Thermal Degradation of Polymeric Materials

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Publisher : iSmithers Rapra Publishing
ISBN 13 : 9781859574980
Total Pages : 324 pages
Book Rating : 4.5/5 (749 download)

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Book Synopsis Thermal Degradation of Polymeric Materials by : Krzysztof Pielichowski

Download or read book Thermal Degradation of Polymeric Materials written by Krzysztof Pielichowski and published by iSmithers Rapra Publishing. This book was released on 2005 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: Understanding the thermal degradation of polymers is of paramount importance for developing a rational technology of polymer processing and higher-temperature applications. Controlling degradation requires understanding of many different phenomena, including chemical mechanisms, the influence of polymer morphology, the complexities of oxidation chemistry, and the effects of stabilisers, fillers and other additives. This book offers a wealth of information for polymer researchers and processors requiring an understanding of the implications of thermal degradation on material and product performance.

Thermal Degradation of Polymeric Materials

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Author :
Publisher : Elsevier
ISBN 13 : 0128230231
Total Pages : 378 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Thermal Degradation of Polymeric Materials by : Krzysztof Pielichowski

Download or read book Thermal Degradation of Polymeric Materials written by Krzysztof Pielichowski and published by Elsevier. This book was released on 2022-11-15 with total page 378 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermal Degradation of Polymeric Materials, Second Edition offers a wealth of information for polymer researchers and processors who require a thorough understanding of the implications of thermal degradation on materials and product performance. Sections cover thermal degradation mechanisms and kinetics, as well as various techniques, such as thermogravimetry in combination with mass spectroscopy and infrared spectrometry to investigate thermal decomposition routes. Other chapters focus on polymers and copolymers, including polyolefins, styrene polymers, polyvinyl chloride, polyamides, polyurethanes, polyesters, polyacrylates, natural polymers, inorganic polymers, high temperature-resistant and conducting polymers, blends, organic-inorganic hybrid materials, nanocomposites, and biocomposites. Finally, other key considerations such as recycling of polymers by thermal degradation, thermal degradation during processing, and modelling, are discussed in detail. Explains mechanisms of polymer degradation, making it possible to understand and predict material behavior at elevated temperatures Offers systematic coverage of each polymer group that is supported by data detailed explanations and critical analysis Investigates thermal decomposition routes in new materials, such as organic-inorganic hybrid materials and polymer nanocomposites

Thermal Degradation of Polymeric Materials

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Author :
Publisher : Elsevier
ISBN 13 : 0128231424
Total Pages : 379 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Thermal Degradation of Polymeric Materials by : Krzysztof Pielichowski

Download or read book Thermal Degradation of Polymeric Materials written by Krzysztof Pielichowski and published by Elsevier. This book was released on 2022-11-05 with total page 379 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermal Degradation of Polymeric Materials, Second Edition offers a wealth of information for polymer researchers and processors who require a thorough understanding of the implications of thermal degradation on materials and product performance. Sections cover thermal degradation mechanisms and kinetics, as well as various techniques, such as thermogravimetry in combination with mass spectroscopy and infrared spectrometry to investigate thermal decomposition routes. Other chapters focus on polymers and copolymers, including polyolefins, styrene polymers, polyvinyl chloride, polyamides, polyurethanes, polyesters, polyacrylates, natural polymers, inorganic polymers, high temperature-resistant and conducting polymers, blends, organic-inorganic hybrid materials, nanocomposites, and biocomposites. Finally, other key considerations such as recycling of polymers by thermal degradation, thermal degradation during processing, and modelling, are discussed in detail. Explains mechanisms of polymer degradation, making it possible to understand and predict material behavior at elevated temperatures Offers systematic coverage of each polymer group that is supported by data detailed explanations and critical analysis Investigates thermal decomposition routes in new materials, such as organic-inorganic hybrid materials and polymer nanocomposites

Polymer Degradation and Stabilization

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 3642693768
Total Pages : 129 pages
Book Rating : 4.6/5 (426 download)

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Book Synopsis Polymer Degradation and Stabilization by : W. L. Hawkins

Download or read book Polymer Degradation and Stabilization written by W. L. Hawkins and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 129 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development of polymers as an important class of material was inhibited at the first by the premature failure of these versatile compounds in many applications. The deterioration of important properties of both natural and synthetic polymers is the result of irreversible changes in composition and structure of polymers molecules. As a result of these reactions, mechanical, electrical and/or aesthetic properties are degraded beyond acceptable limits. It is now generally recognized that stabilization against degradation is necessary if the useful life of polymers is to be extended sufficiently to meet design requirements for long-term applications. Polymers degrade by a wide variety of mechanisms, several of which affect all polymers through to varying degree. This monograph will concentrate on those degradation mechanisms which result from reactions of polymers with oxygen in its various forms and which are accelerated by heat and/or radiation. Those stabilization mechanisms are discussed which are based on an understanding of degradation reaction mechanisms that are reasonably well established. The stabilization of polymers is still undergoing a transition from an art to a science as mechanisms of degradation become more fully developed. A scientific approach to stabilization can only be approached when there is an understanding of the reactions that lead to degradation. Stabilization against biodegradation and burning will not be discussed since there is not a clear understanding of how polymers degrade under these conditions.

Polymer Degradation and Stabilisation

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Author :
Publisher : CUP Archive
ISBN 13 : 9780521357975
Total Pages : 236 pages
Book Rating : 4.3/5 (579 download)

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Book Synopsis Polymer Degradation and Stabilisation by : Norman Grassie

Download or read book Polymer Degradation and Stabilisation written by Norman Grassie and published by CUP Archive. This book was released on 1988-04-14 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: The study of polymer degradation and stabilisation is of considerable practical importance as the industrial uses of polymeric materials continue to expand. In this book, the authors lucidly relate technological phenomena to the chemistry and physics of degradation and stabilisation processes. Degradation embraces a variety of technologically important phenomena ranging from relatively low temperature processes such as 'weathering' of plastics, 'fatigue' of rubbers through the processing of polymers in shearing mixers to very high temperature processes such as flammability and ablation. All these technological phenomena have in common certain basic chemical reactions. Thus 'weathering' has its roots in photo-oxidation, 'fatigue' and melt-degradation in mechano-oxidation and flammability, and ablation in ablation in pyrolysis and vapour phase oxidation.

Physical Properties of Polymers

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Publisher :
ISBN 13 :
Total Pages : 430 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Physical Properties of Polymers by : James E. Mark

Download or read book Physical Properties of Polymers written by James E. Mark and published by . This book was released on 1993 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt: The contents have been divided into sections on physical states of polymers and characterization techniques. Chapters on physical states include discussions of the rubber elastic state, the glassy state, melts and concentrated solutions, the crystalline state, and the mesomorphic state. Characterization techniques described are molecular spectroscopy and scattering techniques.

Reactions and Mechanisms in Thermal Analysis of Advanced Materials

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 1119117704
Total Pages : 616 pages
Book Rating : 4.1/5 (191 download)

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Book Synopsis Reactions and Mechanisms in Thermal Analysis of Advanced Materials by : Atul Tiwari

Download or read book Reactions and Mechanisms in Thermal Analysis of Advanced Materials written by Atul Tiwari and published by John Wiley & Sons. This book was released on 2015-07-29 with total page 616 pages. Available in PDF, EPUB and Kindle. Book excerpt: Strong bonds form stronger materials. For this reason, the investigation on thermal degradation of materials is a significantly important area in research and development activities. The analysis of thermal stability can be used to assess the behavior of materials in the aggressive environmental conditions, which in turn provides valuable information about the service life span of the materiel. Unlike other books published so far that have focused on either the fundamentals of thermal analysis or the degradation pattern of the materials, this book is specifically on the mechanism of degradation of materials. The mechanism of rapturing of chemical bonds as a result of exposure to high-temperature environment is difficult to study and resulting mechanistic pathway hard to establish. Limited information is available on this subject in the published literatures and difficult to excavate. Chapters in this book are contributed by the experts working on thermal degradation and analysis of the wide variety of advanced and traditional materials. Each chapter discusses the material, its possible application, behavior of chemical entities when exposed to high-temperature environment and mode and the mechanistic route of its decomposition. Such information is crucial while selecting the chemical ingredients during the synthesis or development of new materials technology.

Electrical Degradation and Breakdown in Polymers

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Author :
Publisher : IET
ISBN 13 : 9780863411960
Total Pages : 630 pages
Book Rating : 4.4/5 (119 download)

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Book Synopsis Electrical Degradation and Breakdown in Polymers by : Len A. Dissado

Download or read book Electrical Degradation and Breakdown in Polymers written by Len A. Dissado and published by IET. This book was released on 1992 with total page 630 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book is in five parts: Part I introduces the physical and chemical structure of polymers and their breakdown; Part II reviews electrical degradation in polymers, and Part III reviews conduction and deterministic breakdown in solids. Part IV discusses the stochastic nature of break-down from empirical and modelling viewpoints, and Part V indicates practical implications and strategies for engineers. Much of the discussion applies to non-crystalline materials generally.

Thermal Characterization of Polymeric Materials

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Author :
Publisher : Elsevier
ISBN 13 : 0323141889
Total Pages : 987 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Thermal Characterization of Polymeric Materials by : Edith Turi

Download or read book Thermal Characterization of Polymeric Materials written by Edith Turi and published by Elsevier. This book was released on 2012-12-02 with total page 987 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermal Characterization of Polymeric Materials is a critical review and a concise evaluation of the application of thermal analysis in polymer science and engineering. This book is divided into nine chapters that specifically tackle the instrumentation, theory, and a wide variety of applications of thermal characterization. The introductory chapters provide an overview of all aspects of thermal analytical methods and apparatus and the theory underlying the basic principles of thermal analysis. These chapters also examine the theories and functions of state for thermometry, dilatometry, thermomechanical analysis, calorimetry, thermogravimetry. These topics are followed by a discussion on single-component and multicomponent systems and their phase transitions, as influenced by concentration, pressure, deformation, molecular weight, and copolymerization. The subsequent chapters explore the influence of important chemical and physical parameters on the glass transition, crystallization, and melting of thermoplastic materials. The discussion then shifts to the theoretical aspects of polymer-polymer compatibility, phase separation, and miscibility in mixed polymer systems. This book further considers the thermal analysis in thermosets, elastomers, and fibers. The concluding chapters present the methods of obtaining information on the relative flammability properties of polymers, for screening fire retardant additives, and for studying the mechanism of flame inhibition. These chapters also look into the thermal analysis of antioxidants, stabilizers, lubricants, plasticizers, impact modifiers, and fire retardants. Polymer scientists and researchers will find this book invaluable.

Compostable Polymer Materials

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Publisher : Newnes
ISBN 13 : 0080994423
Total Pages : 410 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Compostable Polymer Materials by : Ewa Rudnik

Download or read book Compostable Polymer Materials written by Ewa Rudnik and published by Newnes. This book was released on 2019-06-04 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt: Compostable Polymer Materials, Second Edition, deals with the environmentally important family of polymers designed to be disposed of in industrial and municipal compost facilities after their useful life. These compostable plastics undergo degradation and leave no visible, distinguishable, or toxic residue. Environmental concerns and legislative measures taken in different regions of the world make composting an increasingly attractive route for the disposal of redundant polymers. This book covers the entire spectrum of preparation, degradation, and evironmental issues related to compostable polymers. It emphasizes recent studies concerning compostability and ecotoxilogical assessment of polymer materials. It descibes the thermal behavior, including flammability properties, of compostable polymers. It also explores possible routes of compostable polymers waste disposal through an ecological lens. Finally, the book examines the economic factors at work, including price evolution over the past decade, the current market, and future perspectives. Compostable Polymer Materials is an essential resource for graduate students and scientists working in chemistry, materials science, ecology, and environmental science. Provides a comprehensive study of the composting process Details methods of compostable polymers preparation, including properties, processing and applications Presents the state-of-the-art knowledge on ecotoxicity testing and biodegradation under real composting conditions of compostable polymers, as well as biodegradation in various environments, such as marine environments and anaerobic conditions Discusses the evolution of waste management in Europe and the United States, as well as the status of MSW disposal and treatment methods in countries such as China and Brazil Overviews biodegradation studies under real composting conditions of products made of compostable polymers, e.g. bags, bottles, cutletry Analyzes evolution of market development, including price of compostable polymers during the last decade

Fire Retardancy of Polymeric Materials, Second Edition

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Author :
Publisher : CRC Press
ISBN 13 : 1420084003
Total Pages : 840 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Fire Retardancy of Polymeric Materials, Second Edition by : Charles A. Wilkie

Download or read book Fire Retardancy of Polymeric Materials, Second Edition written by Charles A. Wilkie and published by CRC Press. This book was released on 2009-12-10 with total page 840 pages. Available in PDF, EPUB and Kindle. Book excerpt: When dealing with challenges such as providing fire protection while considering cost, mechanical and thermal performance and simultaneously addressing increasing regulations that deal with composition of matter and life cycle issues, there are no quick, one-size-fits-all answers. Packed with comprehensive coverage, scientific approach, step-by-step directions, and a distillation of technical knowledge, the first edition of Fire Retardancy of Polymeric Materials broke new ground. It supplied a one-stop resource for the development of new fire safe materials. The editors have expanded the second edition to echo the multidisciplinary approach inherent in current flame retardancy technology and put it in a revised, more user-friendly format. More than just an update of previously covered topics, this edition discusses: additional fire retardant chemistry developments in regulations and standards new flame retardant approaches fire safety engineering modeling and fire growth phenomena The book introduces flame retardants polymer-by-polymer, supplemented by a brief overview of mode of action and interaction, and all the other ancillary issues involved in this applied field of materials science. The book delineates what, why, and how to do it, covering the fundamentals of polymer burning/combustion and how to apply these systems and chemistries to specific materials classes. It also provides suggested formulations, discusses why certain materials are preferred for particular uses or applications, and offers a starting point from which to develop fire-safe materials.

Handbook of Environmental Degradation of Materials

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Author :
Publisher : William Andrew
ISBN 13 : 1437734553
Total Pages : 934 pages
Book Rating : 4.4/5 (377 download)

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Book Synopsis Handbook of Environmental Degradation of Materials by : Myer Kutz

Download or read book Handbook of Environmental Degradation of Materials written by Myer Kutz and published by William Andrew. This book was released on 2012-09-24 with total page 934 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nothing stays the same for ever. The environmental degradation and corrosion of materials is inevitable and affects most aspects of life. In industrial settings, this inescapable fact has very significant financial, safety and environmental implications. The Handbook of Environmental Degradation of Materials explains how to measure, analyse, and control environmental degradation for a wide range of industrial materials including metals, polymers, ceramics, concrete, wood and textiles exposed to environmental factors such as weather, seawater, and fire. Divided into sections which deal with analysis, types of degradation, protection and surface engineering respectively, the reader is introduced to the wide variety of environmental effects and what can be done to control them. The expert contributors to this book provide a wealth of insider knowledge and engineering knowhow, complementing their explanations and advice with Case Studies from areas such as pipelines, tankers, packaging and chemical processing equipment ensures that the reader understands the practical measures that can be put in place to save money, lives and the environment. The Handbook's broad scope introduces the reader to the effects of environmental degradation on a wide range of materials, including metals, plastics, concrete,wood and textiles For each type of material, the book describes the kind of degradation that effects it and how best to protect it Case Studies show how organizations from small consulting firms to corporate giants design and manufacture products that are more resistant to environmental effects

Recycling of Polyurethane Foams

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Author :
Publisher : William Andrew
ISBN 13 : 0323511341
Total Pages : 147 pages
Book Rating : 4.3/5 (235 download)

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Book Synopsis Recycling of Polyurethane Foams by : Sabu Thomas

Download or read book Recycling of Polyurethane Foams written by Sabu Thomas and published by William Andrew. This book was released on 2018-06-06 with total page 147 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recycling of Polyurethane Foams introduces the main degradation/depolymerization processes and pathways of polyurethane foam materials, focusing on industrial case studies and academic reviews from recent research and development projects. The book can aid practitioners in understanding the basis of polymer degradation and its relationship with industrial processes, which can be of substantial value to industrial complexes the world over. The main pathways of polymer recycling via different routes and industrial schemes are detailed, covering all current techniques, including regrinding, rebinding, adhesive pressing and compression moulding of recovered PU materials that are then compared with depolymerization approaches. The book examines life cycle assessment and cost analysis associated with polyurethane foams waste management, showing the potential of various techniques. This book will help academics and researchers identify and improve on current depolymerization processes, and it will help industry sustainability professionals choose the appropriate approach for their own waste management systems, thus minimizing the costs and environmental impact of their PU-based end products. Offers a comprehensive review of all polyurethane foam recycling processes, including both chemical and mechanical approaches Assesses the potential of each recycling process Helps industry-based practitioners decide which approach to take to minimize the cost and environmental impact of their end product Enables academics and researchers to identify and improve upon current processes of degradation and depolymerization

SFPE Handbook of Fire Protection Engineering

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Author :
Publisher : National Fire Protection Association (NFPA)
ISBN 13 : 9780877653530
Total Pages : 829 pages
Book Rating : 4.6/5 (535 download)

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Book Synopsis SFPE Handbook of Fire Protection Engineering by : Philip J. DiNenno

Download or read book SFPE Handbook of Fire Protection Engineering written by Philip J. DiNenno and published by National Fire Protection Association (NFPA). This book was released on 1988-01-01 with total page 829 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Polymeric and Nanostructured Materials

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Author :
Publisher : CRC Press
ISBN 13 : 1351376365
Total Pages : 380 pages
Book Rating : 4.3/5 (513 download)

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Book Synopsis Polymeric and Nanostructured Materials by : Aparna Thankappan

Download or read book Polymeric and Nanostructured Materials written by Aparna Thankappan and published by CRC Press. This book was released on 2018-11-20 with total page 380 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume provides in-depth knowledge and recent research on polymers and nanostructured materials from synthesis to advanced applications. Leading researchers from industry, academia, government, and private research institutions across the globe have contributed to this volume, covering new research on nanocomposites, polymer technology, and electrochemistry.

Flame-Retardant Polymeric Materials

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 1468421484
Total Pages : 463 pages
Book Rating : 4.4/5 (684 download)

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Book Synopsis Flame-Retardant Polymeric Materials by : Eli Pearce

Download or read book Flame-Retardant Polymeric Materials written by Eli Pearce and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 463 pages. Available in PDF, EPUB and Kindle. Book excerpt: Flammability has been recognized as an increasingly important social and scientific problem. Fire statistics in the United States (Report of the National Commission on Fire Prevention and Control. "America Burning:' 1973) emphasized the vast devastation to life and property--12.000 lives lost annually due to fire. and these deaths are usually caused by inhaling smoke or toxic gases: 300.000 fire injuries: 11.4 billion dollars in fire cost at which 2.7 billion dollars is related to property loss: a billion dollars to burn injury treatment: and 3.3 billion dollars in productivity loss. It is obvious that much human and economic misery can be attributed to fire situations. In relation to this. polymer flammability has been recognized as an in creasingly important social and scientific problem. The development of flame-retardant polymeric materials is a current example where the initia tive for major scientific and technological developments is motivated by sociological pressure and legislation. This is part of the important trend toward a safer environment and sets a pattern for future example. Flame retardancy deals with our basic everyday life situations-housing. work areas. transportation. clothing and so forth-the "macroenvironment" capsule within which "homosapiens" live. As a result. flame-retardant polymers are now emerging as a specific class of materials leading to new and diversified scientific and technological ventures.

Amorphous Solid Dispersions

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Author :
Publisher : Springer
ISBN 13 : 1493915983
Total Pages : 699 pages
Book Rating : 4.4/5 (939 download)

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Book Synopsis Amorphous Solid Dispersions by : Navnit Shah

Download or read book Amorphous Solid Dispersions written by Navnit Shah and published by Springer. This book was released on 2014-11-21 with total page 699 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume offers a comprehensive guide on the theory and practice of amorphous solid dispersions (ASD) for handling challenges associated with poorly soluble drugs. In twenty-three inclusive chapters, the book examines thermodynamics and kinetics of the amorphous state and amorphous solid dispersions, ASD technologies, excipients for stabilizing amorphous solid dispersions such as polymers, and ASD manufacturing technologies, including spray drying, hot melt extrusion, fluid bed layering and solvent-controlled micro-precipitation technology (MBP). Each technology is illustrated by specific case studies. In addition, dedicated sections cover analytical tools and technologies for characterization of amorphous solid dispersions, the prediction of long-term stability, and the development of suitable dissolution methods and regulatory aspects. The book also highlights future technologies on the horizon, such as supercritical fluid processing, mesoporous silica, KinetiSol®, and the use of non-salt-forming organic acids and amino acids for the stabilization of amorphous systems. Amorphous Solid Dispersions: Theory and Practice is a valuable reference to pharmaceutical scientists interested in developing bioavailable and therapeutically effective formulations of poorly soluble molecules in order to advance these technologies and develop better medicines for the future.