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Author : S. Hornig
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (837 download)
Download or read book Special Issue: Metal-containing and Metallo-supramolecular Polymers and Materials written by S. Hornig and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Masayoshi Higuchi
Publisher : Springer Nature
ISBN 13 : 4431568913
Total Pages : 89 pages
Book Rating : 4.4/5 (315 download)
Download or read book Metallo-Supramolecular Polymers written by Masayoshi Higuchi and published by Springer Nature. This book was released on 2019-11-12 with total page 89 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II). The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.
Author : Stephanie Hornig
Publisher :
ISBN 13 :
Total Pages : 38 pages
Book Rating : 4.:/5 (653 download)
Download or read book Metal-containing and Metallo-supramolecular Polymers and Materials written by Stephanie Hornig and published by . This book was released on 2010 with total page 38 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Alaa S. Abd-El-Aziz
Publisher : John Wiley & Sons
ISBN 13 : 9783527307005
Total Pages : 376 pages
Book Rating : 4.3/5 (7 download)
Download or read book Metal- and Metalloid-Containing Macromolecules written by Alaa S. Abd-El-Aziz and published by John Wiley & Sons. This book was released on 2003-10-03 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt: The past two decades have seen tremendous developments in the field of metal- and metalloid-containing macromolecules. The design of new monomers containing metal and metalloid elements and their subsequent polymerization has resulted in a vast array of inorganic and organometallic polymers with interesting properties and applications. This volume features 30 articles based on presentations given in the Metal- and Metalloid-Containing Macromulecules Symposium at the 39th IUPAC Congress and 86th Conference of the Canadian Society for Chemistry in Ottawa from August 10-15, 2003. The articles, written by some of the leading researchers in the field, describe the synthesis, properties and applications of inorganic and organometallic polymers and the current focuses of research in these fields. The purpose of this symposium was to generate dialogue between these researchers and to allow them to present some of their most recent findings.
Author : Alaa S. Abd-El-Aziz
Publisher : John Wiley & Sons
ISBN 13 : 047008605X
Total Pages : 545 pages
Book Rating : 4.4/5 (7 download)
Download or read book Frontiers in Transition Metal-Containing Polymers written by Alaa S. Abd-El-Aziz and published by John Wiley & Sons. This book was released on 2007-01-29 with total page 545 pages. Available in PDF, EPUB and Kindle. Book excerpt: A detailed, up-to-date review of transition metal-containing polymers Promising advances in the electrical, optical, magnetic, biological, and catalytic properties that metal-containing polymers possess have led to notable expansion in the field of transition metal-containing polymers. Frontiers in Transition Metal-Containing Polymers provides a comprehensive, up-to-date review of the synthesis, properties, and applications of transition metal-containing polymers, including an overview of the historical development of these types of polymers. Written by the leading researchers in the field, this thorough volume covers the routes to organometallic and coordination polymers, as well as characterization and applications of transition metal-containing monomers and polymers. Other topics discussed include: Metallo-supramolecular coordination polymers based on nitrogen ligands Coordination polymers based on phosphorus ligands Polypeptide-based metallobiopolymers and DNA-based metallopolymers Metallodendrimers Self-assembly of metal-containing block copolymers Applications including drug delivery, optics, molecular devices, sensors, conductive materials, and more
Author : Ulrich Schubert
Publisher :
ISBN 13 :
Total Pages : 606 pages
Book Rating : 4.3/5 (91 download)
Download or read book Metal-containing and Metallosupramolecular Polymers and Materials written by Ulrich Schubert and published by . This book was released on 2006 with total page 606 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Containing and Metallo-Supramolecular Polymers and Materials covers a broad range of chapters on metal-containing polymers and materials by leading researchers. These chapters will include design, synthesis, characterization as well as selected applications.Potential applications are identified in the areas of smart or intelligent materials, systems with special photochemical and photophysical properties (such as LEDs or solar cells), nanoscience, sensory materials, as well as materials with very special thermal and mechanical properties.
Author : Alaa S. Abd-El-Aziz
Publisher : John Wiley & Sons
ISBN 13 : 0471466581
Total Pages : 280 pages
Book Rating : 4.4/5 (714 download)
Download or read book Macromolecules Containing Metal and Metal-Like Elements, Volume 1 written by Alaa S. Abd-El-Aziz and published by John Wiley & Sons. This book was released on 2004-02-15 with total page 280 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal- and metalloid-containing macromolecules are defined as large molecules (i.e., polymers, DNA, proteins) that contain a metal or metalloid group affiliated with the molecule. The first volume in this series consists of a number of reviews of the field, to give the reader a background to build upon. Compiled by an all-star cast of macromolecular experts, this guide: Provides useful descriptions of applications for the reader to apply in his/her research into materials, polymers, and medicine/drug development. Covers non-linear optical materials, speciality magnetic materials, liquid crystals, anticancer and antiviral drugs, treatment of arthritis, antibacterial drugs, antifouling materials, treatment of certain vitamin deficiencies, electrical conductors and semiconductors, piezoelectronic materials, electrodes, UV absorption applications, super-strength materials, special lubricants and gaskets, selective catalytic and multisite catalytic agents.
Author : Christian Eschbaumer
Publisher :
ISBN 13 : 9789038627021
Total Pages : 195 pages
Book Rating : 4.6/5 (27 download)
Download or read book Metallo-supramolecular Polymers written by Christian Eschbaumer and published by . This book was released on 2001 with total page 195 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Alaa S. Abd-El-Aziz
Publisher : Wiley
ISBN 13 : 0470527048
Total Pages : 368 pages
Book Rating : 4.4/5 (75 download)
Download or read book Macromolecules Containing Metal and Metal-Like Elements written by Alaa S. Abd-El-Aziz and published by Wiley. This book was released on 2009-11-19 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book series Macromolecules Containing Metal and Metal-like Elements brings new concepts and developments in the titled area of research. Volume 9 focuses attention on the area of supramolecular chemistry, supramolecular architecture and supramolecular self-assemblies that involve materials containing metals and metal-like elements and the potential applications of these interesting hybrid materials.
Author : Charles E. Carraher Jr.
Publisher : Springer
ISBN 13 : 9781461380184
Total Pages : 0 pages
Book Rating : 4.3/5 (81 download)
Download or read book Metal-Containing Polymeric Materials written by Charles E. Carraher Jr. and published by Springer. This book was released on 2011-12-08 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: ''A must for anyone interested in metal-containing polymers and all its aspects.'' ---American Scientist ''Nicely organized...well-written....An excellent shapshot of the current state of this field.'' ---MRS Bulletin, July 1998
Author : Mark Gross Burnworth
Publisher :
ISBN 13 :
Total Pages : 204 pages
Book Rating : 4.:/5 (77 download)
Download or read book Multifunctional Metallo-supramolecular Materials and Sensors written by Mark Gross Burnworth and published by . This book was released on 2011 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt: Supramolecular chemistry has become a rapidly growing field since the Nobel Prize was awarded to the work of Lehn, Pedersen, and Cram in 1987 for their pioneering work on crown ethers and non-covalent host-guest interactions. Metal-ligand interactions represent a particularly useful and well-studied means of preparing supramolecular polymers from telechelic building blocks. This present work focuses on utilizing main-chain metallo-supramolecular polymers or small molecules, based on 2,6-bis(1'-methylbenzimidazolyly)pyridine (Mebip) ligands, to create materials aimed at applications such as light healable polymers, or the detection of chemical warfare agents. With the objective to develop new organic/inorganic hybrid materials, which combine good mechanical properties and other attractive properties with ease of processing, new classes of metallo-supramolecular polymers were explored. The general design approach merged the structure of known polymer systems, for example semiconducting polymers (poly(p-phenylene ethynylene)s) or thermally stable hydrocarbons (poly(p-xylyene)s), with the advantages of a dynamic (reversible) polymerization process, to allow access to materials that are otherwise difficult to process. The new telechelic metallo-supramolecular polymers could be readily solution-processed and represent illustrative examples for metallo-supramolecular polymers with good mechanical properties, while maintaining the properties of parent polymer. Polymers with the ability to repair themselves after sustaining damage are poised to extend the lifetime of materials used in a wide range of applications. Reported here is the development of metallo-supramolecular polymers that can be mended through exposure to light. Upon exposure to ultraviolet light, the metal-ligand motifs are electronically excited and the absorbed energy is converted into heat, causing reversible disengagement of the metal-ligand motif and a temporary reduction in the molecular weight. As a result, defects heal quickly, with high efficiency, and if needed repeatedly. A modular sensory system, for the detection of organophosphates, which utilizes a multi-metal/multi-ligand approach is presented. The sensing scheme relies on fluorescent sensor complexes of Mebip ligands and selected metal ions. Detection of organophosphates is accomplished through competitive coordination of the analyte with the metal. Mixing and matching consciously designed ligands and carefully selected metal ions allows the formation of sensor complexes, which allow organophosphate detection with high selectivity and sensitivity.
Author : John George Hardy
Publisher : Royal Society of Chemistry
ISBN 13 : 1782622675
Total Pages : 417 pages
Book Rating : 4.7/5 (826 download)
Download or read book Functional Metallosupramolecular Materials written by John George Hardy and published by Royal Society of Chemistry. This book was released on 2015-07-13 with total page 417 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is great interest in metallosupramolecular materials because of their use in magnetic, photonic and electronic materials. Functional Metallosupramolecular Materials focuses on the applications of these materials covering the chemistry underlying the synthesis of a variety of ligands to coordinate various metal ions and the generation of 2D and 3D materials based on these constructs. The book starts by looking at different metallosupramolecular systems including naturally occurring functional metallosupramolecular materials; DNA-based metallosupramolecular materials; metallopolymers; metallogels as well as functional materials based on MOFs. Subsequent chapters then systematically cover the different applications such as molecular computation, spin-crossover, light harvesting and as photocatalysts for the production of solar fuels. The book provides an overview of functional metallosupramolecular materials that will be of interest to graduate students, academics and industrial chemists interested in supramolecular chemistry, materials science and the materials applications.
Author : J. Sheats
Publisher : Springer
ISBN 13 :
Total Pages : 448 pages
Book Rating : 4.3/5 (91 download)
Download or read book Inorganic and Metal-Containing Polymeric Materials written by J. Sheats and published by Springer. This book was released on 1990 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research on metal-containing polymers began in the early 1960's when several workers found that vinyl ferrocene and other vinylic transition metal TI -complexes would undergo polymerization under the same conditions as conventional organic monomers to form high polymers which incorporated a potentially reactive metal as an integral part of the polymer structures. Some of these materials could act as semi conductors and possessed one or two dimensional conductivity. Thus applications in electronics could be visualized immediately. Other workers found that reactions used to make simple metal chelates could be used to prepare polymers if the ligands were designed properly. As interest in homogeneous catalysts developed in the late 60's and early 70's, several investigators began binding homogeneous catalysts onto polymers, where the advantage of homogeneous catalysis - known reaction mechanisms and the advantage of heterogeneous catalysis - simplicity and ease of recovery of catalysts could both be obtained. Indeed the polymer matrix itself often enhanced the selectivity of the catalyst. The first symposium on Organometallic Polymers, held at the National Meeting of the American Chemical Society in September 1977, attracted a large number of scientists interested in this field, both established investigators and newcomers. Subsequent symposia in 1977, 1979, 1983, and 1987 have seen the field mature. Hundreds of papers and patents have been published.
Author :
Publisher :
ISBN 13 :
Total Pages : 20 pages
Book Rating : 4.:/5 (574 download)
Download or read book Bio-Inspired Metallo-Supramolecular Polymers for Combined Mechanical Properties written by and published by . This book was released on 2010 with total page 20 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development of materials with combined mechanical properties remains a significant challenge in polymer synthesis. The preparation of such materials could potentially impact a wide range of Army applications. In this work, bio-inspired metallo- supramolecular polymers were designed, synthesized, and characterized. We anticipate these polymers will display enhanced mechanical properties due to the presence of intermediate strength metal-ligand bonds present in the polymer backbone, which forms a compacted, modular molecular topology. The 2,6-bisbenzimidazolylpyridine ligand was prepared and incorporated into a model polymer backbone via thiol-ene click chemistry. The resulting polymer was thoroughly characterized by 1H Nuclear Magnetic Resonance (NMR), gel permeation chromatography (GPC), and differential scanning calorimetry (DSC). Binding of the ligand with Zn2+ and Co2+ was studied using ultraviolet/visible (UV/Vis) spectroscopy, which demonstrated a 2:1 ligand-to-metal ratio.
Author : Alaa S. Abd-El Aziz
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (733 download)
Download or read book Macromolecules Containing Metal and Metal-Like Elements written by Alaa S. Abd-El Aziz and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Anil Mahapatro
Publisher : American Chemical Society
ISBN 13 :
Total Pages : 442 pages
Book Rating : 4.3/5 (91 download)
Download or read book Polymers for Biomedical Applications written by Anil Mahapatro and published by American Chemical Society. This book was released on 2008-04-17 with total page 442 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research on applications of polymers for biomedical applications has increased dramatically to find improved medical plastics for this rapidly evolving field. This book brings together various aspects of recent research and developments within academia and industry related to polymers for biomedical applications.
Author : Rodolphe Antoine
Publisher : MDPI
ISBN 13 : 3039285505
Total Pages : 182 pages
Book Rating : 4.0/5 (392 download)
Download or read book Supramolecular Gold Chemistry written by Rodolphe Antoine and published by MDPI. This book was released on 2020-06-23 with total page 182 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is about supramolecular gold chemistry. This book provides a unique international forum aimed at covering a broad description of results involving the supramolecular chemistry of gold with a special focus on the gold–sulfur interface leading to hybrid materials ranging from gold–thiolate complexes to thiolate-protected gold nanoclusters and gold–thiolate supramolecular assemblies or nanoparticles. The role of thiolates on the structure and optical features of gold nanohybrid systems (ranging from plasmonic gold nanoparticles and fluorescent gold nanoclusters to self-assembled Au-containing thiolated coordination polymers) is highlighted in the 12 papers presented in this book.
