Synthesis Of Chiral Bidentate Aminophosphine Palladium Ii Complexes And Their Use In Asymmetric Cycloaddition Reactions

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Artificial Metalloenzymes and MetalloDNAzymes in Catalysis

Author : Montserrat Diéguez
Publisher : John Wiley & Sons
ISBN 13 : 3527804072
Total Pages : 431 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Artificial Metalloenzymes and MetalloDNAzymes in Catalysis by : Montserrat Diéguez

Download or read book Artificial Metalloenzymes and MetalloDNAzymes in Catalysis written by Montserrat Diéguez and published by John Wiley & Sons. This book was released on 2018-02-21 with total page 431 pages. Available in PDF, EPUB and Kindle. Book excerpt: An important reference for researchers in the field of metal-enzyme hybrid catalysis Artificial Metalloenzymes and MetalloDNAzymes in Catalysis offers a comprehensive review of the most current strategies, developed over recent decades, for the design, synthesis, and optimization of these hybrid catalysts as well as material about their application. The contributors—noted experts in the field—present information on the preparation, characterization, and optimization of artificial metalloenzymes in a timely and authoritative manner. The authors present a thorough examination of this interesting new platform for catalysis that combines the excellent selective recognition/binding properties of enzymes with transition metal catalysts. The text includes information on the various applications of metal-enzyme hybrid catalysts for novel reactions, offers insights into the latest advances in the field, and contains an informative perspective on the future: Explores the development of artificial metalloenzymes, the modern and strongly evolving research field on the verge of industrial application Contains a comprehensive reference to the research area of metal-enzyme hybrid catalysis that has experienced tremendous growth in recent years Includes contributions from leading researchers in the field Shows how this new catalysis combines the selective recognition/binding properties of enzymes with transition metal catalysts Written for catalytic chemists, bioinorganic chemists, biochemists, and organic chemists, Artificial Metalloenzymes and MetalloDNAzymes in Catalysis offers a unique reference to the fundamentals, concepts, applications, and the most recent developments for more efficient and sustainable synthesis.

Transition Metal Catalyzed Enantioselective Allylic Substitution in Organic Synthesis

Author : Uli Kazmaier
Publisher : Springer Science & Business Media
ISBN 13 : 3642227481
Total Pages : 354 pages
Book Rating : 4.6/5 (422 download)

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Book Synopsis Transition Metal Catalyzed Enantioselective Allylic Substitution in Organic Synthesis by : Uli Kazmaier

Download or read book Transition Metal Catalyzed Enantioselective Allylic Substitution in Organic Synthesis written by Uli Kazmaier and published by Springer Science & Business Media. This book was released on 2011-10-29 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: Giovanni Poli, Guillaume Prestat, Frédéric Liron, Claire Kammerer-Pentier: Selectivity in Palladium Catalyzed Allylic Substitution.- Jonatan Kleimark and Per-Ola Norrby: Computational Insights into Palladium-mediated Allylic Substitution Reactions.- Ludovic Milhau, Patrick J. Guiry: Palladium-catalyzed enantioselective allylic substitution.- Wen-Bo Liu, Ji-Bao Xia, Shu-Li You: Iridium-Catalyzed Asymmetric Allylic Substitutions.- Christina Moberg: Molybdenum- and Tungsten-Catalyzed Enantioselective Allylic Substitutions.- Jean-Baptiste Langlois, Alexandre Alexakis: Copper-catalyzed enantioselective allylic substitution.- Jeanne-Marie Begouin, Johannes E. M. N. Klein, Daniel Weickmann, B. Plietker: Allylic Substitutions Catalyzed by Miscellaneous Metals.- Barry M. Trost, Matthew L. Crawley: Enantioselective Allylic Substitutions in Natural Product Synthesis.

Principles and Applications of Asymmetric Synthesis

Author : Guo-Qiang Lin
Publisher : John Wiley & Sons
ISBN 13 : 0471465240
Total Pages : 536 pages
Book Rating : 4.4/5 (714 download)

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Book Synopsis Principles and Applications of Asymmetric Synthesis by : Guo-Qiang Lin

Download or read book Principles and Applications of Asymmetric Synthesis written by Guo-Qiang Lin and published by John Wiley & Sons. This book was released on 2003-05-29 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt: Asymmetric synthesis remains a challenge to practicing scientistsas the need for enantiomerically pure or enriched compoundscontinues to increase. Over the last decade, a large amount ofliterature has been published in this field. Principles andApplications of Asymmetric Synthesis consolidates and evaluates themost useful methodologies into a one-volume resource for theconvenience of practicing scientists and students. Authored by internationally renowned scientists in the field, thisreliable reference covers more than 450 reactions and includesimportant stoichiometric as well as catalytic asymmetric reactions.The first chapter reviews the basic principles, commonnomenclature, and analytical methods, and the remainder of the bookis organized according to reaction type. The text examines suchtopics as: Carbon-carbon bond formations involving carbonyls, enamines,imines, and enolates Asymmetric C-O bond formations including epoxidation,dihydroxylation, and aminohydroxylation Asymmetric synthesis using the Diels-Alder reaction and othercyclizations Applications to the total synthesis of natural products Use of enzymes in asymmetric synthesis Practicing chemists in the pharmaceutical, fine chemical, andagricultural professions as well as graduate students will findthat Principles and Applications of Asymmetric Synthesis affordscomprehensive and current coverage.

Chiral Ferrocenes in Asymmetric Catalysis

Author : Li-Xin Dai
Publisher : John Wiley & Sons
ISBN 13 : 3527322809
Total Pages : 433 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Chiral Ferrocenes in Asymmetric Catalysis by : Li-Xin Dai

Download or read book Chiral Ferrocenes in Asymmetric Catalysis written by Li-Xin Dai and published by John Wiley & Sons. This book was released on 2010-02-01 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book meets the long-felt need for a reference on ferrocenes with the focus on catalysis. It provides a thorough overview of the synthesis and characterization of different types of chiral ferrocene ligands, their application to various catalytic asymmetric reactions, and versatile chiral materials as well as drug intermediates synthesized from them. Written by the "who's who" of ferrocene catalysis, this is a guide to the design of new ferrocene ligands and synthesis of chiral synthetic intermediates, and will thus be useful for organic, catalytic and synthetic chemists working in academia, industrial research or process development.

N-Heterocyclic Carbenes in Organocatalysis

Author : Akkattu T. Biju
Publisher : John Wiley & Sons
ISBN 13 : 3527809058
Total Pages : 440 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis N-Heterocyclic Carbenes in Organocatalysis by : Akkattu T. Biju

Download or read book N-Heterocyclic Carbenes in Organocatalysis written by Akkattu T. Biju and published by John Wiley & Sons. This book was released on 2019-01-07 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: Summarizing the emerging field of N-heterocyclic carbenes used in organocatalysis, this is an excellent overview of the synthesis and applications of NHCs focusing on carbon-carbon and carbon-heteroatom bond formation. Alongside comprehensive coverage of the synthesis, characteristics and applications, this handbook and ready reference also includes chapters on NHCs for polymerization reactions and natural product synthesis.

Chiral Ligands

Author : Montserrat Diéguez
Publisher : CRC Press
ISBN 13 : 1000379000
Total Pages : 298 pages
Book Rating : 4.0/5 (3 download)

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Book Synopsis Chiral Ligands by : Montserrat Diéguez

Download or read book Chiral Ligands written by Montserrat Diéguez and published by CRC Press. This book was released on 2021-05-13 with total page 298 pages. Available in PDF, EPUB and Kindle. Book excerpt: Many new drugs on the market are chiral compounds, that is, they can exist in two non-superimposable mirror-image forms. Asymmetric catalysis encompasses a large variety of processes for obtaining such compounds. The performance of the catalyst in those processes largely depends on the ligand that makes up the catalyst. This book describes the most relevant ligand libraries for some key processes, including an overview of the state of art and the key mechanistic aspects that favor a high catalytic performance. Key Features: The book presents historical content from the time of discovery for each family of ligands. Provides a description of the synthetic route and the ligand library's application in various catalytic asymmetric reactions Suitable as supplementary reading for courses targeting the design, synthesis and application of chiral catalysts, asymmetric catalysis and sustainable production Edited by a distinguished scientist in the field, the book has a diverse audience including research groups in homogeneous catalysis, particularly asymmetric transformations

Comprehensive Coordination Chemistry II

Author : J. A. McCleverty
Publisher : Newnes
ISBN 13 : 0080913164
Total Pages : 11845 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Comprehensive Coordination Chemistry II by : J. A. McCleverty

Download or read book Comprehensive Coordination Chemistry II written by J. A. McCleverty and published by Newnes. This book was released on 2003-12-03 with total page 11845 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.

Asymmetric Catalysis

Author : B. Bosnich
Publisher : Taylor & Francis US
ISBN 13 : 9789024732593
Total Pages : 176 pages
Book Rating : 4.7/5 (325 download)

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Book Synopsis Asymmetric Catalysis by : B. Bosnich

Download or read book Asymmetric Catalysis written by B. Bosnich and published by Taylor & Francis US. This book was released on 1986 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the NATO Advanced Research Workshop on Asymmetric Catalysis, Sanibel Island, Florida, USA, January 2-6, 1984

Superbases for Organic Synthesis

Author : Tsutomu Ishikawa
Publisher : John Wiley & Sons
ISBN 13 : 9780470740866
Total Pages : 336 pages
Book Rating : 4.7/5 (48 download)

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Book Synopsis Superbases for Organic Synthesis by : Tsutomu Ishikawa

Download or read book Superbases for Organic Synthesis written by Tsutomu Ishikawa and published by John Wiley & Sons. This book was released on 2009-01-26 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: Guanidines, amidines and phosphazenes have been attracting attention in organic synthesis due to their potential functionality resulting from their extremely strong basicity. They are also promising catalysts because of their potential for easy molecular modification, possible recyclability, and reduced or zero toxicity. Importantly, these molecules can be derived as natural products – valuable as scientists move towards “sustainable chemistry”, where reagents and catalysts are derived from biomaterial sources. Superbases for Organic Synthesis is an essential guide to these important molecules for preparative organic synthesis. Topics covered include the following aspects: an introduction to organosuperbases physicochemical properties of organic superbases amidines and guanidines in organic synthesis phosphazene: preparation, reaction and catalytic role polymer-supported organosuperbases application of organosuperbases to total synthesis related organocatalysts: proton sponges and urea derivatives amidines and guanidines in natural products and medicines Superbases for Organic Synthesis is a comprehensive, authoritative and up-to-date guide to these important reagents for organic chemists, drug discovery researchers and those interested in the chemistry of natural products.

Organophosphorus Chemistry

Author : David W Allen
Publisher : Royal Society of Chemistry
ISBN 13 : 1788018648
Total Pages : 410 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Organophosphorus Chemistry by : David W Allen

Download or read book Organophosphorus Chemistry written by David W Allen and published by Royal Society of Chemistry. This book was released on 2020-04-15 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt: This annual review of the literature presents a comprehensive and critical survey of the vast field of study involving organophosphorus compounds, from phosphines and related P-C bonded compounds to phosphorus acids, phosphine chalcogenides and nucleotides. The Editors have added to the content with a timely chapter on the recent developments in green synthetic approaches in organophosphorus chemistry to reflect current interests in the area. With an emphasis on interdisciplinary content, this book is aimed at the worldwide organic chemistry and engineering research communities.

Palladacycles

Author : Jairton Dupont
Publisher : John Wiley & Sons
ISBN 13 : 3527317813
Total Pages : 433 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Palladacycles by : Jairton Dupont

Download or read book Palladacycles written by Jairton Dupont and published by John Wiley & Sons. This book was released on 2008-10-13 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: From synthesis to applications in catalysis, material science and biology this much-needed book is the first to comprehensively present everything you need to know about palladacycles. Renowned international authors guarantee high-quality content, making this a must-have for everyone working in the field.

Side Reactions in Organic Synthesis

Author : Florencio Zaragoza Dörwald
Publisher : John Wiley & Sons
ISBN 13 : 3527604987
Total Pages : 389 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Side Reactions in Organic Synthesis by : Florencio Zaragoza Dörwald

Download or read book Side Reactions in Organic Synthesis written by Florencio Zaragoza Dörwald and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 389 pages. Available in PDF, EPUB and Kindle. Book excerpt: Most syntheses in the chemical research laboratory fail and usually require several attempts before proceeding satisfactorily. Failed syntheses are not only discouraging and frustrating, but also cost a lot of time and money. Many failures may, however, be avoided by understanding the structure-reactivity relationship of organic compounds. This textbook highlights the competing processes and limitations of the most important reactions used in organic synthesis. By allowing chemists to quickly recognize potential problems this book will help to improve their efficiency and success-rate. A must for every graduate student but also for every chemist in industry and academia. Contents: 1 Organic Synthesis: General Remarks 2 Stereoelectronic Effects and Reactivity 3 The Stability of Organic Compounds 4 Aliphatic Nucleophilic Substitutions: Problematic Electrophiles 5 The Alkylation of Carbanions 6 The Alkylation of Heteroatoms 7 The Acylation of Heteroatoms 8 Palladium-Catalyzed C-C Bond Formation 9 Cyclizations 10 Monofunctionalization of Symmetric Difunctional Substrates

Organic Syntheses, Collective Volume 12

Author : Charles K. Zercher
Publisher : John Wiley & Sons
ISBN 13 : 1118117824
Total Pages : 1606 pages
Book Rating : 4.1/5 (181 download)

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Book Synopsis Organic Syntheses, Collective Volume 12 by : Charles K. Zercher

Download or read book Organic Syntheses, Collective Volume 12 written by Charles K. Zercher and published by John Wiley & Sons. This book was released on 2015-10-19 with total page 1606 pages. Available in PDF, EPUB and Kindle. Book excerpt: Continuing the tradition of providing significant and interesting procedures, Organic Syntheses, Collective Volume XII is a compilation of revised editions of Annual Volumes 85 through 89. The contents of this volume are organized by primarily by reaction type, with the precise classification made according to the bias of the editor, who attempted to ascertain the primary purpose or utility of the procedure.

Axially Chiral Compounds

Author : Bin Tan
Publisher : John Wiley & Sons
ISBN 13 : 3527347127
Total Pages : 338 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Axially Chiral Compounds by : Bin Tan

Download or read book Axially Chiral Compounds written by Bin Tan and published by John Wiley & Sons. This book was released on 2021-11-22 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: Axially Chiral Compounds Explore this comprehensive and current volume summarizing the characteristics, synthesis, and applications of axial chirality Appearing widely in natural products, biologically active molecules, asymmetric chemistry, and material science, axially chiral motifs constitute the core backbones of the majority of chiral ligands and organocatalysts in asymmetric catalysis. In a new work of particular relevance to synthetic chemists, Axially Chiral Compounds: Asymmetric Synthesis and Applications delivers a clearly structured and authoritative volume covering the classification, characteristics, synthesis, and applications of axial chirality. A must read for every synthetic chemist practicing today, the book follows the development history, research status, and applications of axial chirality. An introductory chapter familiarizes the reader with foundational material before the distinguished authors describe the different classes and the synthesis of axial chiral compounds used in asymmetric synthesis. The book concludes with a focus on the applications of chiral ligands, chiral catalysts, and materials. Readers will also benefit from the inclusion of: A thorough introduction to asymmetric synthesis, including biaryls atropisomers, heterobiaryls atropisomers, and non-biaryls atropisomers Explorations of chiral allene, spiro skeletons, and natural products Practical discussions of asymmetric transformation, chiral ligands, and chiral catalysts An examination of miscellaneous applications of axially chiral compounds Perfect for organic chemists, chemists working with or on organometallics, catalytic chemists, and materials scientists, Axially Chiral Compounds: Asymmetric Synthesis and Applications will also earn a place in the libraries of natural products chemists who seek a one-stop reference for compounds exhibiting axial chirality.

Asymmetric Functionalization of C-H Bonds

Author : Shu-Li You
Publisher : Royal Society of Chemistry
ISBN 13 : 1782621024
Total Pages : 433 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis Asymmetric Functionalization of C-H Bonds by : Shu-Li You

Download or read book Asymmetric Functionalization of C-H Bonds written by Shu-Li You and published by Royal Society of Chemistry. This book was released on 2015-08-13 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: Asymmetric C-H direct functionalization reactions are one of the most active and fascinating areas of research in organic chemistry due to their significance in the construction of molecular complexity without pre-activation, and the step economy and atom economy features in potential synthetic application. Distinguishing the reactivity among numerous C–H bonds in one single molecule represents one of the most challenging issues in organic synthesis and requires precise reaction design. As such, this field is now receiving increasing attention from researchers. This book provides the first comprehensive review of this field, summarizing the origin, mechanism, scope and applications of the asymmetric C-H bond functionalization reaction. It covers organocatalytic reactions and transition-metal-catalyzed reactions, as well as asymmetric C-H functionalization reactions not described in other books. Written by a leading expert in this field, the book is ideal for postgraduates and researchers working in organic synthesis, catalysis, and organometallic chemistry.

Privileged Chiral Ligands and Catalysts

Author : Qi-Lin Zhou
Publisher : John Wiley & Sons
ISBN 13 : 3527635211
Total Pages : 670 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Privileged Chiral Ligands and Catalysts by : Qi-Lin Zhou

Download or read book Privileged Chiral Ligands and Catalysts written by Qi-Lin Zhou and published by John Wiley & Sons. This book was released on 2011-02-10 with total page 670 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalytic asymmetric synthesis has been one of the most active research areas in chemistry (Nobel Prize in 2001). The development of efficient chiral catalysts plays a crucial role in asymmetric catalysis. Although many chiral ligands/catalysts have been developed in the past decades, the most efficient catalysts are derived from a few core structures, called "privileged chiral catalysts". This ultimate "must have" and long awaited reference for every chemist working in the field of asymmetric catalysis starts with the core structure of the catalysts, explaining why a certain ligand or catalyst is so successful. It describes in detail the history, the basic structural characteristics, and the applications of these "privileged catalysts". This novel presentation provides readers with a much deeper insight into the topic and makes it a must-have for organic chemists, catalytic chemists, chemists working with/on organometallics, chemists in industry, and libraries. From the contents: * BINAP * Bisphosphacycles - From DuPhos and BPE to a Diverse Set of Broadly Applied Ligands * Josiphos Ligands: From Discovery to Technical Applications * Chiral Spiro Ligands * Chiral Bisoxazoline Ligands * PHOX Ligands * Chiral Salen Complexes * BINOL * TADDOLate Ligands * Cinchona Alkaloids * Proline Derivatives

Progress in Inorganic Chemistry

Author : Kenneth D. Karlin
Publisher : Wiley-Interscience
ISBN 13 : 9780471326236
Total Pages : 616 pages
Book Rating : 4.3/5 (262 download)

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Book Synopsis Progress in Inorganic Chemistry by : Kenneth D. Karlin

Download or read book Progress in Inorganic Chemistry written by Kenneth D. Karlin and published by Wiley-Interscience. This book was released on 1999-03-05 with total page 616 pages. Available in PDF, EPUB and Kindle. Book excerpt: Straight from the frontier of scientific investigation . . . Nowhere is creative scientific talent busier than in the world of inorganic chemistry. And the respected Progress in Inorganic Chemistry series has long served as an exciting showcase for new research in this area. With contributions from internationally renowned chemists, this latest volume reports the most recent advances in the field, providing a fascinating window on the emerging state of the science. "This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews."-Journal of the American Chemical Society. "[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry."-Chemistry in Britain. CONTENTS OF VOLUME 48: * Synthesis, Structure, and Properties of Organic-Inorganic Perovskites and Related Materials (David B. Mitzi, IBM T. J. Watson Research Center, Yorktown Heights, New York). * Transition Metals in Polymeric ¯1 -Conjugated Organic Frameworks (Richard P. Kingsborough and Timothy M. Swager, Massachusetts Institute of Technology, Cambridge, Massachusetts). * The Transition Metal Coordination Chemistry of Hemilabile Ligands (Caroline S. Slone, Dana A. Weinberger, and Chad A. Mirkin, Northwestern University, Evanston, Illinois). * Organometallic Fluorides of the Main Group Metals Containing the C-M-F Fragment (Balaji R. Jagirdar, Eamonn F. Murphy, and Herbert W. Roesky, Universität Göttingen, Germany). * Coordination Complex Impregnated Molecular Sieves-Synthesis, Characterization, Reactivity, and Catalysis (Partha P. Paul, Southwest Research Institute, San Antonio, Texas). * Advances in Metal Boryl and Metal-Mediated B-X Activation Chemistry (Milton R. Smith III, Michigan State University, East Lansing, Michigan).