Statistical Mechanics Of Sum Frequency Generation Spectroscopy For The Liquid Vapor Interface Of Dilute Aqueous Salt Solutions

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Statistical Mechanics of Sum Frequency Generation Spectroscopy for the Liquid-vapor Interface of Dilute Aqueous Salt Solutions

Author :
Publisher :
ISBN 13 :
Total Pages : 22 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Statistical Mechanics of Sum Frequency Generation Spectroscopy for the Liquid-vapor Interface of Dilute Aqueous Salt Solutions by :

Download or read book Statistical Mechanics of Sum Frequency Generation Spectroscopy for the Liquid-vapor Interface of Dilute Aqueous Salt Solutions written by and published by . This book was released on 2009 with total page 22 pages. Available in PDF, EPUB and Kindle. Book excerpt: We demonstrate a theoretical description of vibrational sum frequency generation (SFG) at the boundary of aqueous electrolyte solutions. This approach identifies and exploits a simple relationship between SFG lineshapes and the statistics of molecular orientation and electric field. Our computer simulations indicate that orientational averages governing SFG susceptibility do not manifest ion-specific shifts in local electric field, but instead, ion-induced polarization of subsurface layers. Counterbalancing effects are obtained for monovalent anions and cations at the same depth. Ions held at different depths induce an imbalanced polarization, suggesting that ion-specific effects can arise from weak, long ranged influence on solvent organization.

Studies of Water and Solvents at Liquid/solid Interfaces by Sum Frequency Generation Vibrational Spectroscopy

Author : Zheng Yang
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (13 download)

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Book Synopsis Studies of Water and Solvents at Liquid/solid Interfaces by Sum Frequency Generation Vibrational Spectroscopy by : Zheng Yang

Download or read book Studies of Water and Solvents at Liquid/solid Interfaces by Sum Frequency Generation Vibrational Spectroscopy written by Zheng Yang and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Specific Ion Effects

Author : Werner Kunz
Publisher : World Scientific
ISBN 13 : 9814271586
Total Pages : 347 pages
Book Rating : 4.8/5 (142 download)

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Book Synopsis Specific Ion Effects by : Werner Kunz

Download or read book Specific Ion Effects written by Werner Kunz and published by World Scientific. This book was released on 2010 with total page 347 pages. Available in PDF, EPUB and Kindle. Book excerpt: Specific ion effects are important in numerous fields of science and technology. This book summarizes the main ideas that came up over the years. It presents the efforts of theoreticians and supports it by the experimental results stemming from various techniques.

Vibrational Sum Frequency Spectroscopy Studies at the Air-liquid Interface

Author : Eric Claude Tyrode
Publisher :
ISBN 13 : 9789171781598
Total Pages : 54 pages
Book Rating : 4.7/5 (815 download)

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Book Synopsis Vibrational Sum Frequency Spectroscopy Studies at the Air-liquid Interface by : Eric Claude Tyrode

Download or read book Vibrational Sum Frequency Spectroscopy Studies at the Air-liquid Interface written by Eric Claude Tyrode and published by . This book was released on 2005 with total page 54 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Improvements on the Analysis and Instrumentation for Sum Frequency Generation Spectroscopy and Microscopy

Author : Joon Hee Jang
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (93 download)

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Book Synopsis Improvements on the Analysis and Instrumentation for Sum Frequency Generation Spectroscopy and Microscopy by : Joon Hee Jang

Download or read book Improvements on the Analysis and Instrumentation for Sum Frequency Generation Spectroscopy and Microscopy written by Joon Hee Jang and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Sum frequency generation (SFG) vibrational spectroscopy has been established as one of the most essential tools to investigate chemistry of the surfaces and interfaces for several decades. Orientation, structure, and chemical reaction of molecules at the interfaces have been examined by using temporally and spatially resolved SFG. As a unique method to observe the chemistry at the interfaces, SFG has a great potential for further developments. In this dissertation, the possibility of extending the SFG field is gauged, including the introduction of detailed theory and formulation of SFG. Firstly, the principle of sum frequency vibrational depletion spectroscopy (SVDS) technique is presented. Newly developed SVDS has been established for observing vibrational behaviors of molecules on the surface with high spatial resolution below the diffraction limit. This technique is accomplished by depletion of the ground state molecules around the center of probing focal spot on the surface. High energy density IR generated is employed to deplete the ground state molecules to its first vibrational excited state. Then, SFG technique has been conducted to measure the vibrational dipoles of the surface molecules from the confined probing area. The instrumentation, theoretical simulation, depletion efficiency and the preliminary experimental results of this technique is reported. In the following chapter, SFG from acetonitrile on rutile TiO2 (110) surface has been measured using distinct polarization combinations and compared to the spectra obtained by polarization mapping and null angle methods. By varying the polarization combinations of SFG, the magnitude and shape of the spectra undergo substantial change, originating from the interference between the non-resonant signal inherent from the rutile substrate and the resonant signal from the adsorbed molecules. Theory, simulation, and analytical methods for obtaining quantitative orientation information in the presence of non-resonant signal of the adsorbed molecules on a semiconductor are presented. In the last chapter, a refined analytical procedure for SFG imaging microscope (SFGIM) is discussed. In order to determine the surface properties, the images need to be fitted using an SFG model equation which contains the physical properties relevant to interpret the surface. Experimental results obtained from SFGIM analysis of binary system of self-assembled monolayers on gold surface have been reported.

Solution Thermodynamics and Its Application to Aqueous Solutions

Author : Yoshikata Koga
Publisher : Elsevier
ISBN 13 : 0444636307
Total Pages : 448 pages
Book Rating : 4.4/5 (446 download)

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Book Synopsis Solution Thermodynamics and Its Application to Aqueous Solutions by : Yoshikata Koga

Download or read book Solution Thermodynamics and Its Application to Aqueous Solutions written by Yoshikata Koga and published by Elsevier. This book was released on 2017-03-28 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solution Thermodynamics and its Application to Aqueous Solutions: A Differential Approach, Second Edition introduces a differential approach to solution thermodynamics, applying it to the study of aqueous solutions. This valuable approach reveals the molecular processes in solutions in greater depth than that gained by spectroscopic and other methods. The book clarifies what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. By applying the same methodology to ions that have been ranked by the Hofmeister series, the author shows that the kosmotropes are either hydrophobes or hydration centers, and that chaotropes are hydrophiles. This unique approach and important updates make the new edition a must-have reference for those active in solution chemistry. Unique differential approach to solution thermodynamics allows for experimental evaluation of the intermolecular interaction Incorporates research findings from over 40 articles published since the previous edition Numerical or graphical evaluation and direct experimental determination of third derivatives, enthalpic and volumetric AL-AL interactions and amphiphiles are new to this edition Features new chapters on spectroscopic study in aqueous solutions as well as environmentally friendly and hostile water aqueous solutions

Fundamentals of Inhomogeneous Fluids

Author : Douglas Henderson
Publisher : CRC Press
ISBN 13 : 1000104834
Total Pages : 616 pages
Book Rating : 4.0/5 (1 download)

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Book Synopsis Fundamentals of Inhomogeneous Fluids by : Douglas Henderson

Download or read book Fundamentals of Inhomogeneous Fluids written by Douglas Henderson and published by CRC Press. This book was released on 2021-12-17 with total page 616 pages. Available in PDF, EPUB and Kindle. Book excerpt: A monograph examining recent progress in the field of inhomogeneous fluids, focusing on the theoretical - as well as experimental - techniques used. It presents the comprehensive theory of first-order phase transitions, including melting, and contains numerous figures, tables and display equations.;The contributors treat such subjects as: exact sum rules for inhomogenous fluids, explaining density functional and integral equation methods; exact solutions for two-dimensional homogeneous and inhomogeneous plasmas; current advances in the theory of interfacial electrochemistry; wetting experiments and the theory of wetting; freezing, with an emphasis on quantum systems and homogeneous nucleation in liquid-vapour and solid-liquid transitions; self-organizing liquids as well as kinetic phenomena in inhomogeneous fluids, using a modified Enskog theory.;Featuring over 1000 bibliographic citations, this volume is aimed at physical, surface, colloid and surfactant chemists; also physicists, electrochemists and graduate-level students in these disciplines.

Physics of Surfaces and Interfaces

Author : Harald Ibach
Publisher : Springer Science & Business Media
ISBN 13 : 3540347100
Total Pages : 653 pages
Book Rating : 4.5/5 (43 download)

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Book Synopsis Physics of Surfaces and Interfaces by : Harald Ibach

Download or read book Physics of Surfaces and Interfaces written by Harald Ibach and published by Springer Science & Business Media. This book was released on 2006-11-18 with total page 653 pages. Available in PDF, EPUB and Kindle. Book excerpt: This graduate-level textbook covers the major developments in surface sciences of recent decades, from experimental tricks and basic techniques to the latest experimental methods and theoretical understanding. It is unique in its attempt to treat the physics of surfaces, thin films and interfaces, surface chemistry, thermodynamics, statistical physics and the physics of the solid/electrolyte interface in an integral manner, rather than in separate compartments. It is designed as a handbook for the researcher as well as a study-text for graduate students. Written explanations are supported by 350 graphs and illustrations.

Surface and Interface Science, Volume 7

Author : Klaus Wandelt
Publisher : Wiley-VCH
ISBN 13 : 9783527680597
Total Pages : 500 pages
Book Rating : 4.6/5 (85 download)

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Book Synopsis Surface and Interface Science, Volume 7 by : Klaus Wandelt

Download or read book Surface and Interface Science, Volume 7 written by Klaus Wandelt and published by Wiley-VCH. This book was released on 2020-01-10 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covering interface science from a novel surface science perspective, this seven-volume handbook offers a comprehensive overview of both these and numerous other topics. The initial chapters treat basic fundamentals on such topics as vacuum technology, while general chapters -- where appropriate -- describe theoretical methods and provide models to help explain the respective phenomena, such as band structure calculations, chemisorption and segregation. Additionally, short references to more specialized methodology accompany the descriptions of the most important techniques. Ideal as a reference for scientists in the field, as well as an introduction to current methods for newcomers.

Structures and Interactions of Ionic Liquids

Author : Suojiang Zhang
Publisher : Springer
ISBN 13 : 3642386199
Total Pages : 201 pages
Book Rating : 4.6/5 (423 download)

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Book Synopsis Structures and Interactions of Ionic Liquids by : Suojiang Zhang

Download or read book Structures and Interactions of Ionic Liquids written by Suojiang Zhang and published by Springer. This book was released on 2013-12-20 with total page 201 pages. Available in PDF, EPUB and Kindle. Book excerpt: Structures, Bonding and Hydrogen Bonds, by Kun Dong, Qian Wang, Xingmei Lu, Suojiang Zhang Aggregation in System of Ionic Liquids, by Jianji Wang, Huiyong Wang Dissolution of Biomass Using Ionic Liquids, by Hui Wang, Gabriela Gurau, Robin D. Rogers Effect of the Structures of Ionic Liquids on Their Physical-Chemical Properties, by Yu-Feng Hu, Xiao-Ming Peng Microstructure study of Ionic liquids by spectroscopy, by Haoran Li Structures and Thermodynamic Properties of Ionic Liquids, by Tiancheng Mu, Buxing Han

Intermolecular and Surface Forces

Author : Jacob N. Israelachvili
Publisher : Academic Press
ISBN 13 : 0123919339
Total Pages : 708 pages
Book Rating : 4.1/5 (239 download)

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Book Synopsis Intermolecular and Surface Forces by : Jacob N. Israelachvili

Download or read book Intermolecular and Surface Forces written by Jacob N. Israelachvili and published by Academic Press. This book was released on 2011-07-22 with total page 708 pages. Available in PDF, EPUB and Kindle. Book excerpt: Intermolecular and Surface Forces describes the role of various intermolecular and interparticle forces in determining the properties of simple systems such as gases, liquids and solids, with a special focus on more complex colloidal, polymeric and biological systems. The book provides a thorough foundation in theories and concepts of intermolecular forces, allowing researchers and students to recognize which forces are important in any particular system, as well as how to control these forces. This third edition is expanded into three sections and contains five new chapters over the previous edition. Starts from the basics and builds up to more complex systems Covers all aspects of intermolecular and interparticle forces both at the fundamental and applied levels Multidisciplinary approach: bringing together and unifying phenomena from different fields This new edition has an expanded Part III and new chapters on non-equilibrium (dynamic) interactions, and tribology (friction forces)

Computational Electrochemistry

Author : S. Paddison
Publisher : The Electrochemical Society
ISBN 13 : 1607686511
Total Pages : 49 pages
Book Rating : 4.6/5 (76 download)

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Book Synopsis Computational Electrochemistry by : S. Paddison

Download or read book Computational Electrochemistry written by S. Paddison and published by The Electrochemical Society. This book was released on 2015-12-28 with total page 49 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Water in Biological and Chemical Processes

Author : Biman Bagchi
Publisher : Cambridge University Press
ISBN 13 : 1107037298
Total Pages : 383 pages
Book Rating : 4.1/5 (7 download)

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Book Synopsis Water in Biological and Chemical Processes by : Biman Bagchi

Download or read book Water in Biological and Chemical Processes written by Biman Bagchi and published by Cambridge University Press. This book was released on 2013-11-14 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: A unified overview of the dynamical properties of water and its unique and diverse role in biological and chemical processes.

Physics and Chemistry of Interfaces

Author : Hans-Jürgen Butt
Publisher : John Wiley & Sons
ISBN 13 : 3527836160
Total Pages : 485 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Physics and Chemistry of Interfaces by : Hans-Jürgen Butt

Download or read book Physics and Chemistry of Interfaces written by Hans-Jürgen Butt and published by John Wiley & Sons. This book was released on 2023-02-07 with total page 485 pages. Available in PDF, EPUB and Kindle. Book excerpt: Physics and Chemistry of Interfaces Comprehensive textbook on the interdisciplinary field of interface science, fully updated with new content on wetting, spectroscopy, and coatings Physics and Chemistry of Interfaces provides a comprehensive introduction to the field of surface and interface science, focusing on essential concepts rather than specific details, and on intuitive understanding rather than convoluted math. Numerous high-end applications from surface technology, biotechnology, and microelectronics are included to illustrate and help readers easily comprehend basic concepts. The new edition contains an increased number of problems with detailed, worked solutions, making it ideal as a self-study resource. In topic coverage, the highly qualified authors take a balanced approach, discussing advanced interface phenomena in detail while remaining comprehensible. Chapter summaries with the most important equations, facts, and phenomena are included to aid the reader in information retention. A few of the sample topics included in Physics and Chemistry of Interfaces are as follows: Liquid surfaces, covering microscopic picture of a liquid surface, surface tension, the equation of Young and Laplace, and curved liquid surfaces Thermodynamics of interfaces, covering surface excess, internal energy and Helmholtz energy, equilibrium conditions, and interfacial excess energies Charged interfaces and the electric double layer, covering planar surfaces, the Grahame equation, and limitations of the Poisson-Boltzmann theory Surface forces, covering Van der Waals forces between molecules, macroscopic calculations, the Derjaguin approximation, and disjoining pressure Physics and Chemistry of Interfaces is a complete reference on the subject, aimed at advanced students (and their instructors) in physics, material science, chemistry, and engineering. Researchers requiring background knowledge on surface and interface science will also benefit from the accessible yet in-depth coverage of the text.

Quantities, Units and Symbols in Physical Chemistry

Author : International Union of Pure and Applied Chemistry. Physical and Biophysical Chemistry Division
Publisher : Royal Society of Chemistry
ISBN 13 : 0854044337
Total Pages : 240 pages
Book Rating : 4.8/5 (54 download)

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Book Synopsis Quantities, Units and Symbols in Physical Chemistry by : International Union of Pure and Applied Chemistry. Physical and Biophysical Chemistry Division

Download or read book Quantities, Units and Symbols in Physical Chemistry written by International Union of Pure and Applied Chemistry. Physical and Biophysical Chemistry Division and published by Royal Society of Chemistry. This book was released on 2007 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: Prepared by the IUPAC Physical Chemistry Division this definitive manual, now in its third edition, is designed to improve the exchange of scientific information among the readers in different disciplines and across different nations. This book has been systematically brought up to date and new sections added to reflect the increasing volume of scientific literature and terminology and expressions being used. The Third Edition reflects the experience of the contributors with the previous editions and the comments and feedback have been integrated into this essential resource. This edition has been compiled in machine-readable form and will be available online.

Analytical and Physical Electrochemistry

Author : Hubert H. Girault
Publisher : CRC Press
ISBN 13 : 1439807841
Total Pages : 448 pages
Book Rating : 4.4/5 (398 download)

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Book Synopsis Analytical and Physical Electrochemistry by : Hubert H. Girault

Download or read book Analytical and Physical Electrochemistry written by Hubert H. Girault and published by CRC Press. This book was released on 2004-10-25 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: The study of electrochemistry is pertinent to a wide variety of fields, including bioenergetics, environmental sciences, and engineering sciences. In addition, electrochemistry plays a fundamental role in specific applications as diverse as the conversion and storage of energy and the sequencing of DNA. Intended both as a basic course for un

Water in Confining Geometries

Author : V. Buch
Publisher : Springer Science & Business Media
ISBN 13 : 9783540004110
Total Pages : 488 pages
Book Rating : 4.0/5 (41 download)

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Book Synopsis Water in Confining Geometries by : V. Buch

Download or read book Water in Confining Geometries written by V. Buch and published by Springer Science & Business Media. This book was released on 2003-04-29 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by leading experts in the field, this book gives a wide-ranging and coherent treatment of water in confining geometries. It compiles and relates interdisciplinary work on this hot topic of research important in many areas of science and technology.