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Disproportionation Of Tetravalent And Pentavalent Plutonium Ions In The Presence Of Hexavalent Plutonium
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Book Synopsis Disproportionation of Tetravalent and Pentavalent Plutonium Ions in the Presence of Hexavalent Plutonium by : Silver G. L.
Download or read book Disproportionation of Tetravalent and Pentavalent Plutonium Ions in the Presence of Hexavalent Plutonium written by Silver G. L. and published by . This book was released on 1970 with total page 50 pages. Available in PDF, EPUB and Kindle. Book excerpt: The concept that the disproportionation reactions of tetravalent and pentavalent plutonium ions are special cases of the general plutonium equilibrium problem is illustrated with the estimation of the distribution of plutonium valence states when tetravalent and pentavalent plutonium ions are allowed to disproportionate in the presence of excess hexavalent plutonium. Sources of errors in disproportionation stoichiometry coefficients are described, and a table of relative errors is presented. A computer program suitable for estimating plutonium valence state distribution for any initial plutonium oxidation number is included. Application of the program to the study of the autoreduction of solutions of hexavalent 238Pu and 239Pu is suggested.
Book Synopsis Plutonium Disproportionation Reactions by : G. L. Silver
Download or read book Plutonium Disproportionation Reactions written by G. L. Silver and published by . This book was released on 1971 with total page 58 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Disproportionation of Tetravalent and Pentavalent Plutonium Ions by : Silver G. L.
Download or read book Disproportionation of Tetravalent and Pentavalent Plutonium Ions written by Silver G. L. and published by . This book was released on 1970 with total page 30 pages. Available in PDF, EPUB and Kindle. Book excerpt: Plutonium literature does not satisfactorily include the four common oxidation states of plutonium in discussions of the stoichiometry of the disproportionation of the tetravalent and pentavalent states of this element. A theoretical study of possible consequences of including all common oxidation states of plutonium in the disproportionation reactions was made. The study, based upon available potential and free energy data, indicates that the disproportionation equations can be written with all four species included. The potential behavior of disproportionated plutonium solutions can be predicted with the aid of these new equations. The equations also predict that the hydrogen ion dependence of plutonium disproportionation reactions should not be exactly fourth power at all acidities.
Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1972 with total page 810 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1973 with total page 1162 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Plutonium in Natural Waters by : Silver Gary L.
Download or read book Plutonium in Natural Waters written by Silver Gary L. and published by . This book was released on 1971 with total page 20 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Optimization and Plutonium Equilibrium by : Gary L. Silver
Download or read book Optimization and Plutonium Equilibrium written by Gary L. Silver and published by . This book was released on 1976 with total page 22 pages. Available in PDF, EPUB and Kindle. Book excerpt: The sequential simplex method has been used to estimate the extent of disproportionation of tetravalent plutonium in dilute acid. A method for simulating potentiometric titrations is proposed, and this method suggests that the stoichiometric end point and the inflection point may not always correspond in the potentiometric titration of plutonium. A possible characteristic equation for the nitrite-plutonium reaction is illustrated, and the method of proportional equations is extended to the iron-plutonium reaction.
Book Synopsis The Mechanism of Disproportionation of Pu(V) by : Robert E. Connick
Download or read book The Mechanism of Disproportionation of Pu(V) written by Robert E. Connick and published by . This book was released on 1946 with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Disproportionation of Pentavalent Plutonium in Lithium Nitrate Solutions by : F. M. Mekhail
Download or read book Disproportionation of Pentavalent Plutonium in Lithium Nitrate Solutions written by F. M. Mekhail and published by . This book was released on 1978 with total page 17 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Radiochemical and Radioanalytical Letters by :
Download or read book Radiochemical and Radioanalytical Letters written by and published by . This book was released on 1971 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Potential-pH Diagrams and Plutonium by : G. L. Silver
Download or read book Potential-pH Diagrams and Plutonium written by G. L. Silver and published by . This book was released on 1974 with total page 26 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Disproportionation and Polymerization of Plutonium(IV) in Dilute Aqueous Solutions by :
Download or read book Disproportionation and Polymerization of Plutonium(IV) in Dilute Aqueous Solutions written by and published by . This book was released on 1983 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt: The rates of polymerization and disproportionation of Pu(IV) have been studied using low concentrations: (1.7 - 10) x 10−M Pu, (0.8 - 12) x 10−M HCl and 0.0iM ionic strength. Osmium(II) complexes such as the tris-4,4'-2,2'-bipyridine complex were found to react rapidly with Pu(IV) but very slowly, if at all, with Pu(IV) polymer, Pu(III), or Pu(V). Thus, it is possible to determine unreacted Pu(IV) in the presence of rection products by using Os(II) complexes. Disproportionation reaction products, Pu(III) and Pu(V), were determined using their reactions with Ce(IV) sulfate. We find -d[Pu(IV)]/dt = k'[Pu(IV)]2 at constant pH. Log k' varies from about 4.25 at pH 3 to about 7.0 at pH 4.1 (units for k' are M−1min−1). The [H] dependence varies from about -2 to -3 over the pH range studied. The measured rate is the sum of those for polymerization and disproportionation; the latter reaction amounts to about 75% of the total at pH 3 and 20% at pH 4. The second-order rate constants for disproportionation are very much larger than expected on the basis of extrapolation from 0.2 to 1.0M HC104 solutions. The products of the reaction do not affect the rate, but U(VI), aged Pu(IV) polymer, and CO2 increase the rate.
Book Synopsis Government Reports Announcements by :
Download or read book Government Reports Announcements written by and published by . This book was released on 1971 with total page 948 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Isotopic Power Sources ... written by and published by . This book was released on 1961 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Inorganic Chemistry by : Egon Wiberg
Download or read book Inorganic Chemistry written by Egon Wiberg and published by Academic Press. This book was released on 2001 with total page 1958 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Bibliography of Scientific and Industrial Reports by :
Download or read book Bibliography of Scientific and Industrial Reports written by and published by . This book was released on 1971 with total page 658 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Nuclear Chemical Engineering by : Manson Benedict
Download or read book Nuclear Chemical Engineering written by Manson Benedict and published by . This book was released on 1957 with total page 618 pages. Available in PDF, EPUB and Kindle. Book excerpt:
