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Author : Thor N. Rhodin
Publisher : North-Holland
ISBN 13 :
Total Pages : 428 pages
Book Rating : 4.3/5 (91 download)
Download or read book The Nature of the Surface Chemical Bond written by Thor N. Rhodin and published by North-Holland. This book was released on 1979 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Nature of the Surface Chemical Bond written by and published by . This book was released on 1979 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Anders Nilsson
Publisher : Elsevier
ISBN 13 : 9780080551913
Total Pages : 532 pages
Book Rating : 4.5/5 (519 download)
Download or read book Chemical Bonding at Surfaces and Interfaces written by Anders Nilsson and published by Elsevier. This book was released on 2011-08-11 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular surface science has made enormous progress in the past 30 years. The development can be characterized by a revolution in fundamental knowledge obtained from simple model systems and by an explosion in the number of experimental techniques. The last 10 years has seen an equally rapid development of quantum mechanical modeling of surface processes using Density Functional Theory (DFT). Chemical Bonding at Surfaces and Interfaces focuses on phenomena and concepts rather than on experimental or theoretical techniques. The aim is to provide the common basis for describing the interaction of atoms and molecules with surfaces and this to be used very broadly in science and technology. The book begins with an overview of structural information on surface adsorbates and discusses the structure of a number of important chemisorption systems. Chapter 2 describes in detail the chemical bond between atoms or molecules and a metal surface in the observed surface structures. A detailed description of experimental information on the dynamics of bond-formation and bond-breaking at surfaces make up Chapter 3. Followed by an in-depth analysis of aspects of heterogeneous catalysis based on the d-band model. In Chapter 5 adsorption and chemistry on the enormously important Si and Ge semiconductor surfaces are covered. In the remaining two Chapters the book moves on from solid-gas interfaces and looks at solid-liquid interface processes. In the final chapter an overview is given of the environmentally important chemical processes occurring on mineral and oxide surfaces in contact with water and electrolytes. Gives examples of how modern theoretical DFT techniques can be used to design heterogeneous catalysts This book suits the rapid introduction of methods and concepts from surface science into a broad range of scientific disciplines where the interaction between a solid and the surrounding gas or liquid phase is an essential component Shows how insight into chemical bonding at surfaces can be applied to a range of scientific problems in heterogeneous catalysis, electrochemistry, environmental science and semiconductor processing Provides both the fundamental perspective and an overview of chemical bonding in terms of structure, electronic structure and dynamics of bond rearrangements at surfaces
Author : Gernot Frenking
Publisher : John Wiley & Sons
ISBN 13 : 3527333150
Total Pages : 569 pages
Book Rating : 4.5/5 (273 download)
Download or read book The Chemical Bond written by Gernot Frenking and published by John Wiley & Sons. This book was released on 2014-07-08 with total page 569 pages. Available in PDF, EPUB and Kindle. Book excerpt: A unique overview of the different kinds of chemical bonds that can be found in the periodic table, from the main-group elements to transition elements, lanthanides and actinides. It takes into account the many developments that have taken place in the field over the past few decades due to the rapid advances in quantum chemical models and faster computers. This is the perfect complement to "Chemical Bonding - Fundamentals and Models" by the same editors, who are two of the top scientists working on this topic, each with extensive experience and important connections within the community.
Author : V. Bortolani
Publisher : Springer Science & Business Media
ISBN 13 : 1468487779
Total Pages : 679 pages
Book Rating : 4.4/5 (684 download)
Download or read book Interaction of Atoms and Molecules with Solid Surfaces written by V. Bortolani and published by Springer Science & Business Media. This book was released on 2013-11-22 with total page 679 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is considerable interest, both fundamental and technological, in the way atoms and molecules interact with solid surfaces. Thus the description of heterogeneous catalysis and other surface reactions requires a detailed understand ing of molecule-surface interactions. The primary aim of this volume is to provide fairly broad coverage of atoms and molecules in interaction with a variety of solid surfaces at a level suitable for graduate students and research workers in condensed matter physics, chemical physics, and materials science. The book is intended for experimental workers with interests in basic theory and concepts and had its origins in a Spring College held at the International Centre for Theoretical Physics, Miramare, Trieste. Valuable background reading can be found in the graduate-Ievel introduction to the physics of solid surfaces by ZangwilI(1) and in the earlier works by Garcia Moliner and F1ores(2) and Somorjai.(3) For specifically molecule-surface interac tions, additional background can be found in Rhodin and Ertl(4) and March.(S) V. Bortolani N. H. March M. P. Tosi References 1. A. Zangwill, Physics at Surfaces, Cambridge University Press, Cambridge (1988). 2. F. Garcia-Moliner and F. Flores, Introduction to the Theory of Solid Surfaces, Cambridge University Press, Cambridge (1979). 3. G. A. Somorjai, Chemistry in Two Dimensions: Surfaces, Cornell University Press, Ithaca, New York (1981). 4. T. N. Rhodin and G. Erd, The Nature of the Surface Chemical Bond, North-Holland, Amsterdam (1979). 5. N. H. March, Chemical Bonds outside Metal Surfaces, Plenum Press, New York (1986).
Author : Norman H. March
Publisher : Springer Science & Business Media
ISBN 13 : 1461321174
Total Pages : 292 pages
Book Rating : 4.4/5 (613 download)
Download or read book Chemical Bonds Outside Metal Surfaces written by Norman H. March and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: The problem of molecules interacting with metal surfaces has for a very long time been recognized to be of considerable technological as well as fundamental importance. Thus in the former category, a substantial number of important synthetic reactions for industrial purposes make use of metal surfaces as catalysts. Or again, problems of corrosion of metals are of great practical importance, such as in nuclear-reactor technology [see, for instance, my earlier articles, in: Physics Bulletin, Volume 25, p. 582, Institute of Physics, UK (1974); and in: Physics and Contemporqry Needs (Riazuddin, ed. ), Vol. 1, p. 53, Plenum Press, New York (1977)]. It is therefore of significance to strive to gain a more fundamental understand ing of the atomic, and ultimately the electronic, processes that occur when a molecule is brought into the proximity of a metal surface. The present volume focuses mainly on the theory and concepts involved; however, it is intended for readers in chemistry, physics, and materials science who are not specialists in theory but nevertheless wish to learn more about this truly interdisciplinary area of theoretical science. The aim of the book is to present the way in which valence theory can be synthesized with the understanding of metals that has been gained over the last half century or so. While advanced theory has at times been necessary, is largely presented in an extensive set of Appendixes.
Author : Gabor A. Somorjai
Publisher : John Wiley & Sons
ISBN 13 : 047050823X
Total Pages : 804 pages
Book Rating : 4.4/5 (75 download)
Download or read book Introduction to Surface Chemistry and Catalysis written by Gabor A. Somorjai and published by John Wiley & Sons. This book was released on 2010-06-08 with total page 804 pages. Available in PDF, EPUB and Kindle. Book excerpt: Now updated-the current state of development of modern surface science Since the publication of the first edition of this book, molecular surface chemistry and catalysis science have developed rapidly and expanded into fields where atomic scale and molecular information were previously not available. This revised edition of Introduction to Surface Chemistry and Catalysis reflects this increase of information in virtually every chapter. It emphasizes the modern concepts of surface chemistry and catalysis uncovered by breakthroughs in molecular-level studies of surfaces over the past three decades while serving as a reference source for data and concepts related to properties of surfaces and interfaces. The book opens with a brief history of the evolution of surface chemistry and reviews the nature of various surfaces and interfaces encountered in everyday life. New research in two crucial areas-nanomaterials and polymer and biopolymer interfaces-is emphasized, while important applications in tribology and catalysis, producing chemicals and fuels with high turnover and selectivity, are addressed. The basic concepts surrounding various properties of surfaces such as structure, thermodynamics, dynamics, electrical properties, and surface chemical bonds are presented. The techniques of atomic and molecular scale studies of surfaces are listed with references to up-to-date review papers. For advanced readers, this book covers recent developments in in-situ surface analysis such as high- pressure scanning tunneling microscopy, ambient pressure X-ray photoelectron spectroscopy, and sum frequency generation vibrational spectroscopy (SFG). Tables listing surface structures and data summarizing the kinetics of catalytic reactions over metal surfaces are also included. New to this edition: A discussion of new physical and chemical properties of nanoparticles Ways to utilize new surface science techniques to study properties of polymers, reaction intermediates, and mobility of atoms and molecules at surfaces Molecular-level studies on the origin of the selectivity for several catalytic reactions A microscopic understanding of mechanical properties of surfaces Updated tables of experimental data A new chapter on "soft" surfaces, polymers, and biointerfaces Introduction to Surface Chemistry and Catalysis serves as a textbook for undergraduate and graduate students taking advanced courses in physics, chemistry, engineering, and materials science, as well as researchers in surface science, catalysis science, and their applications.
Author : Gernot Frenking
Publisher : John Wiley & Sons
ISBN 13 : 352766467X
Total Pages : 566 pages
Book Rating : 4.5/5 (276 download)
Download or read book The Chemical Bond written by Gernot Frenking and published by John Wiley & Sons. This book was released on 2014-06-13 with total page 566 pages. Available in PDF, EPUB and Kindle. Book excerpt: A unique overview of the different kinds of chemical bonds that can be found in the periodic table, from the main-group elements to transition elements, lanthanides and actinides. It takes into account the many developments that have taken place in the field over the past few decades due to the rapid advances in quantum chemical models and faster computers. This is the perfect complement to "Chemical Bonding - Fundamentals and Models" by the same editors, who are two of the top scientists working on this topic, each with extensive experience and important connections within the community.
Author : Linus Pauling
Publisher :
ISBN 13 :
Total Pages : 644 pages
Book Rating : 4.:/5 (79 download)
Download or read book The Nature of the Chemical Bond written by Linus Pauling and published by . This book was released on 1960 with total page 644 pages. Available in PDF, EPUB and Kindle. Book excerpt: Resonance and the chemical bond. The partial ionic character of covalent bonds and the relative electronegativity of atoms.The directed bond. Bond strengths and bond angles. The magnetic criterion for bond type. The resonance of molecules among several valence-bond structures. Interatomic distances and their relation to the structure of molecules and crystals. Types of resonance in molecules. The structure of molecules and complex ions involving bonds with partial double-bond character. The one-electron bond and the three-electron bond. The hydrogen bond. The sizes of ions and the structure of ionic crystals. The metallic bond. A summarizing discussion of resonance and its significance for chemistry.
Author : Rutger A. van Santen
Publisher : John Wiley & Sons
ISBN 13 : 3527694501
Total Pages : 190 pages
Book Rating : 4.5/5 (276 download)
Download or read book Modern Heterogeneous Catalysis written by Rutger A. van Santen and published by John Wiley & Sons. This book was released on 2017-02-15 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by one of the world's leading experts on the topic, this advanced textbook is the perfect introduction for newcomers to this exciting field. Concise and clear, the text focuses on such key aspects as kinetics, reaction mechanism and surface reactivity, concentrating on the essentials. The author also covers various catalytic systems, catalysis by design, and activation-deactivation. A website with supplementary material offers additional figures, original material and references.
Author : K. Binder
Publisher : Elsevier
ISBN 13 : 9780080529325
Total Pages : 389 pages
Book Rating : 4.5/5 (293 download)
Download or read book Cohesion and Structure of Surfaces written by K. Binder and published by Elsevier. This book was released on 1995-12-18 with total page 389 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the past fifteen years there has been a dramatic increase in the number of different surfaces whose structures have been determined experimentally. For example, whereas in 1979 there were only 25 recorded adsorption structures, to date there are more than 250. This volume is therefore a timely review of the state-of-the-art in this dynamic field. Chapter one contains a compilation of the structural data base on surfaces within a series of tables that allows direct comparison of structural parameters for related systems. Experimental structural trends amongst both clean surfaces and adsorbate systems are highlighted and discussed. The next chapter outlines the successes of local density functional theory in predicting the relaxations and reconstructions of clean metal and semiconductor surfaces, and the behaviour of adsorbates such as hydrogen, oxygen and alkali elements on metal surfaces, thereby explaining some of the experimental trends observed within the database. These ab initio density functional calculations are of ground state properties at the absolute zero of temperature. Chapter three provides an introduction to finite temperature effects in a pedagogical review of current statistical mechanical treatments of phase transitions at surfaces, many of which display the prominent role of fluctuations or non-mean field behaviour. The final chapter discusses the relationship of the reactivity of a surface to its morphology and composition, which is particularly relevant to a fundamental understanding of catalysis.
Author : D A Williams
Publisher : Royal Society of Chemistry
ISBN 13 : 1782626336
Total Pages : pages
Book Rating : 4.7/5 (826 download)
Download or read book The Cosmic-Chemical Bond written by D A Williams and published by Royal Society of Chemistry. This book was released on 2015-10-09 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Introducing astrochemistry to a wide audience, this book describes how molecules formed in chemical reactions occur in a range of environments in interstellar and circumstellar space, from shortly after the Big Bang up to the present epoch. Stressing that chemistry in these environments needs to be driven, it helps identify these drivers and the various chemical networks that operate giving rise to signature molecules that enable the physics of the region to be better understood. The book emphasises, in a non-mathematical way, the chemistry of the Milky Way Galaxy and its planet-forming regions, describes how other galaxies may have rather different chemistries and shows how chemistry was important even in the Early Universe when most of the elements had yet to be formed. This book will appeal to anyone with a general interest in chemistry, from students to professional scientists working in interdisciplinary areas and non-scientists fascinated by the evolving and exciting story of chemistry in the cosmos.
Author : Chang Q Sun
Publisher : Springer
ISBN 13 : 9814585211
Total Pages : 807 pages
Book Rating : 4.8/5 (145 download)
Download or read book Relaxation of the Chemical Bond written by Chang Q Sun and published by Springer. This book was released on 2014-07-08 with total page 807 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this book is to explore the detectable properties of a material to the parameters of bond and non-bond involved and to clarify the interdependence of various properties. This book is composed of four parts; Part I deals with the formation and relaxation dynamics of bond and non-bond during chemisorptions with uncovering of the correlation among the chemical bond, energy band and surface potential barrier (3B) during reactions; Part II is focused on the relaxation of bonds between atoms with fewer neighbors than the ideal in bulk with unraveling of the bond order-length-strength (BOLS) correlation mechanism, which clarifies the nature difference between nanostructures and bulk of the same substance; Part III deals with the relaxation dynamics of bond under heating and compressing with revealing of rules on the temperature-resolved elastic and plastic properties of low-dimensional materials; Part IV is focused on the asymmetric relaxation dynamics of the hydrogen bond (O:H-O) and the anomalous behavior of water and ice under cooling, compressing and clustering. The target audience for this book includes scientists, engineers and practitioners in the area of surface science and nanoscience.
Author : Rutger A Van Santen
Publisher : World Scientific
ISBN 13 : 1800614020
Total Pages : 719 pages
Book Rating : 4.8/5 (6 download)
Download or read book Mechanisms In Heterogeneous Catalysis written by Rutger A Van Santen and published by World Scientific. This book was released on 2023-06-28 with total page 719 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous catalysis has developed over the past two centuries as a technology driven by the needs of society, and is part of Nobel Prize-winning science. This book describes the spectacular increase in molecular understanding of heterogenous catalytic reactions in important industrial processes. Reaction mechanism and kinetics are discussed with a unique focus on their relation with the inorganic chemistry of the catalyst material. An introductory chapter presents the development of catalysis science and catalyst discovery from a historical perspective. Five chapters that form the thrust of the book are organized by type of reaction, reactivity principles, and mechanistic theories, which provide the scientific basis to structure-function relationships of catalyst performance. Present-day challenges to catalysis are sketched in a final chapter. Written by one of the world's leading experts on the topic, this definitive text is an essential reference for students, researchers and engineers working in this multibillion-dollar field.
Author : S.R. Morrison
Publisher : Springer Science & Business Media
ISBN 13 : 1489924981
Total Pages : 448 pages
Book Rating : 4.4/5 (899 download)
Download or read book The Chemical Physics of Surfaces written by S.R. Morrison and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: of available information. Even more importantly, some authors who have contributed substantially to an area may have been overlooked. For this I apologize. I have, however, not attempted to trace techniques or observa tions historically, so there is no implication (unless specified) that the authors referred to were or were not the originators of a given method or observation. I would like to acknowledge discussions with co-workers at SFU for input relative to their specialties, to acknowledge the help of students who have pointed out errors and difficulties in the earlier presentation, and to acknowledge the infinite patience of my wife Phyllis while I spent my sabbatical and more in libraries and punching computers. S. Roy Morrison 0 1 Contents Notation XV 1. Introduction 1 1. 1. Surface States and Surface Sites . 1 1. 1. 1. The Chemical versus Electronic Representation of the Surface. 1 1. 1. 2. The Surface State on the Band Diagram 4 1. 1. 3. The Fermi Energy in the Surface State Model. 6 1. 1. 4. Need for Both Surface Site and Surface State Models 6 1. 2. Bonding of Foreign Species to the Solid Surface 7 1. 2. 1. Types of Interaction. 7 1. 2. 2. The Chemical Bond . 10 1. 2. 3. Acid and Basic Surface Sites on Solids . 13 1. 2. 4. Adsorbate Bonding on Various Solid Types. 16 1. 2. 5. Movement of Surface Atoms: Relaxation, Reconstruction, and Relocation .
Author : Milton Kerker
Publisher : Elsevier
ISBN 13 : 1483276732
Total Pages : 680 pages
Book Rating : 4.4/5 (832 download)
Download or read book Plenary and Invited Lectures written by Milton Kerker and published by Elsevier. This book was released on 2013-09-11 with total page 680 pages. Available in PDF, EPUB and Kindle. Book excerpt: Colloid and Interface Science, Volume I: Plenary and Invited Lectures contains papers presented at the International Conference on Colloids and Surfaces, held in San Juan, Puerto Rico, 21-25 June 1976. It consists of the plenary and invited papers, and a general overview of these papers by A. M. Schwartz. These papers were given during the morning sessions. The volume is organized into 10 parts. Part I contains papers on surface forces. Parts II and III present studies on catalysis and aerosols, respectively. Part IV examines solid surfaces, focusing on newer techniques for exploring surface structure and surface reactions. The papers in Part V deal with water at interfaces, including a lecture on the behavior and structure of water at inorganic surfaces including metals, oxides, and silicates. Part VI covers the rheology of disperse systems, including papers on the effect of inertial forces on the motion of solids through liquids and theoretical studies on diffusive heat flux. Part VII takes up stability and instability in disperse systems, steric stabilization, and colloidal stability. Parts VIII and IX examine biological membranes and surface thermodynamics, respectively. Part X on liquid crystals includes discussion of the structures and properties of this state of matter.
Author : K. Christmann
Publisher : Springer Science & Business Media
ISBN 13 : 3662080095
Total Pages : 283 pages
Book Rating : 4.6/5 (62 download)
Download or read book Introduction to Surface Physical Chemistry written by K. Christmann and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 283 pages. Available in PDF, EPUB and Kindle. Book excerpt:
