Selectivity in Carbon-carbon Bond Forming Reactions

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Publisher :
ISBN 13 : 9780444417374
Total Pages : 303 pages
Book Rating : 4.4/5 (173 download)

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Book Synopsis Selectivity in Carbon-carbon Bond Forming Reactions by : E. Buncel

Download or read book Selectivity in Carbon-carbon Bond Forming Reactions written by E. Buncel and published by . This book was released on 1984 with total page 303 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Kinetics and Selectivity of Carbon-carbon Bond Forming Reactions on Oxidized and Reduced Metal Oxides

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Publisher :
ISBN 13 :
Total Pages : 1062 pages
Book Rating : 4.:/5 (396 download)

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Book Synopsis Kinetics and Selectivity of Carbon-carbon Bond Forming Reactions on Oxidized and Reduced Metal Oxides by : James Edward Rekoske

Download or read book Kinetics and Selectivity of Carbon-carbon Bond Forming Reactions on Oxidized and Reduced Metal Oxides written by James Edward Rekoske and published by . This book was released on 1998 with total page 1062 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Carbon-Carbon ?-Bond Formation

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Publisher : Pergamon
ISBN 13 :
Total Pages : 1220 pages
Book Rating : 4.0/5 ( download)

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Book Synopsis Carbon-Carbon ?-Bond Formation by : Barry M. Trost

Download or read book Carbon-Carbon ?-Bond Formation written by Barry M. Trost and published by Pergamon. This book was released on 1991 with total page 1220 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 3 covers carbon-to-carbon single bond forming reactions involving sp3, sp2 and sp carbon centers, but only those which do not involve additions to C-X &pgr;-bonds. The volume first compares and contrasts the alkylation reactions of all types of sp3 carbon nucleophiles and also covers vinyl and alkynyl carbanions. Following on from Volume 2, a separate section covers Friedel-Crafts alkylation reactions, which is complemented by discussions of polyene cyclizations and electrophilic transannular cyclizations in synthesis. Coupling reactions leading to &agr;-bond formation, and involving all types of combinations ofsp3, sp2 and sp carbon centers are next covered, including those reactions based on pinacol, acyloin and phenol oxidative coupling reactions, and also the Kolbe reaction. Rearrangement reactions, leading to carbon-to-carbon &agr;-bond formation, are often used in a clever manner in synthesis. The volume includes all those rearrangement reactions based on intermediate carbonium ions and carbanions, and also includes the benzil-benzilic acid and the Wolff rearrangements. The volume closes with coverage of carbonylation reactions, and the use of carbene insertion reactions into the C-H bond in synthesis.

Selectivity in Carbon-Carbon bond forming reactions. - 1984. - VII, 303 S.

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (256 download)

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Book Synopsis Selectivity in Carbon-Carbon bond forming reactions. - 1984. - VII, 303 S. by : Erwin Buncel

Download or read book Selectivity in Carbon-Carbon bond forming reactions. - 1984. - VII, 303 S. written by Erwin Buncel and published by . This book was released on 1984 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Comprehensive Carbanion Chemistry

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ISBN 13 : 9780444417374
Total Pages : 0 pages
Book Rating : 4.4/5 (173 download)

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Book Synopsis Comprehensive Carbanion Chemistry by : E. Buncel

Download or read book Comprehensive Carbanion Chemistry written by E. Buncel and published by . This book was released on 1984 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Comprehensive carbanion chemistry

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Publisher :
ISBN 13 :
Total Pages : 303 pages
Book Rating : 4.:/5 (54 download)

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Book Synopsis Comprehensive carbanion chemistry by : Erwin Buncel

Download or read book Comprehensive carbanion chemistry written by Erwin Buncel and published by . This book was released on 1984 with total page 303 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Carbon-carbon Bond Formation

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Publisher : CRC Press
ISBN 13 : 9780824767877
Total Pages : 480 pages
Book Rating : 4.7/5 (678 download)

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Book Synopsis Carbon-carbon Bond Formation by : Robert L. Augustine

Download or read book Carbon-carbon Bond Formation written by Robert L. Augustine and published by CRC Press. This book was released on 1979-04-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Comprehensive Carbanion Chemistry

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Publisher :
ISBN 13 : 9780444419132
Total Pages : 0 pages
Book Rating : 4.4/5 (191 download)

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Book Synopsis Comprehensive Carbanion Chemistry by : E. Buncel

Download or read book Comprehensive Carbanion Chemistry written by E. Buncel and published by . This book was released on 1980 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Comprehensive carbanion chemistry

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Publisher :
ISBN 13 :
Total Pages : 303 pages
Book Rating : 4.:/5 (54 download)

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Book Synopsis Comprehensive carbanion chemistry by : Erwin Buncel

Download or read book Comprehensive carbanion chemistry written by Erwin Buncel and published by . This book was released on 1984 with total page 303 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organic Synthesis Highlights

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Publisher : John Wiley & Sons
ISBN 13 : 3527621393
Total Pages : 424 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Organic Synthesis Highlights by : Hans-Josef Altenbach

Download or read book Organic Synthesis Highlights written by Hans-Josef Altenbach and published by John Wiley & Sons. This book was released on 2008-11-20 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: This unusual collection of 49 essays gives an overview of the trends and accomplishments of synthetic organic chemistry in recent years. Unique in its approach, it deals with almost every aspect of modern synthesis. The first part of the book describes methods and reagents, with particular emphasis on rapidly developing organometallic and biooriented procedures. In the second part, these tools are applied to the syntheses of interesting target compounds and natural compounds with remarkable physiological properties. Mechanistic discussions and retrosynthetic analyses are included. More than 1000 up-to-date references help the reader to pursue the topics highlighted here. This book gives both the active researcher and the advanced student insight into the competitive atmosphere, creativity, and resourcefulness so characteristic of organic synthesis today.

Organic Synthesis in Water

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Publisher : Springer Science & Business Media
ISBN 13 : 940114950X
Total Pages : 321 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Organic Synthesis in Water by : P.A. Grieco

Download or read book Organic Synthesis in Water written by P.A. Grieco and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 321 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of water as a medium for promoting organic reactions has been rather neglected in the development of organic synthesis, despite the fact that it is the solvent in which almost all biochemical processes take place. Chemists have only recently started to appreciate the enormous potential water has to offer in the development of new synthetic reactions and strategies, where it can offer benefits in both unique chemistry and reduced environmental impact. In this new book, the editor, well known for his contribution to the development of water as a useful medium in synthetic organic chemistry, has assembled an international team of authors, themselves at the forefront of research into the use of the unique properties of water carrying out organic transformations, to provide a timely and concise overview of current research. By focusing on the practical use of water in synthetic organic chemistry, and with the concern for the use of solvents in organic chemistry, professional chemists, particularly those involved in industrial research and development, will find this book an essential guide to the current state of the art, and a useful starting point in their own research. Academic chemists, including postgraduate and advanced undergraduate students, will find this book an invaluable guide to this exciting and important area of chemistry.

Metal Catalysed Carbon-Carbon Bond-Forming Reactions

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Publisher : John Wiley & Sons
ISBN 13 : 0470862009
Total Pages : 268 pages
Book Rating : 4.4/5 (78 download)

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Book Synopsis Metal Catalysed Carbon-Carbon Bond-Forming Reactions by : Stanley M. Roberts

Download or read book Metal Catalysed Carbon-Carbon Bond-Forming Reactions written by Stanley M. Roberts and published by John Wiley & Sons. This book was released on 2005-01-28 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemist has a vast range of high-tech catalysts to use when working in fine chemical synthesis but the catalysts are generally hard to use and require both time, skill and experience to handle properly. The Catalysts for Fine Chemical Synthesis series contains tested and validated procedures which provide a unique range resources for chemists who work in organic chemistry. "... of great value to synthetic organic chemists..." (The Chemists, Summer 2003) Volume 3 in the series focuses on catalysts for carbon-carbon bond formation and presents practical and detailed protocols on how to use sophisticated catalysts by the "inventors" and "developers" who created them. The combination of protocols and review commentaries helps the reader to easily and quickly understand and use the new high-tech catalysts.

C-H Activation for Asymmetric Synthesis

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Publisher : John Wiley & Sons
ISBN 13 : 3527343407
Total Pages : 294 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis C-H Activation for Asymmetric Synthesis by : Françoise Colobert

Download or read book C-H Activation for Asymmetric Synthesis written by Françoise Colobert and published by John Wiley & Sons. This book was released on 2019-11-11 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides, in one handbook, comprehensive coverage of one of the hottest topics in stereoselective chemistry Written by leading international authors in the field, this book introduces readers to C-H activation in asymmetric synthesis along with all of its facets. It presents stereoselective C-H functionalization with a broad coverage, from outer-sphere to inner-sphere C-H bond activation, and from the control of olefin geometry to the induction of point, planar and axial chirality. Moreover, methods wherein asymmetry is introduced either during the C-H activation or in a different elementary step are discussed. Presented in two parts?asymmetric activation of C(sp3)-H bonds and stereoselective synthesis implying activation of C(sp2)-H bonds?CH-Activation for Asymmetric Synthesis showcases the diversity of stereogenic elements, which can now be constructed by C-H activation methods. Chapters in Part 1 cover: C(sp3)-H bond insertion by metal carbenoids and nitrenoids; stereoselective C-C bond and C-N bond forming reactions through C(sp3)?H bond insertion of metal nitrenoids; enantioselective intra- and intermolecular couplings; and more. Part 2 looks at: C-H activation involved in stereodiscriminant step; planar chirality; diastereoselective formation of alkenes through C(sp2)?H bond activation; amongst other methods. -Covers one of the most rapidly developing fields in organic synthesis and catalysis -Clearly structured in two parts (activation of sp3- and activation of sp2-H bonds) -Edited by two leading experts in C-H activation in asymmetric synthesis CH-Activation for Asymmetric Synthesis will be of high interest to chemists in academia, as well as those in the pharmaceutical and agrochemical industry.

Stereoselective Carbon-carbon Bond Forming Reactions

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Publisher :
ISBN 13 :
Total Pages : 338 pages
Book Rating : 4.:/5 (427 download)

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Book Synopsis Stereoselective Carbon-carbon Bond Forming Reactions by : Elizabeth Diane Burke

Download or read book Stereoselective Carbon-carbon Bond Forming Reactions written by Elizabeth Diane Burke and published by . This book was released on 2004 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: "In the second chapter, a general method for the asymmetric synthesis of alpha,alpha-disubstituted-beta-hydroxy carbonyl compounds is described. This methodology relies on the stereoselective formation of acyclic alpha,alpha-disubstituted amide enolates. These enolates were prepared using methodology developed in the Gleason laboratory. Transmetallation of the initially formed lithium enolate was necessary to achieve high relative and absolute product stereocontrol. The E- and Z-enolate isomers were investigated. The Z-enolate reacted with high stereocontrol, whereas the E-enolate was not able to provide the anti isomer selectively. An X-ray crystal structure confirmed the absolute configuration of the product." --

Radicals in Organic Synthesis

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Publisher : C R C Press Reprints
ISBN 13 :
Total Pages : 318 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Radicals in Organic Synthesis by : Bernd Giese

Download or read book Radicals in Organic Synthesis written by Bernd Giese and published by C R C Press Reprints. This book was released on 1986 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Carbon-Carbon ?-Bond Formation

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Publisher : Pergamon
ISBN 13 : 9780080405940
Total Pages : 1212 pages
Book Rating : 4.4/5 (59 download)

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Book Synopsis Carbon-Carbon ?-Bond Formation by : G. Pattenden

Download or read book Carbon-Carbon ?-Bond Formation written by G. Pattenden and published by Pergamon. This book was released on 1992-01-20 with total page 1212 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 3 covers carbon-to-carbon single bond forming reactions involving sp3, sp2 and sp carbon centers, but only those which do not involve additions to C-X &pgr;-bonds. The volume first compares and contrasts the alkylation reactions of all types of sp3 carbon nucleophiles and also covers vinyl and alkynyl carbanions. Following on from Volume 2, a separate section covers Friedel-Crafts alkylation reactions, which is complemented by discussions of polyene cyclizations and electrophilic transannular cyclizations in synthesis. Coupling reactions leading to &agr;-bond formation, and involving all types of combinations ofsp3, sp2 and sp carbon centers are next covered, including those reactions based on pinacol, acyloin and phenol oxidative coupling reactions, and also the Kolbe reaction. Rearrangement reactions, leading to carbon-to-carbon &agr;-bond formation, are often used in a clever manner in synthesis. The volume includes all those rearrangement reactions based on intermediate carbonium ions and carbanions, and also includes the benzil-benzilic acid and the Wolff rearrangements. The volume closes with coverage of carbonylation reactions, and the use of carbene insertion reactions into the C-H bond in synthesis.

Organic Synthesis

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Publisher : Academic Press
ISBN 13 : 0128008075
Total Pages : 1108 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Organic Synthesis by : Michael Smith

Download or read book Organic Synthesis written by Michael Smith and published by Academic Press. This book was released on 2016-11-22 with total page 1108 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Synthesis, Fourth Edition, provides a reaction-based approach to this important branch of organic chemistry. Updated and accessible, this eagerly-awaited revision offers a comprehensive foundation for graduate students coming from disparate backgrounds and knowledge levels, to provide them with critical working knowledge of basic reactions, stereochemistry and conformational principles. This reliable resource uniquely incorporates molecular modeling content, problems, and visualizations, and includes reaction examples and homework problems drawn from the latest in the current literature. In the Fourth Edition, the organization of the book has been improved to better serve students and professors and accommodate important updates in the field. The first chapter reviews basic retrosynthesis, conformations and stereochemistry. The next three chapters provide an introduction to and a review of functional group exchange reactions; these are followed by chapters reviewing protecting groups, oxidation and reduction reactions and reagents, hydroboration, selectivity in reactions. A separate chapter discusses strategies of organic synthesis, and he book then delves deeper in teaching the reactions required to actually complete a synthesis. Carbon-carbon bond formation reactions using both nucleophilic carbon reactions are presented, and then electrophilic carbon reactions, followed by pericyclic reactions and radical and carbene reactions. The important organometallic reactions have been consolidated into a single chapter. Finally, the chapter on combinatorial chemistry has been removed from the strategies chapter and placed in a separate chapter, along with valuable and forward-looking content on green organic chemistry, process chemistry and continuous flow chemistry. Throughout the text, Organic Synthesis, Fourth Edition utilizes Spartan-generated molecular models, class tested content, and useful pedagogical features to aid student study and retention, including Chapter Review Questions, and Homework Problems. A full Solutions Manual is also available online for qualified instructors, to support teaching. Winner, 2018 Textbook Excellence Award (Texty) from the Textbook and Academic Authors Association Fully revised and updated throughout, and organized into 19 chapters for a more cogent and versatile presentation of concepts Includes reaction examples taken from literature research reported between 2010-2015 Features new full-color art and new chapter content on process chemistry and green organic chemistry Offers valuable study and teaching tools, including Chapter Review Questions and Homework Problems for students; Solutions Manual for qualified course instructors