Synthesis and Properties of Poly(styrene-CO-Butyl Acrylate) Particles Via Microwave-aided Emulsion Copolymerization

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (129 download)

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Book Synopsis Synthesis and Properties of Poly(styrene-CO-Butyl Acrylate) Particles Via Microwave-aided Emulsion Copolymerization by : Youngjae Yoo

Download or read book Synthesis and Properties of Poly(styrene-CO-Butyl Acrylate) Particles Via Microwave-aided Emulsion Copolymerization written by Youngjae Yoo and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Semi-continuous Emulsion Copolymerization of Styrene-butyl Acrylate with Methacrylic Acid

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ISBN 13 :
Total Pages : 214 pages
Book Rating : 4.:/5 (647 download)

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Book Synopsis Semi-continuous Emulsion Copolymerization of Styrene-butyl Acrylate with Methacrylic Acid by : Hong Hua

Download or read book Semi-continuous Emulsion Copolymerization of Styrene-butyl Acrylate with Methacrylic Acid written by Hong Hua and published by . This book was released on 2008 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis and Characterization of Low Molecular Mass Amphiphilic Block Copolymers and Potential Use in Surfactant Assisted Particle Micro-mixing

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ISBN 13 :
Total Pages : pages
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Book Synopsis Synthesis and Characterization of Low Molecular Mass Amphiphilic Block Copolymers and Potential Use in Surfactant Assisted Particle Micro-mixing by : Ekaterini Karakatsanis

Download or read book Synthesis and Characterization of Low Molecular Mass Amphiphilic Block Copolymers and Potential Use in Surfactant Assisted Particle Micro-mixing written by Ekaterini Karakatsanis and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In industry the effective mixing and de-agglomeration of two solid particles is vital in applications that require the intimate contact of homogeneously mixed reagents. One such application is in the preparation of pyrotechnic delay elements with reproducible burn speeds. The concept of surfactant assisted particle micro-mixing is proposed. This theory is based in the use of two amphiphilic polymeric surfactants to form two separate stable dispersions of the two solid particles to be mixed, but with the subsequent requirement that the dispersants are able to interact with each other. The formation of the individual dispersions allows for the deagglomeration of the particles and thus their preparation for homogeneous mixing, which is facilitated by the interacting surfactants. Low molecular mass block copolymers of styrene and acrylic acid and poly(ethylene oxide)-poly(propylene oxide) (PEO-PPO) surfactants are the proposed dispersants which will allow for the surfactant interaction by means of hydrogen bonding between the poly(acrylic acid) block and the PEO. The poly(styrene-co-acrylic acid) block copolymer will be synthesised via Atom Transfer Radical Polymerisation (ATRP) and subsequently used in the dispersion experiments. The synthesis of the polystyrene macroinitiators to initiate the block copolymerisation of the t-butyl acrylate was carried out satisfactorily, with good molecular masses and molecular mass distributions. In addition, lH-NMR analysis carried out on the polystyrene macroinitiators confirmed their synthesis. The use of the polystyrene macroinitiators was successful in synthesising poly(styrene-co-t-butyl acrylate) block copolymers with slightly higher polydispersities in comparison to the macroinitiatiators themselves, but acceptable. Hydrolysis of the poly(styrene-co-t-butyl acrylate) block copolymer to poly(styrene-co-acrylic acid) was successful in the presence of trifluoroacetic acid as catalyst. Attempts to hydrolyse in basic conditions (NaOH) and alternatively in acidic conditions (HCI) were not successful. Use of the poly(styrene-co-acrylic acid) amphiphilic block copolymer to emulsion polymerise styrene requires the ionised form of the polymer and was therefore not favourable to observe surfactant-surfactant hydrogen bonding. In addition, attempts to synthesise a wax emulsion stabilised by a PEO containing surfactant proved to be unsuccessful. Subsequently, the micro-mixing experiments were carried out by using a poly(acrylic acid) stabilised melamine dispersion and a commercially available PEO containing surfactant stabilised wax emulsion. The interaction between the melamine and the poly(acrylic acid) allows for the formation of a stable melamine dispersion at above 7% poly(acrylic acid) : melamine ratio (mass basis). Analysis by SEM shows that without the poly(acrylic acid) dispersant no wax particles are found to occur on the melamine particle surface. However, in an attempt to determine whether the amount of wax interaction increases with poly(acrylic acid) content, it was found that in the absence of poly(acrylic acid) dispersant, the most amount of wax precipitated out with the melamine. This is possibly attributable to the preferential occlusion of the wax particles between the melamine particles rather than surface attachment. Introduction of the poly(acrylic acid), however, shows via SEM analysis that the hydrogen bond interaction between the acrylic acid group and the ethylene oxide group does occur, since the attachment of the wax particles on the melamine particle surface is observed. Although results show that the surfactant-surfactant interaction allows for the micro mixing of particles, some refinement is required with respect to the systems that this phenomenon can be applied to. In addition, factors such as particle type, particle size and surfactant type will influence the micro-mixing interaction. It is therefore recommended that these factors be investigated in order to completely identify the micro-mixing phenomenon.

Microwave-assisted Polymer Synthesis

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Publisher : Springer
ISBN 13 : 3319422413
Total Pages : 357 pages
Book Rating : 4.3/5 (194 download)

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Book Synopsis Microwave-assisted Polymer Synthesis by : Richard Hoogenboom

Download or read book Microwave-assisted Polymer Synthesis written by Richard Hoogenboom and published by Springer. This book was released on 2016-09-02 with total page 357 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science.The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics.Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned.Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students

Nitroxides

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Publisher : Royal Society of Chemistry
ISBN 13 : 1788019660
Total Pages : 611 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Nitroxides by : Olivier Ouari

Download or read book Nitroxides written by Olivier Ouari and published by Royal Society of Chemistry. This book was released on 2021-05-13 with total page 611 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nitroxides are versatile small organic molecules possessing a stabilised free radical. With their unpaired electron spin they display a unique reactivity towards various environmental factors, enabling a diverse range of applications. They have uses as synthetic tools, such as catalysts or building blocks; imaging agents and probes in biomedicine and materials science; for medicinal antioxidant applications; and in energy storage. Polynitroxides (polymers bearing pendant nitroxide sidechains) have been used in organic radical batteries, oxidation catalysts and in exchange reactions for constructing complex architectures. Chapters in this book cover the synthesis of nitroxides, EPR studies and magnetic resonance applications, physiochemical studies, and applications including in batteries, imaging and organic synthesis. With contributions from leaders in the field, Nitroxides will be of interest to graduate students and researchers across chemistry, physics, biology and materials science.

Self-Healing Polymers

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Publisher : John Wiley & Sons
ISBN 13 : 3527670203
Total Pages : 638 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Self-Healing Polymers by : Wolfgang H. Binder

Download or read book Self-Healing Polymers written by Wolfgang H. Binder and published by John Wiley & Sons. This book was released on 2013-03-29 with total page 638 pages. Available in PDF, EPUB and Kindle. Book excerpt: Self-healing is a well-known phenomenon in nature: a broken bone merges after some time and if skin is damaged, the wound will stop bleeding and heals again. This concept can be mimicked in order to create polymeric materials with the ability to regenerate after they have suffered degradation or wear. Already realized applications are used in aerospace engineering, and current research in this fascinating field shows how different self-healing mechanisms proven successful by nature can be adapted to produce even more versatile materials. The book combines the knowledge of an international panel of experts in the field and provides the reader with chemical and physical concepts for self-healing polymers, including aspects of biomimetic processes of healing in nature. It shows how to design self-healing polymers and explains the dynamics in these systems. Different self-healing concepts such as encapsulated systems and supramolecular systems are detailed. Chapters on analysis and friction detection in self-healing polymers and on applications round off the book.

Antioxidant Polymers

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Publisher : John Wiley & Sons
ISBN 13 : 1118445511
Total Pages : 601 pages
Book Rating : 4.1/5 (184 download)

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Book Synopsis Antioxidant Polymers by : Giuseppe Cirillo

Download or read book Antioxidant Polymers written by Giuseppe Cirillo and published by John Wiley & Sons. This book was released on 2012-06-07 with total page 601 pages. Available in PDF, EPUB and Kindle. Book excerpt: Antioxidant Polymers is an exhaustive overview of the recent developments in the field of polymeric materials showing antioxidant properties. This research area has grown rapidly in the last decade because antioxidant polymers have wide industry applications ranging from materials science to biomedical, pharmaceuticals and cosmetics.

Polymeric Surfactants

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Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 3110487527
Total Pages : 301 pages
Book Rating : 4.1/5 (14 download)

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Book Synopsis Polymeric Surfactants by : Tharwat F. Tadros

Download or read book Polymeric Surfactants written by Tharwat F. Tadros and published by Walter de Gruyter GmbH & Co KG. This book was released on 2017-05-08 with total page 301 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymeric Surfactants covers the structure and stability origins of these highly useful surfactants. Adsorption and solution properties in emulsions are discussed based on their underlying thermodynamics and kinetics. Research scientists and Ph.D. students investigating chemistry, chemical engineering and colloidal science will benefit from this text on polymeric surfactants and their value in preparation and stabilization of disperse systems.

Chemical Abstracts

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ISBN 13 :
Total Pages : 2668 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Chemical Abstracts by :

Download or read book Chemical Abstracts written by and published by . This book was released on 2002 with total page 2668 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Polymer Particles

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Publisher : Springer Science & Business Media
ISBN 13 : 9783540229230
Total Pages : 388 pages
Book Rating : 4.2/5 (292 download)

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Book Synopsis Polymer Particles by : Masayoshi Okubo

Download or read book Polymer Particles written by Masayoshi Okubo and published by Springer Science & Business Media. This book was released on 2005-02-10 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this special volume on polymer particles, recent trends and developments in the synthesis of nano- to micron-sized polymer particles by radical polymerization (Emulsion, Miniemulsion, Microemulsion, and Dispersion Polymerizations) of vinyl monomers in environmentally friendly heterogeneous aqueous and supercritical carbon dioxide fluid media are reviewed by prominent worldwide researchers. In addition to the important challenges and possibilities with regards to design and preparation of functionalized polymer particles of controlled size, the topics described are of great current interest due to the increased awareness of environmental issues.

Renewable Polymers

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Publisher : MDPI
ISBN 13 : 3039287664
Total Pages : 206 pages
Book Rating : 4.0/5 (392 download)

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Book Synopsis Renewable Polymers by : Marc A. Dubé

Download or read book Renewable Polymers written by Marc A. Dubé and published by MDPI. This book was released on 2020-04-22 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt: The utilization of bio-resourced macromolecules for polymer applications has been the subject of increasing interest, mainly for sustainability and functionality reasons. This Special Issue of Processes brings together nine papers from leading scientists and researchers active in the area of “Sustainable and Renewable Polymers, Processing, and Chemical Modifications”. The collected papers include seven original research and two review articles related to renewable feedstock for polymer applications, processes for the fabrication of renewable polymer-based nanomaterials, the design and modification of renewable polymers, and applications of renewable polymers. The journal Processes will continue to nurture progress in this field through its position as an open access platform.

Elements of Polymer Science & Engineering

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Publisher : Elsevier
ISBN 13 : 0080505473
Total Pages : 529 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Elements of Polymer Science & Engineering by : Alfred Rudin

Download or read book Elements of Polymer Science & Engineering written by Alfred Rudin and published by Elsevier. This book was released on 1998-09-21 with total page 529 pages. Available in PDF, EPUB and Kindle. Book excerpt: Tremendous developments in the field of polymer science, its growing importance, and an increase in the number of polymer science courses in both physics and chemistry departments have led to the revision of the First Edition. This new edition addresses subjects as spectroscopy (NMR), dynamic light scattering, and other modern techniques unknown before the publication of the First Edition. The Second Edition focuses on both theory (physics and chemistry) and engineering applications which make it useful for chemistry, physics, and chemical engineering departments.

Microwave Assisted Organic Synthesis

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Publisher : John Wiley & Sons
ISBN 13 : 1405168447
Total Pages : 296 pages
Book Rating : 4.4/5 (51 download)

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Book Synopsis Microwave Assisted Organic Synthesis by : Jason Tierney

Download or read book Microwave Assisted Organic Synthesis written by Jason Tierney and published by John Wiley & Sons. This book was released on 2009-02-12 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first reports on the application of microwaves in organicsynthesis date back to 1986, but it was not until the recentintroduction of specifically designed and constructed equipment,which countered the safety and reproducibility concerns, thatsynthetic application of microwaves has become established as alaboratory technique. Microwave assisted synthesis is now beingadopted in many industrial and academic laboratories to takeadvantage of the novel chemistry that can be carried out using avariety of organic reaction types. This book demonstrates the underlying principles of microwavedielectric heating and, by reference to a range of organic reactiontypes, it's effective use in synthetic organic chemistry. Toillustrate the impact microwave assisted organic synthesis can haveon chemical research, case studies drawn mainly from thepharmaceutical industry are presented.

Polymeric Dispersions: Principles and Applications

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Publisher : Springer Science & Business Media
ISBN 13 : 9401155127
Total Pages : 571 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Polymeric Dispersions: Principles and Applications by : J.M. Asua

Download or read book Polymeric Dispersions: Principles and Applications written by J.M. Asua and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 571 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive and up to date survey of the science and technology of polymeric dispersions. The book discusses the kinetics and mechanisms of polymerization in dispersed media, examines the processes controlling particle morphology, presents both off-line and on-line methods for the characterization of polymer colloids, considers reactor engineering and control, and covers a wide variety of applications, such as latex paint formulations, encapsulation of inorganic particles, reactive latexes, adhesives, paper coating, and biomedical and pharmaceutical applications. Audience: A valuable resource for scientists and engineers, academic and industrial, who are involved in the manufacture or application of polymeric dispersions.

Polysaccharide Based Graft Copolymers

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Publisher : Springer Science & Business Media
ISBN 13 : 3642365663
Total Pages : 358 pages
Book Rating : 4.6/5 (423 download)

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Book Synopsis Polysaccharide Based Graft Copolymers by : Susheel Kalia

Download or read book Polysaccharide Based Graft Copolymers written by Susheel Kalia and published by Springer Science & Business Media. This book was released on 2013-05-23 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: Renowned experts give all essential aspects of the techniques and applications of graft copolymers based on polysaccharides. Polysaccharides are the most abundant natural organic materials and polysaccharide based graft copolymers are of great importance and widely used in various fields. Natural polysaccharides have recently received more attention due to their advantages over synthetic polymers by being non-toxic, biodegradable and available at low cost. Modification of polysaccharides through graft copolymerization improves the properties of polysaccharides. Grafting is known to improve the characteristic properties of the backbones. Such properties include water repellency, thermal stability, flame resistance, dye-ability and resistance towards acid-base attack and abrasion. Polysaccharides and their graft copolymers find extensive applications in diversified fields. Applications of modified polysaccharides include drug delivery devices, controlled release of fungicides, selective water absorption from oil-water emulsions, purification of water etc.

Handbook of Industrial Water Soluble Polymers

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Publisher : John Wiley & Sons
ISBN 13 : 0470994193
Total Pages : 344 pages
Book Rating : 4.4/5 (79 download)

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Book Synopsis Handbook of Industrial Water Soluble Polymers by : Peter A. Williams

Download or read book Handbook of Industrial Water Soluble Polymers written by Peter A. Williams and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: Natural and synthetic water soluble polymers are used in a wide range of familiar industrial and consumer products, including coatings and inks, papers, adhesives, cosmetics and personal care products. They perform a variety of functions without which these products would be significantly more expensive, less effective or both. Written for research, development and formulation chemists, technologists and engineers at graduate level and beyond in the fine and specialty chemicals, polymers, food and pharmaceutical industries, the Handbook of Industrial Water Soluble Polymers deals specifically with the functional properties of both natural and synthetic water soluble polymers. By taking a function based approach, rather than a “polymer specific” approach the book illustrates how polymer structure leads to effect, and shows how different polymer types can be employed to achieve appropriate product properties.

Polymer Dispersions and Their Industrial Applications

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Publisher : Wiley-VCH
ISBN 13 :
Total Pages : 436 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Polymer Dispersions and Their Industrial Applications by : Dieter Urban

Download or read book Polymer Dispersions and Their Industrial Applications written by Dieter Urban and published by Wiley-VCH. This book was released on 2002 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aqueous polymer dispersions are environmentally friendly and therefore they have replaced in many applications polymers dissolved in organic solvents. This substitution process is still ongoing. This book discusses the world of aqueous polymer dispersions from the viewpoint of how they are applied. For a better understanding it starts with a general description of the synthesis of polymer dispersions and their characterization. The following chapters are dedicated to a wide variety of applications, including history, modern processes, and typical formulations and performance. The selection and the usage of a polymer dispersion are not uniform around the world because of historical and regional differences of the technical developments and marketing demands. Leading scientists from industry contributed to this book ensuring that practical issues are emphasized.