photophysical Properties of New Heterometallic Platinum(II)-iridium(III) Complexes and Their Polymers

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ISBN 13 :
Total Pages : 330 pages
Book Rating : 4.:/5 (833 download)

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Book Synopsis Synthesis and the Photophysical Properties of New Heterometallic Platinum(II)-iridium(III) Complexes and Their Polymers by : Ahmed M. Soliman

Download or read book Synthesis and the Photophysical Properties of New Heterometallic Platinum(II)-iridium(III) Complexes and Their Polymers written by Ahmed M. Soliman and published by . This book was released on 2012 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Phosphorescent Cyclometalated Iridium(III) Complexes and Corresponding Conducting Metallopolymers

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ISBN 13 :
Total Pages : 312 pages
Book Rating : 4.:/5 (798 download)

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Book Synopsis Phosphorescent Cyclometalated Iridium(III) Complexes and Corresponding Conducting Metallopolymers by : Travis Wayne Hesterberg

Download or read book Phosphorescent Cyclometalated Iridium(III) Complexes and Corresponding Conducting Metallopolymers written by Travis Wayne Hesterberg and published by . This book was released on 2012 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Conducting metallopolymers have been investigated for a variety of applications due to their ability to take advantage of both the mechanical processability of the polymer material, as well as the optical and electronic properties of the metal. Our project goal is to design, synthesize and characterize novel iridium(III)-containing conducting metallopolymers for use as the active layer in polymer light-emitting diodes. We have utilized thiophene functionalized ligands that can be readily electropolymerized into conducting polymer thin films and can be easily incorporated into a device structure. Iridium(III) was chosen as the metal center due to its promising photophysical properties, as similar complexes have demonstrated high luminescent quantum yields and short phosphorescent lifetimes. The coordination environment around the metal can be altered synthetically to tune the emission wavelength across the visible spectrum. The synthetic control over the polymer backbone, as well as the iridium(III) ligand environment, allowed us to independently vary each component, which has provided a variety of materials. The materials are characterized through 1H and 13C NMR, mass spectrometry, elemental analysis, electrochemistry, X-Ray diffraction and X-Ray Photoelectron Spectroscopy. The photophysical properties of the materials are studied through UV-Visible absorption spectroscopy, UV-Vis-NIR spectroelectrochemistry and steady-state/ time-resolved emission spectroscopy.

Stereoselective Synthesis of Cyclometalated Rhodium(III) Complexes

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ISBN 13 :
Total Pages : 134 pages
Book Rating : 4.:/5 (853 download)

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Book Synopsis Stereoselective Synthesis of Cyclometalated Rhodium(III) Complexes by : Liana Ghizdavu

Download or read book Stereoselective Synthesis of Cyclometalated Rhodium(III) Complexes written by Liana Ghizdavu and published by . This book was released on 1999 with total page 134 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Novel HEXOL-type Cyclometallated Iridium(III) Complexes: Stereoselective Synthesis and Structure Elucidation

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Book Synopsis Novel HEXOL-type Cyclometallated Iridium(III) Complexes: Stereoselective Synthesis and Structure Elucidation by :

Download or read book Novel HEXOL-type Cyclometallated Iridium(III) Complexes: Stereoselective Synthesis and Structure Elucidation written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Two diastereoisomers of tetranuclear cyclometallated iridium complexes, either having an inner core of HEXOL-type [Ir(IrCl2)3]6 unit and a surface of six chiral, didentate, cyclometallated ligands, are stereoselectively synthesized from an enantiopure pinenopyridine derivative.

Synthesis and Characterization of (alkenyl)iridium (III) Complexes

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ISBN 13 :
Total Pages : 178 pages
Book Rating : 4.:/5 (411 download)

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Book Synopsis Synthesis and Characterization of (alkenyl)iridium (III) Complexes by : Brian Thomas Lottig

Download or read book Synthesis and Characterization of (alkenyl)iridium (III) Complexes written by Brian Thomas Lottig and published by . This book was released on 1998 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis, Characterization, and Thermal Reactions of Some Iridium (III) Complexes Containing the Ligand Β, Β' Β"-triaminotriethylamine

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ISBN 13 :
Total Pages : 48 pages
Book Rating : 4.:/5 (856 download)

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Book Synopsis Synthesis, Characterization, and Thermal Reactions of Some Iridium (III) Complexes Containing the Ligand Β, Β' Β"-triaminotriethylamine by : Dana Carabillo

Download or read book Synthesis, Characterization, and Thermal Reactions of Some Iridium (III) Complexes Containing the Ligand Β, Β' Β"-triaminotriethylamine written by Dana Carabillo and published by . This book was released on 2013 with total page 48 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Journal

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ISBN 13 :
Total Pages : 1042 pages
Book Rating : 4.:/5 (334 download)

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Book Synopsis Journal by : American Chemical Society

Download or read book Journal written by American Chemical Society and published by . This book was released on 2004 with total page 1042 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Cyclometalation Reactions

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Publisher : Springer Science & Business Media
ISBN 13 : 4431546049
Total Pages : 214 pages
Book Rating : 4.4/5 (315 download)

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Book Synopsis Cyclometalation Reactions by : Iwao Omae

Download or read book Cyclometalation Reactions written by Iwao Omae and published by Springer Science & Business Media. This book was released on 2014-01-23 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a review of cyclometalation reactions and organometallic intramolecular-coordination five-membered ring products, the most active type of reactions in synthetic organic reactions and their products. Included is the discovery of intramolecular-coordination bonds in cyclometalation reactions and the characteristics of those reactions, as well as the reasons that their five-membered ring compounds are very easily synthesized through such reactions. In addition, the applications of cyclometalation reactions and five-membered ring products, synthetic applications, catalysts, and other products are described. These topics are of special interest for industrial researchers.

Anion Sensing

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Publisher : Springer Science & Business Media
ISBN 13 : 9783540232476
Total Pages : 252 pages
Book Rating : 4.2/5 (324 download)

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Book Synopsis Anion Sensing by : Eric V. Anslyn

Download or read book Anion Sensing written by Eric V. Anslyn and published by Springer Science & Business Media. This book was released on 2005-05-06 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt: with contributions by numerous experts

Medicinal Organometallic Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 3642131840
Total Pages : 305 pages
Book Rating : 4.6/5 (421 download)

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Book Synopsis Medicinal Organometallic Chemistry by : Gérard Jaouen

Download or read book Medicinal Organometallic Chemistry written by Gérard Jaouen and published by Springer Science & Business Media. This book was released on 2010-09-14 with total page 305 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contents: Gérard Jaouen, Nils Metzler-Nolte : Introduction ; Stéphane GIBAUD and Gérard JAOUEN: Arsenic - based drugs: from Fowler’s solution to modern anticancer chemotherapy; Ana M. Pizarro, Abraha Habtemariam and Peter J. Sadler : Activation Mechanisms for Organometallic Anticancer Complexes; Angela Casini, Christian G. Hartinger, Alexey A. Nazarov, Paul J. Dyson : Organometallic antitumour agents with alternative modes of action; Elizabeth A. Hillard, Anne Vessières, Gerard Jaouen : Ferrocene functionalized endocrine modulators for the treatment of cancer; Megan Hogan and Matthias Tacke : Titanocenes – Cytotoxic and Anti-Angiogenic Chemotherapy Against Advanced Renal-Cell Cancer; Seann P. Mulcahy and Eric Meggers : Organometallics as Structural Scaffolds for Enzyme Inhibitor Design; Christophe Biot and Daniel Dive : Bioorganometallic Chemistry and Malaria; Nils Metzler-Nolte : Biomedical applications of organometal-peptide conjugates; Roger Alberto : Organometallic Radiopharmaceuticals; Brian E. Mann : Carbon Monoxide – an essential signaling molecule.

Handbook of Photochemistry

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Publisher : CRC Press
ISBN 13 : 1420015192
Total Pages : 662 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Handbook of Photochemistry by : Marco Montalti

Download or read book Handbook of Photochemistry written by Marco Montalti and published by CRC Press. This book was released on 2006-02-21 with total page 662 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the publication of the second edition of this handbook in 1993, the field of photochemical sciences has continued to expand across several disciplines including organic, inorganic, physical, analytical, and biological chemistries, and, most recently, nanosciences. Emphasizing the important role light-induced processes play in all of these fie

Iridium Catalysis

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Publisher : Springer Science & Business Media
ISBN 13 : 364215333X
Total Pages : 244 pages
Book Rating : 4.6/5 (421 download)

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Book Synopsis Iridium Catalysis by : Pher G. Andersson

Download or read book Iridium Catalysis written by Pher G. Andersson and published by Springer Science & Business Media. This book was released on 2011-01-05 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: From the contents: Robert H Crabtree: Introduction and History. - Montserrat Diéguez, Oscar Pàmies and Carmen Claver: Iridium-catalysed hydrogenation using phosphorous ligands. - David H. Woodmansee and Andreas Pfaltz: Iridium Catalyzed Asymmetric Hydrogenation of Olefins with Chiral N,P and C,N Ligands. - Ourida Saidi and Jonathan M J Williams: Iridium-catalyzed Hydrogen Transfer Reactions. - John F. Bower and Michael J. Krische: Formation of C-C Bonds via Iridium Catalyzed Hydrogenation and Transfer Hydrogenation. - Jongwook Choi, Alan S. Goldman: Ir-Catalyzed Functionalization of CH Bonds. - Mark P. Pouy and John F. Hartwig: Iridium-Catalyzed Allylic Substitution. - Daniel Carmona and Luis A. Oro: Iridium-catalyzed 1.3-dipolar cycloadditions.

Inorganic Chemical Biology

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Publisher : John Wiley & Sons
ISBN 13 : 111851002X
Total Pages : 437 pages
Book Rating : 4.1/5 (185 download)

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Book Synopsis Inorganic Chemical Biology by : Gilles Gasser

Download or read book Inorganic Chemical Biology written by Gilles Gasser and published by John Wiley & Sons. This book was released on 2014-06-23 with total page 437 pages. Available in PDF, EPUB and Kindle. Book excerpt: Understanding, identifying and influencing the biological systems are the primary objectives of chemical biology. From this perspective, metal complexes have always been of great assistance to chemical biologists, for example, in structural identification and purification of essential biomolecules, for visualizing cellular organelles or to inhibit specific enzymes. This inorganic side of chemical biology, which continues to receive considerable attention, is referred to as inorganic chemical biology. Inorganic Chemical Biology: Principles, Techniques and Applications provides a comprehensive overview of the current and emerging role of metal complexes in chemical biology. Throughout all of the chapters there is a strong emphasis on fundamental theoretical chemistry and experiments that have been carried out in living cells or organisms. Outlooks for the future applications of metal complexes in chemical biology are also discussed. Topics covered include: • Metal complexes as tools for structural biology • IMAC, AAS, XRF and MS as detection techniques for metals in chemical biology • Cell and organism imaging and probing DNA using metal and metal carbonyl complexes • Detection of metal ions, anions and small molecules using metal complexes • Photo-release of metal ions in living cells • Metal complexes as enzyme inhibitors and catalysts in living cells Written by a team of international experts, Inorganic Chemical Biology: Principles, Techniques and Applications is a must-have for bioinorganic, bioorganometallic and medicinal chemists as well as chemical biologists working in both academia and industry.

Diradicaloids

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Publisher : CRC Press
ISBN 13 : 1000565254
Total Pages : 638 pages
Book Rating : 4.0/5 (5 download)

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Book Synopsis Diradicaloids by : Jishan Wu

Download or read book Diradicaloids written by Jishan Wu and published by CRC Press. This book was released on 2022-04-01 with total page 638 pages. Available in PDF, EPUB and Kindle. Book excerpt: π-Conjugated molecules with an even number of π-electrons usually have a closed-shell ground state. However, recent studies have demonstrated that a certain type of molecules could show open-shell singlet ground state and display diradical-like (diradicaloid) behavior. Their electronic structure can be understood in terms of the “diradical character” and “aromaticity” concepts. They display very different electronic properties from traditional closed-shell π-conjugated molecules and could be used as next-generation molecular materials. This book provides a comprehensive review on the chemistry, physics, and material applications of open-shell singlet diradicaloids. Particularly, it elaborates the fundamental structure–diradical character–electronic property relationships both theoretically and experimentally. The book has been written by leading scientists in the field from Japan, Germany, Spain, Italy, China, and Singapore.

Gold Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 3527320865
Total Pages : 425 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Gold Chemistry by : Fabian Mohr

Download or read book Gold Chemistry written by Fabian Mohr and published by John Wiley & Sons. This book was released on 2009-04-20 with total page 425 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by world-class authors, this most recent major book on the topic highlights new and current trends as well as future directions. It is comprehensive in its scope, covering all aspects of gold chemistry -- from homogeneous to heterogeneous catalysis, from supramolecular assemblies to sensors and medicinal applications. The result is an invaluable work for both organic and inorganic chemists working in universities and industry, as well as material scientists.