Ni- and Fe-Based Cross-Coupling Reactions

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Author :
Publisher : Springer
ISBN 13 : 3319497847
Total Pages : 338 pages
Book Rating : 4.3/5 (194 download)

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Book Synopsis Ni- and Fe-Based Cross-Coupling Reactions by : Arkaitz Correa

Download or read book Ni- and Fe-Based Cross-Coupling Reactions written by Arkaitz Correa and published by Springer. This book was released on 2016-11-26 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Cross-Coupling Reactions

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Author :
Publisher : Springer
ISBN 13 : 354045313X
Total Pages : 248 pages
Book Rating : 4.5/5 (44 download)

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Book Synopsis Cross-Coupling Reactions by : Norio Miyaura

Download or read book Cross-Coupling Reactions written by Norio Miyaura and published by Springer. This book was released on 2003-07-01 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1972, a very powerful catalytic cycle for carbon-carbon bond formation was 2 first discovered by the coupling reaction of Grignard reagents at the sp -carbon. Over the past 30 years, the protocol has been substantially improved and expanded to other coupling reactions of Li,B,N,O,Al,Si,P,S,Cu,Mn,Zn,In,Sn, and Hg compounds. These reactions provided an indispensable and simple methodology for preparative organic chemists. Due to the simplicity and rel- bility in the carbon-carbon, carbon-heteroatom, and carbon-metalloid bo- formations,as well as high efficiency of the catalytic process,the reactions have been widely employed by organic chemists in various fields. Application of the protocol ranges from various syntheses of complex natural products to the preparation of biologically relevant molecules including drugs, and of sup- molecules, and to functional materials. The reactions on solid surfaces allow robot synthesis and combinatorial synthesis. Now, many organic chemists do not hesitate to use transition metal complexes for the transformation of org- ic molecules. Indeed, innumerable organic syntheses have been realized by the catalyzed reactions of transition metal complexes that are not achievable by t- ditional synthetic methods. Among these, the metal-catalyzed cross-coupling reactions have undoubtedly contributed greatly to the development of such a new area of “metal-catalyzed organic syntheses”. An excellent monograph for the cross-coupling reactions and other met- catalyzed C-C bond-forming reactions recently appeared in Metal-catalyzed Cross-coupling Reactions (Wiley-VCH,1998).

Applied Cross-Coupling Reactions

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 3642323685
Total Pages : 245 pages
Book Rating : 4.6/5 (423 download)

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Book Synopsis Applied Cross-Coupling Reactions by : Yasushi Nishihara

Download or read book Applied Cross-Coupling Reactions written by Yasushi Nishihara and published by Springer Science & Business Media. This book was released on 2012-12-14 with total page 245 pages. Available in PDF, EPUB and Kindle. Book excerpt: “Applied Cross-Coupling Reactions” provides students and teachers of advanced organic chemistry with an overview of the history, mechanisms and applications of cross-coupling reactions. Since the discovery of the transition-metal-catalyzed cross-coupling reactions in 1972, numerous synthetic uses and industrial applications have been developed. The mechanistic studies of the cross-coupling reactions have disclosed that three fundamental reactions: oxidative addition, transmetalation, and reductive elimination, are involved in a catalytic cycle. Cross-coupling reactions have allowed us to produce a variety of compounds for industrial purposes, such as natural products, pharmaceuticals, liquid crystals and conjugate polymers for use in electronic devices. Indeed, the Nobel Prize for Chemistry in 2010 was awarded for work on cross-coupling reactions. In this book, the recent trends in cross-coupling reactions are also introduced from the point of view of synthesis design and catalytic activities of transition-metal catalysts.

Advances in Cross-Coupling Reactions

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Author :
Publisher : MDPI
ISBN 13 : 3039435671
Total Pages : 234 pages
Book Rating : 4.0/5 (394 download)

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Book Synopsis Advances in Cross-Coupling Reactions by : José Pérez Sestelo

Download or read book Advances in Cross-Coupling Reactions written by José Pérez Sestelo and published by MDPI. This book was released on 2020-12-03 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this Special Issue, recent advances in cross-coupling reactions are presented in the form of original research articles, reviews, and short communications. These contributions cover different topics in this area, including novel coupling reactions, reaction conditions, synthetic alternatives, metal ligands, and applications for new pharmaceutical compounds and organic materials. In particular, the reviews deal with methodologies such as the synthesis of diarylketones through palladium catalysis and the most relevant examples of Suzuki–Miyaura and Buchwald–Hartwig coupling reactions in the synthesis of bioactive compounds. The synthetic utility of cross-coupling reactions for the synthesis of medium-size rings and the utility of Stille and Suzuki coupling reactions for the synthesis of new molecular machines based on sterically hindered anthracenyl trypticenyl units are also summarized. The original research articles present the synthesis of 2-alkynylpyrrols by inverse Sonogashira coupling and the synthesis of indoles under oxidative dearomative cross-dehydrogenative conditions. The efficient combination of iridium-catalyzed C–H borylation of aryl halides with the Sonogashira coupling and a sequential iridium-catalyzed borylation of NH-free pyrroles followed by a Suzuki–Miyaura reaction are included. The synthesis of aryl propionic acids, a common structural motif in medicinal chemistry, and the synthesis of new organic dyes are also covered.

Main Group Metals in Organic Synthesis

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 3527605355
Total Pages : 905 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Main Group Metals in Organic Synthesis by : Hisashi Yamamoto

Download or read book Main Group Metals in Organic Synthesis written by Hisashi Yamamoto and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 905 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the first handbook to cover in detail all aspects of this fascinating field of chemistry. In this handy two-volume set, readers will instantly find the information they need, clearly structured according to the individual metals in the main groups, hitherto only accessible after much time-consuming research. The result is in indispensable aid for everyday work in the lab. Alongside all the classical organic reactions, this book focuses on the modern variations as well as novel, current reactions in organic synthesis that are closely linked to main group elements - both stoechiometric and catalytic. With this work the two prizewinning editors have succeeded in producing a comprehensive compendium of the main group metals as reagents for organic reactions. In short, this is a must for every organic chemist, whether as an efficient introduction to current research, for retaining an overview or for looking up detailed information.

Carbon-Carbon and Carbon-Heteroatom

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Author :
Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 3110759543
Total Pages : 398 pages
Book Rating : 4.1/5 (17 download)

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Book Synopsis Carbon-Carbon and Carbon-Heteroatom by : Rakesh Kumar Sharma

Download or read book Carbon-Carbon and Carbon-Heteroatom written by Rakesh Kumar Sharma and published by Walter de Gruyter GmbH & Co KG. This book was released on 2022-08-22 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon-carbon and carbon-heteroatom bond-forming reactions are the backbone of synthetic organic chemistry. Scientists are constantly developing and improving these techniques in order to maximize the diversity of synthetically available molecules. These techniques must be developed in a sustainable manner in order to limit their environmental impact. This book highlights green carbon-carbon and carbon-heteroatom bond forming reactions.

Nickel Catalysis in Organic Synthesis

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 3527344071
Total Pages : 348 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Nickel Catalysis in Organic Synthesis by : Sensuke Ogoshi

Download or read book Nickel Catalysis in Organic Synthesis written by Sensuke Ogoshi and published by John Wiley & Sons. This book was released on 2020-03-09 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive reference to nickel chemistry for every scientist working with organometallic catalysts Written by one of the world?s leading reseachers in the field, Nickel Catalysis in Organic Synthesis presents a comprehensive review of the high potential of modern nickel catalysis and its application in synthesis. Structured in a clear and assessible manner, the book offers a collection of various reaction types, such as cross-coupling reactions, reactions for the activation of unreactive bonds, carbon dioxide fixation, and many more. Nickel has been recognized as one of the most interesting transition metals for homogeneous catalysis. This book offers an overview to the recently developed new ligands, new reaction conditions, and new apparatus to control the reactivity of nickel catalysts, allowing scientists to apply nickel catalysts to a variety of bond-forming reactions. A must-read for anyone working with organometallic compounds and their application in organic synthesis, this important guide: -Reviews the numerous applications of nickel catalysis in synthesis -Explores the use of nickel as a relatively cheap and earth-abundant metal -Examines the versatility of nickel catalysis in reactions like cross-coupling reactions and CH activations -Offers a resource for academics and industry professionals Written for catalytic chemists, organic chemists, inorganic chemists, structural chemists, and chemists in industry, Nickel Catalysis in Organic Synthesis provides a much-needed overview of the most recent developments in modern nickel catalysis and its application in synthesis.

The Chemistry of Phenols, 2 Volume Set

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Author :
Publisher : Wiley-Interscience
ISBN 13 :
Total Pages : 866 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis The Chemistry of Phenols, 2 Volume Set by : Zvi Rappoport

Download or read book The Chemistry of Phenols, 2 Volume Set written by Zvi Rappoport and published by Wiley-Interscience. This book was released on 2003-09-11 with total page 866 pages. Available in PDF, EPUB and Kindle. Book excerpt: As phenols represent an important functional group category, The Chemistry of Phenols is an essential addition to any chemistry library. Written by experts, all aspects concerning these compounds are covered making this an essential reference book, bringing together invaluable information into one source for organic, organometallic chemists as well as chemists from a variety of other organic sub-disciplines. Single Source information – essential for organic, organometallic and chemists from organic sub-disciplines Covers phenols as anti-oxidants, synthetic intermediates, polymers and hydrogen bonds Discusses electrophilic and photochemical reactions The Patai Series publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopic methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical and environmental aspects. To date, over 100 volumes have been published in the series. Also Available Online The Chemistry of Phenols as well as the other titles within the Patai Series is also available in electronic format on Wiley InterScience. All new titles will be published online and a growing list of older titles will be added every year.

Organic Reactions, Volume 100

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 1119456665
Total Pages : 1130 pages
Book Rating : 4.1/5 (194 download)

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Book Synopsis Organic Reactions, Volume 100 by :

Download or read book Organic Reactions, Volume 100 written by and published by John Wiley & Sons. This book was released on 2019-12-05 with total page 1130 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by a "who is who" of leading organic chemists, this anniversary volume represent the Organic Reactions editors' choice of the most important, ground-breaking and versatile reactions in current organic synthesis. The 15 reaction types selected for this volume include reactions for carbon-carbon bond formation, cross-coupling reactions, hydro- and halofunctionalizations, among many others. In line with the successful recipe of the series, each chapter is focused on a single reaction, discussing its mechanism and stereochemistry, scope and limitations, applications to synthesis, comparison with other methods, and experimental procedures. Each chapter concludes with a tabular survey of selected key application examples, complete with reported reaction conditions and yields, to serve as a quick reference guide for synthesis planning.

Cross-Coupling Reactions

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 3540421750
Total Pages : 253 pages
Book Rating : 4.5/5 (44 download)

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Book Synopsis Cross-Coupling Reactions by : S.L. Buchwald

Download or read book Cross-Coupling Reactions written by S.L. Buchwald and published by Springer Science & Business Media. This book was released on 2002-01-11 with total page 253 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1972, a very powerful catalytic cycle for carbon-carbon bond formation was 2 first discovered by the coupling reaction of Grignard reagents at the sp -carbon. Over the past 30 years, the protocol has been substantially improved and expanded to other coupling reactions of Li,B,N,O,Al,Si,P,S,Cu,Mn,Zn,In,Sn, and Hg compounds. These reactions provided an indispensable and simple methodology for preparative organic chemists. Due to the simplicity and rel- bility in the carbon-carbon, carbon-heteroatom, and carbon-metalloid bo- formations,as well as high efficiency of the catalytic process,the reactions have been widely employed by organic chemists in various fields. Application of the protocol ranges from various syntheses of complex natural products to the preparation of biologically relevant molecules including drugs, and of sup- molecules, and to functional materials. The reactions on solid surfaces allow robot synthesis and combinatorial synthesis. Now, many organic chemists do not hesitate to use transition metal complexes for the transformation of org- ic molecules. Indeed, innumerable organic syntheses have been realized by the catalyzed reactions of transition metal complexes that are not achievable by t- ditional synthetic methods. Among these, the metal-catalyzed cross-coupling reactions have undoubtedly contributed greatly to the development of such a new area of “metal-catalyzed organic syntheses”. An excellent monograph for the cross-coupling reactions and other met- catalyzed C-C bond-forming reactions recently appeared in Metal-catalyzed Cross-coupling Reactions (Wiley-VCH,1998).

C-C Cross Couplings with 3d Base Metal Catalysts

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Author :
Publisher : Springer Nature
ISBN 13 : 3031328671
Total Pages : 403 pages
Book Rating : 4.0/5 (313 download)

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Book Synopsis C-C Cross Couplings with 3d Base Metal Catalysts by : Xiao-Feng Wu

Download or read book C-C Cross Couplings with 3d Base Metal Catalysts written by Xiao-Feng Wu and published by Springer Nature. This book was released on 2023-06-13 with total page 403 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume presents recent progress on 3d base metal catalyzed C-C cross coupling reactions. The contributions provide detailed discussions on the use of cheap metal catalysts such as Cr, Mn, Fe, Co, Ni, Cu, and Zn to construct Csp2-Csp2, Csp2-Csp3 and Csp3-Csp3 bonds with a variety of substrates. These non-noble metal catalyst have many advantages such as being inexpensive, having low toxicity and are environmentally benign. Therefore the use of cheap metal catalysts in organic synthesis has gained much attention in efforts to develop more sustainable synthetic green chemistry. Each chapter is written by international experts in the field and is a great resource for students, researchers and chemists working in industry to gain an overview on the latest developments.

Perfluoroalkyl Substances

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Author :
Publisher : Royal Society of Chemistry
ISBN 13 : 1839165685
Total Pages : 651 pages
Book Rating : 4.8/5 (391 download)

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Book Synopsis Perfluoroalkyl Substances by : Bruno Améduri

Download or read book Perfluoroalkyl Substances written by Bruno Améduri and published by Royal Society of Chemistry. This book was released on 2022-08-15 with total page 651 pages. Available in PDF, EPUB and Kindle. Book excerpt: This title provides a balanced overview of the field, from basic synthesis through to applications, why some current PFASs are and may remain the right substance for the job, as well as addressing the challenges and alternatives.

Amide Bond Activation

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 352783026X
Total Pages : 533 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Amide Bond Activation by : Michal Szostak

Download or read book Amide Bond Activation written by Michal Szostak and published by John Wiley & Sons. This book was released on 2022-10-18 with total page 533 pages. Available in PDF, EPUB and Kindle. Book excerpt: Amide Bond Activation Comprehensive resource on the pivotal role of the amide bond in organic synthesis This book provides the reader with insight into the advances that have taken place in the field of amide bond activation. It focuses on both the fundamental structural properties of the amide bond and the synthetic reactions mediated by transition-metals. By discussing amide bond activation in terms of modern organic synthesis, the reader is provided with a thorough overview of the area and its crucial role in forging carbon-carbon and carbon-heteroatom bonds. Sample topics discussed within the work include: Cross-coupling of amides Amide bond activation by twisting and nitrogen pyramidalization Electrophilic amide bond functionalization Transition metal-catalyzed radical reactions of amides Amide bond esterification, hydrolysis and transamidation Classical bridged lactams and anomeric amides Computational studies of amide C-N bond activation Cross-coupling of esters by C-O activation The book is immensely valuable to synthetic chemists in academia and the pharmaceutical industry who wish to gain an in-depth understanding of the concept of amide bond activation.

Organozinc Derivatives and Transition Metal Catalysts

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Author :
Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 311072894X
Total Pages : 305 pages
Book Rating : 4.1/5 (17 download)

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Book Synopsis Organozinc Derivatives and Transition Metal Catalysts by : Janine Cossy

Download or read book Organozinc Derivatives and Transition Metal Catalysts written by Janine Cossy and published by Walter de Gruyter GmbH & Co KG. This book was released on 2023-05-22 with total page 305 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organozinc reagents are less reactive than Grignard reagents but they are much more chemoselective. Since the Negishi cross-coupling reaction developed by Ei-ichi Negishi, who was awarded the Nobel Price in chemistry in 2010, a number of cross-coupling reactions involving organozinc derivatives and transition metal catalysts (Pd, Ni, Fe, Co, Cu, ...) has been tuned up to form C-C bonds. This book on "Organozinc derivatives and transition metal catalysts" has been written by experts in the field and is a complement to the book entitled "Grignard reagents and transition metal catalysts" (a De Gruyter book, edited by J. Cossy). Grignard reagents or organozinc reagents, that is the question? From a given substrate, what is the best organometallic reagent and the best transition metal to form a C-C bond by using a cross-coupling reaction? The solution might be found in these two books.

Organic Nanochemistry

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 111887045X
Total Pages : 292 pages
Book Rating : 4.1/5 (188 download)

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Book Synopsis Organic Nanochemistry by : Yuming Zhao

Download or read book Organic Nanochemistry written by Yuming Zhao and published by John Wiley & Sons. This book was released on 2024-01-18 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: ORGANIC NANOCHEMISTRY How-to guide for entry-level practitioners to quickly learn the cutting-edge research concepts and methodologies of modern organic nanochemistry Organic Nanochemistry describes the fundamentals of organic nanochemistry research, encompassing modern synthetic reactions, supramolecular strategies, nanostructure and property characterization techniques, and state-of-the-art data analysis and processing methods, along with synthetic chemistry as applied to organic nanomaterials and molecular devices. Accompanying each of these principles are case studies (from basic design to detailed experimental implementation) to help the reader fully comprehend the concepts and methods involved. Various theories suitable for nanoscale simulations, including quantum mechanics, semi-empirical quantum mechanics, and molecular dynamics theories, are discussed at an introductory level. Computational examples are provided, allowing interested readers to grasp essential modelling techniques for better understanding of organic nanochemistry. The content is paired with online supplementary material that includes instructional materials and guides to using common scientific software for computational modelling and simulations. Written by a highly qualified professor, Organic Nanochemistry includes discussion on: Key concepts and theories of organic chemistry, which are essential to understand the fundamental properties of organic molecular and supramolecular systems Useful synthetic methodologies for the synthesis and functionalization of organic nanomaterials, and the chemistry and application of exotic carbon nanomaterials Supramolecular aspects in organic nanochemistry, especially the well-developed disciplines of host-guest chemistry and organic self-assembly chemistry Construction and testing of molecular devices and molecular machines and state-of-the-art computational modelling methods for properties of nanoscale organic systems Guiding the reader on a journey from familiar chemical concepts and principles to cutting-edge research of nano-science and technology, Organic Nanochemistry serves as an excellent textbook learning resource for advanced and graduate students, as well as a self-study guide or how-to reference for practicing chemists.

Colloidal Metal Oxide Nanoparticles

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Author :
Publisher : Elsevier
ISBN 13 : 0128133589
Total Pages : 608 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Colloidal Metal Oxide Nanoparticles by :

Download or read book Colloidal Metal Oxide Nanoparticles written by and published by Elsevier. This book was released on 2019-10-16 with total page 608 pages. Available in PDF, EPUB and Kindle. Book excerpt: Colloidal Metal Oxide Nanoparticles: Synthesis, Characterization and Applications is a one-stop reference for anyone with an interest in the fundamentals, synthesis and applications of this interesting materials system. The book presents a simple, effective and detailed discussion on colloidal metal oxide nanoparticles. It begins with a general introduction of colloidal metal oxide nanoparticles, then delves into the most relevant synthesis pathways, stabilization procedures, and synthesis and characterization techniques. Final sections discuss promising applications, including bioimaging, biosensing, diagnostic, and energy applications—i.e., solar cells, supercapacitors and environment applications—i.e., the treatment of contaminated soil, water purification and waste remediation. Provides the most comprehensive resource on the topic, from fundamentals, to synthesis and characterization techniques Presents key applications, including biomedical, energy, electronic and environmental Discusses the most relevant techniques for synthesis, patterning and characterization

Metal-catalyzed Cross-coupling Reactions

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 3527612203
Total Pages : 540 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Metal-catalyzed Cross-coupling Reactions by : François Diederich

Download or read book Metal-catalyzed Cross-coupling Reactions written by François Diederich and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon-carbon bond forming reactions are arguably the most important processes in chemistry, as they represent key steps in the building of complex molecules from simple precursors. Among these reactions, metal-catalyzed cross-coupling reactions are extensively employed in a wide range of areas of preparative organic chemistry, ranging from the synthesis of complex natural products, to supramolecular chemistry, and materials science. In this work, a dozen internationally renowned experts and leaders in the field bring the reader up to date by documenting and critically analyzing current developments and uses of metal-catalyzed cross-coupling reactions. A particularly attractive and useful feature, that enhances the practical value of this monograph, is the inclusion of key synthetic protocols, in experimental format, chosen for broad utility and application. This practice-oriented book can offer the practitioner short cuts to ensure they remain up-to-date with the latest developments.