Synthesis and Photophysical Studies of Copper (II) and Copper (I) Complexes with a Tetradentate Ligand Based on 2, 9-dimethyl-1, 10-phenanthroline

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ISBN 13 :
Total Pages : 154 pages
Book Rating : 4.:/5 (841 download)

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Book Synopsis Synthesis and Photophysical Studies of Copper (II) and Copper (I) Complexes with a Tetradentate Ligand Based on 2, 9-dimethyl-1, 10-phenanthroline by : Yuan Yao

Download or read book Synthesis and Photophysical Studies of Copper (II) and Copper (I) Complexes with a Tetradentate Ligand Based on 2, 9-dimethyl-1, 10-phenanthroline written by Yuan Yao and published by . This book was released on 1991 with total page 154 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Master's Theses Directories

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ISBN 13 :
Total Pages : 688 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Master's Theses Directories by :

Download or read book Master's Theses Directories written by and published by . This book was released on 1992 with total page 688 pages. Available in PDF, EPUB and Kindle. Book excerpt:

A Study of Some Complexes of Copper with 2, 9-dimethyl-1, 10-phenanthroline

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ISBN 13 :
Total Pages : 78 pages
Book Rating : 4.:/5 (374 download)

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Book Synopsis A Study of Some Complexes of Copper with 2, 9-dimethyl-1, 10-phenanthroline by : Noel Kevin Marchant

Download or read book A Study of Some Complexes of Copper with 2, 9-dimethyl-1, 10-phenanthroline written by Noel Kevin Marchant and published by . This book was released on 1962 with total page 78 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Synthesis and Study of Some Copper (II) Complexes Using Pyrrole-diimine Tetradentate Ligands

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ISBN 13 :
Total Pages : 50 pages
Book Rating : 4.:/5 (297 download)

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Book Synopsis The Synthesis and Study of Some Copper (II) Complexes Using Pyrrole-diimine Tetradentate Ligands by : Richard Everett Clarke

Download or read book The Synthesis and Study of Some Copper (II) Complexes Using Pyrrole-diimine Tetradentate Ligands written by Richard Everett Clarke and published by . This book was released on 1967 with total page 50 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Development of Copper(I)-2,9-di-tert-butyl-1,10-phenanthroline Chemistry and Applications Thereof

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ISBN 13 :
Total Pages : 330 pages
Book Rating : 4.:/5 (891 download)

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Book Synopsis Development of Copper(I)-2,9-di-tert-butyl-1,10-phenanthroline Chemistry and Applications Thereof by : Bhavesh A. Gandhi

Download or read book Development of Copper(I)-2,9-di-tert-butyl-1,10-phenanthroline Chemistry and Applications Thereof written by Bhavesh A. Gandhi and published by . This book was released on 2007 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Phenanthroline-based Copper Complexes for Water Splitting Applications

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (11 download)

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Book Synopsis Phenanthroline-based Copper Complexes for Water Splitting Applications by : Kai Stührenberg

Download or read book Phenanthroline-based Copper Complexes for Water Splitting Applications written by Kai Stührenberg and published by . This book was released on 2017 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The future environmental issues are inseparably connected with todays energy source mix, which is mainly based on fossil fuels. In order to retain the planet earth from severe climate changes, it is important to change the basis of our energy system towards renewable and sustainable sources. The utilization of nearly unlimited sources, like solar energy, is in this context a reasonable choice as point of origin.This dissertation pursues the goal to further establish copper as central metal for water splitting applications by thorough spectroscopic analysis in order to conclude structure-property relationships. Photoactive copper(I) complexes of 2,9-bis(halomethyl)-1,10-phenanthroline were synthesized and characterized by a variety of spectroscopic methods. Chemical analytic, like single crystal X-ray diffraction, NMR spectroscopy, mass spectrometry and X-ray absorption spectroscopy, provided structural confirmation and insights into coordination geometry and electronic properties. During the cycle as photosensitizer, copper(I) is photo-oxidized to copper(II). The related structural and electronic changes during this photooxidation were investigated in detail using an combination of electrochemistry with UV/VIS absorption spectroscopy. The analysis of the spectroscopic data was also supported by computational chemistry to identify and assign transitions in the experimental data.In the case of water oxidation catalysis, precursors of copper(II) water oxidation catalysts were synthesized by conversion of a copper(II) salt with commercially available and tailored non-redox innocent ligands and analyzed by identified by a combination of single crystal X-ray diffraction and IR spectroscopy. Although the synthesis was assumed to be straightforward, a variety of interesting species were obtained in dependency on reaction parameters. ; eng

Anion Sensing

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Publisher : Springer Science & Business Media
ISBN 13 : 9783540232476
Total Pages : 252 pages
Book Rating : 4.2/5 (324 download)

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Book Synopsis Anion Sensing by : Eric V. Anslyn

Download or read book Anion Sensing written by Eric V. Anslyn and published by Springer Science & Business Media. This book was released on 2005-05-06 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt: with contributions by numerous experts

Copper(I) Complex of 4,7-dimethyl-2,3,8,9-dibenzo-1,10-phenanthroline

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ISBN 13 :
Total Pages : 106 pages
Book Rating : 4.:/5 (576 download)

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Book Synopsis Copper(I) Complex of 4,7-dimethyl-2,3,8,9-dibenzo-1,10-phenanthroline by : Humphrey Cheung

Download or read book Copper(I) Complex of 4,7-dimethyl-2,3,8,9-dibenzo-1,10-phenanthroline written by Humphrey Cheung and published by . This book was released on 1975 with total page 106 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Photochemical Reduction Processes in the Copper(II)-2,9-dimethyl- 1,10-phenanthroline System

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ISBN 13 :
Total Pages : 262 pages
Book Rating : 4.:/5 (351 download)

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Book Synopsis Photochemical Reduction Processes in the Copper(II)-2,9-dimethyl- 1,10-phenanthroline System by : Subramaniam Sundararajan

Download or read book Photochemical Reduction Processes in the Copper(II)-2,9-dimethyl- 1,10-phenanthroline System written by Subramaniam Sundararajan and published by . This book was released on 1971 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Copper(II) and Cobalt(II) Complexes Based on Methyl Trifluorosalicylate and Bipyridine-Type Ligands

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ISBN 13 :
Total Pages : 24 pages
Book Rating : 4.:/5 (129 download)

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Book Synopsis Copper(II) and Cobalt(II) Complexes Based on Methyl Trifluorosalicylate and Bipyridine-Type Ligands by : Evgeny V. Shchegolkov

Download or read book Copper(II) and Cobalt(II) Complexes Based on Methyl Trifluorosalicylate and Bipyridine-Type Ligands written by Evgeny V. Shchegolkov and published by . This book was released on 2020 with total page 24 pages. Available in PDF, EPUB and Kindle. Book excerpt: The synthesis of bis(salicylato)Cu(II) and Co(II) chelates based on methyl trifluorosalicylate and the corresponding M(OAc) 2 in the presence of alkali is reported. The following reaction with 2,2'-bipyridine and 1,10 phenanthroline in refluxing methanol affords heteroligand complexes containing methyl trifluorosalicylate and azaheterocyclic ligands in the ratio 2:1. However, the refluxing of Co(II) chelates in ethanol resulted in transesterification of methyl ester group to form heteroligand complexes of ethyl trifluorosalicylate while Cu(II) chelates underwent hydrolysis of ester group to obtain heteroligand complexes of trifluorosalicylic acid. The structures of obtained metal complexes were confirmed by X-Ray diffraction experiment, IR spectroscopy and elemental analysis. The antimycotic and antibacterial activities of synthesized metal complexes were investigated. The heteroligand metal complexes were found to exhibit moderate anti-Candida albicans activity. Among new series of complexes, the most activity showed the mixed metal complexes of trifluorosalicylates and 1,10-phenanthroline revealing a wide range of action in relation to pathogenic fungi and bacteria.

Aynthesis, Characterization and Reactivity of Copper(I) and Copper(II) Complexes Containing Tripodal Tetradentate Ligands

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ISBN 13 :
Total Pages : 236 pages
Book Rating : 4.:/5 (246 download)

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Book Synopsis Aynthesis, Characterization and Reactivity of Copper(I) and Copper(II) Complexes Containing Tripodal Tetradentate Ligands by : Richard Robert Jacobson

Download or read book Aynthesis, Characterization and Reactivity of Copper(I) and Copper(II) Complexes Containing Tripodal Tetradentate Ligands written by Richard Robert Jacobson and published by . This book was released on 1989 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Structure Correlation

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Publisher : John Wiley & Sons
ISBN 13 : 352761608X
Total Pages : 936 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Structure Correlation by : Hans-Beat Bürgi

Download or read book Structure Correlation written by Hans-Beat Bürgi and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 936 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book leaves the conventional view of chemical structures far behind: it demonstrates how a wealth of valuable, but hitherto unused information can be extracted from available structural data. For example, a single structure determination does not reveal much about a reaction pathway, but a sufficiently large number of comparable structures does. Finding the 'right' question is as important as is the intelligent use of crystallographic databases. Contributions by F.H. Allen, T.L. Blundell, I.D. Brown, H.B. Bürgi, J.D. Dunitz, L. Leiserowitz and others, authoritatively discuss the structure correlation method as well as illustrative results in detail, covering such apparently unrelated subjects as * Bond strength relations in soldis * Crystal structure prediction * Reaction pathways of organic molecules * Ligand/receptor interactions and enzyme mechanisms This book will be useful to the academic and industrial reader alike. It offers both fundamental aspects and diverse applications of what will surely become a powerful branch of structural chemistry.

Beauty in Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 3642283411
Total Pages : 180 pages
Book Rating : 4.6/5 (422 download)

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Book Synopsis Beauty in Chemistry by : Luigi Fabbrizzi

Download or read book Beauty in Chemistry written by Luigi Fabbrizzi and published by Springer Science & Business Media. This book was released on 2012-02-22 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Beauty of Chemistry in the Words of Writers and in the Hands of Scientists, by Margherita Venturi, Enrico Marchi und Vincenzo Balzani Living in a Cage Is a Restricted Privilege, by Luigi Fabbrizzi Inner and Outer Beauty, by Kenneth N. Raymond und Casey J. Brown The Mechanical Bond: A Work of Art, by Carson J. Bruns und J. Fraser Stoddart The Beauty of Knots at the Molecular Level, by Jean-Pierre Sauvage und David B. Amabilino

Synthesis and Characterization of Copper (II) Complexes with 1,4,7,10-tetrabenzyl-1,4,7,10-tetraazacyclododecane

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ISBN 13 :
Total Pages : 126 pages
Book Rating : 4.:/5 (121 download)

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Book Synopsis Synthesis and Characterization of Copper (II) Complexes with 1,4,7,10-tetrabenzyl-1,4,7,10-tetraazacyclododecane by : Mary Christine Styka

Download or read book Synthesis and Characterization of Copper (II) Complexes with 1,4,7,10-tetrabenzyl-1,4,7,10-tetraazacyclododecane written by Mary Christine Styka and published by . This book was released on 1974 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Ultrafast Structural Rearrangements in the MLCT Excited State for Copper(I) Bis-Phenanthrolines in Solution

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ISBN 13 :
Total Pages : 51 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Ultrafast Structural Rearrangements in the MLCT Excited State for Copper(I) Bis-Phenanthrolines in Solution by :

Download or read book Ultrafast Structural Rearrangements in the MLCT Excited State for Copper(I) Bis-Phenanthrolines in Solution written by and published by . This book was released on 2006 with total page 51 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ultrafast excited state structural dynamics of [Cu{sup I}(dmp)2] (dmp = 2,9-dimethyl-1,10-phenanthroline) have been studied to identify structural origins of transient spectroscopic changes during the photoinduced metal-to-ligand-charge-transfer (MLCT) transition that induces an electronic configuration change from Cu(I) (3d1°) to Cu(II) (3d9). This study has important connections with the flattening of the Franck-Condon state tetrahedral geometry and the ligation of Cu(II)* with the solvent observed in the thermally equilibrated MLCT state by our previous laser-initiated time-resolved x-ray absorption spectroscopy (LITR-XAS) results. To better understand the structural photodynamics of Cu(I) complexes, we have studied both [Cu{sup I}(dmp)2] and [Cu{sup I}(dpp)2]+ (dpp = 2,9-diphenyl-1,10-phenanthroline) in solvents with different dielectric constants, viscosities and thermal diffusivities by transient absorption spectroscopy. The observed spectral dynamics suggest that a solvent-independent inner-sphere relaxation process is occurring despite the large amplitude motions due to the flattening of the tetrahedral coordinated geometry. The singlet fluorescence dynamics of photoexcited [Cu{sup I}(dmp)2]+ were measured in the coordinating solvent acetonitrile, using the fluorescence upconversion method at different emission wavelengths. At the bluest emission wavelengths, a prompt fluorescence lifetime of 66 fs is attributed to the excited state deactivation processes due to the internal conversion and intersystem crossing at the Franck-Condon state geometry. The differentiation between the prompt fluorescence lifetime with the tetrahedral Franck-Condon geometry and that with the flattened tetrahedral geometry uncovers an unexpected ultrafast flattening process in the MLCT state of [Cu{sup I}(dmp)2]+. These results provide guidance for future x-ray structural studies on ultrafast time scale, as well as for synthesis towards its applications in solar energy conversion.

Copper(II) Complexes of Symmetrical and Unsymmetrical Tetradentate Schiff Base Ligands Incorporating 1-benzoylacetone

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (943 download)

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Book Synopsis Copper(II) Complexes of Symmetrical and Unsymmetrical Tetradentate Schiff Base Ligands Incorporating 1-benzoylacetone by :

Download or read book Copper(II) Complexes of Symmetrical and Unsymmetrical Tetradentate Schiff Base Ligands Incorporating 1-benzoylacetone written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Direct Synthesis of Metal Complexes

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Publisher : Elsevier
ISBN 13 : 0128110627
Total Pages : 470 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Direct Synthesis of Metal Complexes by : B.I. Kharisov

Download or read book Direct Synthesis of Metal Complexes written by B.I. Kharisov and published by Elsevier. This book was released on 2018-04-19 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt: Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water Includes experimental procedures, with examples of direct synthesis, at the end of each chapter