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Physisorption Kinetics
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Book Synopsis Physisorption Kinetics by : Hans Jürgen Kreuzer
Download or read book Physisorption Kinetics written by Hans Jürgen Kreuzer and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 333 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph deals with the kinetics of adsorption and desorption of molecules physisorbed on solid surfaces. Although frequent and detailed reference is made to experiment, it is mainly concerned with the theory of the subject. In this, we have attempted to present a unified picture based on the master equation approach. Physisorption kinetics is by no means a closed and mature subject; rather, in writing this monograph we intended to survey a field very much in flux, to assess its achievements so far, and to give a reasonable basis from which further developments can take off. For this reason we have included many papers in the bibliography that are not referred to in the text but are of relevance to physisorption. To keep this monograph to a reasonable size, and also to allow for some unity in the presentation of the material, we had to omit a number of topics related to physisorption kinetics. We have not covered to any extent the equilibrium properties of physisorbed layers such as structures, phase tr- sitions and thermodynamic properties in general. A number of excellent revIew articles, listed in the bibliography, cover this material. Likewise, little is said about scattering off solid surfaces; this subject is again covered in several books and many review articles. Lastly, little is said about chemisorption kinetics, for which microscopic thebries and models have not been fully developed but are still at a rather early exploratory stage.
Book Synopsis Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces by : W.A. Steele
Download or read book Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces written by W.A. Steele and published by Elsevier. This book was released on 1996-12-17 with total page 909 pages. Available in PDF, EPUB and Kindle. Book excerpt: The fact that the surfaces of real solids are geometrically distorted and chemically non-uniform has long been realized by the scientists investigating various phenomena occurring on solid surfaces. Even in the case when diffraction experiments show a well-organized bulk solid structure, the surface atoms or molecules will usually exhibit a much smaller degree of surface organization. In addition to the results obtained from electron diffraction, this can be seen in the impressive images obtained from STM and AFM microscopies. This geometric and chemical disorder is the source of the energetic heterogeneity for molecules adsorbing on real solid surfaces. Hundreds of papers have been published showing that this heterogeneity is a major factor in determining the behaviour of real adsorption systems. Studies of adsorption on energetically heterogeneous surfaces have proceeded along three somewhat separate paths, with only minor coupling of ideas. One was the study of adsorption equilibria on heterogeneous solid surfaces. The second path was the study of time evolution of adsorption processes such as surface diffusion or adsorption-desorption kinetics on heterogeneous surfaces, and the third was the study of adsorption in porous solids, or more generally, adsorption in systems with limited dimensions. The present monograph is a first attempt to provide a synthesis of the ways that surface geometric and energetic heterogeneities affect both the equilibria and the time evolution of adsorption on real solids. The book contains 17 chapters written by a team of internationally recognized specialists, some of whom have already published books on adsorption.
Book Synopsis Catalytic Kinetics by : Dmitry Yu Murzin
Download or read book Catalytic Kinetics written by Dmitry Yu Murzin and published by Elsevier. This book was released on 2005-11-07 with total page 485 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemistry and chemical technology have been at the heart of the revolutionary developments of the 20th century. The chemical industry has a long history of combining theory (science) and practice (engineering) to create new and useful products. Worldwide, the process industry (which includes chemicals, petrochemicals, petroleum refining, and pharmaceuticals) is a huge, complex, and interconnected global business with an annual production value exceeding 4 trillion dollars. Although in industry special focus is in heterogeneous catalysis, homogeneous, enzymatic, photochemical and electrochemical catalysis should not be overlooked; as the major aim is to produce certain chemicals in the best possible way, applying those types of catalysis, which suit a particular process in the most optimal way. Catalysis according to the very definition of it deals with enhancement of reaction rates, that is, with catalytic kinetics. This book unifies the main sub disciplines forming the cornerstone of catalytic kinetics. * Provides a broad overview catalytic kinetics* Bridges the gaps that exist between hetero-, homo- and bio-catalysis* Written by internationally renowned experts in this field
Book Synopsis Adsorption Analysis: Equilibria And Kinetics (With Cd Containing Computer Matlab Programs) by : Duong D Do
Download or read book Adsorption Analysis: Equilibria And Kinetics (With Cd Containing Computer Matlab Programs) written by Duong D Do and published by World Scientific. This book was released on 1998-09-22 with total page 915 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers topics of equilibria and kinetics of adsorption in porous media. Fundamental equilibria and kinetics are dealt with for homogeneous as well as heterogeneous particles. Five chapters of the book deal with equilibria and eight chapters deal with kinetics. Single component as well as multicomponent systems are discussed. In kinetics analysis, we deal with the various mass transport processes and their interactions inside a porous particle. Conventional approaches as well as the new approach using Maxwell-Stefan equations are presented. Various methods to measure diffusivity, such as the Differential Adsorption Bed (DAB), the time lag, the diffusion cell, chromatography, and the batch adsorber methods are also covered by the book. It can be used by lecturers and engineers who wish to carry out research in adsorption. A number of programming codes written in MatLab language are included so that readers can use them directly to better understand the behavior of single and multicomponent adsorption systems.
Book Synopsis Thermodynamics and Kinetics in Materials Science by : Boris S. Bokstein
Download or read book Thermodynamics and Kinetics in Materials Science written by Boris S. Bokstein and published by OUP Oxford. This book was released on 2005-06-30 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text presents a concise and thorough introduction to the main concepts and practical applications of thermodynamics and kinetics in materials science. It is designed with two types of uses in mind: firstly for a one or two semester university course for mid- to upper-level undergraduate or first year graduate students in a materials-science-oriented discipline and secondly for individuals who want to study the material on their own. The following major topics are discussed: basic laws of classical and irreversible thermodynamics, phase equilibria, theory of solutions, chemical reaction thermodynamics and kinetics, surface phenomena, stressed systems, diffusion and statistical thermodynamics. A large number of example problems with detailed solutions are included as well as accompanying computer-based self-tests, consisting of over 400 questions and 2000 answers with hints for students. Computer-based laboratories are provided, in which a laboratory problem is posed and the experiment described. The student can "perform" the experiments and change the laboratory conditions to obtain the data required for meeting the laboratory objective. Each "laboratory" is augmented with background material to aid analysis of the experimental results.
Book Synopsis Energy, Society and the Environment by : Ali Salehabadi
Download or read book Energy, Society and the Environment written by Ali Salehabadi and published by Springer Nature. This book was released on 2020-05-21 with total page 104 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive and contemporary overview of advances in energy and energy storage technologies. Although the coverage is varied and diverse, the book also addresses unifying patterns and trends in order to enrich readers’ understanding of energy and energy storage systems, particularly hydrogen energy storage, including e.g. their morphology, porosity and material structure. Readers will also gain insights into the hydrogen storage performance landscape, based on data released by the US Department of Energy (DOE), providing a basis for understanding real-world applications. The book also discusses the superior hydrogen storage performance of solid-state materials and explores the physical and chemical properties that can potentially affect their performance.
Book Synopsis Principles of Adsorption and Reaction on Solid Surfaces by : Richard I. Masel
Download or read book Principles of Adsorption and Reaction on Solid Surfaces written by Richard I. Masel and published by John Wiley & Sons. This book was released on 1996-03-22 with total page 826 pages. Available in PDF, EPUB and Kindle. Book excerpt: Principles of Adsorption and Reaction on Solid Surfaces As with other books in the field, Principles of Adsorption and Reaction on Solid Surfaces describes what occurs when gases come in contact with various solid surfaces. But, unlike all the others, it also explains why. While the theory of surface reactions is still under active development, the approach Dr. Richard Masel takes in this book is to outline general principles derived from thermodynamics and reaction rate theory that can be applied to reactions on surfaces, and to indicate ways in which these principles may be applied. The book also provides a comprehensive treatment of the latest quantitative surface modeling techniques with numerous examples of their use in the fields of chemical engineering, physical chemistry, and materials science. A valuable working resource and an excellent graduate-level text, Principles of Adsorption and Reaction on Solid Surfaces provides readers with: * A detailed look at the latest advances in understanding and quantifying reactions on surfaces * In-depth reviews of all crucial background material * 40 solved examples illustrating how the methods apply to catalysis, physical vapor deposition, chemical vapor deposition, electrochemistry, and more * 340 problems and practice exercises * Sample computer programs * Universal plots of many key quantities * Detailed, class-tested derivations to help clarify key results The recent development of quantitative techniques for modeling surface reactions has led to a number of exciting breakthroughs in our understanding of what happens when gases come in contact with solid surfaces. While many books have appeared describing various experimental modeling techniques and the results obtained through their application, until now, there has been no single-volume reference devoted to the fundamental principles governing the processes observed. The first book to focus on governing principles rather than experimental techniques or specific results, Principles of Adsorption and Reaction on Solid Surfaces provides students and professionals with a quantitative treatment of the application of principles derived from the fields of thermodynamics and reaction rate theory to the investigation of gas adsorption and reaction on solid surfaces. Writing for a broad-based audience including, among others, chemical engineers, chemists, and materials scientists, Dr. Richard I. Masel deftly balances basic background in areas such as statistical mechanics and kinetics with more advanced applications in specialized areas. Principles of Adsorption and Reaction on Solid Surfaces was also designed to provide readers an opportunity to quickly familiarize themselves with all of the important quantitative surface modeling techniques now in use. To that end, the author has included all of the key equations involved as well as numerous real-world illustrations and solved examples that help to illustrate how the equations can be applied. He has also provided computer programs along with universal plots that make it easy for readers to apply results to their own problems with little computational effort. Principles of Adsorption and Reaction on Solid Surfaces is a valuable working resource for chemical engineers, physical chemists, and materials scientists, and an excellent text for graduate students in those disciplines.
Book Synopsis Physisorption Kinetics in Carbon Nanotube Bundles by : Jared T. Burde
Download or read book Physisorption Kinetics in Carbon Nanotube Bundles written by Jared T. Burde and published by . This book was released on 2011 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon nanotube bundles hold great promise for adsorption applications. However, most of the work done thus far has focused on the equilibrium properties of adsorption; the kinetics of adsorption is still not well understood. There also exist large discrepancies in the reported uptake of particles in the internal adsorption sites of carbon nanotube bundles. The purpose of this project was to elucidate the kinetics of adsorption in carbon nanotube bundles and to determine what kinetic factors, if any, may have caused the variations in experimental results. As a result of this project, we now know that the equilibration time of a system depends primarily on the binding energy of the adsorbates and the temperature. Specifically, the highest adsorption rates and shortest equilibration times are observed in systems with low binding energies and high temperatures. We also discovered that equilibration time for internal adsorption phases can be several orders of magnitude larger than those for external phases, which may have led to the disagreements in reported experimental results. Because of this work, we now better understand the process of equilibration.
Book Synopsis Bioprocess Engineering by : Shijie Liu
Download or read book Bioprocess Engineering written by Shijie Liu and published by Elsevier. This book was released on 2020-04-07 with total page 960 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioprocess Engineering: Kinetics, Sustainability, and Reactor Design, Third Edition, is a systematic and comprehensive textbook on bioprocess kinetics, molecular transformation, bioprocess systems, sustainability and reaction engineering. The book reviews the relevant fundamentals of chemical kinetics, batch and continuous reactors, biochemistry, microbiology, molecular biology, reaction engineering and bioprocess systems engineering, introducing key principles that enable bioprocess engineers to engage in the analysis, optimization, selection of cultivation methods, design and consistent control over molecular biological and chemical transformations. The quantitative treatment of bioprocesses is the central theme in this text, however more advanced techniques and applications are also covered. Includes biological molecules and chemical reaction basics, cell biology and genetic engineering Describes kinetics and catalysis at molecular and cellular levels, along with the principles of fermentation Covers advanced topics and treatise in interactive enzyme and molecular regulations, also covering solid catalysis Explores bioprocess kinetics, mass transfer effects, reactor analysis, control and design
Download or read book Physical Adsorption written by L.W. Bruch and published by Courier Dover Publications. This book was released on 2007-03-29 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive account of the phenomena that occur when simple gases interact with surfaces, this text takes a fundamental perspective. Physical adsorption involves atomic or molecular films bound to surfaces by less than 0.5 eV per particle. Physically absorbed thin films exhibit remarkably diverse properties and behave in a manner characteristic of two-dimensional matter. This exploration focuses on monolayer physics, emphasizing atomic rather than molecular adsorption. The phase diagrams of physically absorbed films are diverse and rich in structure because of the subtle and varied competition between the two interactions: the mutual interaction between adsorbed molecules, and the force binding each molecule to the surface. The authors explain the microscopic origin of these forces in terms of constituent electrons and nuclei. They then examine the structural and dynamical properties of these films in the context of atomic and solid-state physics, statistical mechanics, and computer simulations. This text will be of interest to research chemists, physicists, and engineers alike, as well as students in these fields. Key literature citations allow readers to trace important developments, and thought-provoking problems are addressed in detail.
Book Synopsis Adsorption Science and Technology by : D. Do Duong
Download or read book Adsorption Science and Technology written by D. Do Duong and published by World Scientific. This book was released on 2000 with total page 764 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is the proceedings of the second Pacific Basin Conference on Adsorption Science and Technology that was held May 14-18, 2000 in Brisbane, Australia.
Book Synopsis Bio-organic Amendments for Heavy Metal Remediation by : Allah Ditta
Download or read book Bio-organic Amendments for Heavy Metal Remediation written by Allah Ditta and published by Elsevier. This book was released on 2024-07-23 with total page 756 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bio-organic Amendments for Heavy Metal Remediation: Water, soil and plant focuses on these core continuum media to explore remediation options using microbial, organic and combined approached. A volume in the Plant Biology, Sustainability and Climate Change series, this book offers a comprehensive view of techniques and approaches for addressing contamination by heavy metals.As anthropogenic activities increasingly negatively impact natural resources, there has been significant disturbance of water, soil, and plant continuum due to the accumulation of heavy metals. The bioaccumulation of heavy metals in the food chain could pose life-threatening effects on plants as well as humans, and there is need to find effective and sustainable remediation options. The application of bio-organic amendments could serve as a sustainable solution to this problem.Employing microbial, organic and combined approaches to reduce the accumulation of heavy metals in the food chain ultimately would lead to the production of safe food for humans.This book provides a comprehensive view of the challenge with a focus on the bioremediation of heavy metals contamination using ecotechnological approaches to protecting the soil, water and plant continuum. Highlights remediation techniques/approaches for heavy metals under water, soil and plant continuums Presents case-studies for real-world insights as well as current practices Includes regulatory aspects for ensuring safe implementation
Book Synopsis Metal Oxide-Carbon Hybrid Materials by : Muhammad Akram Chaudhry
Download or read book Metal Oxide-Carbon Hybrid Materials written by Muhammad Akram Chaudhry and published by Elsevier. This book was released on 2022-03-20 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Oxide–Carbon Hybrid Materials: Synthesis, Properties and Applications reviews the advances in the fabrication and application of metal oxide–carbon-based nanocomposite materials. Their unique properties make them ideal materials for gas-sensing, photonics, catalysis, opto-electronic, and energy-storage applications. In the first section, the historical background to the hybrid materials based on metal oxide–carbon and the hybridized metal oxide composites is provided. It also highlights several popular methods for the preparation of metal oxide–carbon composites through solid-state or solution-phase reactions, and extensively discusses the materials’ properties. Fossil fuels and renewable energy sources cannot meet the ever-increasing energy demands of an industrialized and technology-driven global society. Therefore, the role of metal oxide–carbon composites in energy generation, hydrogen production, and storage devices, such as rechargeable batteries and supercapacitors, is of extreme importance. These problems are discussed in in the second section of the book. Rapid industrialization has resulted in serious environmental issues which in turn have caused serious health problems that require the immediate attention of researchers. In the third section, the use of metal oxide–carbon composites in water purification, photodegradation of industrial contaminants, and biomedical applications that can help to clean the environment and provide better healthcare solutions is described. The final section is devoted to the consideration of problems associated with the development of sensors for various applications. Numerous studies performed in this area have shown that the use of composites can significantly improve the operating parameters of such devices. Metal Oxide–Carbon Hybrid Materials: Synthesis, Properties and Applications presents a comprehensive review of the science related to metal oxide–carbon composites and how researchers are utilizing these materials to provide solutions to a large array of problems. Reviews the fundamental properties and fabrication methods of metal-oxide–carbon composites Discusses applications in energy, including energy generation, hydrogen production and storage, rechargeable batteries, and supercapacitors Includes current and emerging applications in environmental remediation and sensing
Book Synopsis Lectures on Kinetic Processes in Materials by : Han-Ill Yoo
Download or read book Lectures on Kinetic Processes in Materials written by Han-Ill Yoo and published by Springer Nature. This book was released on 2020-05-09 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides beginning graduate or senior-level undergraduate students in materials disciplines with a primer of the fundamental and quantitative ideas on kinetic processes in solid materials. Kinetics is concerned with the rate of change of the state of existence of a material system under thermodynamic driving forces. Kinetic processes in materials typically involve chemical reactions and solid state diffusion in parallel or in tandem. Thus, mathematics of diffusion in continuum is first dealt with in some depth, followed by the atomic theory of diffusion and a brief review of chemical reaction kinetics. Chemical diffusion in metals and ionic solids, diffusion-controlled kinetics of phase transformations, and kinetics of gas-solid reactions are examined. Through this course of learning, a student will become able to predict quantitatively how fast a kinetic process takes place, to understand the inner workings of the process, and to design the optimal process of material state change. Provides students with the tools to predict quantitatively how fast a kinetic process takes place and solve other diffusion related problems; Learns fundamental and quantitative ideas on kinetic processes in solid materials; Examines chemical diffusion in metals and ionic solids, diffusion-controlled kinetics of phase transformations, and kinetics of gas-solid reactions, among others; Contains end-of chapter exercise problems to help reinforce students' grasp of the concepts presented within each chapter.
Book Synopsis Encyclopedia of Surface and Colloid Science by : P. Somasundaran
Download or read book Encyclopedia of Surface and Colloid Science written by P. Somasundaran and published by CRC Press. This book was released on 2006 with total page 1000 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Handbook of Hydrogen Energy by : S.A. Sherif
Download or read book Handbook of Hydrogen Energy written by S.A. Sherif and published by CRC Press. This book was released on 2014-07-29 with total page 1062 pages. Available in PDF, EPUB and Kindle. Book excerpt: Can hydrogen and electricity supply all of the world’s energy needs? Handbook of Hydrogen Energy thoroughly explores the notion of a hydrogen economy and addresses this question. The handbook considers hydrogen and electricity as a permanent energy system and provides factual information based on science. The text focuses on a large cross section of applications such as fuel cells and catalytic combustion of hydrogen. The book also includes information on inversion curves, physical and thermodynamic tables, and properties of storage materials, data on specific heats, and compressibility and temperature–entropy charts and more. Analyzes the principles of hydrogen energy production, storage, and utilization Examines electrolysis, thermolysis, photolysis, thermochemical cycles, and production from biomass and other hydrogen production methods Covers all modes of hydrogen storage: gaseous, liquid, slush, and metal hydride storage Handbook of Hydrogen Energy serves as a resource for graduate students, as well as a reference for energy and environmental engineers and scientists.
Book Synopsis Polyphenols in Plants by : Ronald Ross Watson
Download or read book Polyphenols in Plants written by Ronald Ross Watson and published by Academic Press. This book was released on 2018-08-14 with total page 442 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyphenols in Plants: Isolation, Purification and Extract Preparation, 2nd edition, provides a detailed insight into polyphenols that occur naturally in plants and how they can be affected during growth and development, then effectively removed and optimized for various applications in food production. Historically, plants have been the major sources for drugs and health promotion. While there are a small number of nutrients contained, the growing focus is on the very diverse, complex ring structures: polyphenols that are not nutritious. In order to study or use them in patient treatment, the polyphenols need to be isolated, identified, and purified for application and study. This book brings together experts in the field who share their ongoing examination of isolation and purification of polyphenols as well as determination of their structures and composition. Polyphenols in Plants covers a range of new topics including polyphenols in vegetable waste and agricultural byproducts, extraction methods and characterization of polyphenols, and isolation techniques in the development of new compounds and their use in cancer therapy. This book will be useful to plant scientists and dietary supplement producers, as well as scientists in the food industry and alternative medicine who are interested in the specific health benefits of various dietary extracts and other polyphenol resources. Fully revised and updated to present the latest developments in the field Advances understanding of isolation, characterization, and identification of critical polyphenols vital to industrial development as therapies Defines conditions of growth affecting polyphenol levels Describes techniques critical to identifying and defining polyphenols
