Studies On Group Iv And Group V Transition Metal Complexes Containing The Hydrotrispyrazolylborato Hydrotris35 Dimethylpyrazolyl Borato And Cyclopentadienyl Ligands

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Some Aspects of the Organometallic Chemistry of the Group VI Transition Metals

Author : Ezra Eddy Isaacs
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (144 download)

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Book Synopsis Some Aspects of the Organometallic Chemistry of the Group VI Transition Metals by : Ezra Eddy Isaacs

Download or read book Some Aspects of the Organometallic Chemistry of the Group VI Transition Metals written by Ezra Eddy Isaacs and published by . This book was released on 1974 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The reaction of cycloheptatrienyltricarbonyl molybdenum cation with various main group V donor ligands (L) yielded, in general, mono-substituted complexes, [C[subscript 7]H[subscript 7]Mo(CO)[subscript 2]L][superscript +]. [superscript 31]P nmr studies on some related di-tertiary phosphine complexes provided a convenient and unequivocal determination of the stereochemistry. The reduction of the cationic cycloheptatrienyl complexes with sodium borohydride provided a suitable synthetic route to the group V derivatives of cyclo- heptatrienetricarbonylmolybdenum. The infrared, [superscript l]H and [superscript 13]C nmr, and mass spectral properties of these complexes were studied. Some main group IV ligands bonded to cycloheptatrienyldicarbonylmolybdenum were also prepared and studied by spectral means. A number of main group IV - group VI metal penta- carbonyl anionic derivatives have been prepared by the reaction of the chloropentacarbonyl anions with the organolithium compounds of the group IV elements. These compounds have the general formula, [R[subscript 3]M' -M(CO)[subscript 5]][superscript -] (where R = Me, Ph or halogen; M' = Si, Ge, Sn or Pb; M = Cr, Mo or W). Approximate carbonyl force constants were calculated from the infrared carbonyl stretching vibrations and these provided some insight into the nature of the metal-metal bonds. Transition metal nitrosyl derivatives have also been prepared by the reaction of some anionic complexes with nitrosonium hexafluorophosphate. These compounds have the general formula LM(CO)[subscript 4]NO (where L is a main group IV ligand or a halogen group and M is Mo or W). The carbonyl and nitrosyl force constants were calculated and are discussed in terms of the relative bonding properties of CO and NO ligands. Finally, the oxidation reaction of some dinuclear metal carbonyls with AgNO[subscript 2] led to the formation of metal carbonyls containing nitro ligands. Linkage isomerism involving nitro and nitrito species was encountered in solution. The [(CH[subscript 3]CN)[subscript 3]Re(CO)[subscript 3]] + cation was formed 2 - from the oxidation reaction of [Re[subscript 4](CO)[subscript 16]][superscript 2-] in acetonitrile.

Groups IV, V, and VI Transition Metals and Compounds

Author : T. F. Connolly
Publisher : Springer Science & Business Media
ISBN 13 : 1468462040
Total Pages : 219 pages
Book Rating : 4.4/5 (684 download)

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Book Synopsis Groups IV, V, and VI Transition Metals and Compounds by : T. F. Connolly

Download or read book Groups IV, V, and VI Transition Metals and Compounds written by T. F. Connolly and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 219 pages. Available in PDF, EPUB and Kindle. Book excerpt: responsibility.) To Betty Edwards and Emily Copenhaver my thanks for what must have seemed endless typing, retyping and correcting of these bibliographies over a span of years. Availability of Documents U. S. Government contractor reports, usually identified by an alpha-numeric report number, can be purchased from National Technical Information Service U. S. Department of Commerce Springfield, Virginia 22151 and, often, on request from the issuing installation. USAEC reports are also available from International Atomic Energy Agency Kaerntnerring A 1010 Vienna, Austria National Lending Library Boston Spa England Monographs and reports of the National Bureau of Standards are for sale by Superintendent of Documents U. S. Government Printing Office Washington, D. C. 20402 Theses, listed as Dissertation Abstracts + number, are available in North or South America from University Microfilms Dissertation Copies P. O. Box 1764 Ann Arbor, Michigan 48106 and elsewhere from University Microfilms, Ltd. St. John's Road Tylers Green Penn, Buckinghamshire England Other Information Centers and New Journals New journals Information centers Field and and other sources serials Ultra purification 4, 8, 11, 13, 15, 16,19, 20, 9,11,15, 24, 31, 32 and 21, 28, 30, 32, 33, 42, 58, 59 crystal growth ix Preface Field Information centers New journals and and other -sources serials Characterization Miscellaneous 3,4, 8, 11, 13, 16, 19, 20, 1,3,4,8,11,15,17, 21, 26, 28, 30, 31, 32, 33, 35, 24, 25, 28, 29, 30, 31, 37, 38, 39, 40, 42, 46, 53, 56, 32 58, 60, 61, 62

On Being Well-coordinated: A Half-century Of Research On Transition Metal Complexes

Author : John L Burmeister
Publisher : World Scientific
ISBN 13 : 9814488003
Total Pages : 654 pages
Book Rating : 4.8/5 (144 download)

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Book Synopsis On Being Well-coordinated: A Half-century Of Research On Transition Metal Complexes by : John L Burmeister

Download or read book On Being Well-coordinated: A Half-century Of Research On Transition Metal Complexes written by John L Burmeister and published by World Scientific. This book was released on 2003-10-14 with total page 654 pages. Available in PDF, EPUB and Kindle. Book excerpt: This invaluable book distils the research accomplishments of Professor Fred Basolo during the five decades when he served as a world leader in the modern renaissance of inorganic chemistry. Its primary focus is on the very important area of chemistry known as coordination chemistry.Most of the elements in the periodic table are metals, and most of the chemistry of metals involves coordination chemistry. This is the case in the currently significant areas of research, including organometallic homogenous catalysis, biological reactions of metalloproteins, and even the solid state extended structures of new materials. In these systems, the metals are of primary importance because they are the sites of ligand substitution or redox reactions. In the solid materials, the coordination number of the metal and its stereochemistry are of major importance.Some fifty years of research on transition metal complexes carried out in the laboratory of Professor Basolo at Northwestern University is recorded here as selected scientific publications. The book is divided into three different major research areas, each dealing with some aspect of coordination chemistry. In each case, introductory remarks are presented which indicate what prompted the research projects and what the major accomplishments were. Although the research was of the academic, curiosity-driven type, some aspects have proven to be useful to others involved in projects that were much more applied in nature.

Organometallic Syntheses

Author : R. Bruce King
Publisher : Elsevier
ISBN 13 : 1483289931
Total Pages : 686 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Organometallic Syntheses by : R. Bruce King

Download or read book Organometallic Syntheses written by R. Bruce King and published by Elsevier. This book was released on 2013-10-22 with total page 686 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic Syntheses, Volume 3 focuses on the synthesis of compounds containing carbon-metal bonds, including ligands, compounds, chlorides, and derivatives. The selection first elaborates on bis(cyclopentadienyl) organolanthanide and organoyttrium chloride, methyl, and hydride complexes and base stabilized alkali metal halide adducts of bis (pentamethylcyclopentadienyl) lanthanide chlorides. The text then examines cyclopentadienyl metal carbonyl and nitrosyl derivatives, ferrocenylamine, cobalticinium and rhodicinium salts, and alkyl transition metal derivatives. The publication takes a look at transition metal complexes containing organophosphorus ligands, transition metal derivatives containing chalcogen ligands, and coinage metal derivatives. The text also reviews transition metal organometallic compounds, including compounds of group IA, IIA, IIB, and IVA. The selection is a vital reference for researchers interested in the synthesis of compounds containing carbon-metal bonds.

Macromolecules Containing Metal and Metal-Like Elements, Volume 6

Author : Alaa S. Abd-El-Aziz
Publisher : John Wiley & Sons
ISBN 13 : 0471747300
Total Pages : 235 pages
Book Rating : 4.4/5 (717 download)

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Book Synopsis Macromolecules Containing Metal and Metal-Like Elements, Volume 6 by : Alaa S. Abd-El-Aziz

Download or read book Macromolecules Containing Metal and Metal-Like Elements, Volume 6 written by Alaa S. Abd-El-Aziz and published by John Wiley & Sons. This book was released on 2005-10-27 with total page 235 pages. Available in PDF, EPUB and Kindle. Book excerpt: This series provides a useful, applications-oriented forum for the next generation of macromolecules and materials. The sixth volume in this series provides useful descriptions of the transition metals and their applications, edited by high-quality team of macromolecular experts from around the world.

Transition Metal-Dinitrogen Complexes

Author : Yoshiaki Nishibayashi
Publisher : John Wiley & Sons
ISBN 13 : 3527344276
Total Pages : 510 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Transition Metal-Dinitrogen Complexes by : Yoshiaki Nishibayashi

Download or read book Transition Metal-Dinitrogen Complexes written by Yoshiaki Nishibayashi and published by John Wiley & Sons. This book was released on 2019-01-25 with total page 510 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive book that explores nitrogen fixation by using transition metal-dinitrogen complexes Nitrogen fixation is one of the most prominent fields of research in chemistry. This book puts the focus on the development of catalytic ammonia formation from nitrogen gas under ambient reaction conditions that has been recently repowered by some research groups. With contributions from noted experts in the field, Transition Metal-Dinitrogen Complexes offers an important guide and comprehensive resource to the most recent research and developments on the topic of nitrogen fixation by using transition metal-dinitrogen. The book is filled with the information needed to understand the synthesis of transition metal-dinitrogen complexes and their reactivity. This important book: -Offers a resource for understanding nitrogen fixation chemistry that is essential for explosives, pharmaceuticals, dyes, and all forms of life -Includes the information needed for anyone interested in the field of nitrogen fixation by using transition metal-dinitrogen complexes -Contains state-of-the-art research on synthesis of transition metal-dinitrogen complexes and their reactivity in nitrogen fixation -Incorporates contributions from well-known specialists and experts with an editor who is an innovator in the field of dinitrogen chemistry Written for chemists and scientists with an interest in nitrogen fixation, Transition Metal-Dinitrogen Complexes is a must-have resource to the burgeoning field of nitrogen fixation by using transition metal-dinitrogen complexes.

Organometallic Chemistry of the Transition Elements

Author : Florian P. Pruchnik
Publisher : Springer Science & Business Media
ISBN 13 : 9780306431920
Total Pages : 784 pages
Book Rating : 4.4/5 (319 download)

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Book Synopsis Organometallic Chemistry of the Transition Elements by : Florian P. Pruchnik

Download or read book Organometallic Chemistry of the Transition Elements written by Florian P. Pruchnik and published by Springer Science & Business Media. This book was released on 1990-09-30 with total page 784 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry belongs to the most rapidly developing area of chemistry today. This is due to the fact that research dealing with the structure of compounds and chemical bonding has been greatly intensified in recent years. Additionally, organometallic compounds have been widely utilized in catalysis, organic synthesis, electronics, etc. This book is based on my lectures concerning basic organometallic chemistry for fourth and fifth year chemistry students and on my lectures concerning advanced organometallic chemistry and homogeneous catalysis for Ph.D. graduate students. Many recent developments in the area of organometallic chemistry as weIl as homogeneous catalysis are presented. Essential research results dealing with a given class of organometallic compounds are discussed briefly. Results of physicochemical research methods of various organometallic compounds as weIl as their synthesis, properties, structures, reactivities, and applications are discussed more thoroughly. The selection of tabulated data is arbitrary because, often, it has been impossible to avoid omissions. Nevertheless, these data can be very helpful in understanding properties of organometaIlic compounds and their reactivities. All physical data are given in SI units; the interatomic distances are given in pm units in figures and tables. I am indebted to Professor S. A. Duraj for translating and editing this book. His remarks, discussions, and suggestions are greatly appreciated. I also express gratitude to Virginia E. Duraj for editing and proofreading.

Groups IV, V, and VI Transition Metals and Compounds

Author :
Publisher :
ISBN 13 :
Total Pages : 197 pages
Book Rating : 4.:/5 (969 download)

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Book Synopsis Groups IV, V, and VI Transition Metals and Compounds by :

Download or read book Groups IV, V, and VI Transition Metals and Compounds written by and published by . This book was released on 1970 with total page 197 pages. Available in PDF, EPUB and Kindle. Book excerpt:

On Being Well-coordinated

Author : Fred Basolo
Publisher : World Scientific Publishing Company Incorporated
ISBN 13 : 9789812380876
Total Pages : 640 pages
Book Rating : 4.3/5 (88 download)

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Book Synopsis On Being Well-coordinated by : Fred Basolo

Download or read book On Being Well-coordinated written by Fred Basolo and published by World Scientific Publishing Company Incorporated. This book was released on 2003-01-01 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: This invaluable book distils the research accomplishments of Professor Fred Basolo during the five decades when he served as a world leader in the modern renaissance of inorganic chemistry. Its primary focus is on the very important area of chemistry known as coordination chemistry. Most of the elements in the periodic table are metals, and most of the chemistry of metals involves coordination chemistry. This is the case in the currently significant areas of research, including organometallic homogenous catalysis, biological reactions of metalloproteins, and even the solid state extended structures of new materials. In these systems, the metals are of primary importance because they are the sites of ligand substitution or redox reactions. In the solid materials, the coordination number of the metal and its stereochemistry are of major importance. Some fifty years of research on transition metal complexes carried out in the laboratory of Professor Basolo at Northwestern University is recorded here as selected scientific publications. The book is divided into three different major research areas, each dealing with some aspect of coordination chemistry. In each case, introductory remarks are presented which indicate what prompted the research projects and what the major accomplishments were. Although the research was of the academic, curiosity-driven type, some aspects have proven to be useful to others involved in projects that were much more applied in nature.