Direct Synthesis Of Metal Complexes

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Direct Synthesis of Metal Complexes

Author : B.I. Kharisov
Publisher : Elsevier
ISBN 13 : 0128110627
Total Pages : 468 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Direct Synthesis of Metal Complexes by : B.I. Kharisov

Download or read book Direct Synthesis of Metal Complexes written by B.I. Kharisov and published by Elsevier. This book was released on 2018-04-19 with total page 468 pages. Available in PDF, EPUB and Kindle. Book excerpt: Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water Includes experimental procedures, with examples of direct synthesis, at the end of each chapter

Direct Synthesis of Coordination and Organometallic Compounds

Author : A.D. Garnovskii
Publisher : Elsevier
ISBN 13 : 9780080530444
Total Pages : 244 pages
Book Rating : 4.5/5 (34 download)

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Book Synopsis Direct Synthesis of Coordination and Organometallic Compounds by : A.D. Garnovskii

Download or read book Direct Synthesis of Coordination and Organometallic Compounds written by A.D. Garnovskii and published by Elsevier. This book was released on 1999-08-13 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinetics of metal dissolution in various non-aqueous media is discussed in detail. Many methods are used nowadays to synthesize coordination compounds. Metal complexes are obtained mainly by the direct interaction of the components (the ligands and a source of the complex-forming metal), as a result of ligand and metal exchange, and under the conditions of template synthesis, which also include the method of nascent reagents. In these methods the source of the metal is either its salts or carbonyls. At the same time, it has long been known that coordination compounds may be obtained as a result of direct synthesis from zero-valent metals. Methods for the synthesis of complex compounds under the conditions of gas-phase reactions, oxidative dissolution of zero-valent metals in non-aqueous media, and in the solid phase have been developed. These methods have become the basis of a new field in synthetic chemistry - the direct synthesis of coordination and organometallic compounds from zero-valent metals. Particular aspects of the above problem have been described in a series of reviews and monographs. However, on the whole these main parts of the direct synthesis of metal complexes has not been dealt with in the review and monograph publications on coordination chemistry. So, the main objective of this book is to analyze, discuss and generalize the existing information in the area of direct reactions leading to the coordination and organometallic reactions. Some methods of direct synthesis have been developed in the former USSR (in particular, a lot of works on cryosynthesis, pioneered (1972-1973) and recent works on electrosynthesis) but, in spite of their novelty and/or wide applicability, they are practically unknown elsewhere due to the language barrier. Thus, another objective of this book is to acquaint the readers with the mentioned achievements. Every chapter contains the tables which describe all the reported data on direct reaction between metal atoms, metal particles or bulk metals with (in)organic ligans. There are some illustrations also (for example, the scheme of the reactor for gas-phase reaction between metal small particles and &bgr;-diketones).

Carbonylation

Author : H.M. Colquhoun
Publisher : Springer Science & Business Media
ISBN 13 : 1475795769
Total Pages : 295 pages
Book Rating : 4.4/5 (757 download)

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Book Synopsis Carbonylation by : H.M. Colquhoun

Download or read book Carbonylation written by H.M. Colquhoun and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the publication of our earlier book on transition metal mediated organic synthesis, * there has been a widespread increase of interest in this topic, and transition metal based methodology has become firmly established in many areas of organic chemistry. The direct, catalytic formation of organic carbonyl compounds using carbon monoxide as the source of the carbonyl group has seen exceptional progress, and this carbonylation chemistry is being used increasingly in research and on a larger scale for fine chemicals production. In view of these developments, there is a need for a modem, practi cally oriented book dealing with transition metal based carbonylation chemistry. The present monograph should help fulfill this need, since it is intended specifically to foster the adoption of catalytic carbonylation as a general tool in synthetic organic chemistry. It deals exclusively with reactions involving the interconversion of carbon monoxide and organic carbonyl compounds, and although the majority of the reactions discussed involve catalytic formation of carbonyl compounds, potentially valuable syntheses requiring stoichiometric quantities of transition metal are also included. In addition, a chapter is devoted to the remarkably useful reverse transformation (decarbonylation), in which an organic carbonyl group is eliminated in the form of carbon monoxide.

Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds

Author : A.J.L. Pombeiro
Publisher : Springer Science & Business Media
ISBN 13 : 9780792320777
Total Pages : 698 pages
Book Rating : 4.3/5 (27 download)

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Book Synopsis Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds by : A.J.L. Pombeiro

Download or read book Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds written by A.J.L. Pombeiro and published by Springer Science & Business Media. This book was released on 1993 with total page 698 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the NATO Advanced Research Workshop, Sintra, Portugal, March 25-29, 1992

Reaction Mechanisms of Metal Complexes

Author : R W Hay
Publisher : Elsevier
ISBN 13 : 1782420630
Total Pages : 177 pages
Book Rating : 4.7/5 (824 download)

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Book Synopsis Reaction Mechanisms of Metal Complexes by : R W Hay

Download or read book Reaction Mechanisms of Metal Complexes written by R W Hay and published by Elsevier. This book was released on 2000-03-01 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text provides a general background as a course module in the area of inorganic reaction mechanisms, suitable for advanced undergraduate and postgraduate study and/or research. The topic has important research applications in the metallurgical industry and is of interest in the science of biochemistry, biology, organic, inorganic and bioinorganic chemistry. In addition to coverage of substitution reactions in four-, five- and six-coordinate complexes, the book contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands. It is relevant in other fields such as organic, bioinorganic and biological chemistry, providing a bridge to organic reaction mechanisms. The book also contains a chapter on the kinetic background to the subject with many illustrative examples which should prove useful to those beginning research. Provides a general background as a course module in the area of inorganic reaction mechanisms, which has important research applications in the metallurgical industry Contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands

Synthetic Coordination and Organometallic Chemistry

Author : Alexander D. Garnovskii
Publisher : CRC Press
ISBN 13 : 1135542376
Total Pages : 568 pages
Book Rating : 4.1/5 (355 download)

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Book Synopsis Synthetic Coordination and Organometallic Chemistry by : Alexander D. Garnovskii

Download or read book Synthetic Coordination and Organometallic Chemistry written by Alexander D. Garnovskii and published by CRC Press. This book was released on 2003-04-25 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.

Synthesis of Pesticides Chemical Structure and Biological Activity Natural Products with Biological Activity

Author : H. Geissbühler
Publisher : Elsevier
ISBN 13 : 1483278514
Total Pages : 348 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Synthesis of Pesticides Chemical Structure and Biological Activity Natural Products with Biological Activity by : H. Geissbühler

Download or read book Synthesis of Pesticides Chemical Structure and Biological Activity Natural Products with Biological Activity written by H. Geissbühler and published by Elsevier. This book was released on 2013-10-22 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Pesticide Science, Part 2: Synthesis of Pesticides, Chemical Structure and Biological Activity, Natural Products with Biological Activity is a collection of papers presented at the Fourth International Congress of Pesticide Chemistry, held in Zurich, Switzerland on July 24-28, 1978. This book is composed of forty eight chapters, and begins with the synthesis of pesticides. The succeeding chapters deal with heterocyclic synthesis by rearrangement, synthesis and transformations of nitrogen and sulphurcontaining bicyclic heterocyclic systems. These topics are followed by discussions on synthesis of bmc-analogous n-heterocycles from 1,2-, 1,3-, 1,4-, and 1,5- diamines. Other chapters describe the synthesis and herbicidal activity of 4-acylpyrazole derivatives, the synthesis and properties of plant growth regulators, the carboxyphenyl derivatives of five and six membered heterocycles and potential phosphorus-containing intermediates for the synthesis of pesticides. The final chapters consider the influence of antagonistic fungi on the spore-formation of rust fungi. This book will prove useful to agriculturists and organic chemists.

Synthetic Coordination and Organometallic Chemistry

Author : Alexander D. Garnovskii
Publisher : CRC Press
ISBN 13 : 9780203911525
Total Pages : 536 pages
Book Rating : 4.9/5 (115 download)

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Book Synopsis Synthetic Coordination and Organometallic Chemistry by : Alexander D. Garnovskii

Download or read book Synthetic Coordination and Organometallic Chemistry written by Alexander D. Garnovskii and published by CRC Press. This book was released on 2003-04-25 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt: This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.

Deuteride Materials

Author : Jiping Liu
Publisher : Springer
ISBN 13 : 9811369623
Total Pages : 289 pages
Book Rating : 4.8/5 (113 download)

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Book Synopsis Deuteride Materials by : Jiping Liu

Download or read book Deuteride Materials written by Jiping Liu and published by Springer. This book was released on 2019-02-27 with total page 289 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the very first book that offers an up-to-date and comprehensive overview on deuteride. It not only includes the concept, existing forms, key characteristics, but also reviews the preparation and characterization technologies and the latest research developments of deuteride. The special properties such as the nuclear properties, isotropic and neutron effect, poisonousness, radioactivity, volume expansion are systematically discussed to build up the sound understanding of the materials. In particular, this work reviews a number of commercial and scientific uses of the materials including nuclear reactors, NMR spectroscopy and medicines. Researchers and industrial professionals in medicine, chemistry, biochemistry, environmental sciences and defense sciences will benefit from this work.

Structural and Biological Applications of Schiff Base Metal Complexes

Author : Pallavi Jain
Publisher : CRC Press
ISBN 13 : 1000865444
Total Pages : 265 pages
Book Rating : 4.0/5 (8 download)

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Book Synopsis Structural and Biological Applications of Schiff Base Metal Complexes by : Pallavi Jain

Download or read book Structural and Biological Applications of Schiff Base Metal Complexes written by Pallavi Jain and published by CRC Press. This book was released on 2023-05-31 with total page 265 pages. Available in PDF, EPUB and Kindle. Book excerpt: Coordination compounds have been well-known for their wide variety of applications for over a century, as well as enhancing the researcher’s interest and concern in evaluating their action mechanism. It is certainly one of the most intensely discussed research topics. Coordination compounds involve different metal-ion-ligand phenomenon. The involved metal ions play a significant role in structural association and functioning of several processes in the genetic and metabolism system. In recent years, Schiff base ligands have gained significant interest and received a keen interest of many researchers. Schiff’s base ligands have been recognized to hold a wide variety of biological and medicinal activities due to the presence of donor atoms. They have proved exceptional pharmalogical actions such as antimicrobial, anti-tuberclosis, antiplatelet, antidiabetic, antiarthritis, antioxidant, anti-inflammatory, anticancer, antiviral, antimalarial, and analgesic. These biologically active Schiff base ligands have also been shown to inhibit enzyme mobilization and, when bound to a metal ion, exhibit enhanced biological activity, making them useful in a number of fields. As a result, metal complexes of Schiff base ligands are gaining popularity due to their unique properties and functionalities. Schiff base complex-based research for educational and industrial purposes is booming, and the number of publications is gradually increasing. Despite these interests, there is currently no detailed book on Schiff base metal complexes that covers the structures, biological activities, and other non-biological perspectives. This book delves into the structures of Schiff base metal complexes, which are critical in assessing the biological viability of any complex. It also highlights their biological significance in pharma and drug discovery like antibacterial, antifungal, anticancer, anti-inflammatory, anti-arthritis, anti-diabetic, antioxidants, anti-proliferative, antitumor, anticancer, antiviral. The fundamentals of metal complexes are described, as well as an up-to-date outline of developments in synthesis, characterization methods, properties- chemical, thermal, optical, structural, and applications. This book also discusses the other applications of Schiff base metal complexes: as sensor (luminescent, electrochemical, and biosensor), as pigments in dying and paint industries, as photocatalyst to improve the degradation rate. Features : This book would be useful for academia, researchers and engineers working in the area of Schiff base and their metal complexes. This book will give an in-depth account of the properties of Schiff base and their metal complexes. This book will discuss the details of synthesis methods for Schiff base and their metal complexes. This book will cover emerging trends in the use of Schiff base metal complexes in the industry. This book will provide an overview of the wider biological applications of Schiff base metal complexes

Green Carbon Dioxide

Author : Gabriele Centi
Publisher : John Wiley & Sons
ISBN 13 : 1118831942
Total Pages : 284 pages
Book Rating : 4.1/5 (188 download)

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Book Synopsis Green Carbon Dioxide by : Gabriele Centi

Download or read book Green Carbon Dioxide written by Gabriele Centi and published by John Wiley & Sons. This book was released on 2014-01-17 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: PROMISING NEW APPROACHES TO RECYCLE CARBON DIOXIDE AND REDUCE EMISSIONS With this book as their guide, readers will learn a variety of new approaches and methods to recycle and reuse carbon dioxide (CO2) in order to produce green fuels and chemicals and, at the same time, minimize CO2 emissions. The authors demonstrate how to convert CO2 into a broad range of essential products by using alternative green energy sources, such as solar, wind, and hydro-power as well as sustainable energy sources. Readers will discover that CO2 can be a driving force for the sustainable future of both the chemical industry and the energy and fuels industry. Green Carbon Dioxide features a team of expert authors, offering perspectives on the latest breakthroughs in CO2 recycling from Asia, Europe, and North America. The book begins with an introduction to the production of CO2-based fuels and chemicals. Next, it covers such topics as: Transformation of CO2 to useable products through free-radical-induced reactions Hydrogenation of CO2 to liquid fuels Direct synthesis of organic carbonates from CO2 and alcohols using heterogeneous oxide catalysts Electrocatalytic reduction of CO2 in methanol medium Fuel production from photocatalytic reduction of CO2 with water using TiO2-based nanocomposites Use of CO2 in enhanced oil recovery and carbon capture and sequestration More than 1,000 references enable readers to explore individual topics in greater depth. Green Carbon Dioxide offers engineers, chemists, and managers in the chemical and energy and fuel industries a remarkable new perspective, demonstrating how CO2 can play a significant role in the development of a sustainable Earth.

Schiff Base Metal Complexes

Author : Pranjit Barman
Publisher : John Wiley & Sons
ISBN 13 : 3527350705
Total Pages : 229 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Schiff Base Metal Complexes by : Pranjit Barman

Download or read book Schiff Base Metal Complexes written by Pranjit Barman and published by John Wiley & Sons. This book was released on 2023-05-15 with total page 229 pages. Available in PDF, EPUB and Kindle. Book excerpt: Schiff Base Metal Complexes Schiff bases are compounds created from a condensed amino compounds, which frequently form complexes with metal ions. They have diverse applications in biology, catalysis, material science and industry. Understanding these compounds, their properties, and the available methods for synthesizing them is a key to unlocking industrial innovation. Schiff Base Metal Complexes provides a comprehensive overview of these compounds. It introduces the compounds and their properties before discussing their various synthesizing methods. A survey of existing and potential applications gives a complete picture and makes this a crucial guide for researchers and industry professionals looking to work with Schiff base complexes. Schiff Base Metal Complexes readers will also find: A systematic and organized structure designed to make information instantly accessible Detailed coverage of thermal synthesis, photochemical synthesis, and more Challenges with different methods described in order to help readers make the correct choice for their own work Schiff Base Metal Complexes is a useful reference for organic chemists, materials scientists, and researchers or industry professionals working with organometallics.

Alkaline-Earth Metal Compounds

Author : Sjoerd Harder
Publisher : Springer
ISBN 13 : 3642362702
Total Pages : 275 pages
Book Rating : 4.6/5 (423 download)

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Book Synopsis Alkaline-Earth Metal Compounds by : Sjoerd Harder

Download or read book Alkaline-Earth Metal Compounds written by Sjoerd Harder and published by Springer. This book was released on 2013-07-20 with total page 275 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Chemical kinetics

Author : Elena Burlakova
Publisher : CRC Press
ISBN 13 : 9067644307
Total Pages : 534 pages
Book Rating : 4.0/5 (676 download)

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Book Synopsis Chemical kinetics by : Elena Burlakova

Download or read book Chemical kinetics written by Elena Burlakova and published by CRC Press. This book was released on 2005-10-28 with total page 534 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume is devoted to the problem of chemical kinetics on modern level. The book includes information on chemical physics of nanocomposites, degradation, stabilization and flammability of polymeric materials as well as free radical mechanism of oxidation of organic compounds, thermostability, mechanism of action of catalytical systems and inhibitors in free radical reactions in liquid and solid phase, pure and applied chemistry of antioxidants (synthesis and application), ionic reactions, effect of chemoluminescence in the processes of oxidation, biodegradation and application of polymers in medicine, problems of adhesion of microorganisms on the surface of materials, thermo-, photo- and hydrolitic reactions, creation of new ecologically friendly flame retaradnts for polymers, polymer composites and polymer blends as well as filled polymers.

Russian Chemical Reviews

Author :
Publisher :
ISBN 13 :
Total Pages : 428 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Russian Chemical Reviews by :

Download or read book Russian Chemical Reviews written by and published by . This book was released on 2005 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Advances in Organometallic Chemistry

Author : Anthony F. Hill
Publisher : Academic Press
ISBN 13 : 0124078419
Total Pages : 484 pages
Book Rating : 4.1/5 (24 download)

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Book Synopsis Advances in Organometallic Chemistry by : Anthony F. Hill

Download or read book Advances in Organometallic Chemistry written by Anthony F. Hill and published by Academic Press. This book was released on 2013-09-11 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field that has expanded enormously since the publication of Volume 1 in 1964. Informs and updates on all the latest developments in the field Contributions from leading authorities and industry experts

Oxide-based Systems at the Crossroads of Chemistry

Author : C. Colella
Publisher : Elsevier
ISBN 13 : 9780080538303
Total Pages : 452 pages
Book Rating : 4.5/5 (383 download)

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Book Synopsis Oxide-based Systems at the Crossroads of Chemistry by : C. Colella

Download or read book Oxide-based Systems at the Crossroads of Chemistry written by C. Colella and published by Elsevier. This book was released on 2001-11-27 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume includes papers presented at the second International Workshop on Oxide-based Systems at the Crossroads of Chemistry, held at Villa Olmo in Como, Italy, 8-11 October. The selected papers present the highlights of recent research in the field of oxide structure. A wide range of oxidic materials, including real oxides, zeolites and layer-structured systems, is considered and described in terms of preparation methods, structural characterization and the relation between active sites, structure and catalytic properties. The application of the most powerful simulation and physical-chemical techniques show their usefulness in discovering and explaining structural and dynamic properties of complex materials. Moreover the development of sophisticated spectroscopical and analytical techniques are shown to significantly improve the growth of surface oxide science, generating new tools for the knowledge of catalyst structure and reaction mechanisms. An interesting feature is the inclusion of papers which show the mutual roles of experiment and theoretical models.