Mechanistic Studies Of Cu Catalyzed Aerobic Oxidation Reactions

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Liquid Phase Aerobic Oxidation Catalysis

Author : Shannon S. Stahl
Publisher : John Wiley & Sons
ISBN 13 : 3527337814
Total Pages : 454 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Liquid Phase Aerobic Oxidation Catalysis by : Shannon S. Stahl

Download or read book Liquid Phase Aerobic Oxidation Catalysis written by Shannon S. Stahl and published by John Wiley & Sons. This book was released on 2016-10-10 with total page 454 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock. With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.

Oxidative Cross-Coupling Reactions

Author : Aiwen Lei
Publisher : John Wiley & Sons
ISBN 13 : 3527681019
Total Pages : 240 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Oxidative Cross-Coupling Reactions by : Aiwen Lei

Download or read book Oxidative Cross-Coupling Reactions written by Aiwen Lei and published by John Wiley & Sons. This book was released on 2016-08-12 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first handbook on this emerging field provides a comprehensive overview of transition metal-catalyzed coupling reactions in the presence of an oxidant. Following an introduction to the general concept and mechanism of this reaction class, the team of authors presents chapters on C-C cross-coupling reactions using organometallic partners, C-Heteroatom bond forming reactions via oxidative couplings, and C-H couplings via C-H activation. The text also covers such groundbreaking topics as recent achievements in the fields of C-C and C-X bond formation reactions as well as C-H activation involving oxidative couplings. With its novel and concise approach towards important building blocks in organic chemistry and its focus on synthetic applications, this handbook is of great interest to all synthetic chemists in academia and industry alike.

Copper-Mediated Cross-Coupling Reactions

Author : Gwilherm Evano
Publisher : John Wiley & Sons
ISBN 13 : 1118060458
Total Pages : 851 pages
Book Rating : 4.1/5 (18 download)

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Book Synopsis Copper-Mediated Cross-Coupling Reactions by : Gwilherm Evano

Download or read book Copper-Mediated Cross-Coupling Reactions written by Gwilherm Evano and published by John Wiley & Sons. This book was released on 2013-11-11 with total page 851 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing comprehensive insight into the use of copper in cross-coupling reactions, Copper-Mediated Cross-Coupling Reactions provides a complete up-to-date collection of the available reactions and catalytic systems for the formation of carbon-heteroatom and carbon-carbon bonds. This essential reference covers a broad scope of copper-mediated reactions, their variations, key advances, improvements, and an array of academic and industrial applications that have revolutionized the field of organic synthesis. The text also discusses the mechanism of these transformations, the use of copper as cost-efficient alternative to palladium, as well as recently developed methods for conducting copper-mediated reactions with supported catalysts.

Mechanistic Studies of Palladium-catalyzed Aerobic Alcohol Oxidation

Author : Bradley A. Steinhoff
Publisher :
ISBN 13 :
Total Pages : 254 pages
Book Rating : 4.:/5 (89 download)

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Book Synopsis Mechanistic Studies of Palladium-catalyzed Aerobic Alcohol Oxidation by : Bradley A. Steinhoff

Download or read book Mechanistic Studies of Palladium-catalyzed Aerobic Alcohol Oxidation written by Bradley A. Steinhoff and published by . This book was released on 2005 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Oxidation of Primary Alcohols to Carboxylic Acids

Author : Gabriel Tojo
Publisher : Springer Science & Business Media
ISBN 13 : 0387354328
Total Pages : 124 pages
Book Rating : 4.3/5 (873 download)

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Book Synopsis Oxidation of Primary Alcohols to Carboxylic Acids by : Gabriel Tojo

Download or read book Oxidation of Primary Alcohols to Carboxylic Acids written by Gabriel Tojo and published by Springer Science & Business Media. This book was released on 2007-05-31 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt: As the second volume in a comprehensive encyclopedia of organic reactions, this work provides an elaborated description of the experimental methods used for the oxidation of alcohols to acids. It supplies important data on possible interferences from protecting groups and functional groups, as well as on potential side-reactions. This book is a must for anyone involved in the preparation of organic compounds.

Oxidation of Alcohols to Aldehydes and Ketones

Author : Gabriel Tojo
Publisher : Springer Science & Business Media
ISBN 13 : 038725725X
Total Pages : 388 pages
Book Rating : 4.3/5 (872 download)

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Book Synopsis Oxidation of Alcohols to Aldehydes and Ketones by : Gabriel Tojo

Download or read book Oxidation of Alcohols to Aldehydes and Ketones written by Gabriel Tojo and published by Springer Science & Business Media. This book was released on 2006-06-15 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this book is to help people performing routine operations in Organic Synthesis in a laboratory. This book, the first one in a series, focuses on the oxidation of alcohols to aldehydes and ketones. Probably, this is the most important routine operation in Organic Synthesis.

Organic Reaction Mechanisms 2018

Author : Mark G. Moloney
Publisher : John Wiley & Sons
ISBN 13 : 1119532000
Total Pages : 692 pages
Book Rating : 4.1/5 (195 download)

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Book Synopsis Organic Reaction Mechanisms 2018 by : Mark G. Moloney

Download or read book Organic Reaction Mechanisms 2018 written by Mark G. Moloney and published by John Wiley & Sons. This book was released on 2021-08-17 with total page 692 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Reaction Mechanisms 2018, the 54th annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2018. The following classes of organic reaction mechanisms are comprehensively reviewed: Reaction of Aldehydes and Ketones and their Derivatives Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives Oxidation and Reduction Carbenes and Nitrenes Nucleophilic Aromatic Substitution Electrophilic Aromatic Substitution Carbocations Nucleophilic Aliphatic Substitution Carbanions and Electrophilic Aliphatic Substitution Elimination Reactions Polar Addition Reactions Cycloaddition Reactions Molecular Rearrangements Transition Metal Coupling Radical Reactions An experienced team of authors compile these reviews every year, so that the reader can rely on a continuing quality of selection and presentation.

Redox-Active Ligands

Author : Marine Desage-El Murr
Publisher : John Wiley & Sons
ISBN 13 : 352783088X
Total Pages : 373 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Redox-Active Ligands by : Marine Desage-El Murr

Download or read book Redox-Active Ligands written by Marine Desage-El Murr and published by John Wiley & Sons. This book was released on 2024-01-31 with total page 373 pages. Available in PDF, EPUB and Kindle. Book excerpt: Redox-Active Ligands Authoritative resource showcasing a new family of ligands that can lead to better catalysts and promising applications in organic synthesis Redox-Active Ligands gives a comprehensive overview of the unique features of redox-active ligands, describing their structure and synthesis, the characterization of their coordination complexes, and important applications in homogeneous catalysis. The work reflects the diversity of the subject by including ongoing research spanning coordination chemistry, organometallic chemistry, bioinspired catalysis, proton and electron transfer, and the ability of such ligands to interact with early and late transition metals, lanthanides, and actinides. The book is divided into three parts, devoted to introduction and concepts, applications, and case studies. After the introduction on key concepts related to the field, and the different types of ligands and complexes in which ligand-centered redox activity is commonly observed, mechanistic and computational studies are described. The second part focuses on catalytic applications of redox-active complexes, including examples from radical transformations, coordination chemistry and organic synthesis. Finally, case studies of redox-active guanidine ligands, and of lanthanides and actinides are presented. Other specific sample topics covered include: An overview of the electronic features of redox-active ligands, covering their historical perspective and biological background The versatility and mode of action of redox-active ligands, which sets them apart from more classic and tunable ligands such as phosphines or N-heterocyclic carbenes Preparation and catalytic applications of complexes of stable N-aryl radicals Metal complexes with redox-active ligands in H+/e- transfer transformations By providing up-to-date information on important concepts and applications, Redox-Active Ligands is an essential reading for researchers working in organometallic and coordination chemistry, catalysis, organic synthesis, and (bio)inorganic chemistry, as well as newcomers to the field.

Methods of Electronic Structure Theory

Author : Henry F. Schaefer
Publisher : Springer Science & Business Media
ISBN 13 : 1475708874
Total Pages : 476 pages
Book Rating : 4.4/5 (757 download)

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Book Synopsis Methods of Electronic Structure Theory by : Henry F. Schaefer

Download or read book Methods of Electronic Structure Theory written by Henry F. Schaefer and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 476 pages. Available in PDF, EPUB and Kindle. Book excerpt: These two volumes deal with the quantum theory of the electronic structure of molecules. Implicit in the term ab initio is the notion that approximate solutions of Schrödinger's equation are sought "from the beginning," i. e. , without recourse to experimental data. From a more pragmatic viewpoint, the distin guishing feature of ab initio theory is usually the fact that no approximations are involved in the evaluation of the required molecular integrals. Consistent with current activity in the field, the first of these two volumes contains chapters dealing with methods per se, while the second concerns the application of these methods to problems of chemical interest. In asense, the motivation for these volumes has been the spectacular recent success of ab initio theory in resolving important chemical questions. However, these applications have only become possible through the less visible but equally important efforts of those develop ing new theoretical and computational methods and models. Henry F Schaefer Vll Contents Contents of Volume 4 XIX Chapter 1. Gaussian Basis Sets for Molecular Calculations Thom. H. Dunning, Ir. and P. Ieffrey Hay 1. Introduction . . . . . . . . . . . . . . . . 1 1. 1. Slater Functions and the Hydrogen Moleeule 1 1. 2. Gaussian Functions and the Hydrogen Atom 3 2. Hartree-Fock Calculations on the First Row Atoms 5 2. 1. Valence States of the First Row Atoms 6 7 2. 2. Rydberg States of the First Row Atoms 9 2. 3.

Modern Organic Synthesis

Author : George S. Zweifel
Publisher : John Wiley & Sons
ISBN 13 : 1119086760
Total Pages : 416 pages
Book Rating : 4.1/5 (19 download)

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Book Synopsis Modern Organic Synthesis by : George S. Zweifel

Download or read book Modern Organic Synthesis written by George S. Zweifel and published by John Wiley & Sons. This book was released on 2017-03-13 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book bridges the gap between sophomore and advanced / graduate level organic chemistry courses, providing students with a necessary background to begin research in either an industry or academic environment. • Covers key concepts that include retrosynthesis, conformational analysis, and functional group transformations as well as presents the latest developments in organometallic chemistry and C–C bond formation • Uses a concise and easy-to-read style, with many illustrated examples • Updates material, examples, and references from the first edition • Adds coverage of organocatalysts and organometallic reagents

Mechanistic Studies on Transition Metal-Catalyzed C–H Activation Reactions Using Combined Mass Spectrometry and Theoretical Methods

Download Mechanistic Studies on Transition Metal-Catalyzed C–H Activation Reactions Using Combined Mass Spectrometry and Theoretical Methods PDF Online Free

Author : Gui-Juan Cheng
Publisher : Springer
ISBN 13 : 9811045216
Total Pages : 140 pages
Book Rating : 4.8/5 (11 download)

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Book Synopsis Mechanistic Studies on Transition Metal-Catalyzed C–H Activation Reactions Using Combined Mass Spectrometry and Theoretical Methods by : Gui-Juan Cheng

Download or read book Mechanistic Studies on Transition Metal-Catalyzed C–H Activation Reactions Using Combined Mass Spectrometry and Theoretical Methods written by Gui-Juan Cheng and published by Springer. This book was released on 2017-06-07 with total page 140 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis presents detailed mechanistic studies on a series of important C-H activation reactions using combined computational methods and mass spectrometry experiments. It also provides guidance on the design and improvement of catalysts and ligands. The reactions investigated include: (i) a nitrile-containing template-assisted meta-selective C-H activation, (ii) Pd/mono-N-protected amino acid (MPAA) catalyzed meta-selective C-H activation, (iii) Pd/MPAA catalyzed asymmetric C-H activation reactions, and (iv) Cu-catalyzed sp3 C-H cross-dehydrogenative-coupling reaction. The book reports on a novel dimeric Pd-M (M = Pd or Ag) model for reaction (i), which successfully explains the meta-selectivity observed experimentally. For reaction (ii), with a combined DFT/MS method, the author successfully reveals the roles of MPAA ligands and a new C-H activation mechanism, which accounts for the improved reactivity and high meta-selectivity and opens new avenues for ligand design. She subsequently applies ion-mobility mass spectrometry to capture and separate the [Pd(MPAA)(substrate)] complex at different stages for the first time, providing support for the internal-base model for reaction (iii). Employing DFT studies, she then establishes a chirality relay model that can be widely applied to MPAA-assisted asymmetric C-H activation reactions. Lastly, for reaction (iv) the author conducts detailed computational studies on several plausible pathways for Cu/O2 and Cu/TBHP systems and finds a reliable method for calculating the single electron transfer (SET) process on the basis of benchmark studies.

The Chemistry of Organocopper Compounds

Author : Zvi Rappoport
Publisher : John Wiley & Sons
ISBN 13 : 0470772964
Total Pages : 1183 pages
Book Rating : 4.4/5 (77 download)

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Book Synopsis The Chemistry of Organocopper Compounds by : Zvi Rappoport

Download or read book The Chemistry of Organocopper Compounds written by Zvi Rappoport and published by John Wiley & Sons. This book was released on 2009-12-21 with total page 1183 pages. Available in PDF, EPUB and Kindle. Book excerpt: Copper in organic synthesis has seen a tremendous development over the past ten years. This text represents the most comprehensive survey on the use of Copper and Cuprates in organic synthesis. The first time that the Patai Series touches on Copper compounds, it contains contributions by leading experts, and delivers the quality expected from the Patai Series.

Transition Metal Catalysis in Aerobic Alcohol Oxidation

Author : Francesca Cardona
Publisher : Royal Society of Chemistry
ISBN 13 : 1849738238
Total Pages : 304 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Transition Metal Catalysis in Aerobic Alcohol Oxidation by : Francesca Cardona

Download or read book Transition Metal Catalysis in Aerobic Alcohol Oxidation written by Francesca Cardona and published by Royal Society of Chemistry. This book was released on 2015 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with the search for environmentally benign procedures for the oxidation of alcohols and gives an overview of their transition-metal-catalyzed aerobic oxidation.

Chemical Applications of Atomic and Molecular Electrostatic Potentials

Author : Peter Politzer
Publisher : Springer Science & Business Media
ISBN 13 : 147579634X
Total Pages : 473 pages
Book Rating : 4.4/5 (757 download)

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Book Synopsis Chemical Applications of Atomic and Molecular Electrostatic Potentials by : Peter Politzer

Download or read book Chemical Applications of Atomic and Molecular Electrostatic Potentials written by Peter Politzer and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 473 pages. Available in PDF, EPUB and Kindle. Book excerpt: On March 26-27, 1980, a symposium organized by one of us (P. P. ) was held at the l79th American Chemical Society National ~1eeting in Houston, Texas, under the sponsorship of the Theoretical Chemistry Subdivision of the Division of Physical Chemistry. The symposium was entitled "The Role of the Electrostatic Potential in Chemistry," and it served as a stimulus for this book. The original scope and coverage have been broadened, however; included here, in addition to contributions from the eleven invited symposium speakers and two of the poster-session participants, are four papers that were specially invited for this book. Furthermore, several authors have taken this opportunity to present at least partial reviews of the areas being discussed. Most of the manuscripts were completed in the late spring and early summer of 1980. We hope that this book will achieve two goals: First, we are trying to provide an overall picture, including recent advances, of current chemical research, both fundamental and applied, involving the electrostatic potential. Second, we want to convey an appreci ation of both the powers and also the limitations of the electro static potential approach. In order to achieve these goals, we have selected contributors whose research areas provide a very broad coverage of the field. Throughout the book, we have used a. u.

Catalysis by Microporous Materials

Author : H.K. Beyer
Publisher : Elsevier
ISBN 13 : 0080544673
Total Pages : 811 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Catalysis by Microporous Materials by : H.K. Beyer

Download or read book Catalysis by Microporous Materials written by H.K. Beyer and published by Elsevier. This book was released on 1995-05-19 with total page 811 pages. Available in PDF, EPUB and Kindle. Book excerpt: ZEOCAT '95 is the eleventh in the series of symposia devoted to special fields of zeolite chemistry. Six plenary lectures, forty oral and forty-two poster presentations were included in the program. The accepted papers cover every aspect of catalysis on microporous materials. A significant number of the contributions describe the synthesis, modification, instrumental and chemical characterisation of zeolites and other micro- and mesoporous materials. Catalytic reactions involve hydrocarbon cracking, nucleophilic aromatic substitution, methanol to hydrocarbon conversion, hydration of acetylene, various alkylation reactions, redox transformations, Claisen rearrangement, etc.

Catalytic Asymmetric Synthesis

Author : Takahiko Akiyama
Publisher : John Wiley & Sons
ISBN 13 : 1119736412
Total Pages : 798 pages
Book Rating : 4.1/5 (197 download)

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Book Synopsis Catalytic Asymmetric Synthesis by : Takahiko Akiyama

Download or read book Catalytic Asymmetric Synthesis written by Takahiko Akiyama and published by John Wiley & Sons. This book was released on 2022-05-27 with total page 798 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalytic Asymmetric Synthesis Seminal text presenting detailed accounts of the most important catalytic asymmetric reactions known today This book covers the preparation of enantiomerically pure or enriched chemical compounds by use of chiral catalyst molecules. While reviewing the most important catalytic methods for asymmetric organic synthesis, this book highlights the most important and recent developments in catalytic asymmetric synthesis. Edited by two well-qualified experts, sample topics covered in the work include: Metal catalysis, organocatalysis, photoredox catalysis, enzyme catalysis C–H bond functionalization reactions Carbon–carbon bond formation reactions, carbon–halogen bond formation reactions, hydrogenations, polymerizations, flow reactions Axially chiral compounds Retaining the best of its predecessors but now thoroughly up to date with the important and recent developments in catalytic asymmetric synthesis, the 4th edition of Catalytic Asymmetric Synthesis serves as an excellent desktop reference and text for researchers and students, from upper-level undergraduates all the way to experienced professionals in industry or academia.

Catalysis By Gold

Author : Geoffrey C Bond
Publisher : World Scientific
ISBN 13 : 1908979852
Total Pages : 383 pages
Book Rating : 4.9/5 (89 download)

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Book Synopsis Catalysis By Gold by : Geoffrey C Bond

Download or read book Catalysis By Gold written by Geoffrey C Bond and published by World Scientific. This book was released on 2006-08-15 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: Gold has traditionally been regarded as inactive as a catalytic metal. However, the advent of nanoparticulate gold on high surface area oxide supports has demonstrated its high catalytic activity in many chemical reactions. Gold is active as a heterogeneous catalyst in both gas and liquid phases, and complexes catalyse reactions homogeneously in solution. Many of the reactions being studied will lead to new application areas for catalysis by gold in pollution control, chemical processing, sensors and fuel cell technology. This book describes the properties of gold, the methods for preparing gold catalysts and ways to characterise and use them effectively in reactions. The reaction mechanisms and reasons for the high activities are discussed and the applications for gold catalysis considered./a