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Synthesis And Reactivity Studies Of Rhenium Complexes With Sulfur Containing Organic Ligands
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Book Synopsis Synthesis and Reactivity Studies of Rhenium Complexes with Sulfur Containing Organic Ligands by : Jeffery Alan Kanney
Download or read book Synthesis and Reactivity Studies of Rhenium Complexes with Sulfur Containing Organic Ligands written by Jeffery Alan Kanney and published by . This book was released on 2002 with total page 406 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Characterization, and Reactivity Studies of Hexanuclear Rhenium Cluster Complexes with Oxygen and Sulfur Donor Ligands by : Julia A. Edwards
Download or read book Synthesis, Characterization, and Reactivity Studies of Hexanuclear Rhenium Cluster Complexes with Oxygen and Sulfur Donor Ligands written by Julia A. Edwards and published by . This book was released on 2008 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Reactivity, and Removal Studies of Rhenium Based Cluster Complexes with Heterocyclic Terminal Ligands by : Joan N. Tirado
Download or read book Synthesis, Reactivity, and Removal Studies of Rhenium Based Cluster Complexes with Heterocyclic Terminal Ligands written by Joan N. Tirado and published by . This book was released on 2011 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Reactivity, and Structural Studies of Rhodium(III) and Rhodium(II) Complexes of Novel Bis(oxazoline) Pincer Ligands by : Jennifer Krumper
Download or read book Synthesis, Reactivity, and Structural Studies of Rhodium(III) and Rhodium(II) Complexes of Novel Bis(oxazoline) Pincer Ligands written by Jennifer Krumper and published by . This book was released on 2003 with total page 460 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Rhenium Complexes with O, N, S Ligands by : Sulochana Junnotula
Download or read book Rhenium Complexes with O, N, S Ligands written by Sulochana Junnotula and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The main focus of this thesis is the synthesis and characterization of nonradioactive rhenium complexes containing O, N, S ligands. Chapter 2 describes the rhenium labeling of four somatostatin analogues. Confirmation for the formation of nonradioactive rhenium labeled peptides was accomplished with LC-MS. Purification was done by analytical HPLC. Chapter 3 describes the synthesis, characterization and determination of acid dissociation constant values for the two rhenium complexes with ethylenediamine type ligands. This chapter also describes the synthesis and characterization of a rhenium amine complex with the 2-aminoethanethiolate ligand and a phosphine ligand.
Book Synopsis Synthesis, Reactions and Mechanistic Studies of Rhenium-platinum Complexes by : Yan Wang
Download or read book Synthesis, Reactions and Mechanistic Studies of Rhenium-platinum Complexes written by Yan Wang and published by . This book was released on 1993 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactivity of Rhenium and Technetium Polyaryl Complexes by : Christopher Alan Morse
Download or read book Synthesis and Reactivity of Rhenium and Technetium Polyaryl Complexes written by Christopher Alan Morse and published by . This book was released on 1998 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Characterization, and Reactivity of Technetium and Rhenium Complexes in Intermediate Oxidation States by : Harvey Stewart Trop
Download or read book Synthesis, Characterization, and Reactivity of Technetium and Rhenium Complexes in Intermediate Oxidation States written by Harvey Stewart Trop and published by . This book was released on 1979 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Optical and Luminescence Studies of Rhenium(i) Diimine Alkynyl Complexes and Their Utilization As Building Blocks for the Assembly of Multinuclear and Mixed-Metal Complexes by : CHAN-FUNG. LAM
Download or read book Synthesis, Optical and Luminescence Studies of Rhenium(i) Diimine Alkynyl Complexes and Their Utilization As Building Blocks for the Assembly of Multinuclear and Mixed-Metal Complexes written by CHAN-FUNG. LAM and published by . This book was released on 2017-01-26 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Synthesis, Optical and Luminescence Studies of Rhenium(I) Diimine Alkynyl Complexes and Their Utilization as Building Blocks for the Assembly of Multinuclear and Mixed-metal Complexes" by Chan-fung, Lam, 林親鳳, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Abstract of thesis entitled SYNTHESIS, OPTICAL AND LUMINESCENCE STUDIES OF RHENIUM(I) DIIMINE ALKYNYL COMPLEXES AND THEIR UTILIZATION AS BUILDING BLOCKS FOR THE ASSEMBLY OF MULTINUCLEAR AND MIXED-METAL COMPLEXES submitted by LAM Chan Fung for the degree of Doctor of Philosophy at The University of Hong Kong in July 2005 A series of mononuclear rhenium(I) diimine complexes with hyperbranched or functional alkynyl ligands, [C H -1,3-(HC C C H C C) -5-{Re(CO) (N N)(C C 6 3 6 4 2 3 t C H C C)}] (N N = bpy, Bu bpy) and [Re(CO) (N N)(C C C C R)] (R = C H I-p, 6 4 2 3 6 4 C H C C SiMe -p, CHC C H-p, C H OSiMe Bu-p, CHOH-p) have been 6 4 3 6 4 6 4 2 6 4 synthesized. The X-ray crystal structures of [CH-1,3-(HCCCHCC)-5-{Re(CO)(Bubpy)(CCCHCC)}] and 63 64 2 32 64 [Re(CO)(Bubpy)(CCCCCHCCH-p)] have been presented. By employing 32 64 [Re(CO) (N N)(C C C C C H I-p)] as a precursor, a series of dinuclear rhenium(I) 3 6 4 alkynyl complexes with extended conjugation, [Re(CO) (N N)(C CC C C H C C 3 6 4 t (C H ) C C C H C CC C)Re(CO) (N N)] [n = 0, 1; N N = Bu bpy, (CF ) bpy], 6 4 n 6 4 3 2 3 2 have been prepared. Additionally, a series of symmetrical and unsymmetrical trinuclear rhenium(I) alkynyl complexes, [C H -1,3,5-{Re(CO) (N N)(C C C C 6 3 3 t t C H C C)} ] [N N = Bu bpy, (CF ) bpy] and [C H -1,3-{Re(CO) (Bu bpy)(C C 6 4 3 2 3 2 6 3 3 2 C C C H C C C H C C)} -5-{Re(CO) ( Bu bpy)(C C C H C C)}], have also 6 4 6 4 2 3 2 6 4 been synthesized. The lowest-lying excited states of these complexes were 3 3 tentatively assigned as admixture of MLCT[d (Re) *(N N)], LLCT[ (C C R) 3 *(N N)] and IL[ (C C R) *(C C R)] origin. Besides, a series of luminescent heterometallic rhenium(I) palladium(II) t complexes, trans-[Pd(PEt ) Cl{(C C Ar C C)Re(CO) (N N)}] (N N = bpy, Bu bpy; 3 2 3 2 Ar = C H S, C H ) and trans-[Pd(PEt ) {(C C C H C C)Re(CO) ( Bu bpy)} ], have 4 2 6 4 3 2 6 4 3 2 2 been synthesized. The X-ray crystal structures of t trans-[Pd(PEt)Cl{(CCCHCC)Re(CO)(N N)}] (N N = bpy, Bu bpy) have been 32 64 3 2 determined. Their emission was attributed to MLCT[d (Re) *(N N)] 3 phosphorescence mixed with LLCT[ (C C R) *(N N)] character. A lower emission energy for the hetero-bimetallic complex was observed upon coordination of the electron-rich palladium(II) moiety into the rhenium(I) alkynyl system. However, replacement of the remaining chloro group on the palladium centre with an additional rhenium(I) alkynyl moiety resulted in a higher energy emission for the hetero-trimetallic complex. A series of luminescent heterometallic rhenium(I) platinum(II) phosphine complexes, [{Re(CO)(NN)(CCCHCC)}Pt(PP)] [PP = dppe, depe, 3 6 4 2 t cis-(PEt), trans-(PEt ); N N = Bu bpy, (CF ) bpy], have been synthesized. The 32 3 2 2 3 2 X-ray crystal structure of [{Re(CO){(CF)bpy}(C C CH C C)}Pt(dppe)] has 3 3 2 6 4 2 been determined. The emission was ascribed as derived from states of a [d (Re) 3 3 *(N N)] MLCT origin that mixed with LLCT[ (C C R) *(N N)] character; or alternatively, as an excited state of a [ {C C C H C C Pt(P P)} *(N N)] 6 4 metalloligand-to-ligand charge transfer character. Another new class of luminescent heterometallic rhenium(I)platinum(II) polypyridine alkynyl complexes, t [Re
Book Synopsis Synthesis, Characterization, and Reactivity of Hexanuclear Rhenium Clusters Containing Nitrogen-donor Ligands by : Jessica L. Durham
Download or read book Synthesis, Characterization, and Reactivity of Hexanuclear Rhenium Clusters Containing Nitrogen-donor Ligands written by Jessica L. Durham and published by . This book was released on 2012 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactivity of Some Novel Metal-sulfur Complexes by : Michael Gallagher
Download or read book Synthesis and Reactivity of Some Novel Metal-sulfur Complexes written by Michael Gallagher and published by . This book was released on 1984 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Synthesis and Reactivity of Rhenium Complex with Metal-carbon-multiple Bond by : Long Yiu Tsang
Download or read book The Synthesis and Reactivity of Rhenium Complex with Metal-carbon-multiple Bond written by Long Yiu Tsang and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactivity of Rhenium Sulfido and Polysulfido Complexes by : Sarah Hobert Pawlicki
Download or read book Synthesis and Reactivity of Rhenium Sulfido and Polysulfido Complexes written by Sarah Hobert Pawlicki and published by . This book was released on 2002 with total page 476 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Rhenium Carbonyl Complexes Obtained by Ligand Exchange Reactions by : Franklin R. Beckles Araque
Download or read book Synthesis and Characterization of Rhenium Carbonyl Complexes Obtained by Ligand Exchange Reactions written by Franklin R. Beckles Araque and published by . This book was released on 2005 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactivity of Rhenium (VII) Neopentylidene and Neopentylidyne Complexes by : D. Scott Edwards
Download or read book Synthesis and Reactivity of Rhenium (VII) Neopentylidene and Neopentylidyne Complexes written by D. Scott Edwards and published by . This book was released on 1983 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactions of Rhenium Pi-propargyl Complexes by : John Robert Nash
Download or read book Synthesis and Reactions of Rhenium Pi-propargyl Complexes written by John Robert Nash and published by . This book was released on 1997 with total page 790 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactions of Cationic Rhenium Allyl Complexes by : Chae Sung Yi
Download or read book Synthesis and Reactions of Cationic Rhenium Allyl Complexes written by Chae Sung Yi and published by . This book was released on 1991 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt: