The Mechanisms of Atmospheric Oxidation of the Aromatic Hydrocarbons

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Author :
Publisher : Oxford University Press
ISBN 13 : 9780199771547
Total Pages : 570 pages
Book Rating : 4.7/5 (715 download)

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Book Synopsis The Mechanisms of Atmospheric Oxidation of the Aromatic Hydrocarbons by : Jack G. Calvert

Download or read book The Mechanisms of Atmospheric Oxidation of the Aromatic Hydrocarbons written by Jack G. Calvert and published by Oxford University Press. This book was released on 2002-02-14 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text reviews many of the aspects of the chemistry of the aromatic hydrocarbons and a consensus evaluation of the data by seven of the leading atmospheric scientists. The book covers topics ranging from the relative importance of the compounds in ozone and haze development to methods of estimating elemantary rate coefficients based on structural features of the compounds to mechanisms of aerosol generation and atmostpheric reaction of the polycyclic compounds to photochemical processes. It identifies features of the aromatic hydrocarbons requiring further study and appendicies give the structural formulas and nomenclature of the compounds reviewed in the book.

The Mechanisms of Atmospheric Oxidation of Aromatic Hydrocarbons

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Author :
Publisher : Oxford University Press on Demand
ISBN 13 : 9780195146288
Total Pages : 556 pages
Book Rating : 4.1/5 (462 download)

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Book Synopsis The Mechanisms of Atmospheric Oxidation of Aromatic Hydrocarbons by : Jack George Calvert

Download or read book The Mechanisms of Atmospheric Oxidation of Aromatic Hydrocarbons written by Jack George Calvert and published by Oxford University Press on Demand. This book was released on 2002 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text reviews many of the aspects of the chemistry of the aromatic hydrocarbons and a consensus evaluation of the data by seven of the leading atmospheric scientists. The book covers topics ranging from the relative importance of the compounds in ozone and haze development to methods of estimating elemantary rate coefficients based on structural features of the compounds to mechanisms of aerosol generation and atmostpheric reaction of the polycyclic compounds to photochemical processes. It identifies features of the aromatic hydrocarbons requiring further study and appendicies give the structural formulas and nomenclature of the compounds reviewed in the book.

Mechanistic Studies on the OH-initiated Atmospheric Oxidation of Selected Aromatic Hydrocarbons

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Author :
Publisher : Forschungszentrum Jülich
ISBN 13 : 3893368043
Total Pages : 145 pages
Book Rating : 4.8/5 (933 download)

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Book Synopsis Mechanistic Studies on the OH-initiated Atmospheric Oxidation of Selected Aromatic Hydrocarbons by : Sascha Nehr

Download or read book Mechanistic Studies on the OH-initiated Atmospheric Oxidation of Selected Aromatic Hydrocarbons written by Sascha Nehr and published by Forschungszentrum Jülich. This book was released on 2012 with total page 145 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Mechanisms of Atmospheric Oxidation of the Alkanes

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Author :
Publisher : Oxford University Press
ISBN 13 : 0199710880
Total Pages : 1005 pages
Book Rating : 4.1/5 (997 download)

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Book Synopsis Mechanisms of Atmospheric Oxidation of the Alkanes by : Jack G Calvert

Download or read book Mechanisms of Atmospheric Oxidation of the Alkanes written by Jack G Calvert and published by Oxford University Press. This book was released on 2008-09-15 with total page 1005 pages. Available in PDF, EPUB and Kindle. Book excerpt: An international team of eminent atmospheric scientists have prepared Mechanisms of Atmospheric Oxidation of the Alkanes as an authoritative source of information on the role of alkanes in the chemistry of the atmosphere. The book includes the properties of the alkanes and haloalkanes, as well as a comprehensive review and evaluation of the existing literature on the atmospheric chemistry of the alkanes and their major atmospheric oxidation products, and the various approaches now used to model the alkane atmospheric chemistry. Comprehensive coverage is given of both the unsubstituted alkanes and the many haloalkanes. All the existing quality measurements of the rate coefficients for the reactions of OH, Cl, O(3P), NO3, and O3 with the alkanes, the haloalkanes, and their major oxidation products have been reviewed and evaluated. The expert authors then give recommendations of the most reliable kinetic data. They also review the extensive literature on the mechanisms and rates and modes of photodecomposition of the haloalkanes and the products of atmospheric oxidation of the alkanes and the haloalkanes, and make recommendations for future use by atmospheric scientists. The evaluations presented allow an extrapolation of the existing kinetic and photochemical data to those alkanes and haloalkanes that are as yet unstudied. The current book should be of special interest and value to the modelers of atmospheric chemistry as a useful input for development of realistic modules designed to simulate the atmospheric chemistry of the alkanes, their major oxidation products, and their influence on ozone and other trace gases within the troposphere.

Mechanisms of Atmospheric Oxidation of the Oxygenates

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Author :
Publisher : OUP USA
ISBN 13 : 0199767076
Total Pages : 1634 pages
Book Rating : 4.1/5 (997 download)

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Book Synopsis Mechanisms of Atmospheric Oxidation of the Oxygenates by : Jack Calvert

Download or read book Mechanisms of Atmospheric Oxidation of the Oxygenates written by Jack Calvert and published by OUP USA. This book was released on 2011-09-29 with total page 1634 pages. Available in PDF, EPUB and Kindle. Book excerpt: Prepared by an international team of eminent atmospheric scientists, Mechanisms of Atmospheric Oxidation of the Oxygenates is an authoritative source of information on the role of oxygenates in the chemistry of the atmosphere. The oxygenates, including the many different alcohols, ethers, aldehydes, ketones, acids, esters, and nitrogen-atom containing oxygenates, are of special interest today due to their increased use as alternative fuels and fuel additives. This book describes the physical properties of oxygenates, as well as the chemical and photochemical parameters that determine their reaction pathways in the atmosphere. Quantitative descriptions of the pathways of the oxygenates from release or formation in the atmosphere to final products are provided, as is a comprehensive review and evaluation of the extensive kinetic literature on the atmospheric chemistry of the different oxygenates and their many halogen-atom substituted analogues. This book will be of interest to modelers of atmospheric chemistry, environmental scientists and engineers, and air quality planning agencies as a useful input for development of realistic modules designed to simulate the atmospheric chemistry of the oxygenates, their major oxidation products, and their influence on ozone and other trace gases within the troposhere.

Atmospheric Oxidation of Selected Aromatic Hydrocarbons

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Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (516 download)

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Book Synopsis Atmospheric Oxidation of Selected Aromatic Hydrocarbons by : Romeo Iulian Olariu

Download or read book Atmospheric Oxidation of Selected Aromatic Hydrocarbons written by Romeo Iulian Olariu and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Chemical Processes in Atmospheric Oxidation

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 3642592163
Total Pages : 316 pages
Book Rating : 4.6/5 (425 download)

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Book Synopsis Chemical Processes in Atmospheric Oxidation by : Georges Le Bras

Download or read book Chemical Processes in Atmospheric Oxidation written by Georges Le Bras and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxidation and removal of atmospheric constituents involve complex sequences of reactions which can lead to the production of photo-oxidants such as ozone. In order to understand and model these complex reaction sequences, it is necessary to have a comprehensive understanding of reaction mechanisms and accurate estimates of kinetic parameters for relevant gas-phase atmospheric reactions. This book presents recent advances in the field and includes the following topics: e.g. the oxidation of simple organic compounds, NOx kinetics and mechanisms, OH radical production and rate constants for the OH attack on more complex organic compounds, peroxy and alkoxy radical reactions, photo-oxidation of aromatic and biogenic compounds, and the interaction between radical species.

The Mechanisms of Atmospheric Oxidation of the Alkenes

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Author :
Publisher :
ISBN 13 :
Total Pages : 574 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis The Mechanisms of Atmospheric Oxidation of the Alkenes by : Jack George Calvert

Download or read book The Mechanisms of Atmospheric Oxidation of the Alkenes written by Jack George Calvert and published by . This book was released on 2000 with total page 574 pages. Available in PDF, EPUB and Kindle. Book excerpt: The formation of smog in urban atmospheres involves the interaction of sunlight with an air mixture containing nitrogen oxides and reactive hydrocarbons -- the most reactive class of these hydrocarbons being alkenes. This important new book, by a team of leading atmospheric chemists, reviews and evaluates the existing literature on the atmospheric chemistry of these compounds, focusing on the search for a more quantitative understanding of the phenomenon which can then be applied to control methods. It includes detailed examinations of the reactions of alkenes and even suggests areas for further laboratory studies. This book is ideal for climatologists, meteorologists, and scientists studying the chemistry of the atmosphere and can also serve as a valuable text for graduate courses in atmospheric chemistry and atmospheric science.

A DOAS Study on the Oxidation Mechanism of Aromatic Hydrocarbons Under Simulated Atmospheric Conditions

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Author :
Publisher :
ISBN 13 : 9783898254571
Total Pages : 152 pages
Book Rating : 4.2/5 (545 download)

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Book Synopsis A DOAS Study on the Oxidation Mechanism of Aromatic Hydrocarbons Under Simulated Atmospheric Conditions by : Rainer Volkamer

Download or read book A DOAS Study on the Oxidation Mechanism of Aromatic Hydrocarbons Under Simulated Atmospheric Conditions written by Rainer Volkamer and published by . This book was released on 2001 with total page 152 pages. Available in PDF, EPUB and Kindle. Book excerpt:

A DOAS Study on the Oxidation Mechanism of Aromatic Hydrocarbons Under Simulated Atmospheric Conditions

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (671 download)

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Book Synopsis A DOAS Study on the Oxidation Mechanism of Aromatic Hydrocarbons Under Simulated Atmospheric Conditions by :

Download or read book A DOAS Study on the Oxidation Mechanism of Aromatic Hydrocarbons Under Simulated Atmospheric Conditions written by and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this work was to improve the understanding of the OH-radical initiated oxidation of aromatic hydrocarbons (benzene, toluene, p-xylene (BTX) and 1,3,5-trimethylbenzene (TMB)). These mechanisms are considered a major uncertainty in state-of-the-art photochemical models as they are used to predict photooxidant formation from urban air. Differential Optical Absorption Spectroscopy (DOAS) was employed in a systematic outdoor smog-chamber study at the European Photo Reactor (EUPHORE) located at the CEAM-Institute, Valencia/Spain. The available DOAS system was improved for this purpose. The yields of ring-retaining products (phenol from benzene, phenol-type and aldehyde-type compounds from p-xylene and TMB) and glyoxal (from BTX) were investigated. The phenol yield (Y(PHEN)= 53) was found more than two times higher than presently available literature values. Further, the bicycloalkyl-radical pathway was identified as a major pathway from BTX. It was demonstrated that the results of this study are representative for the atmosphere. Deviations from the the degradation pathways of BTX and TMB were further observed under conditions of high NOx (e.g. several ppm). The results of this work indicate that the representations of aromatics in photochemical models need to be updated. The results indicate that the contribution of aromatic hydrocarbons to the formation of photooxidants (i.e. ozone) is underestimated today.

Volatile Organic Compounds in the Atmosphere

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 0470994150
Total Pages : 512 pages
Book Rating : 4.4/5 (79 download)

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Book Synopsis Volatile Organic Compounds in the Atmosphere by : Ralf Koppmann

Download or read book Volatile Organic Compounds in the Atmosphere written by Ralf Koppmann and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: Every day, large quantities of volatile organic compounds (VOCs) are emitted into the atmosphere from both anthropogenic and natural sources. The formation of gaseous and particulate secondary products caused by oxidation of VOCs is one of the largest unknowns in the quantitative prediction of the earth’s climate on a regional and global scale, and on the understanding of local air quality. To be able to model and control their impact, it is essential to understand the sources of VOCs, their distribution in the atmosphere and the chemical transformations which remove these compounds from the atmosphere. In recent years techniques for the analysis of organic compounds in the atmosphere have been developed to increase the spectrum of detectable compounds and their detection limits. New methods have been introduced to increase the time resolution of those measurements and to resolve more complex mixtures of organic compounds. Volatile Organic Compounds in the Atmosphere describes the current state of knowledge of the chemistry of VOCs as well as the methods and techniques to analyse gaseous and particulate organic compounds in the atmosphere. The aim is to provide an authoritative review to address the needs of both graduate students and active researchers in the field of atmospheric chemistry research.

Mechanisms of Atmospheric Oxidation of the Oxygenates

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Author :
Publisher : Oxford University Press
ISBN 13 : 0199877475
Total Pages : 1634 pages
Book Rating : 4.1/5 (998 download)

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Book Synopsis Mechanisms of Atmospheric Oxidation of the Oxygenates by : Jack Calvert

Download or read book Mechanisms of Atmospheric Oxidation of the Oxygenates written by Jack Calvert and published by Oxford University Press. This book was released on 2011-08-01 with total page 1634 pages. Available in PDF, EPUB and Kindle. Book excerpt: Prepared by an international team of eminent atmospheric scientists, Mechanisms of Atmospheric Oxidation of the Oxygenates is an authoritative source of information on the role of oxygenates in the chemistry of the atmosphere. The oxygenates, including the many different alcohols, ethers, aldehydes, ketones, acids, esters, and nitrogen-atom containing oxygenates, are of special interest today due to their increased use as alternative fuels and fuel additives. This book describes the physical properties of oxygenates, as well as the chemical and photochemical parameters that determine their reaction pathways in the atmosphere. Quantitative descriptions of the pathways of the oxygenates from release or formation in the atmosphere to final products are provided, as is a comprehensive review and evaluation of the extensive kinetic literature on the atmospheric chemistry of the different oxygenates and their many halogen-atom substituted analogues. This book will be of interest to modelers of atmospheric chemistry, environmental scientists and engineers, and air quality planning agencies as a useful input for development of realistic modules designed to simulate the atmospheric chemistry of the oxygenates, their major oxidation products, and their influence on ozone and other trace gases within the troposhere.

Mechanisms of Atmospheric Oxidation of the Alkanes

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Author :
Publisher : OUP USA
ISBN 13 : 019536581X
Total Pages : 1005 pages
Book Rating : 4.1/5 (953 download)

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Book Synopsis Mechanisms of Atmospheric Oxidation of the Alkanes by : Jack G Calvert

Download or read book Mechanisms of Atmospheric Oxidation of the Alkanes written by Jack G Calvert and published by OUP USA. This book was released on 2008-09-15 with total page 1005 pages. Available in PDF, EPUB and Kindle. Book excerpt: An authoritative source of information on the role of alkanes in the chemistry of the atmosphere.

Atmospheric Acidity

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Publisher : Springer Science & Business Media
ISBN 13 : 9781851667772
Total Pages : 624 pages
Book Rating : 4.6/5 (677 download)

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Book Synopsis Atmospheric Acidity by : Miroslav Radojevic

Download or read book Atmospheric Acidity written by Miroslav Radojevic and published by Springer Science & Business Media. This book was released on 1992-12-31 with total page 624 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the first publication to offer a comprehensive and balanced view of atmospheric acidity. It is organised in three sections. The first part consists of reviews of sources of acidic compounds, the second part outlines the environmental consequences and the final part discusses the technological, legal and political aspects of control strategies.

Atmospheric Oxidation and Antioxidants

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Publisher : Elsevier
ISBN 13 : 0444597026
Total Pages : 556 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Atmospheric Oxidation and Antioxidants by : Bozzano G Luisa

Download or read book Atmospheric Oxidation and Antioxidants written by Bozzano G Luisa and published by Elsevier. This book was released on 2012-12-02 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume examines the oxidation chemistry of carbon-based materials in more detail with emphasis on the technological phenomena that result from the attack of oxygen and the practical procedures developed to prevent them.

Toxicological Profile for Polycyclic Aromatic Hydrocarbons

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Publisher :
ISBN 13 :
Total Pages : 500 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Toxicological Profile for Polycyclic Aromatic Hydrocarbons by :

Download or read book Toxicological Profile for Polycyclic Aromatic Hydrocarbons written by and published by . This book was released on 1995 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Atmospheric Multiphase Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 111942240X
Total Pages : 765 pages
Book Rating : 4.1/5 (194 download)

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Book Synopsis Atmospheric Multiphase Chemistry by : Hajime Akimoto

Download or read book Atmospheric Multiphase Chemistry written by Hajime Akimoto and published by John Wiley & Sons. This book was released on 2020-04-01 with total page 765 pages. Available in PDF, EPUB and Kindle. Book excerpt: An important guide that highlights the multiphase chemical processes for students and professionals who want to learn more about aerosol chemistry Atmospheric Multiphase Reaction Chemistry provides the information and knowledge of multiphase chemical processes and offers a review of the fundamentals on gas-liquid equilibrium, gas phase reactions, bulk aqueous phase reactions, and gas-particle interface reactions related to formation of secondary aerosols. The authors—noted experts on the topic—also describe new particle formation, and cloud condensation nuclei activity. In addition, the text includes descriptions of field observations on secondary aerosols and PM2.5. Atmospheric aerosols play a critical role in air quality and climate change. There is growing evidence that the multiphase reactions involving heterogeneous reactions on the air-particle interface and the reactions in the bulk liquid phase of wet aerosol and cloud/fog droplets are important processes forming secondary aerosols in addition to gas-phase oxidation reactions to form low-volatile compounds. Comprehensive in scope, the book offers an understanding of the topic by providing a historical overview of secondary aerosols, the fundamentals of multiphase reactions, gas-phase reactions of volatile organic compounds, aqueous phase and air-particle interface reactions of organic compound. This important text: Provides knowledge on multiphase chemical processes for graduate students and research scientists Includes fundamentals on gas-liquid equilibrium, gas phase reactions, bulk aqueous phase reactions, and gas-particle interface reactions related to formation of secondary aerosols Covers in detail reaction chemistry of secondary organic aerosols Written for students and research scientists in atmospheric chemistry and aerosol science of environmental engineering, Atmospheric Multiphase Reaction Chemistry offers an essential guide to the fundamentals of multiphase chemical processes.