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Author : Joyce Lai Chu Chim
Publisher :
ISBN 13 :
Total Pages : 582 pages
Book Rating : 4.:/5 (411 download)
Download or read book Synthesis and Reactivities of Complexes Containing Metal-nitrogen Multiple Bonds written by Joyce Lai Chu Chim and published by . This book was released on 1998 with total page 582 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Scott M. Rocklage
Publisher :
ISBN 13 :
Total Pages : 386 pages
Book Rating : 4.:/5 (15 download)
Download or read book Synthesis and Reactivity of Early Transition Metal Complexes Containing Multiple Metal to Carbon, Nitrogen, Or Oxygen Bonds written by Scott M. Rocklage and published by . This book was released on 1982 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Yoshiaki Nishibayashi
Publisher : John Wiley & Sons
ISBN 13 : 352734425X
Total Pages : 496 pages
Book Rating : 4.5/5 (273 download)
Download or read book Transition Metal-Dinitrogen Complexes written by Yoshiaki Nishibayashi and published by John Wiley & Sons. This book was released on 2019-05-06 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive book that explores nitrogen fixation by using transition metal-dinitrogen complexes Nitrogen fixation is one of the most prominent fields of research in chemistry. This book puts the focus on the development of catalytic ammonia formation from nitrogen gas under ambient reaction conditions that has been recently repowered by some research groups. With contributions from noted experts in the field, Transition Metal-Dinitrogen Complexes offers an important guide and comprehensive resource to the most recent research and developments on the topic of nitrogen fixation by using transition metal-dinitrogen. The book is filled with the information needed to understand the synthesis of transition metal-dinitrogen complexes and their reactivity. This important book: -Offers a resource for understanding nitrogen fixation chemistry that is essential for explosives, pharmaceuticals, dyes, and all forms of life -Includes the information needed for anyone interested in the field of nitrogen fixation by using transition metal-dinitrogen complexes -Contains state-of-the-art research on synthesis of transition metal-dinitrogen complexes and their reactivity in nitrogen fixation -Incorporates contributions from well-known specialists and experts with an editor who is an innovator in the field of dinitrogen chemistry Written for chemists and scientists with an interest in nitrogen fixation, Transition Metal-Dinitrogen Complexes is a must-have resource to the burgeoning field of nitrogen fixation by using transition metal-dinitrogen complexes.
Author : David Samuel Glueck
Publisher :
ISBN 13 :
Total Pages : 394 pages
Book Rating : 4.:/5 (33 download)
Download or read book The Synthesis and Chemistry of Organolridium Complexes Containing Metal-oxygen and Metal-nitrogen Bonds written by David Samuel Glueck and published by . This book was released on 1990 with total page 394 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : David N. Williams
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (6 download)
Download or read book Synthesis, Reactivity and Bonding of Compounds Containing Transition Metal-nitrogen Multiple Bonds and Related Studies written by David N. Williams and published by . This book was released on 1990 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :
Publisher : Academic Press
ISBN 13 : 0080580408
Total Pages : 429 pages
Book Rating : 4.0/5 (85 download)
Download or read book Advances in Organometallic Chemistry written by and published by Academic Press. This book was released on 1996-02-12 with total page 429 pages. Available in PDF, EPUB and Kindle. Book excerpt: This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branchesof chemistry now interface with organometallic chemistry--the study of compounds containing carbon metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry. In basic research, organometallics have contributed inter alia to: Metal cluster chemistry Surface chemistry The stabilization of highly reactive species by metal coordination Chiral synthesis The formulation of multiple bonds between carbon and the other elements and between the elements themselves
Author : Robert Donald Simpson
Publisher :
ISBN 13 :
Total Pages : 476 pages
Book Rating : 4.:/5 (33 download)
Download or read book The Synthesis and Reactivity of Organometallic Compounds Containing Metal-heteroatom Bonds written by Robert Donald Simpson and published by . This book was released on 1992 with total page 476 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Robert West
Publisher :
ISBN 13 :
Total Pages : 436 pages
Book Rating : 4.4/5 (541 download)
Download or read book Multiply Bonded Main Group Metals and Metalloids written by Robert West and published by . This book was released on 1996 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume surveys major advances in the area of organometallic chemistry - the synthesis of stable, multiply bonded compounds of main group metals and metalloids. Notable advances occurred in this field in 1981, when the synthesis of stable compounds containing Si=C, Si=Si, and P-P multiple bonds were announced. Until these discoveries, organometallic chemistry had been limited by the double-bond rule, which asserted that elements outside the first row of the periodic table would not form stable multiple bonds. During the intervening 14 years, many other stable multiply bonded compounds have been discovered, and the field of organometallic chemistry has expanded as a result.
Author : 李富華
Publisher : Open Dissertation Press
ISBN 13 : 9781374727748
Total Pages : 244 pages
Book Rating : 4.7/5 (277 download)
Download or read book SYNTHESES STRUCTURES & REACTIV written by 李富華 and published by Open Dissertation Press. This book was released on 2017-01-27 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Syntheses, Structures and Reactivity of the Group 6 and 7 Metal Complexes Containing Chelating Nitrogen Donor Ligands and Metal-ligand Multiple Bonds" by 李富華, Fu-wa, Lee, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Abstract of thesis entitled "SYNTHESES, STRUCTURES AND REACTIVITY OF THE GROUP 6 AND 7 METAL COMPLEXES CONTAINING CHELATING NITROGEN DONOR LIGANDS AND METAL-LIGAND MULTIPLE BONDS" submitted by Lee Fu Wa for the degree of Doctor of Philosophy at the University of Hong Kong in September, 1997. ____________________________________________________________________ [Cr(CRMe )Cl ] (CRMe =meso-2,3,7,11,12-pentamethyl-3,7,11,17- 3 2 3 2+ tetraazabicyclo[11.3.1]-heptadeca-1(17),13,15-triene), [Cr(CRMe )Cl(H O)], 3 2 2+ + [Cr(CRMe )Cl(CH CN)] and [Cr(CRMe )(N )(OH)] are prepared. Upon addition 3 3 3 3 2+ 2+ of PhI=O to solutions of [Cr(CRMe )Cl(CH CN)] and [Cr(CRMe )Cl(H O)] 3 3 3 2 respectively in CH CN, the UV-visible absorption spectra of the two mixtures show similar isosbestic spectral changes attributed to the formation of V 2+ [Cr (CRMe )Cl(O)] . Addition of PhP causes the immediate recovery of 3 3 2+ [Cr(CRMe )Cl(CH CN)] as the isosbestic changes are reversed. Irradiation of 3 3 [Cr(CRMe )(N )(OH)] in acetonitrile with UV-visible light gives an azide-free 3 3 product, the FAB-MS of which shows a molecular ion peak indicative of V + + ([Cr (CRMe )(N)]ClO ). The UV-visible spectra of [Cr(CRMe )Cl ], 3 4 3 2 2+ 2+ [Cr(CRMe )Cl(H O)] and [Cr(CRMe )Cl(CH CN)] measured in water are 3 2 3 3 3+ similar to that of [Cr(CRMe )(H O) ] . Results from the conductivity measurement 3 2 2 + 2+ show that in water, [Cr(CRMe )Cl ], [Cr(CRMe )Cl(H O)] and 3 2 3 2 2+ [Cr(CRMe )Cl(CH CN)] behave as 3:1 electrolytes. The species which exists in 3 3 3+ water is likely to be the di-aquo complex [Cr(CRMe )(H O) ] . 3 2 2 2+ 2+ [Cr(CRMe )Cl(H O)] and [Cr(CRMe )Cl(CH CN)] are both found to give a 3 2 3 3 reversible oxidation couple at +1.11 V vs. SCE in aqueous solutions at pH=1 which is assigned to Cr(III)/(IV). iii t + The bis(imido) complexes [(TACN)M(N Bu) Cl] (M=Cr, Mo; TACN=1,4,7-triazacyclononane) and their 1,4,7-trimethyl derivatives are prepared, the crystal structures of which reveal the trans influence of the imido group. These 0 +/0 d species display a quasi-reversible couple at potentials 0.86 - 1.20 V vs. Cp Fe in acetonitrile assignable to a imido ligand-centred oxidation. (Me TACN)Mo(CO), 1,4,7-Tri((S)-2-methylbutyl)-1,4,7-triazacyclononane 3 3 * * * (L ) and L Mo(CO) are synthesized. (Me TACN)Mo(CO) and L Mo(CO) show 3 3 3 3 +/0 reversible oxidation couples at -0.26 V and -0.24 V vs. Cp Fe in CH CN 2 3 I/0 respectively which are assigned to Mo . The comparable electronic effect of * Me TACN and L in this system is therefore implied. 2+ [(Me TACN) Mn (μ-O)(μ-OCOCH ) ] is prepared and found to mediate 3 2 2 3 2 aziridination of styrene, methylstyrene, cis- and trans-stilbene, 1,1-diphenylethene and norbornene by PhI=NTs in CH Cl at 25 C. The nitrene transfer to cis- and 2 2 trans-stilbene is found to be stereoselective to exclusively give the trans-aziridine product. + + [(Me TACN)(CO) M CPh] (M=Mo, W) and [(TACN)(CO) Mo CPh] 3 2 2 are prepared. [(Me TACN)(CO) M CPh] (M=Mo, W) exhibit a reversible 3 2 +/0 reduction couple at -2.15 V vs Fe Cp and an irreversible wave at 0.77 V vs +/0 Fe Cp, which are ascribed to a reduction centred at the phenyl ring and oxidation of the terminal CO respectively. Treatment of Cl(
Author :
Publisher : Academic Press
ISBN 13 : 0080580378
Total Pages : 383 pages
Book Rating : 4.0/5 (85 download)
Download or read book Advances in Organometallic Chemistry written by and published by Academic Press. This book was released on 1994-04-22 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branchesof chemistry now interface with organometallic chemistry-the study of compounds containing carbon-metal bonds. Organometallic compounds range from species that are so reactive that they only have a transient existence at ambient temperatures to those thatare thermally very stable. They are used extensively in the synthesis of useful compounds on both small and large scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advances in organometallic chemistry. In basic research, organometallics have contributed inter alia to: Metal cluster chemistry Surface chemistry The stabilization of highly reactive species by metal coordination Chiral synthesis The formulation of multiple bonds between carbon and the other elements and between the elements themselves Each volume of Advances in Organometallic Chemistry contains an index, and each chapter includes references
Author : Lisa Dawn Vasquez
Publisher :
ISBN 13 :
Total Pages : 578 pages
Book Rating : 4.:/5 (429 download)
Download or read book Synthesis and Reactivity of Transition Metal Complexes Containing Nitrogen Heterocycles written by Lisa Dawn Vasquez and published by . This book was released on 1998 with total page 578 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Darryl Patrick Klein
Publisher :
ISBN 13 :
Total Pages : 314 pages
Book Rating : 4.:/5 (7 download)
Download or read book The Synthesis and Reactivity of Organoiridium Complexes Containing Metal-heteroatom Bonds written by Darryl Patrick Klein and published by . This book was released on 1989 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Richard S. Morris
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (13 download)
Download or read book Synthesis and Reactivity Studies of Square Pyramidal Complexes on Group 5 and 6 Metals for Nitrogen and Small Molecule Fixation written by Richard S. Morris and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Fu-wa Lee
Publisher :
ISBN 13 :
Total Pages : 504 pages
Book Rating : 4.:/5 (513 download)
Download or read book Syntheses, Structures and Reactivity of the Group 6 and 7 Metal Complexes Containing Chelating Nitrogen Donor Ligands and Metal-ligand Multiple Bonds written by Fu-wa Lee and published by . This book was released on 1997 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : B.I. Kharisov
Publisher : Elsevier
ISBN 13 : 0128110627
Total Pages : 470 pages
Book Rating : 4.1/5 (281 download)
Download or read book Direct Synthesis of Metal Complexes written by B.I. Kharisov and published by Elsevier. This book was released on 2018-04-19 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt: Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water Includes experimental procedures, with examples of direct synthesis, at the end of each chapter
Author : Hayley Ann Burkill
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (93 download)
Download or read book Synthesis and Reactivity of Transition Metal Complexes Containing Ligands with Hydrogen-bonding Moieties written by Hayley Ann Burkill and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : John Frederick Hartwig
Publisher :
ISBN 13 :
Total Pages : 434 pages
Book Rating : 4.:/5 (33 download)
Download or read book Synthesis and Reactivity of Compounds Containing Ruthenium-carbon, -nitrogen, and -oxygen Bonds written by John Frederick Hartwig and published by . This book was released on 1990 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt:
