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Self Initiated Polymerization Of Methyl Methacrylate Using Atom Teransfer Radical Polymerization Method
Download Self Initiated Polymerization Of Methyl Methacrylate Using Atom Teransfer Radical Polymerization Method full books in PDF, epub, and Kindle. Read online Self Initiated Polymerization Of Methyl Methacrylate Using Atom Teransfer Radical Polymerization Method ebook anywhere anytime directly on your device. Fast Download speed and no annoying ads. We cannot guarantee that every ebooks is available!
Book Synopsis Self Initiated Polymerization of Methyl Methacrylate Using Atom Teransfer Radical Polymerization Method by : Hanim Hafizah Mazlan
Download or read book Self Initiated Polymerization of Methyl Methacrylate Using Atom Teransfer Radical Polymerization Method written by Hanim Hafizah Mazlan and published by . This book was released on 2008 with total page 48 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Trichlorocyanuric acid initiated atom transfer radical polymerization of methyl methacrylate by : Deniz Yuluğ
Download or read book Trichlorocyanuric acid initiated atom transfer radical polymerization of methyl methacrylate written by Deniz Yuluğ and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Organic-Inorganic Hybrid Nanomaterials by : Susheel Kalia
Download or read book Organic-Inorganic Hybrid Nanomaterials written by Susheel Kalia and published by Springer. This book was released on 2014-12-04 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.
Book Synopsis POLYMERIZATION AND CHARACTERIZATION OF METHYLMETHACRYLATE BY ATOM TRANSFER RADICAL POLYMERIZATION. by :
Download or read book POLYMERIZATION AND CHARACTERIZATION OF METHYLMETHACRYLATE BY ATOM TRANSFER RADICAL POLYMERIZATION. written by and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In this work, methylmethacrylate, MMA was polymerized by ATRP method to obtain low molecular weight living polymers. The initiator was p-toluenesulfonylchloride and catalyst ligand complex system were CuCl-4,4’ dimethyl 2,2’bipyridine. Polymers with controlled molecular weight were obtained. The polymer chains were shown by NMR investigation to be mostly syndiotactic. The molecular weight and molecular weight distribution of some polymer samples were measured by GPC method. The K and a constants in [h]=K Ma equation were measured as 9.13x10-5 and 0.74, respectively. FT-IR and X-Ray results showed regularity in polymer chains. The molecular weight-Tg relations were verified from results of molecular weight-DSC results.
Book Synopsis Metal Catalysts and Initiators for the Controlled Atom Transfer Radical Polymerization of Methyl Acrylate and Methyl Methacrylate by : Christina Ng
Download or read book Metal Catalysts and Initiators for the Controlled Atom Transfer Radical Polymerization of Methyl Acrylate and Methyl Methacrylate written by Christina Ng and published by . This book was released on 1999 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Atom Transfer Radical Polymerization of Methyl Methacrylate in Ionic Liquid Media of 1-Methylimidazolium Alkyltes by : Fumin Ma
Download or read book The Atom Transfer Radical Polymerization of Methyl Methacrylate in Ionic Liquid Media of 1-Methylimidazolium Alkyltes written by Fumin Ma and published by . This book was released on 2011 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt: Three brønsted acidic ionic liquids, 1-methylimidazolium acetate ([Hmim][CH3COO]), 1-methylimidazolium propionate ([Hmim][CH3CH2COO]) and 1-methylimidazolium butyrate ([Hmim][CH3CH2CH2COO]) were used as reaction medium for atom transfer radical polymerization of methyl methacrylate with ethyl 2-bromoisobutyrate (EBiB)/CuBr as the initiating system. Kinetic studies, chain extension and block copolymerization confirmed the well-controlled manner of these polymerizations in three brønsted acidic ionic liquids. The reactions were fast and the polydispersities of the polymers were quite narrow (1.10
Book Synopsis Atom Transfer Radical Polymerization by Continuous Feeding of Activators by : Mary Nguyen
Download or read book Atom Transfer Radical Polymerization by Continuous Feeding of Activators written by Mary Nguyen and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Atom transfer radical polymerizations (ATRP) of methyl acrylate (MA), methyl methacrylate (MMA) and styrene (St) were conducted by continuous feeding of Cu(I)X/Ligand activators. Typically, the monomer, the initiator, and a certain amount of deactivator, Cu(II)X2/Ligand, were placed in a Schlenk flask deoxygenized by bubbling with N2. The activator, Cu(I)X/Ligand, was placed in a gas-tight syringe and was added at a constant rate to the Schlenk flask using a syringe pump. In ATRP, the Cu(I) catalyst would undergo many oxidation/reduction cycles when the propagation of polymer chains is taking place. However, some of the Cu(I) would finally be oxidized to Cu(II) irreversibly. According to the principle of halogen conservation, the end-group loss equals the amount of Cu(I) that is permanently oxidized to Cu(II). Thus, by reducing the amount of Cu(I) added to the reaction, ATRP by continuous feeding of activators sets an upper limit of the potential end-group loss. The end-group fidelity information is readily known at the beginning of the reaction.
Book Synopsis Controlled Radical Polymerization with Dendrimers Containing Stable Radicals by :
Download or read book Controlled Radical Polymerization with Dendrimers Containing Stable Radicals written by and published by . This book was released on 1996 with total page 22 pages. Available in PDF, EPUB and Kindle. Book excerpt: TEMPO-based stable radicals were attached to dendrimers of variable size and used to control radical polymerization of styrene, vinyl acetate and (meth)acrylates. Thermal polymerization of styrene with (G-2)-TEMPO proceeded in a similar but not better controlled manner than with TEMPO alone. In the polymerization of styrene initiated with BPO, the kinetics and the molecular weigh/conversion relations showed the same tendency as with TEMPO, though the polydispersity was higher than in the absence of dendrimers. This indicates that homolytic cleavage occurs at the reaction temperature, monomer can diffuse inside the cavity of dendrimer, and polymer is at least partially compatible with dendrimer. Model reactions indicate that the higher observed polydispersities could not be ascribed to transfer to benzyl hydrogen atoms. Therefore, the higher polydispersities could originate from the self-initiated polymerization of styrene outside of the dendrimers as well as the slow exchange of these chains with chains attached to dendrimers. To evaluate the effect of self-initiation, vinyl acetate, methyl methacrylate, and n-butyl acrylate were used, however, the resulting polymers were incompatible with the dendrimers. The growing chains are easily released from the cavity of the dendrimers into solution, and their return into the cavities of the dendrimers was not fast enough to control the polymerization. The results of the polymerization in decalin solution indicate that polymerization of these monomers is better controlled but only at the early stages of the polymerizations. The subsequent precipitation of polymers attached to the dendrimers prevent further polymerization.
Book Synopsis Miktoarm Star Polymers by : Ashok Kakkar
Download or read book Miktoarm Star Polymers written by Ashok Kakkar and published by Royal Society of Chemistry. This book was released on 2017-04-13 with total page 241 pages. Available in PDF, EPUB and Kindle. Book excerpt: The term ‘miktoarm polymers’ refers to asymmetric branched macromolecules, a relatively new entry to the macromolecular field. Recent advances in their synthesis and intriguing supramolecular chemistry in a desired medium has seen a fast expansion of their applications. The composition of miktoarm polymers can be tailored and even pre-defined to allow a desired combination of functions, meaning polymer chemists can have complete control of the overall architecture of these macromolecules. By carefully selecting the composition, they can create supramolecular structures with intriguing properties, particularly for applications in biology. Miktoarm Star Polymers features chapters from experts actively working in this field, and provides the reader with a unique introduction to the fundamental principles of this exciting macromolecular system. Topics covered include the design, synthesis, characterization, self-assembly and applications of miktoarm polymers. The book is an excellent overview and up to date guide to those working in research in polymer chemistry, materials science, and polymers for medical applications.
Book Synopsis Controlled/Living Radical Polymerization by : Krzysztof Matyjaszewski
Download or read book Controlled/Living Radical Polymerization written by Krzysztof Matyjaszewski and published by OUP USA. This book was released on 2007-01-04 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The preparation and characterization of new materials with precisely controlled macromolecular dimensions, functionalities, and decomposition, as well as with well-defined topologies, is perhaps the main focus of contemporary polymer synthesis. The best control of molecular functions can be achieved in a controlled/living polymerization -- a chain growth process without chain breaking reactions. Recently, controlled/living polymerizations have extended to radical systems which are not only commercially important, but also have the largest potential due to the availability of radically polymerizable monomers, facile copolymerization and undemanding experimental conditions. Controlled Radical Polymerization will examine recent advances in mechanistic and synthetic aspects of controlled/living radical (co)polymerization systems. Not only will this book be focused on recent progress in the dynamically developing field of controlled/living radical polymerization, but it will be a sequel to the very popular ACS Symposium Series 685, 768, and 854. The book will consist of >30 chapters separated into seven subsections: Fundamentals, Mechanism of ATRP, Mechanisms of SFRP and Degenerative Transfer Processes, Controlled Architecture by CRP, Organic-inorganic Hybrids by CRP, Biomaterials by CRP and Industrial Applications. This book targets chemists and polymer scientists in academia and in industry.
Book Synopsis Fundamentals of Polymerization by : Broja Mohan Mandal
Download or read book Fundamentals of Polymerization written by Broja Mohan Mandal and published by World Scientific. This book was released on 2013 with total page 468 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and dispersion polymerization (in polar solvents). Apart from the developments in the chemistry of polymerization, methods have been developed for the evaluation of highly reliable rate constants of propagation in radical as well as cationic polymerization. All these have revolutionized the field of synthetic polymer chemistry. In the book, fundamentals of both the new and old polymerization chemistry have been dealt with. The new chemistry has been given nearly equal space along with the old.
Book Synopsis Atom Transfer Radical Polymerization of Methyl Methacrylate and Styrene Catalyzed by CuCI/tripodal Ligands Bearing Ferrocene and Benzyl Moieties by : Nuttaporn Wisutsri
Download or read book Atom Transfer Radical Polymerization of Methyl Methacrylate and Styrene Catalyzed by CuCI/tripodal Ligands Bearing Ferrocene and Benzyl Moieties written by Nuttaporn Wisutsri and published by . This book was released on 2009 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Molecularly Imprinted Catalysts by : Songjun Li
Download or read book Molecularly Imprinted Catalysts written by Songjun Li and published by Elsevier. This book was released on 2015-09-30 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecularly Imprinted Catalysts: Principle, Synthesis, and Applications is the first book of its kind to provide an in-depth overview of molecularly imprinted catalysts and selective catalysis, including technical details, principles of selective catalysis, preparation processes, the catalytically active polymers themselves, and important progress made in this field. It serves as an important reference for scientists, students, and researchers who are working in the areas of molecular imprinting, catalysis, molecular recognition, materials science, biotechnology, and nanotechnology.Comprising a diverse group of experts from prestigious universities and industries across the world, the contributors to this book provide access to the latest knowledge and eye-catching achievements in the field, and an understanding of what progress has been made and to what extent it is being advanced in industry. - The first book in the field on molecularly imprinted catalysts (MIPs) - Provides a systematic background to selective catalysis, especially the basic concepts and key principles of the different MIP-based catalysts - Features state-of-the art presentation of preparation methods and applications of MIPs - Written by scientists from prestigious universities and industries across the world, and edited by veteran researchers in molecular imprinting and selective catalysis
Book Synopsis Controlled Radical Polymerization at and from Solid Surfaces by : Philipp Vana
Download or read book Controlled Radical Polymerization at and from Solid Surfaces written by Philipp Vana and published by Springer. This book was released on 2015-08-11 with total page 231 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science. The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics. Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist. Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned. Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students
Book Synopsis Polymer Surfaces and Interfaces by : Manfred Stamm
Download or read book Polymer Surfaces and Interfaces written by Manfred Stamm and published by Springer Science & Business Media. This book was released on 2008-01-26 with total page 337 pages. Available in PDF, EPUB and Kindle. Book excerpt: In what is an extremely practical and applicable new work, experts provide concise explanations, with examples and illustrations, of the key techniques in this important field. In each case, after basic principles have been reviewed, applications of the experimental techniques are discussed and illustrated with specific examples. Scientists and engineers in research and development will benefit from an application-oriented book that helps them to find solutions to both fundamental and applied problems. They will know that the surfaces and interfaces of polymers play an important role in most of the application areas of polymers, from moulds, foils, and composites, to biomaterials and applications in micro- and nanotechnology.
Book Synopsis Design of Polymeric Platforms for Selective Biorecognition by : Juan Rodríguez-Hernández
Download or read book Design of Polymeric Platforms for Selective Biorecognition written by Juan Rodríguez-Hernández and published by Springer. This book was released on 2015-08-21 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses in an integrated manner all the critical aspects for building the next generation of biorecognition platforms - from biomolecular recognition to surface fabrication. The most recent strategies reported to create surface nano and micropatterns are thoroughly analyzed. This book contains descriptions of the types of molecules immobilized at surfaces that can be used for specific biorecognition, how to immobilize them, and how to control their arrangement and functionality at the surface. Small molecules, peptides, proteins and oligonucleotides are at the core of the biorecognition processes and will constitute a special part of this book. The authors include detailed information on biological processes, biomolecular screening, biosensing, diagnostic and detection devices, tissue engineering, development of biocompatible materials and biomedical devices.
Book Synopsis Self-Assembled Structures by : Jingcheng Hao
Download or read book Self-Assembled Structures written by Jingcheng Hao and published by CRC Press. This book was released on 2016-04-19 with total page 250 pages. Available in PDF, EPUB and Kindle. Book excerpt: Self-assembly is a process in which a disordered system forms an organized structure without external direction. Examples include the formation of molecular crystals, lipid bilayers, and polymer brushes. This book reviews the fabrication and use of various self-assembled materials. In particular, the author pays special attention to self-assembled