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The Belousov Zhabotinskii Reaction
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Book Synopsis The Belousov-Zhabotinskii Reaction by : J.J. Tyson
Download or read book The Belousov-Zhabotinskii Reaction written by J.J. Tyson and published by Springer Science & Business Media. This book was released on 2013-03-13 with total page 138 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1958 B. P. Belousov discovered that the oxidation of citric acid by bromate in the presence of cerium ions does not proceed to equilibrium methodically and uniformly, like most chemical reactions, but rather oscillates with clocklike precision between a yellow and colorless state. See Fig. 11. 1, p. 30. A. M. Zhabotinskii followed up on Belousov's original observation and in 1964 his first investigations appeared in the Russian journal Biofizika. Though H. Degn (in Copenhagen at the time) knew of Zhabotinskii's work and published his own account of the mechanism of oscillation in Nature (1967), this interesting reaction attracted little attention among Western scientists until 1968, when Zhabotinskii and his coworkers and Busse (from Braunschweig, W. Germany) reported on their work at an international conference on biological and biochemical oscillators held in Prague. Shortly thereafter appeared· a flurry of papers on temporal oscillations and spatial patterns in this reaction system. Vavilin and Zhabotinskii (1969) [and later Kasperek and Bruice (1971)] studied the kinetics of the oxidation 3 of Ce+ by Br0 and the oxidation of organic species by Ce+4. Busse (1969) 3 reported his observation of colored bands of chemical activity propagating up and down in a long tube of unstirred solution. Zaikin and Zhabotinskii (1970) observed circular chemical waves in thin layers of solution.
Book Synopsis Frontiers in Mathematical Biology by : Simon A. Levin
Download or read book Frontiers in Mathematical Biology written by Simon A. Levin and published by Springer Science & Business Media. This book was released on 2013-03-13 with total page 637 pages. Available in PDF, EPUB and Kindle. Book excerpt: From a mathematical point of view, physiologically structured population models are an underdeveloped branch of the theory of infinite dimensional dynamical systems. We have called attention to four aspects: (i) A choice has to be made about the kind of equations one extracts from the predominantly verbal arguments about the basic assumptions, and subsequently uses as a starting point for a rigorous mathematical analysis. Though differential equations are easy to formulate (different mechanisms don't interact in infinites imal time intervals and so end up as separate terms in the equations) they may be hard to interpret rigorously as infinitesimal generators. Integral equations constitute an attractive alternative. (ii) The ability of physiologically structured population models to increase our un derstanding of the relation between mechanisms at the i-level and phenomena at the p-level will depend strongly on the development of dynamical systems lab facilities which are applicable to this class of models. (iii) Physiologically structured population models are ideally suited for the for mulation of evolutionary questions. Apart from the special case of age (see Charlesworth 1980, Yodzis 1989, Caswell 1989, and the references given there) hardly any theory exists at the moment. This will, hopefully, change rapidly in the coming years. Again the development of appropriate software may turn out to be crucial.
Book Synopsis The Belousov-Zhabotinskii Reaction by : J J Tyson
Download or read book The Belousov-Zhabotinskii Reaction written by J J Tyson and published by . This book was released on 1976-07-01 with total page 144 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The History of Research on Chemical Periodic Processes by : Alexander Pechenkin
Download or read book The History of Research on Chemical Periodic Processes written by Alexander Pechenkin and published by Springer. This book was released on 2018-08-24 with total page 93 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a survey of the historic development of selected areas of chemistry and chemical physics, discussing in detail the European, American and Russian approaches to the development of chemistry. Other key topics include the kinetics and non-linear thermodynamics of chemical reactions and mathematical modeling, which have found new applications in the theory of dynamical systems. The first observations of the periodicity of chemical reactions were lost in the mist of time. In the second half of the 19th century, the phenomenon of chemical periodicity was studied in relation to electrochemistry, solutions and colloids. Discovered in the late 19th century, Liesegang rings are still enigmatic and remain attractive for researchers. However, the discovery of the Belousov–Zhabotinsky reaction marked the successful culmination of the efforts to find a true chemical oscillatory reaction. The book investigates chemical phenomena that were neglected in the past, but have been rediscovered, placing them into a new conceptual framework. For example, it notes that William Bray, who discovered the first oscillatory homogeneous reaction in 1921, was influenced by the first bio-mathematicians who predicted chemical oscillations in homogeneous systems.
Book Synopsis Chemical Kinetics and Reaction Dynamics by : Santosh K. Upadhyay
Download or read book Chemical Kinetics and Reaction Dynamics written by Santosh K. Upadhyay and published by Springer Science & Business Media. This book was released on 2007-04-29 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical Kinetics and Reaction Dynamics brings together the major facts and theories relating to the rates with which chemical reactions occur from both the macroscopic and microscopic point of view. This book helps the reader achieve a thorough understanding of the principles of chemical kinetics and includes: Detailed stereochemical discussions of reaction steps Classical theory based calculations of state-to-state rate constants A collection of matters on kinetics of various special reactions such as micellar catalysis, phase transfer catalysis, inhibition processes, oscillatory reactions, solid-state reactions, and polymerization reactions at a single source. The growth of the chemical industry greatly depends on the application of chemical kinetics, catalysts and catalytic processes. This volume is therefore an invaluable resource for all academics, industrial researchers and students interested in kinetics, molecular reaction dynamics, and the mechanisms of chemical reactions.
Book Synopsis Chemical Oscillations and Instabilities by : Peter Gray
Download or read book Chemical Oscillations and Instabilities written by Peter Gray and published by Oxford University Press on Demand. This book was released on 1994 with total page 453 pages. Available in PDF, EPUB and Kindle. Book excerpt: Scientists in many fields are now expressing considerable interest in non-linearity and the ideas of oscillations and chaos. Chemical reactions provide perfect examples of these phenomena, as oscillating reactions, explosions, ignition, travelling waves, patterns, quasiperiodicity, and chaosare all features of chemical kinetics.Now available in paperback, this book introduces non-linear phenomena in chemical kinetics using simple model schemes. These models involve chemical feedback, such as chain branching, autocatalysis, and self-heating. The emphasis is on physical and pictorial representation, and on identifying thosegross features which are essential. The experimental conditions under which such behaviour will occur can be predicted using simple mathematical recipes, and these are also included.The first part of the book begins with a discussion of long-lived oscillations for autocatalytic or exothermic reactions in closed vessels. Stationary states, bistability, and oscillations in continuous flow reactors and diffusion cells are then considered. This is followed by chemical wavepropagation and by pattern selection and oscillations. Complex oscillations, quasiperiodicity, and chemical chaos, either forced or spontaneous, are introduced. Part 2 deals with real experimental systems, describing observed experimental behaviour and its interpretation in terms of the underlyingchemical mechanisms or simplified models. The Belousov-Zhabotinskii reactions is discussed in some detail as the most extensively studied system, and the behaviour of important gas phase reactions is presented.
Book Synopsis An Introduction to Nonlinear Chemical Dynamics by : Irving R. Epstein
Download or read book An Introduction to Nonlinear Chemical Dynamics written by Irving R. Epstein and published by Oxford University Press. This book was released on 1998-10-22 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: Just a few decades ago, chemical oscillations were thought to be exotic reactions of only theoretical interest. Now known to govern an array of physical and biological processes, including the regulation of the heart, these oscillations are being studied by a diverse group across the sciences. This book is the first introduction to nonlinear chemical dynamics written specifically for chemists. It covers oscillating reactions, chaos, and chemical pattern formation, and includes numerous practical suggestions on reactor design, data analysis, and computer simulations. Assuming only an undergraduate knowledge of chemistry, the book is an ideal starting point for research in the field. The book begins with a brief history of nonlinear chemical dynamics and a review of the basic mathematics and chemistry. The authors then provide an extensive overview of nonlinear dynamics, starting with the flow reactor and moving on to a detailed discussion of chemical oscillators. Throughout the authors emphasize the chemical mechanistic basis for self-organization. The overview is followed by a series of chapters on more advanced topics, including complex oscillations, biological systems, polymers, interactions between fields and waves, and Turing patterns. Underscoring the hands-on nature of the material, the book concludes with a series of classroom-tested demonstrations and experiments appropriate for an undergraduate laboratory.
Book Synopsis Out-of-Equilibrium (Supra)molecular Systems and Materials by : Nicolas Giuseppone
Download or read book Out-of-Equilibrium (Supra)molecular Systems and Materials written by Nicolas Giuseppone and published by John Wiley & Sons. This book was released on 2021-03-30 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: A must-have resource that covers everything from out-of-equilibrium chemical systems and materials to dissipative self-assemblies Out-of-Equilibrium Supramolecular Systems and Materials presents a comprehensive overview of the synthetic approaches that use supramolecular bonds in various out-of-thermodynamic equilibrium situations. With contributions from noted experts on the topic, the text contains information on the design of dissipative self-assemblies that maintain their structures when fueled by an external source of energy. The contributors also examine molecules and nanoscale objects and materials that can produce mechanical work based on molecular machines. Additionally, the book explores non-equilibrium supramolecular polymers that can be trapped in kinetically stable states, as well as out-of-equilibrium chemical systems and oscillators that are important to understand the emergence of complex behaviors and, in particular, the origin of life. This important book: Offers comprehensive coverage of fields from design of dissipative self-assemblies to non-equilibrium supramolecular polymers Presents information on a highly emerging and interdisciplinary topic Includes contributions from internationally renowned scientists Written for chemists, physical chemists, biochemists, material scientists, Out-of-Equilibrium Supramolecular Systems and Materials is an indispensable resource written by top scientists in the field.
Book Synopsis Classic Chemistry Demonstrations by : Ted Lister
Download or read book Classic Chemistry Demonstrations written by Ted Lister and published by Royal Society of Chemistry. This book was released on 1995 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: An essential resource book for all chemistry teachers, containing a collection of experiments for demonstration in front of a class of students from school to undergraduate age.
Book Synopsis Artificial Life and Evolutionary Computation by : Marcello Pelillo
Download or read book Artificial Life and Evolutionary Computation written by Marcello Pelillo and published by Springer. This book was released on 2018-04-02 with total page 323 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book constitutes the revised selected papers of the 12th Italian Workshop on Advances in Artificial Life, Evolutionary Computation, WIVACE 2017, held in Venice, Italy, in September 2017.The 23 full papers presented were thoroughly reviewed and selected from 33 submissions. They cover the following topics: physical-chemical phenomena; biological systems; economy and society; complexity; optimization.
Book Synopsis Noise-Induced Transitions by : W. Horsthemke
Download or read book Noise-Induced Transitions written by W. Horsthemke and published by Springer Science & Business Media. This book was released on 2006-09-12 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: The study of phase transitions is among the most fascinating fields in physics. Originally limited to transition phenomena in equilibrium systems, this field has outgrown its classical confines during the last two decades. The behavior of far from equilibrium systems has received more and more attention and has been an extremely active and productive subject of research for physicists, chemists and biologists. Their studies have brought about a more unified vision of the laws which govern self-organization processes of physico-chemical and biological sys tems. A major achievement has been the extension of the notion of phase transi tion to instabilities which occur only in open nonlinear systems. The notion of phase transition has been proven fruitful in apphcation to nonequilibrium ins- bihties known for about eight decades, like certain hydrodynamic instabilities, as well as in the case of the more recently discovered instabilities in quantum optical systems such as the laser, in chemical systems such as the Belousov-Zhabotinskii reaction and in biological systems. Even outside the realm of natural sciences, this notion is now used in economics and sociology. In this monograph we show that the notion of phase transition can be extend ed even further. It apphes also to a new class of transition phenomena which occur only in nonequilibrium systems subjected to a randomly fluctuating en vironment.
Book Synopsis A Review of the Belousov-Zhabotinsky Reaction by : Adam Miller
Download or read book A Review of the Belousov-Zhabotinsky Reaction written by Adam Miller and published by . This book was released on 2002 with total page 70 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Wave Motion written by J. Billingham and published by Cambridge University Press. This book was released on 2001-01-22 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Waves are a ubiquitous and important feature of the physical world, and throughout history it has been a major challenge to understand them. They can propagate on the surfaces of solids and of fluids; chemical waves control the beating of your heart; traffic jams move in waves down lanes crowded with vehicles. This introduction to the mathematics of wave phenomena is aimed at advanced undergraduate courses on waves for mathematicians, physicists or engineers. Some more advanced material on both linear and nonlinear waves is also included, thus making the book suitable for beginning graduate courses. The authors assume some familiarity with partial differential equations, integral transforms and asymptotic expansions as well as an acquaintance with fluid mechanics, elasticity and electromagnetism. The context and physics that underlie the mathematics is clearly explained at the beginning of each chapter. Worked examples and exercises are supplied throughout, with solutions available to teachers.
Book Synopsis Candid Science III by : István Hargittai
Download or read book Candid Science III written by István Hargittai and published by World Scientific. This book was released on 2003-03-21 with total page 520 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this invaluable book, 36 famous chemists, including 18 Nobel laureates, tell the reader about their lives in science, the beginnings of their careers, their aspirations, and their hardships and triumphs. The reader will learn about their seminal discoveries, and the conversations in the book bring out the humanity of these great scientists. Highlighted in the stories are the discovery of new elements and compounds, the VSEPR model, computational chemistry, organic synthesis, natural products, polysaccharides, supramolecular chemistry, peptide synthesis, combinatorial chemistry, X-ray crystallography, the reaction mechanism and kinetics, electron transfer in small and large systems, non-equilibrium systems, oscillating reactions, atmospheric chemistry, chirality, and the history of chemistry. Contents: Glenn T SeaborgWilliam N LipscombNeil BartlettRonald J GillespieLawrence S BartellPaul von Rague SchleyerAlbert EschenmoserGilbert StorkEndre A BalazsAlfred BaderJacquelin K BartonAd BaxDonald J CramJean-Marie LehnBruce MerrifieldArpad FurkaGuy OurissonMildred CohnPaul D BoyerJohn E WalkerHerbert A HauptmanJack D DunitzHartmut MichelJohann DeisenhoferRobert HuberManfred EigenJohn C PolanyiDudley R HerschbachHenry TaubeRudolph A MarcusIlya PrigogineAnatol M ZhabotinskyRichard N ZarePaul J CrutzenReiko KurodaStephen Mason Readership: Chemists and other scientists. Keywords:Chemistry;Nobel Prize;History of Chemistry;Famous ChemistsReviews:“This book makes interesting light reading, especially for chemists who have watched the field develop over the past 30 to 60 years … it makes a worthwhile contribution to the oral history of science, and I recommend it for both libraries and individuals.”Nature “István Hargittai's interviews with eminent scientists are a lively and important way of entering the minds of prominent chemists … this makes a wonderful bedside book that attractively opens up a gallery of people, and a window onto the development of science.”Chemistry & Industry “I have come back to these interviews time after time after my first read through. It's always inspiring to read about people who are good at what they do. To paraphrase Jack Dunitz, if you want value for your money in a predictable way, I think Hargittai's book is a good value. I strongly recommend it.”Southwest Retort “Hargittai has done a superb job in selecting both chemical topics and appropriate interview subjects who know the topics first-hand … Candid Science III is an interesting source of information on both current and recent chemistry and its practitioners, from a first-hand perspective of those practitioners. It also promises to be a valuable sourcebook for historians of the chemistry of this time.”The Alchemist, The ChemWeb Magazine “I recommend this useful volume, suitable for complete reading or browsing, not only to historians of chemistry and science but also to practicing chemists and students, who will benefit from these inspiring stories by some of chemistry's most eminent contributors.”Chemical Heritage “I recommend this handy volume, admirably suited for complete reading or browsing, not only to historians of chemistry and of science but also to practicing scientists, especially beginning ones, as well as to students, who will surely benefit from these inspiring stories by some of chemistry's leading luminaries.”The Chemical Educator
Book Synopsis Mathematical Models in the Applied Sciences by : A. C. Fowler
Download or read book Mathematical Models in the Applied Sciences written by A. C. Fowler and published by Cambridge University Press. This book was released on 1997-11-28 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents a thorough grounding in the techniques of mathematical modelling, and proceeds to explore a range of classical and continuum models from an array of disciplines.
Book Synopsis Chemical Chaos by : Stephen K. Scott
Download or read book Chemical Chaos written by Stephen K. Scott and published by Oxford University Press. This book was released on 1993 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: Table of contents: 1. Introduction. 2. Mappings. 3. Flows. 1. Two-variable systems. 4. Flows II. Three-vairable systems. 5. Forced systems. 6. Coupled systems. 7.Experimental methods. 8. The Belousov-Zhabotinskii reaction and other solution-phase reactions. 9. Gas-phase reactions. 10. Heterogeneous catalysis. 11. Electrodissolution reactions. 12. Biochemical systems. Index.
Book Synopsis Oscillations and Traveling Waves in Chemical Systems by : Maria Burger
Download or read book Oscillations and Traveling Waves in Chemical Systems written by Maria Burger and published by Wiley-Interscience. This book was released on 1985-04-02 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Brings together in one comprehensive volume information on oscillating chemical systems and their experimental behavior. As the first major work in this area, it details their mechanistic interpretation and relationship to theories of oscillatory and related behavior. Topics discussed include: the mathematical aspects of temporal oscillations in reacting systems, chemical oscillators based on iodate ion and hydrogen peroxide, numerical techniques for modeling and analysis oscillating reactions, halogen-based oscillators in a flow reactor, periodically perturbed chemical systems, and the structure and variety of chemical waves.
