Specific Interactions And The Miscibility Of Polymer Blends

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Specific Interactions and the Miscibility of Polymer Blends

Author : Michael M. Coleman
Publisher : Routledge
ISBN 13 : 1351415158
Total Pages : 435 pages
Book Rating : 4.3/5 (514 download)

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Book Synopsis Specific Interactions and the Miscibility of Polymer Blends by : Michael M. Coleman

Download or read book Specific Interactions and the Miscibility of Polymer Blends written by Michael M. Coleman and published by Routledge. This book was released on 2017-11-13 with total page 435 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book with software provides powerful tools for the analysis, prediction and creation of new polymer blends, an area of significant commercial potential. The R&D approaches and methods described in the book have attracted the interest of polymer R&D leaders in industry, and have been put into use in several major chemical companies. The companion set of computer programs speeds and facilitates work in this area. FROM THE AUTHORS' PREFACE: During the 1980's a steadily increasing number of compatible systems [polymer blends] have been reported. We believe that miscible mixtures will prove to be fairly common and the purpose of this book is to explore the circumstances in which single phase materials can be obtained. We will also describe a model for the phase behavior of these mixtures which we believe to have a predictive value, or be used as a practical guide to polymer miscibility. Our approach is based on the use of association models which have until recently been largely ignored in treating hydrogen bonding in polymer mixtures. They have most frequently been applied to mixtures of alcohols with simple hydrocarbons, where the equilibrium constants used to describe association have most frequently been determined by a fit to thermodynamic data (e.g., vapor pressures, heat of mixing). In our work we have sought to, first, adapt this approach to a description of the phase behavior of polymer mixtures; second, develop spectroscopic methods that provide an independent measurement of the equilibrium constants. Our purpose in this book is to explore and describe this approach and illustrate its broad utility. We address two overlapping yet different audiences. One would be primarily interested in the broad nature of this approach and the practical applications of a simple model. The second would be more interested in the derivations of the equations and some of the fundamental aspects of the spectroscopy of these systems. Accor

Specific Interactions and the Miscibility of Polymer Blends

Author : Michael M. Coleman
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (141 download)

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Book Synopsis Specific Interactions and the Miscibility of Polymer Blends by : Michael M. Coleman

Download or read book Specific Interactions and the Miscibility of Polymer Blends written by Michael M. Coleman and published by . This book was released on 1991 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Polymer-Polymer Miscibility

Author : Olagoke Olabis
Publisher : Elsevier
ISBN 13 : 0323153070
Total Pages : 383 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Polymer-Polymer Miscibility by : Olagoke Olabis

Download or read book Polymer-Polymer Miscibility written by Olagoke Olabis and published by Elsevier. This book was released on 2012-12-02 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer–Polymer Miscibility discusses miscibility of polymeric mixtures. This book explains the theoretical and practical aspects of polymer miscibility, which has become a considerable area of research in many academic and industrial laboratories. Comprised of seven chapters, this book starts with an overview of the physical nature of the variations of the basic polymer structure. This monograph then discusses the two cases of miscible polymer blends, namely, poly(vinyl chloride) (PVC)–butadiene/acrylonitrile copolymer (NBR) and polystyrene–poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) blends. This text explores the useful and unique properties of blends of poly(vinyl chloride) and butadiene/acrylonitrile copolymer rubber. Other chapters discuss the thermodynamic theories for the phase separation of block copolymers. The reader is also introduced to other variations of chemical structure, which can result in the permanent attachment of polymers to each other through block and graft copolymers. This text also explores the feasibility of covalent bonding of polymer components. This book is intended for chemical engineers and materials scientists.

Characterization of Polymer Blends

Author : Sabu Thomas
Publisher : John Wiley & Sons
ISBN 13 : 3527331530
Total Pages : 972 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Characterization of Polymer Blends by : Sabu Thomas

Download or read book Characterization of Polymer Blends written by Sabu Thomas and published by John Wiley & Sons. This book was released on 2015-02-09 with total page 972 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling the gap for a reference dedicated to the characterization of polymer blends and their micro and nano morphologies, this book provides comprehensive, systematic coverage in a one-stop, two-volume resource for all those working in the field. Leading researchers from industry and academia, as well as from government and private research institutions around the world summarize recent technical advances in chapters devoted to their individual contributions. In so doing, they examine a wide range of modern characterization techniques, from microscopy and spectroscopy to diffraction, thermal analysis, rheology, mechanical measurements and chromatography. These methods are compared with each other to assist in determining the best solution for both fundamental and applied problems, paying attention to the characterization of nanoscale miscibility and interfaces, both in blends involving copolymers and in immiscible blends. The thermodynamics, miscibility, phase separation, morphology and interfaces in polymer blends are also discussed in light of new insights involving the nanoscopic scale. Finally, the authors detail the processing-morphology-property relationships of polymer blends, as well as the influence of processing on the generation of micro and nano morphologies, and the dependence of these morphologies on the properties of blends. Hot topics such as compatibilization through nanoparticles, miscibility of new biopolymers and nanoscale investigations of interfaces in blends are also addressed. With its application-oriented approach, handpicked selection of topics and expert contributors, this is an outstanding survey for anyone involved in the field of polymer blends for advanced technologies.

Miscible Polymer Blends

Author : Michael M. Coleman
Publisher : DEStech Publications, Inc
ISBN 13 : 193207855X
Total Pages : 40 pages
Book Rating : 4.9/5 (32 download)

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Book Synopsis Miscible Polymer Blends by : Michael M. Coleman

Download or read book Miscible Polymer Blends written by Michael M. Coleman and published by DEStech Publications, Inc. This book was released on 2006-12 with total page 40 pages. Available in PDF, EPUB and Kindle. Book excerpt: The accompanying CD-ROM contains a set of original programs that allow one to calculate solubility parameters, provide a guide to polymer miscibility, and allow the calculation of the phase behavior of hydrogen-bonded polymer systems. The book is divided into two parts. In the first part, the authors describe the principles underlying the simple guide to polymer blend miscibility, which are the basis of the programs Miscibility Checker and Miscibility Guide. The second part is more rigorous and pertains to hydrogen bonded polymer blends and forms the basis of the program Phase Calculator.

Polymer Blends Handbook

Author : L. A. Utracki
Publisher :
ISBN 13 : 9789400760653
Total Pages : 1800 pages
Book Rating : 4.7/5 (66 download)

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Book Synopsis Polymer Blends Handbook by : L. A. Utracki

Download or read book Polymer Blends Handbook written by L. A. Utracki and published by . This book was released on 2014-01-31 with total page 1800 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by an international group of highly respected contributors, this fundamental reference work covers all aspects of polymer blends: science, engineering, technology and applications.

Specific Interactions and the Miscibility of Polymer Blends

Author : Michael M. Coleman
Publisher : CRC Press
ISBN 13 : 1351415166
Total Pages : 516 pages
Book Rating : 4.3/5 (514 download)

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Book Synopsis Specific Interactions and the Miscibility of Polymer Blends by : Michael M. Coleman

Download or read book Specific Interactions and the Miscibility of Polymer Blends written by Michael M. Coleman and published by CRC Press. This book was released on 2017-11-13 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book with software provides powerful tools for the analysis, prediction and creation of new polymer blends, an area of significant commercial potential. The R&D approaches and methods described in the book have attracted the interest of polymer R&D leaders in industry, and have been put into use in several major chemical companies. The companion set of computer programs speeds and facilitates work in this area. FROM THE AUTHORS' PREFACE: During the 1980's a steadily increasing number of compatible systems [polymer blends] have been reported. We believe that miscible mixtures will prove to be fairly common and the purpose of this book is to explore the circumstances in which single phase materials can be obtained. We will also describe a model for the phase behavior of these mixtures which we believe to have a predictive value, or be used as a practical guide to polymer miscibility. Our approach is based on the use of association models which have until recently been largely ignored in treating hydrogen bonding in polymer mixtures. They have most frequently been applied to mixtures of alcohols with simple hydrocarbons, where the equilibrium constants used to describe association have most frequently been determined by a fit to thermodynamic data (e.g., vapor pressures, heat of mixing). In our work we have sought to, first, adapt this approach to a description of the phase behavior of polymer mixtures; second, develop spectroscopic methods that provide an independent measurement of the equilibrium constants. Our purpose in this book is to explore and describe this approach and illustrate its broad utility. We address two overlapping yet different audiences. One would be primarily interested in the broad nature of this approach and the practical applications of a simple model. The second would be more interested in the derivations of the equations and some of the fundamental aspects of the spectroscopy of these systems. Accor

Nanostructured Polymer Blends

Author : Chandran C. Sarath
Publisher : Elsevier Inc. Chapters
ISBN 13 : 0128090782
Total Pages : 576 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Nanostructured Polymer Blends by : Chandran C. Sarath

Download or read book Nanostructured Polymer Blends written by Chandran C. Sarath and published by Elsevier Inc. Chapters. This book was released on 2013-11-28 with total page 576 pages. Available in PDF, EPUB and Kindle. Book excerpt: Miscibility and compatibility in polymer blends is a topic of great academic and industrial importance. This is because miscibility and compatibility contribute to morphology, properties, and performance. Miscibility results in one phase; compatibility creates a disperse phase with size and stability determined by interfacial interactions. Miscible polymer properties are averaged similar to a plasticizer polymer, and compatible polymers retain properties of each component, such as toughening or reinforcement. With miscible polymer blends the continuous phase dominates properties; the disperse phase contributes via stress transfer. This chapter revisits the criteria for miscibility or compatibility in polymer blends and the contributors of compatibility compared with miscibility and incompatibility. Development of copolymers and their blending with thermosets and thermoplastics result in complex two-phase morphologies. The dynamics of phase separation observed in polymer blends leading to different morphologies and the criteria for phase separation is explained. A nanometer-dispersed phase requires strong interfacial interactions to stabilize the large interfacial area, and this is favored by rapid spinodal phase separation compared with size diminution by high shear. Nanoblends open up a new arena for polymer blends, and research shows that nanoblends have outstanding optical and mechanical properties.

Polymer Blends Volume 1

Author : Donald R Paul
Publisher : Elsevier
ISBN 13 : 0323138896
Total Pages : 520 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Polymer Blends Volume 1 by : Donald R Paul

Download or read book Polymer Blends Volume 1 written by Donald R Paul and published by Elsevier. This book was released on 2012-12-02 with total page 520 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer Blends, Volume 1 highlights the importance of polymer blends as a major new branch of macromolecular science. Topics range from polymer-polymer compatibility and the statistical thermodynamics of polymer blends to the phase separation behavior of polymer-polymer mixtures, transport phenomena in polymer blends, and mechanical properties of multiphase polymer blends. The optical behavior, solid state transition behavior, and rheology of polymer blends are also discussed. This book is organized into 10 chapters and begins with an overview of polymer blends, with emphasis on terminology and the effect of molecular weight on the thermodynamics of polymer blends as well as phase equilibria and transitions. The discussion then turns to the miscibility of homopolymers and copolymers, in bulk and in solution, from the experimental and theoretical viewpoints. The chapters that follow explore the statistical thermodynamics of polymer blends, paying particular attention to the Flory and lattice fluid theories, along with the phase relationship in polymer mixtures. The interfacial energy, structure, and adhesion between polymers in relation to the properties of polymer blends are considered. The final chapter examines the phenomena of low molecular weight penetrant transport. Currently accepted models for unsteady-state and steady-state permeation of polymeric materials are presented. A discussion of unsteady-state absorption and desorption behavior observed in a variety of polymer blends complements the treatment of permeation behavior. This book is intended to provide academic and industrial research scientists and technologists with a broad background in current principles and practice concerning mixed polymer systems.

Compatibilization of Polymer Blends

Author : Ajitha A. R
Publisher : Elsevier
ISBN 13 : 0128162880
Total Pages : 640 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Compatibilization of Polymer Blends by : Ajitha A. R

Download or read book Compatibilization of Polymer Blends written by Ajitha A. R and published by Elsevier. This book was released on 2019-10-10 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: Compatibilization of Polymer Blends: Micro and Nano Scale Phase Morphologies, Interphase Characterization and Properties offers a comprehensive approach to the use of compatibilizers in polymer blends, examining both fundamental and advanced knowledge in the field. The book begins by introducing polymer blends, describing thermodynamics, miscibility, and phase separation, and explaining the main concepts of compatibilization. Other sections cover theoretical approaches for nearly compatible blends, incompatible blends, nanofillers, physical compatibilization, reactive compatibilization, morphological and structural characterization, and physico-mechanical characterization. Finally, key application areas are covered, including biomedical applications, packaging and automobile engineering. While this book will be a highly valuable reference source for academics, researchers and postgraduate students interested in polymer blends, it will also be ideal for anyone involved in the fields of polymer science, polymer chemistry, polymer physics, materials science, scientists, R&D professionals, and engineers in involved in the development or engineering of polymer products. Offers detailed and systematic coverage of essential and advanced topics relating to the compatibilization of polymer blends Presents a critical analysis of the effect of compatibilization on morphology and thermal, mechanical, electrical and viscoelastic properties of polymer blends Draws on novel studies and state-of-the-art research, discussing the latest issues and developments

Polymer Thermodynamics

Author : Kal Renganathan Sharma
Publisher : CRC Press
ISBN 13 : 1439826404
Total Pages : 371 pages
Book Rating : 4.4/5 (398 download)

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Book Synopsis Polymer Thermodynamics by : Kal Renganathan Sharma

Download or read book Polymer Thermodynamics written by Kal Renganathan Sharma and published by CRC Press. This book was released on 2011-10-10 with total page 371 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer Thermodynamics: Blends, Copolymers and Reversible Polymerization describes the thermodynamic basis for miscibility as well as the mathematical models used to predict the compositional window of miscibility and construct temperature versus volume-fraction phase diagrams. The book covers the binary interaction model, the solubility parameter

Nanostructured Immiscible Polymer Blends

Author : Suprakas Sinha Ray
Publisher : Elsevier
ISBN 13 : 0128168781
Total Pages : 240 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Nanostructured Immiscible Polymer Blends by : Suprakas Sinha Ray

Download or read book Nanostructured Immiscible Polymer Blends written by Suprakas Sinha Ray and published by Elsevier. This book was released on 2019-09-17 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanostructured Immiscible Polymer Blends: Migration and Interface covers a wide range of nanoparticle types, emphasizing the mechanisms and parameters involved in the migration of nanofillers inside immiscible polymer blends. This book explores the influence of nanoparticle migration on the localization, and hence, morphology development, electrical conductivity, and met-rheological properties of blended composite materials. As the influence of solid particles, ranging in size from several hundred nanometers to a few microns in immiscible polymer blends has been extensively studied for use as compatibilizers, morphology stabilizers, and reinforcement agents, this book is a timely resource. Outlines techniques used to prepare nanoparticles-modified immiscible polymer blend composites Explains the structural and morphological development, and melt-state rheological behaviors of nanoparticles-modified immiscible polymer blend composites Discusses major industrial applications

Nanostructured Polymer Blends

Author : Sabu Thomas
Publisher : William Andrew
ISBN 13 : 1455731609
Total Pages : 570 pages
Book Rating : 4.4/5 (557 download)

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Book Synopsis Nanostructured Polymer Blends by : Sabu Thomas

Download or read book Nanostructured Polymer Blends written by Sabu Thomas and published by William Andrew. This book was released on 2013-11-28 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over 30% of commercial polymers are blends or alloys or one kind or another. Nanostructured blends offer the scientist or plastics engineer a new range of possibilities with characteristics including thermodynamic stablility; the potential to improve material transparency, creep and solvent resistance; the potential to simultaneously increase tensile strength and ductility; superior rheological properties; and relatively low cost. Nanostructured Polymer Blends opens up immense structural possibilities via chemical and mechanical modifications that generate novel properties and functions and high-performance characteristics at a low cost. The emerging applications of these new materials cover a wide range of industry sectors, encompassing the coatings and adhesives industry, electronics, energy (photovoltaics), aerospace and medical devices (where polymer blends provide innovations in biocompatible materials). This book explains the science of nanostructure formation and the nature of interphase formations, demystifies the design of nanostructured blends to achieve specific properties, and introduces the applications for this important new class of nanomaterial. All the key topics related to recent advances in blends are covered: IPNs, phase morphologies, composites and nanocomposites, nanostructure formation, the chemistry and structure of additives, etc. Introduces the science and technology of nanostructured polymer blends – and the procedures involved in melt blending and chemical blending to produce new materials with specific performance characteristics Unlocks the potential of nanostructured polymer blends for applications across sectors, including electronics, energy/photovoltaics, aerospace/automotive, and medical devices (biocompatible polymers) Explains the performance benefits in areas including rheological properties, thermodynamic stablility, material transparency, solvent resistance, etc.

Polymer Synthesis Polymer-Polymer Complexation

Author :
Publisher : Springer
ISBN 13 : 3540494243
Total Pages : 215 pages
Book Rating : 4.5/5 (44 download)

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Book Synopsis Polymer Synthesis Polymer-Polymer Complexation by :

Download or read book Polymer Synthesis Polymer-Polymer Complexation written by and published by Springer. This book was released on 2003-07-03 with total page 215 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Polymer Blends

Author : Lloyd M. Robeson
Publisher : Hanser Gardner Publications
ISBN 13 : 9781569904084
Total Pages : 459 pages
Book Rating : 4.9/5 (4 download)

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Book Synopsis Polymer Blends by : Lloyd M. Robeson

Download or read book Polymer Blends written by Lloyd M. Robeson and published by Hanser Gardner Publications. This book was released on 2007 with total page 459 pages. Available in PDF, EPUB and Kindle. Book excerpt: It has been well-recognized that polymer blends offer a key option in solving emerging application requirements. The ability to combine existing polymers into new compositions with commercializable properties offers the advantage of reduced research and development expense compared to the development of new monomers and polymers to yield a similar property profile. An additional advantage is the much lower capital expense involved with scale-up and commercialization. Another specific advantage of polymer blends versus new monomer/polymer compositions is that blends often offer property profile combinations not easily obtained with new polymeric structures. In the rapidly emerging technology landscape, polymer blend technology can quickly respond to developing needs.

Polymer Blends and Alloys

Author : George P. Simon
Publisher : Routledge
ISBN 13 : 1351423614
Total Pages : 865 pages
Book Rating : 4.3/5 (514 download)

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Book Synopsis Polymer Blends and Alloys by : George P. Simon

Download or read book Polymer Blends and Alloys written by George P. Simon and published by Routledge. This book was released on 2019-07-16 with total page 865 pages. Available in PDF, EPUB and Kindle. Book excerpt: Distinguishing among blends, alloys and other types of combinations, clarifying terminology and presenting data on new processes and materials, this work present up-to-date and effective compounding techniques for polymers. It offers extensive analyses on the challenging questions that surround miscibility, compatibility, dynamic processing, interaction/phase behaviour, and computer simulations for predicting behaviours of polymer mixture and interaction.

Nanofillers for Binary Polymer Blends

Author : Sabu Thomas
Publisher : Elsevier
ISBN 13 : 0323886434
Total Pages : 542 pages
Book Rating : 4.3/5 (238 download)

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Book Synopsis Nanofillers for Binary Polymer Blends by : Sabu Thomas

Download or read book Nanofillers for Binary Polymer Blends written by Sabu Thomas and published by Elsevier. This book was released on 2024-06-28 with total page 542 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanofillers for Binary Polymer Blends covers major advances in the field of polymer-blend nanocomposites. The book encompasses the fundamentals of polymer blends, various nanofillers, experimental techniques used in their fabrication, the characterization of various polymer blend nanocomposites, and theoretical evaluations of various properties. The properties and potential applications that have been achieved in various polymer blends by the addition of nanofillers are also highlighted. Applications for commercial products, including automotive parts, packaging, construction materials, biotechnology, medical devices, building materials, computer housings, car interiors, etc., are also covered in detail.This is an important reference source for materials scientists and engineers looking to increase their understanding of how nanofillers are being used in polymer blends. Outlines the various types of nanofillers, explaining how the properties of each enhances the morphology, rheology, mechanical, dynamic mechanical, viscoelastic, electrical and thermal properties of polymer blends Provides information on the theory, modeling and simulation of nano-filled polymer blends Assesses the mechanism of selective localization of nanofillers in polymer blends, the effect of localization of nanofillers on the microstructure, and the relative performance of polymer blends