Transition Metal Promoted Carbometallation Of Alkynols

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Transition Metal Reagents and Catalysts

Author : Jiro Tsuji
Publisher : John Wiley & Sons
ISBN 13 : 9780471560272
Total Pages : 500 pages
Book Rating : 4.5/5 (62 download)

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Book Synopsis Transition Metal Reagents and Catalysts by : Jiro Tsuji

Download or read book Transition Metal Reagents and Catalysts written by Jiro Tsuji and published by John Wiley & Sons. This book was released on 2002-08-16 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: Im Laufe der vergangenen 35 Jahre wurden unzahlige Synthesewege entwickelt, bei denen Ubergangsmetallkomplexe entweder als Reagenzien oder als Katalysatoren fungieren. Dieses Buch bietet besonders denjenigen Synthesechemikern interessante und moderne Einblicke, die bisher noch nicht mit den vielfaltigen Moglichkeiten der Organometallchemie mit Ubergangsmetallen vertraut sind. Zu wichtigen ubergangsmetallkatalysierten Reaktionen werden Anwendungsbeispiele diskutiert. (01/00)

Metal-Based Catalysts in Organic Synthesis

Author : Manas Sutradhar
Publisher : MDPI
ISBN 13 : 3036510621
Total Pages : 68 pages
Book Rating : 4.0/5 (365 download)

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Book Synopsis Metal-Based Catalysts in Organic Synthesis by : Manas Sutradhar

Download or read book Metal-Based Catalysts in Organic Synthesis written by Manas Sutradhar and published by MDPI. This book was released on 2021-08-30 with total page 68 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysts play a crucial role in the path towards the transformation of organic compounds. This book describes the recent development of metal-based catalysis in organic synthesis. Applications of various catalysts to interesting organic transformations are discussed. It covers important organic reactions such as cyclohexane oxidation under different energy stimuli, use of Pd-nanoparticles for carbonylation of aniline, ammoximation of methyl ethyl ketone by Ni-modified TS-1 and carbozincation of substituted 2-alkynylamines. This book will be a useful reference for researchers in the field of catalysis, organic chemistry and materials science. It is also intended to attract the attention of researchers with an industrial interest.

Comprehensive Organic Synthesis: Additions to and substitutions at C-C[pi]-Bonds

Author : Barry M. Trost
Publisher : Elsevier
ISBN 13 : 9780080405957
Total Pages : 1328 pages
Book Rating : 4.4/5 (59 download)

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Book Synopsis Comprehensive Organic Synthesis: Additions to and substitutions at C-C[pi]-Bonds by : Barry M. Trost

Download or read book Comprehensive Organic Synthesis: Additions to and substitutions at C-C[pi]-Bonds written by Barry M. Trost and published by Elsevier. This book was released on 1991 with total page 1328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 4 focuses on additions and the resulting substitutions at carbon-carbon &pgr;-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient &pgr;-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to &pgr;-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.

Heteroatom Manipulation

Author : E. Winterfeldt
Publisher : Elsevier
ISBN 13 : 0080912494
Total Pages : 1217 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Heteroatom Manipulation by : E. Winterfeldt

Download or read book Heteroatom Manipulation written by E. Winterfeldt and published by Elsevier. This book was released on 1992-09-08 with total page 1217 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this volume, those functional groups containing heteroatoms that have gained importance in organic synthesis are dealt with in detail. The introduction of these various groups and their relevant transformations are described and the various aspects of chemoselectivity, regioselectivity and stereoselectivity are discussed. After a compilation of the synthetically most useful substitution processes, there is a series of chapters on the various types of acylation reactions and in this context the different methods of acyl group activation are discussed. As functional group protection is of very general importance for organic synthesis, a corresponding chapter is included. This is followed by a section on the preparation of carbonyl derivatives and the most important transformations and rearrangements of functional group derivatives. At the end of the volume one finds chapters on all types of elimination reactions and related thermal reactions together with a survey on fragmentation processes in organic synthesis.

Combining C-C ?-Bonds

Author : L.A. Paquette
Publisher : Elsevier
ISBN 13 : 0080912486
Total Pages : 1360 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Combining C-C ?-Bonds by : L.A. Paquette

Download or read book Combining C-C ?-Bonds written by L.A. Paquette and published by Elsevier. This book was released on 1992-09-08 with total page 1360 pages. Available in PDF, EPUB and Kindle. Book excerpt: The guiding principle underlying the subject matter specifically compiled in Volume 5 has been to make available to the organic chemical community a sourcebook comprehensively covering all the important &pgr;-bond-dependent transformations. Thermal, photochemical, and metal-catalyzed cycloadditions of every major type are expertly detailed by the most knowledgeable researchers in these areas. The synthetically useful electrocyclic and sigmatropic processes where alkenic centers are intimately involved in the structural change are similarly canvassed in compact detail. With added attention given to ene reactions, small-ring rearrangements, and related transition metal-associated reactions, coverage has been achieved of the full range of organic transformations directly involving the rebonding of alkenic centers. As a consequence, this volume should serve as the comprehensive sourcebook of the field for the next decade and beyond.

Comprehensive Organic Synthesis

Author : Barry M. Trost
Publisher : Elsevier
ISBN 13 : 9780080405995
Total Pages : 1174 pages
Book Rating : 4.4/5 (59 download)

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Book Synopsis Comprehensive Organic Synthesis by : Barry M. Trost

Download or read book Comprehensive Organic Synthesis written by Barry M. Trost and published by Elsevier. This book was released on 1991 with total page 1174 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 8.

The Chemistry of Organozinc Compounds

Author : Zvi Rappoport
Publisher : John Wiley & Sons
ISBN 13 : 0470093382
Total Pages : 1140 pages
Book Rating : 4.4/5 (7 download)

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Book Synopsis The Chemistry of Organozinc Compounds by : Zvi Rappoport

Download or read book The Chemistry of Organozinc Compounds written by Zvi Rappoport and published by John Wiley & Sons. This book was released on 2007-09-27 with total page 1140 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Patai Series publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopic methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical and environmental aspects. To date, over 110 volumes have been published in the series. Recently Published Titles The chemistry of the Cyclopropyl Group (Volume 2) The chemistry of the Hydrazo, Azo and Azoxy Groups (Volume 2, 2 parts) The chemistry of Double-Bonded Functional Groups (Volume 3, 2 parts) The chemistry of Organophosphorus Compounds (Volume 4) The chemistry of Halides, Pseudo-Halides and Azides (Volume 2, 2 parts) The chemistry of the Amino, Nitro and Nitroso Groups (2 volumes, 2 parts) The chemistry of Dienes and Polyenes (2 volumes) The chemistry of Organic Derivatives of Gold and Silver The chemistry of Organic Silicon Compounds (2 volumes, 4 parts) The chemistry of Organic Germanium, Tin and Lead Compounds (Volume 2, 2 parts) The chemistry of Phenols (2 parts) The chemistry of Organolithium Compounds (2 volumes, 3 parts) The chemistry of Cyclobutanes (2 parts) The chemistry of Peroxides (Volume 2, 2 parts) The chemistry of Organozinc Compounds (2 parts) Forthcoming Titles The chemistry of Anilines The chemistry of Organomagnesium Compounds The Patai Series Online The Patai Series is available in electronic format on Wiley InterScience. All new titles will be published as online books and a growing list of older titles will be added every year. It is the ultimate goal that all titles published in the Patai Series will be available in electronic format. For more information see under Online Books on: www.interscience.wiley.com

Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds

Author : Lutz Ackermann
Publisher : John Wiley & Sons
ISBN 13 : 3527340130
Total Pages : 414 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds by : Lutz Ackermann

Download or read book Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds written by Lutz Ackermann and published by John Wiley & Sons. This book was released on 2018-02-20 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling a gap in the literature, this book comprehensively reviews catalytic C-H addition reactions of (hetero)aromatic hydrocarbons across carbon-carbon multiple bonds. In so doing, it summarizes both the scope as well as the limitations of different catalyst systems and building blocks, while highlighting their application to the synthesis of pharmaceuticals as well as commodity chemicals. Focusing on the latest developments, the team of authors comprising leaders in the field covers such topics as the hydroarylation of olefins, alkyne hydroarylation in the presence of transition metal catalysts, reaction of alkynes with arylboronic acids, and allene hydroarylation, as well as the synthesis of functionalized arenes and heteroaromatics. A must-have for synthetic chemists in academia and industry dealing with catalysis, organometallic chemistry, the synthesis of natural products, fine chemicals, pharmaceuticals, products of the chemical industry and organic materials.

Additions to and Substitutions at C-C ?-Bonds

Author : M.F. Semmelhack
Publisher : Elsevier
ISBN 13 : 0080912478
Total Pages : 1322 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Additions to and Substitutions at C-C ?-Bonds by : M.F. Semmelhack

Download or read book Additions to and Substitutions at C-C ?-Bonds written by M.F. Semmelhack and published by Elsevier. This book was released on 1992-09-08 with total page 1322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 4 focuses on additions and the resulting substitutions at carbon-carbon &pgr;-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient &pgr;-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to &pgr;-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.

Comprehensive Organic Functional Group Transformations II

Author :
Publisher : Elsevier
ISBN 13 : 0080523471
Total Pages : 9196 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Comprehensive Organic Functional Group Transformations II by :

Download or read book Comprehensive Organic Functional Group Transformations II written by and published by Elsevier. This book was released on 2004-12-16 with total page 9196 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Organic Functional Group Transformations II (COFGT-II) will provide the first point of entry to the literature for all scientists interested in chemical transformations. Presenting the vast subject of organic synthesis in terms of the introduction and interconversion of all known functional groups, COFGT-II provides a unique information source documenting all methods of efficiently performing a particular transformation. Organised by the functional group formed, COFGT-II consists of 144 specialist reviews, written by leading scientists who evaluate and summarise the methods available for each functional group transformation. Also available online via ScienceDirect – featuring extensive browsing, searching, and internal cross-referencing between articles in the work, plus dynamic linking to journal articles and abstract databases, making navigation flexible and easy. For more information, pricing options and availability visit www.info.sciencedirect.com. By systematically treating each functional group in turn the work also identifies what is not known, thus pointing the way to new research areas Follows the systematic layout of the successful 1995 COFGT reference work, based on the arrangement and bonding of hetero-atoms around a central carbon atom The work will save researchers valuable time in their research as each chapter is written by experts who have critically read and reviewed the literature and presented the best methods of forming every known functional group

Reduction

Author : Barry M. Trost
Publisher : Elsevier
ISBN 13 : 0080912516
Total Pages : 1166 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Reduction by : Barry M. Trost

Download or read book Reduction written by Barry M. Trost and published by Elsevier. This book was released on 1992-09-08 with total page 1166 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains 37 chapters on methods for reducing functional groups, organized into four main parts. (i) Reduction of C=X systems, where X is an electronegative heteroatom, divided into 14 chapters based on the degree of reduction, the oxidation level of the C=X substrate, and on the nature of the reagent. (ii) Reduction of X=Y systems, divided into three chapters, covering the reduction of such groups as nitro, azo, and the various kinds of P=O and S=O groups. (iii) Reduction of C=C and C≡C, divided into 12 chapters based on the method of reduction, with aromatic, heteroaromatic, and conjugated systems treated separately, and including an extensive discussion of hydrometallation. (iv) Reduction of single bonds, C-X to C-H, in eight chapters, including the hydrogenolysis of the various kinds of C-X bonds, the reduction of epoxides, and the reduction of vinyl derivatives to alkenes. Each chapter includes a discussion of chemoselectivity, regioselectivity, and stereoselectivity, wherever it is appropriate, and most include advice on the reagent of choice, and the mechanistic basis of the various methods of reduction. In short, it is, within the space available, as near to a comprehensive account of reduction in organic chemistry as one could hope for.

Carbon-Carbon ?-Bond Formation

Author : G. Pattenden
Publisher : Elsevier
ISBN 13 : 008091246X
Total Pages : 1209 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Carbon-Carbon ?-Bond Formation by : G. Pattenden

Download or read book Carbon-Carbon ?-Bond Formation written by G. Pattenden and published by Elsevier. This book was released on 1992-09-08 with total page 1209 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 3 covers carbon-to-carbon single bond forming reactions involving sp3, sp2 and sp carbon centers, but only those which do not involve additions to C-X &pgr;-bonds. The volume first compares and contrasts the alkylation reactions of all types of sp3 carbon nucleophiles and also covers vinyl and alkynyl carbanions. Following on from Volume 2, a separate section covers Friedel-Crafts alkylation reactions, which is complemented by discussions of polyene cyclizations and electrophilic transannular cyclizations in synthesis. Coupling reactions leading to &agr;-bond formation, and involving all types of combinations ofsp3, sp2 and sp carbon centers are next covered, including those reactions based on pinacol, acyloin and phenol oxidative coupling reactions, and also the Kolbe reaction. Rearrangement reactions, leading to carbon-to-carbon &agr;-bond formation, are often used in a clever manner in synthesis. The volume includes all those rearrangement reactions based on intermediate carbonium ions and carbanions, and also includes the benzil-benzilic acid and the Wolff rearrangements. The volume closes with coverage of carbonylation reactions, and the use of carbene insertion reactions into the C-H bond in synthesis.

Oxidation

Author : Barry M. Trost
Publisher : Elsevier
ISBN 13 : 0080912508
Total Pages : 1039 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Oxidation by : Barry M. Trost

Download or read book Oxidation written by Barry M. Trost and published by Elsevier. This book was released on 1992-09-08 with total page 1039 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume covers all methods of oxidation for use in organic synthesis. Emphasis has been placed on selectivity and functional group compatibility together with practical utility and applications. The volume is broadly divided to cover oxidation of unactivated carbon-hydrogen bonds, oxidation of activated carbon-hydrogen bonds, that is to say those adjacent to activating substituents and adjacent to heteroatoms, and oxidation of carbon-carbon double bonds. The volume also covers oxidation of C-X bonds, carbon-carbon single bonds, heteroatom oxidation and a number of special topics such as electrochemical methods, oxidative rearrangements, solid supported reagents, electron transfer oxidation, and biological methods.

Additions to C-X ?-Bonds

Author : Barry M. Trost
Publisher : Elsevier
ISBN 13 : 0080912451
Total Pages : 1258 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Additions to C-X ?-Bonds by : Barry M. Trost

Download or read book Additions to C-X ?-Bonds written by Barry M. Trost and published by Elsevier. This book was released on 1992-09-08 with total page 1258 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 2 deals mainly with the addition reactions of delocalized carbanions (enolates) and their synthetic relatives (metalloenamines, enol ethers, allyl organometallics) with carbonyl compounds, imines and iminium ions. Major emphasis is placed on C-C bond-forming reactions such as the aldol and Mannich reactions. Acylation reactions are also included in this volume. Several topics that have not previously been reviewed are covered, including the use of enzymatic aldol reactions in synthesis and the Passerini-Ugi reactions.

Cumulative Indexes

Author : Barry M. Trost
Publisher : Elsevier
ISBN 13 : 0080912524
Total Pages : 828 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Cumulative Indexes by : Barry M. Trost

Download or read book Cumulative Indexes written by Barry M. Trost and published by Elsevier. This book was released on 1992-09-08 with total page 828 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cumulative Indexes

Comprehensive Organic Synthesis: Additions to and substitutions at C-C[pi]-Bonds

Author :
Publisher :
ISBN 13 :
Total Pages : 1332 pages
Book Rating : 4.:/5 (318 download)

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Book Synopsis Comprehensive Organic Synthesis: Additions to and substitutions at C-C[pi]-Bonds by :

Download or read book Comprehensive Organic Synthesis: Additions to and substitutions at C-C[pi]-Bonds written by and published by . This book was released on 1991 with total page 1332 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Comprehensive Medicinal Chemistry II

Author : David J Triggle
Publisher : Elsevier
ISBN 13 : 0080445136
Total Pages : 9367 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Comprehensive Medicinal Chemistry II by : David J Triggle

Download or read book Comprehensive Medicinal Chemistry II written by David J Triggle and published by Elsevier. This book was released on 2006-12-29 with total page 9367 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first edition of Comprehensive Medicinal Chemistry was published in 1990 and was very well received. Comprehensive Medicinal Chemistry II is much more than a simple updating of the contents of the first edition. Completely revised and expanded, this new edition has been refocused to reflect the significant developments and changes over the past decade in genomics, proteomics, bioinformatics, combinatorial chemistry, high-throughput screening and pharmacology, and more. The content comprises the most up-to-date, authoritative and comprehensive reference text on contemporary medicinal chemistry and drug research, covering major therapeutic classes and targets, research strategy and organisation, high-throughput technologies, computer-assisted design, ADME and selected case histories. It is this coverage of the strategy, technologies, principles and applications of medicinal chemistry in a single work that will make Comprehensive Medicinal Chemistry II a unique work of reference and a single point of entry to the literature for pharmaceutical and biotechnology scientists of all disciplines and for many industry executives as well. Also available online via ScienceDirect (2006) - featuring extensive browsing, searching, and internal cross-referencing between articles in the work, plus dynamic linking to journal articles and abstract databases, making navigation flexible and easy. For more information, pricing options and availability visit www.info.sciencedirect.com. Comprehensively reviews - the strategies, technologies, principles and applications of modern medicinal chemistry Provides a global and current perspective of today's drug discovery process and discusses the major therapeutic classes and targets Includes a unique collection of case studies and personal assays reviewing the discovery and development of key drugs