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Metal Organic Frameworks For Gas Storage And Separation
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Book Synopsis Functional Metal-Organic Frameworks: Gas Storage, Separation and Catalysis by : Martin Schröder
Download or read book Functional Metal-Organic Frameworks: Gas Storage, Separation and Catalysis written by Martin Schröder and published by Springer Science & Business Media. This book was released on 2010-09-07 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: - Microporous Organic Polymers: Design, Synthesis, and Function By J.-X. Jiang and A. I. Cooper - Hydrogen, Methane and Carbon Dioxide Adsorption in Metal-Organic Framework Materials By X. Lin, N. R. Champness, and M. Schröder -Doping of Metal-Organic Frameworks with Functional Guest Molecules and Nanoparticles By F. Schröder and R. A. Fischer -Chiral Metal-Organic Porous Materials: Synthetic Strategies and Applications in Chiral Separation and Catalysis By K. Kim, M. Banerjee, M. Yoon, and S. Das -Controlled Polymerization by Incarceration of Monomers in Nanochannels By T. Uemura and S. Kitagawa -Designing Metal-Organic Frameworks for Catalytic Applications L. Ma and W. Lin -Magnetic and Porous Molecule-Based Materials By N. Roques, V. Mugnaini, and J. Veciana
Book Synopsis Metal-Organic Frameworks by : David Farrusseng
Download or read book Metal-Organic Frameworks written by David Farrusseng and published by John Wiley & Sons. This book was released on 2011-09-19 with total page 415 pages. Available in PDF, EPUB and Kindle. Book excerpt: An international and interdisciplinary team of leading experts from both academia and industry report on the wide range of hot applications for MOFs, discussing both the advantages and limits of the material. The resulting overview covers everything from catalysis, H2 and CH4 storage and gas purification to drug delivery and sensors. From the Contents: - Design of Porous Coordination Polymers/Metal-Organic Frameworks: Past, Present and Future - Design of Functional Metal-Organic Frameworks by Post-Synthetic Modification - Thermodynamic Methods for Prediction of Gas Separation in Flexible Frameworks - Separation and purification of gases by MOFs - Opportunities for MOFs in CO2 capture from flue gases, natural gas and syngas by adsorption - Manufacture of MOF thin films on structured supports for separation and catalysis - Research status of Metal-Organic Frameworks for on-board cryo-adsorptive hydrogen storage applications - Separation of xylene isomers - Metal-Organic Frameworks as Catalysts for Organic Reactions - Biomedical applications of Metal Organic Frameworks - Metal Organic Frameworks for Biomedical Imaging - Luminescent Metal-Organic Frameworks - Deposition of thin films for sensor applications - Industrial MOF Synthesis - MOF shaping and immobilisation A must-have for every scientist in the field.
Book Synopsis Gas Adsorption in Metal-Organic Frameworks by : T. Grant Glover
Download or read book Gas Adsorption in Metal-Organic Frameworks written by T. Grant Glover and published by CRC Press. This book was released on 2018-09-03 with total page 530 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text discusses the synthesis, characterization, and application of metal-organic frameworks (MOFs) for the purpose of adsorbing gases. It provides details on the fundamentals of thermodynamics, mass transfer, and diffusion that are commonly required when evaluating MOF materials for gas separation and storage applications and includes a discussion of molecular simulation tools needed to examine gas adsorption in MOFs. Additionally, the work presents techniques that can be used to characterize MOFs after gas adsorption has occurred and provides guidance on the water stability of these materials. Lastly, applications of MOFs are considered with a discussion of how to measure the gas storage capacity of MOFs, a discussion of how to screen MOFs to for filtration applications, and a discussion of the use of MOFs to perform industrial separations, such as olefin/paraffin separations. Throughout the work, fundamental information, such as a discussion on the calculation of MOF surface area and description of adsorption phenomena in packed-beds, is balanced with a discussion of the results from research literature.
Book Synopsis Metal-Organic Framework Materials by : Leonard R. MacGillivray
Download or read book Metal-Organic Framework Materials written by Leonard R. MacGillivray and published by John Wiley & Sons. This book was released on 2014-09-19 with total page 1210 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis. Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc
Book Synopsis Metal-Organic Frameworks for Gas Storage and Separation by : Jarad Adam Mason
Download or read book Metal-Organic Frameworks for Gas Storage and Separation written by Jarad Adam Mason and published by . This book was released on 2015 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt: The work presented in this dissertation describes the design, synthesis, and characterization of metal-organic frameworks for applications in gas storage and gas separations, with a specific focus on natural gas and hydrogen storage for mobile applications and on post-combustion carbon dioxide capture from coal- or natural gas-fired power plants. A wide variety of techniques and spectroscopic methods are covered, including gas adsorption, x-ray diffraction, infrared and UV-vis-NIR spectroscopies, and calorimetry. Chapter One provides a brief introduction to metal-organic frameworks as a new class of porous materials for gas adsorption-related applications. The potential of metal-organic frameworks for use in post-combustion carbon dioxide capture and natural gas storage is discussed, and the unique and promising properties of adsorbents with stepped adsorption isotherms for these applications are highlighted. In Chapter Two, two representative metal-organic frameworks, Zn4O(BTB)2 (BTB3- = 1,3,5-benzenetribenzoate; MOF-177) and Mg2(dobdc) (dobdc4- = 1,4-dioxido-2,5-benzenedicarboxylate; Mg-MOF-74, CPO-27-Mg), are evaluated in detail for their potential use in post-combustion CO2 capture via temperature swing adsorption (TSA). Low-pressure single-component CO2 and N2 adsorption isotherms were measured every 10 °C from 20 to 200 °C, allowing the performance of each material to be analyzed precisely. In order to gain a more complete understanding of the separation phenomena and the thermodynamics of CO2 adsorption, the isotherms were analyzed using a variety of methods. These results show that the presence of strong CO2 adsorption sites is essential for a metal-organic framework to be of utility in post-combustion CO2 capture via a TSA process, and present a methodology for the evaluation of new metal-organic frameworks via analysis of single-component gas adsorption isotherms. Chapter Three briefly discusses high-pressure adsorption measurements and reviews efforts to develop metal-organic frameworks with high methane storage capacities. To illustrate the most important properties for evaluating adsorbents for natural gas storage and for designing a next generation of improved materials, six metal-organic frameworks and an activated carbon, with a range of surface areas, pore structures, and surface chemistries representative of the most promising adsorbents for methane storage, are evaluated in detail. High-pressure methane adsorption isotherms are used to compare gravimetric and volumetric capacities, isosteric heats of adsorption, and usable storage capacities. Additionally, the relative importance of increasing volumetric capacity, rather than gravimetric capacity, for extending the driving range of natural gas vehicles is highlighted. Other important systems-level factors, such as thermal management, mechanical properties, and the effects of impurities, are also considered, and potential materials synthesis contributions to improving performance in a complete adsorbed natural gas system are discussed. Chapter Four discusses the design and validation of a high-throughput multicomponent adsorption instrument that can measure equilibrium adsorption isotherms for mixtures of gases at conditions that are representative of an actual flue gas from a power plant. This instrument is used to study 15 different metal-organic frameworks, zeolites, mesoporous silicas, and activated carbons representative of the broad range of solid adsorbents that have received attention for CO2 capture. While the multicomponent results provide many interesting fundamental insights, only adsorbents functionalized with alkylamines are shown to have any significant CO2 capacity in the presence of N2 and H2O at equilibrium partial pressures similar to those expected in a carbon capture process. Most significantly, the amine-appended metal organic framework mmen-Mg2(dobpdc) (mmen = N,N′-dimethylethylenediamine, dobpdc4– = 4,4′-dioxido-3,3′-biphenyldicarboxylate) exhibits a record CO2 capacity of 4.2±0.2 mmol/g (16 wt %) at 0.1 bar and 40 °C in the presence of a high partial pressure of H2O. In Chapter Five, the flexible metal-organic frameworks M(bdp) (M = Fe, Co; bdp2– = 1,4-benzene-dipyrazolate) are shown to exhibit methane adsorption isotherms that feature a sharp step, giving rise to unprecedented performance characteristics for ambient temperature methane storage. Adsorption measurements combined with in situ powder X-ray diffraction and microcalorimetry experiments performed on Co(bdp) demonstrate a new approach to designing adsorbents for gas storage, wherein a reversible phase transition is used to achieve a high deliverable capacity while providing intrinsic thermal management. Importantly, the energy of the phase transition, together with the adsorption and desorption step pressures, can be controlled through variations in the framework structure, such as replacing Co with Fe, or by application of mechanical pressure. This approach overcomes many of the challenges to developing adsorbents for natural gas storage discussed in Chapter Three and is also relevant to other gas storage applications. Chapter Six discusses the synthesis and characterization of a new Ti(III) metal-organic framework that is constructed from 1,4-benzenedicarboxylate bridged Ti3O(COO)6 clusters. While many metal-organic frameworks have been synthesized with exposed divalent metal cations, there are comparatively few examples of metal-organic frameworks with coordinatively unsaturated trivalent metal centers. Among other potential applications, frameworks with exposed trivalent metal cations are of particular interest for ambient temperature H2 storage. Additionally, there are also very few reported titanium-based metal-organic frameworks and none that contain all titanium(III). Through a combination of adsorption measurements, diffraction analysis, EPR, infrared, and UV-vis-NIR spectroscopies, and magnetic measurements, this framework is shown to contain five-coordinate Ti3+ cations that irreversibly bind O2 to form titanium(IV)-superoxo and -peroxo species.
Book Synopsis Functional Metal-Organic Frameworks by : Martin Schr Der
Download or read book Functional Metal-Organic Frameworks written by Martin Schr Der and published by . This book was released on 2010-09-18 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Industrial Gas Handbook by : Frank G. Kerry
Download or read book Industrial Gas Handbook written by Frank G. Kerry and published by CRC Press. This book was released on 2007-02-22 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt: Drawing on Frank G. Kerry's more than 60 years of experience as a practicing engineer, the Industrial Gas Handbook: Gas Separation and Purification provides from-the-trenches advice that helps practicing engineers master and advance in the field. It offers detailed discussions and up-to-date approaches to process cycles for cryogenic separation of
Book Synopsis Gas Storage and Separations in Metal-Organic Frameworks with Open Metal Sites by : Eric Douglas Bloch
Download or read book Gas Storage and Separations in Metal-Organic Frameworks with Open Metal Sites written by Eric Douglas Bloch and published by . This book was released on 2014 with total page 123 pages. Available in PDF, EPUB and Kindle. Book excerpt: The work presented in this dissertation describes the synthesis and characterization of metal-organic frameworks for gas storage and separation applications. A specific class of materials investigated is metal-organic frameworks containing coordinatively-unsaturated metal cation sites, as these sites perform the bulk of the work for the separations discussed. A wide variety of techniques and spectroscopic methods are covered, including gas adsorption, structural analysis, infrared and Mössbauer spectroscopies, and breakthrough experiments.
Book Synopsis Metal-Organic Frameworks by : Hermenegildo García
Download or read book Metal-Organic Frameworks written by Hermenegildo García and published by John Wiley & Sons. This book was released on 2018-07-16 with total page 530 pages. Available in PDF, EPUB and Kindle. Book excerpt: Focusing on applications in separation, adsorption and catalysis, this handbook underlines the importance of this hot and exciting topic. It provides an excellent insight into the synthesis and modification of MOFs, their synthesis on an industrial scale, their use as CO2 and chemical warfare adsorbers, and the role of defects in catalysis. In addition, the authors treat such new aspects as biocatalysis and applications in photocatalysis and optoelectronic devices.
Book Synopsis Metal-Organic Frameworks by : Leonard R. MacGillivray
Download or read book Metal-Organic Frameworks written by Leonard R. MacGillivray and published by John Wiley & Sons. This book was released on 2010-12-17 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-organic frameworks represent a new class of materials that may solve the hydrogen storage problem associated with hydrogen-fueled vehicles. In this first definitive guide to metal-organic framework chemistry, author L. MacGillivray addresses state-of-art developments in this promising technology for alternative fuels. Providing professors, graduate and undergraduate students, structural chemists, physical chemists, and chemical engineers with a historical perspective, as well as the most up-to-date developments by leading experts, Metal-Organic Frameworks examines structure, symmetry, supramolecular chemistry, surface engineering, metal-organometallic frameworks, properties, and reactions.
Book Synopsis Introduction to Reticular Chemistry by : Omar M. Yaghi
Download or read book Introduction to Reticular Chemistry written by Omar M. Yaghi and published by John Wiley & Sons. This book was released on 2019-03-22 with total page 684 pages. Available in PDF, EPUB and Kindle. Book excerpt: A concise introduction to the chemistry and design principles behind important metal-organic frameworks and related porous materials Reticular chemistry has been applied to synthesize new classes of porous materials that are successfully used for myraid applications in areas such as gas separation, catalysis, energy, and electronics. Introduction to Reticular Chemistry gives an unique overview of the principles of the chemistry behind metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and zeolitic imidazolate frameworks (ZIFs). Written by one of the pioneers in the field, this book covers all important aspects of reticular chemistry, including design and synthesis, properties and characterization, as well as current and future applications Designed to be an accessible resource, the book is written in an easy-to-understand style. It includes an extensive bibliography, and offers figures and videos of crystal structures that are available as an electronic supplement. Introduction to Reticular Chemistry: -Describes the underlying principles and design elements for the synthesis of important metal-organic frameworks (MOFs) and related materials -Discusses both real-life and future applications in various fields, such as clean energy and water adsorption -Offers all graphic material on a companion website -Provides first-hand knowledge by Omar Yaghi, one of the pioneers in the field, and his team. Aimed at graduate students in chemistry, structural chemists, inorganic chemists, organic chemists, catalytic chemists, and others, Introduction to Reticular Chemistry is a groundbreaking book that explores the chemistry principles and applications of MOFs, COFs, and ZIFs.
Book Synopsis Metal-organic Framework Membranes For Molecular Gas Separations by : Moises A Carreon
Download or read book Metal-organic Framework Membranes For Molecular Gas Separations written by Moises A Carreon and published by World Scientific. This book was released on 2020-07-30 with total page 283 pages. Available in PDF, EPUB and Kindle. Book excerpt: This unique compendium describes research progress on metal-organic framework (MOF) membranes for different relevant industrial gas separations. Specifically, the book focuses mainly on gas separations which are important in flue gas treatment, natural gas purification, hydrogen purification, and nuclear reprocessing. The advantages of using MOFs in mixed matrix membranes are discussed. Some of the pressing challenges in the field, and strategies to potentially overcome them are also distinctly outlined.This volume is a useful reference materials for professionals, academics, researchers and postgraduate students in chemical engineering and materials engineering.
Book Synopsis Hybrid Metal-Organic Framework and Covalent Organic Framework Polymers by : Bo Wang
Download or read book Hybrid Metal-Organic Framework and Covalent Organic Framework Polymers written by Bo Wang and published by Royal Society of Chemistry. This book was released on 2021-11-12 with total page 313 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal–organic frameworks (MOFs) are crystalline porous materials constructed from metal ions/clusters and organic linkers, combining the merits of both organic and inorganic components. Due to high porosity, rich functionalities, well-defined open channels and diverse structures, MOFs show great potentials in field such as gas storage and separation, catalysis, and sensing. Combining them with polymers tunes their chemical, mechanical, electrical and optical properties, and endows MOFs with processability. Covalent organic frameworks (COFs) are crystalline porous materials built from organic molecular units with diverse structures and applications. Hybrid materials with intriguing properties can be achieved by appropriate preparation methods and careful selection of MOFs/COFs and polymers, broadening their potential applications. This book documents the latest research progress in MOF/COF-polymer hybrid materials and reviews and summarises hybridization strategies to achieve MOF/COF polymeric composites. It also introduces various applications and potential applicable scenarios of hybrid MOF/COF polymers. Hybrid Metal–Organic Framework and Covalent Organic Framework Polymers offers an overview to readers who are new to this field, and will appeal to graduate students and researchers working on porous materials, polymers, hybrid materials, and supramolecular chemistry.
Book Synopsis Fabrication of Metal–Organic Framework Derived Nanomaterials and Their Electrochemical Applications by : Wei Xia
Download or read book Fabrication of Metal–Organic Framework Derived Nanomaterials and Their Electrochemical Applications written by Wei Xia and published by Springer. This book was released on 2018-04-03 with total page 148 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis systematically introduces readers to a new metal-organic framework approach to fabricating nanostructured materials for electrochemical applications. Based on the metal-organic framework (MOF) approach, it also demonstrates the latest ideas on how to create optimal MOF and MOF-derived nanomaterials for electrochemical reactions under controlled conditions. The thesis offers a valuable resource for researchers who want to understand electrochemical reactions at nanoscale and optimize materials from rational design to achieve enhanced electrochemical performance. It also serves as a useful reference guide to fundamental research on advanced electrochemical energy storage materials and the synthesis of nanostructured materials.
Book Synopsis Metal-Organic Frameworks by : Jianwen Jiang
Download or read book Metal-Organic Frameworks written by Jianwen Jiang and published by Pan Stanford. This book was released on 2015-01-28 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-organic frameworks (MOFs) have emerged as a new family of nanoporous materials. With an enormous choice of inorganic/organic building blocks, MOFs possess a wide range of surface area, pore size, and functionality and, thus, have been considered versatile materials for many potential applications. This book presents a broad collection of recent modeling studies in the field of MOFs toward potential engineering applications, such as gas storage/separation, carbon capture, catalysis, water purification, and drug delivery. The subject of this book renders it unique, for while the various topics on MOFs boast vast literature, there is not yet a single coherent collection for modeling endeavors. The book will appeal to scientists, engineers, and students in the multidisciplinary intersections of materials science, chemistry, and engineering.
Book Synopsis Metal-Organic Frameworks (MOFs) for Environmental Applications by : Sujit K. Ghosh
Download or read book Metal-Organic Frameworks (MOFs) for Environmental Applications written by Sujit K. Ghosh and published by Elsevier. This book was released on 2019-06-07 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Organic Frameworks for Environmental Applications examines this important topic, looking at potential materials and methods for the remediation of pressing pollution issues, such as heavy-metal contaminants in water streams, radioactive waste disposal, marine oil-spillage, the treatment of textile and dye industry effluents, the clean-up of trace amounts of explosives in land and water, and many other topics. This survey of the cutting-edge research and technology of MOFs is an invaluable resource for researchers working in inorganic chemistry and materials science, but it is also ideal for graduate students studying MOFs and their applications. Examines the applications of metal-organic frameworks for the remediation of environmental pollutants Features leading experts who research the applications of MOFs from around the world, including contributions from the United States, India and China Explores possible solutions to some of today’s most pressing environmental challenges, such as heavy-metal contamination in bodies of water, oil spills and clean-up of explosives hidden in land and water Provides an excellent reference for researchers and graduate students studying in the areas of inorganic chemistry, materials chemistry and environmental science
Book Synopsis Introduction to Machine Learning by : Ethem Alpaydin
Download or read book Introduction to Machine Learning written by Ethem Alpaydin and published by MIT Press. This book was released on 2014-08-22 with total page 639 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction -- Supervised learning -- Bayesian decision theory -- Parametric methods -- Multivariate methods -- Dimensionality reduction -- Clustering -- Nonparametric methods -- Decision trees -- Linear discrimination -- Multilayer perceptrons -- Local models -- Kernel machines -- Graphical models -- Brief contents -- Hidden markov models -- Bayesian estimation -- Combining multiple learners -- Reinforcement learning -- Design and analysis of machine learning experiments.
