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Fluctuation Theory Of Solutions
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Book Synopsis Fluctuation Theory of Solutions by : Paul E. Smith
Download or read book Fluctuation Theory of Solutions written by Paul E. Smith and published by CRC Press. This book was released on 2016-04-19 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: There are essentially two theories of solutions that can be considered exact: the McMillan-Mayer theory and Fluctuation Solution Theory (FST). The first is mostly limited to solutes at low concentrations, while FST has no such issue. It is an exact theory that can be applied to any stable solution regardless of the number of components and their co
Book Synopsis Structure, Fluctuation, and Relaxation in Solutions by : H. Nomura
Download or read book Structure, Fluctuation, and Relaxation in Solutions written by H. Nomura and published by Elsevier. This book was released on 1995-12-20 with total page 445 pages. Available in PDF, EPUB and Kindle. Book excerpt: The results of a special research project carried out for "Molecular Approaches to Non-equilibrium Process in Solution" were presented during The 42nd Yamada Conference on "Structure, Fluctuation and Relaxation in Solution" which was held from 11-15 December, 1994. The following topics were discussed at the conference: 1. Solvation Dynamics 2. Relaxation, Fluctuation and Reaction Dynamics 3. Dynamic Structure and Reaction Mechanisms in Solutions. These topics were the main concern of this conference.
Book Synopsis Dynamic Spin-Fluctuation Theory of Metallic Magnetism by : Nikolai B. Melnikov
Download or read book Dynamic Spin-Fluctuation Theory of Metallic Magnetism written by Nikolai B. Melnikov and published by Springer. This book was released on 2018-08-02 with total page 287 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a theoretical framework for magnetism in ferromagnetic metals and alloys at finite temperatures. The objective of the book is twofold. First, it gives a detailed presentation of the dynamic spin-fluctuation theory that takes into account both local and long-wave spin fluctuations with any frequency. The authors provide a detailed explanation of the fundamental role of quantum spin fluctuations in the mechanism of metallic magnetism and illustrate the theory with concrete examples. The second objective of the book is to give an accurate and self-contained presentation of many-body techniques such as the functional integral method and Green's functions, via a number of worked examples. These computational methods are of great use to solid state physicists working in a range of specialties. The book is intended primarily for researchers, but can also be used as textbook. The introductory chapters offer clear and complete derivations of the fundamentals, which makes the presentation self-contained. The main text is followed by a number of well-organized appendices that contain a detailed presentation of the necessary many-body techniques and computational methods. The book also includes a list of symbols and detailed index. This volume will be of interest to a wide range of physicists interested in magnetism and solid state physics in general, both theoreticians and experimentalists.
Book Synopsis Thermodynamics of Solutions by : Eli Ruckenstein
Download or read book Thermodynamics of Solutions written by Eli Ruckenstein and published by Springer Science & Business Media. This book was released on 2009-06-17 with total page 349 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book consists of a number of papers regarding the thermodynamics and structure of multicomponent systems that we have published during the last decade. Even though they involve different topics and different systems, they have something in common which can be considered as the “signature” of the present book. First, these papers are concerned with “difficult” or very nonideal systems, i. e. systems with very strong interactions (e. g. , hyd- gen bonding) between components or systems with large differences in the partial molar v- umes of the components (e. g. , the aqueous solutions of proteins), or systems that are far from “normal” conditions (e. g. , critical or near-critical mixtures). Second, the conventional th- modynamic methods are not sufficient for the accurate treatment of these mixtures. Last but not least, these systems are of interest for the pharmaceutical, biomedical, and related ind- tries. In order to meet the thermodynamic challenges involved in these complex mixtures, we employed a variety of traditional methods but also new methods, such as the fluctuation t- ory of Kirkwood and Buff and ab initio quantum mechanical techniques. The Kirkwood-Buff (KB) theory is a rigorous formalism which is free of any of the - proximations usually used in the thermodynamic treatment of multicomponent systems. This theory appears to be very fruitful when applied to the above mentioned “difficult” systems.
Book Synopsis Physical Principles and Techniques of Protein Chemistry Part B by : Sydney Leach
Download or read book Physical Principles and Techniques of Protein Chemistry Part B written by Sydney Leach and published by Elsevier. This book was released on 2012-12-02 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt: Physical Principles and Techniques of Protein Chemistry, Part B deals with the theories and application of selected physical methods in protein chemistry evaluation. This book is divided into seven chapters that cover the ultracentrifugal analysis, light scattering, infrared (IR) methods, nuclear magnetic resonance (NMR) spectroscopy, and differential thermal analysis of protein properties. This text first describes the fundamental ideas and methodology of sedimentation analysis of ideal noninteracting solutes and the problems of nonideality and solute-solute interaction. This book then deals with the problems involved in the interpretation of viscometric data for evaluation of intrinsic viscosity of proteins. The following chapters examine the principles, measurement and analysis of spectra, and experimental techniques of light scattering, IR, and NMR spectroscopic methods. Discussions on coordination phenomena, identification of binding sites, and ion binding in the crystalline state and in protein solutions are included. The concluding chapter presents some examples of protein analysis using differential thermal analysis technique. This book is of great value to chemists, biologists, and researchers who have great appreciation of protein chemistry.
Book Synopsis Polymers and Electromagnetic Radiation by : Wolfram Schnabel
Download or read book Polymers and Electromagnetic Radiation written by Wolfram Schnabel and published by John Wiley & Sons. This book was released on 2014-01-10 with total page 361 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first book to cover the interaction of polymers with radiation from the entire electromagnetic spectrum adopts a multidisciplinary approach to bridge polymer chemistry and physics, photochemistry, photophysics and materials science. The text is equally unique in its scope, devoting equal amounts of attention to the three aspects of synthesis, characterization, and applications. The first part deals with the interaction of polymers with non-ionizing radiation in the frequency-range from sub-terahertz via infrared radiation to visible and ultraviolet light, while the second covers interaction with ionizing radiation from the extreme ultraviolet to ?-ray photons. The result is a systematic overview of how both types of radiation can be used for different polymerization approaches, spectroscopy methods and lithography techniques. Authored by a world-renowned researcher and teacher with over 40 years of experience in the field, this is a highly practical and authoritative guide.
Book Synopsis Physical Chemistry of Polymer Solutions by : K. Kamide
Download or read book Physical Chemistry of Polymer Solutions written by K. Kamide and published by Elsevier. This book was released on 2000-10-16 with total page 675 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is mainly concerned with building a narrow but secure ladder which polymer chemists or engineers can climb from the primary level to an advanced level without great difficulty (but by no means easily, either). This book describes some fundamentally important topics, carefully chosen, covering subjects from thermodynamics to molecular weight and its distribution effects. For help in self-education the book adopts a "Questions and Answers" format. The mathematical derivation of each equation is shown in detail. For further reading, some original references are also given. Numerous physical properties of polymer solutions are known to be significantly different from those of low molecular weight solutions. The most probable explanation of this obvious discrepancy is the large molar volume ratio of solute to solvent together with the large number of consecutive segments that constitute each single molecule of the polymer chains present as solute. Thorough understanding of the physical chemistry of polymer solutions requires some prior mathematical background in its students. In the original literature, detailed mathematical derivations of the equations are universally omitted for the sake of space-saving and simplicity. In textbooks of polymer science only extremely rough schemes of the theories and then the final equations are shown. As a consequence, the student cannot learn, unaided, the details of the theory in which he or she is interested from the existing textbooks; however, without a full understanding of the theory, one cannot analyze actual experimental data to obtain more basic and realistic physical quantities. In particular, if one intends to apply the theories in industry, accurate understanding and ability to modify the theory are essential.
Book Synopsis The Potential Distribution Theorem and Models of Molecular Solutions by : Tom L. Beck
Download or read book The Potential Distribution Theorem and Models of Molecular Solutions written by Tom L. Beck and published by Cambridge University Press. This book was released on 2006-08-31 with total page 245 pages. Available in PDF, EPUB and Kindle. Book excerpt: An understanding of statistical thermodynamic molecular theory is fundamental to the appreciation of molecular solutions. This complex subject has been simplified by the authors with down-to-earth presentations of molecular theory. Using the potential distribution theorem (PDT) as the basis, the text provides a discussion of practical theories in conjunction with simulation results. The authors discuss the field in a concise and simple manner, illustrating the text with useful models of solution thermodynamics and numerous exercises. Modern quasi-chemical theories that permit statistical thermodynamic properties to be studied on the basis of electronic structure calculations are given extended development, as is the testing of those theoretical results with ab initio molecular dynamics simulations. The book is intended for students taking up research problems of molecular science in chemistry, chemical engineering, biochemistry, pharmaceutical chemistry, nanotechnology and biotechnology.
Book Synopsis Modern Theory of Polymer Solutions by : Hiromi Yamakawa
Download or read book Modern Theory of Polymer Solutions written by Hiromi Yamakawa and published by . This book was released on 1971 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Statistical Mechanics for Chemistry and Materials Science by : Biman Bagchi
Download or read book Statistical Mechanics for Chemistry and Materials Science written by Biman Bagchi and published by CRC Press. This book was released on 2018-07-06 with total page 513 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the broad subject of equilibrium statistical mechanics along with many advanced and modern topics such as nucleation, spinodal decomposition, inherent structures of liquids and liquid crystals. Unlike other books on the market, this comprehensive text not only deals with the primary fundamental ideas of statistical mechanics but also covers contemporary topics in this broad and rapidly developing area of chemistry and materials science.
Book Synopsis Stochastic Processes Problems and Solutions by : L. Takacs
Download or read book Stochastic Processes Problems and Solutions written by L. Takacs and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 143 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is not so very long ago that up-to-date text-books on statistics were almost non-existent. In the last few decades this deficiency has largely been remedied, but in order to cope with a broad and rapidly expanding subject many of these books have been fairly big and expensive. The success of Methuen's existing series of monographs, in physics or in biology, for example, stresses the value of short inexpensive treatments to which a student can turn for an introduc tion to, or a revision of, specialised topics. In this new Methuen series the still-growing importance of prob ability theory in its applied aspects has been recognised by coupling together Probability and Statistics; and included in the series are some of the newer applications of probability theory to stochastic models in various fields, storage and service problems, 'Monte Carlo' techniques, etc. , as well as monographs on particular statistical topics. M. S. BARTLETT ix AUTHOR'S PREFACE The theory of stochastic processes has developed in the last three decades. Its field of application is constantly expanding and at present it is being applied in nearly every branch of science. So far several books have been written on the mathematical theory of stochastic processes. The nature of this book is different because it is primarily a collection of problems and their solutions, and is intended for readers who are already familiar with probability theory.
Book Synopsis A Dynamic Light Scattering Study of Isorefractive Ternary Polymer Solutions by : Adam Scott Cantor
Download or read book A Dynamic Light Scattering Study of Isorefractive Ternary Polymer Solutions written by Adam Scott Cantor and published by . This book was released on 1991 with total page 422 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Scattering of Light and Other Electromagnetic Radiation by : Milton Kerker
Download or read book The Scattering of Light and Other Electromagnetic Radiation written by Milton Kerker and published by Elsevier. This book was released on 2016-06-03 with total page 684 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Scattering of Light and other Electromagnetic Radiation covers the theory of electromagnetic scattering and its practical applications to light scattering. This book is divided into 10 chapters that particularly present examples of practical applications to light scattering from colloidal and macromolecular systems. The opening chapters survey the physical concept of electromagnetic waves and optics. The subsequent chapters deal with the theory of scattering by spheres and infinitely long cylinders. These topics are followed by discussions on the application of light scattering to the determination of the size distribution of colloidal particles. The last chapters are devoted to the Rayleigh-Debye scattering and the scattering by liquids, as well as the concept of anisotropy. These chapters also describe the effect upon light scattering of partial orientation of anisotropic particles in electrical and magnetic fields and in viscous flow. This book is of value to physical chemists and physical chemistry researchers, teachers, and students.
Book Synopsis The Physics and Chemistry of Aqueous Ionic Solutions by : M.C. Bellissent-Funel
Download or read book The Physics and Chemistry of Aqueous Ionic Solutions written by M.C. Bellissent-Funel and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 479 pages. Available in PDF, EPUB and Kindle. Book excerpt: J.E. Enderby At the last NATO-ASI on liquids held in Corsica, (August 1977),Professor de Gennes, in his summary of that meeting, suggested that the next ASI should concentrate on some specific aspect of the subject and mentioned explicitly ionic solutions as one possibility. The challenge was taken up by Marie-Claire Bellissent-Funel and George Neilson; I am sure that all the participants would wish to congratulate our two colleagues for putting together an outstanding programme of lectures, round tables and poster session. The theory which underlies the subject was covered by four leading authorities: J.-P. Hansen (Paris) set out the general framework in terms of the statistical mechanics of bulk and surface properties; H.L. Friedman (Stony Brook) focused attention on ionic liquids at equilibrium, and J.B. Hubbard considered non-equilibrium properties such as the electrical conductivity and ionic friction coefficients. Finally, the basic theory of polyelectrolytes treated as charged linear polymers in aqueous solution was presented by J.M. Victor (Paris).
Book Synopsis Macromolecules in Solution and Brownian Relativity by : Stefano Antonio Mezzasalma
Download or read book Macromolecules in Solution and Brownian Relativity written by Stefano Antonio Mezzasalma and published by Academic Press. This book was released on 2008-07-22 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: Macromolecules in Solution and Brownian Relativity illustrates the recent picture of statistical physics of polymers and polymer solutions that emerges from some paradigms of contemporary science joint together. Among its principal aims are discussing the consequences of a novel self-diffusion theory, which benefits from an extension towards relativistic-like principles, and the generalization of usual concepts met in polymer science in terms of geometry alone. The monograph gives the whole fundamentals necessary to handle the view proposed, which is set in the final chapters. All the formers see about to provide the reader with a comprehensive treatation of the necessary fundamentals of classical, relativistic, quantum and statistical mechanics. Among the most important mechanical theories ever developed, a chapter on the Brownian movement and another on macromolecules prepare the ground that is specific to face universality and scaling behaviors in polymer solutions. The scope of the book is therefore two-fold: On the one hand, it wishes to involve the readers and scholars into a new research on polymer physics and chemistry. On the other, to get close chemical physicists and physical chemists to disciplines which, traditionally, are far from their direct fields of interest. Cross-disciplinarity Novelty Potentiality
Book Synopsis Effect of the Ionosphere on Space Systems and Communications by : John M. Goodman
Download or read book Effect of the Ionosphere on Space Systems and Communications written by John M. Goodman and published by . This book was released on 1975 with total page 520 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Fluid Transport in Nanoporous Materials by : Wm. Curtis Conner
Download or read book Fluid Transport in Nanoporous Materials written by Wm. Curtis Conner and published by Springer Science & Business Media. This book was released on 2006-05-06 with total page 681 pages. Available in PDF, EPUB and Kindle. Book excerpt: The last several years have seen a dramatic increase in the synthesis of new nanoporous materials. The most promising include molecular sieves which are being developed as inorganic or polymeric systems with 0. 3-30nm in pore dimensions. These nanoporous solids have a broad spectrum of applications in chemical and biochemical processes. The unique applications of molecular sieves are based on their sorption and transport selectivity. Yet, the transport processes in nanoporous systems are not understood well. At the same time, the theoretical capabilities have increased exponentially catalyzed by increases in computational capabilities. The interactions between a diffusing species and the host solid are being studied with increasing details and realism. Further, in situ experimental techniques have been developed which give an understanding of the interactions between diffusing species and nanoporous solids that was not available even a few years ago. The time was ripe to bring together these areas of common interest and study to understand what is known and what has yet to be determined concerning transport in nanoporous solids. Molecular sieves are playing an increasing role in a broad range of industrial petrochemical and biological processes. These include shape-selective separations and catalysis as well as sensors and drug delivery. Molecular sieves are made from inorganic as well as organic solids, e. g. , polymers. They can be employed in packed beds, as membranes and as barrier materials. Initially, the applications of molecular sieves were dominated by the use of zeolites.
