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Author : E. Elemesov
Publisher :
ISBN 13 :
Total Pages : 6 pages
Book Rating : 4.:/5 ( download)
Download or read book Selective Hydrogenation of Benzene on a Rhodium Catalyst written by E. Elemesov and published by . This book was released on 1988 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Zhongyi Liu
Publisher : Springer Nature
ISBN 13 : 9811564116
Total Pages : 355 pages
Book Rating : 4.8/5 (115 download)
Download or read book Catalytic Technology for Selective Hydrogenation of Benzene to Cyclohexene written by Zhongyi Liu and published by Springer Nature. This book was released on 2020-09-10 with total page 355 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive description of the catalytic technologies for selective hydrogenation of benzene to cyclohexene. Focusing on selective hydrogenation of benzene to prepare cyclohexene and its downstream products, such as cyclohexanone, bulk chemicals and high-value fine chemicals, it also discusses the objective laws, reaction mechanisms and scientific significance based on experimental data, analysis and characterization results. Given its scope, the book will appeal to a broad readership, particularly professionals at universities and scientific research institutes, senior undergraduates, master's and doctoral graduate students as well as practitioners in industry.
Author : Warren Elwood Campbell
Publisher :
ISBN 13 :
Total Pages : 124 pages
Book Rating : 4.:/5 (831 download)
Download or read book Competitive Hydrogenation of Benzene, Toluene and the Polymethylbenzenes on Rhodium Catalyst written by Warren Elwood Campbell and published by . This book was released on 1962 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : L. Cervený
Publisher : Elsevier
ISBN 13 : 0080960618
Total Pages : 705 pages
Book Rating : 4.0/5 (89 download)
Download or read book Catalytic Hydrogenation written by L. Cervený and published by Elsevier. This book was released on 1986-08-01 with total page 705 pages. Available in PDF, EPUB and Kindle. Book excerpt: The collection of contributions in this volume presents the most up-to-date findings in catalytic hydrogenation. The individual chapters have been written by 36 top specialists each of whom has achieved a remarkable depth of coverage when dealing with his particular topic. In addition to detailed treatment of the most recent problems connected with catalytic hydrogenations, the book also contains a number of previously unpublished results obtained either by the authors themselves or within the organizations to which they are affiliated.Because of its topical and original character, the book provides a wealth of information which will be invaluable not only to researchers and technicians dealing with hydrogenation, but also to all those concerned with homogeneous and heterogeneous catalysis, organic technology, petrochemistry and chemical engineering.
Author : D. V. Sokolskii
Publisher :
ISBN 13 :
Total Pages : 11 pages
Book Rating : 4.:/5 (227 download)
Download or read book Hydrogenation of Benzene and Certain of Its Derivatives on the Rhodium-platinum Alloy Catalyst in the Liquid Phase written by D. V. Sokolskii and published by . This book was released on 1969 with total page 11 pages. Available in PDF, EPUB and Kindle. Book excerpt: A study was made of the effect of various hydrocarbon side groups on the hydrogenation of benzene. According to their hydrogenation speed, the studied compounds appear in the following order: benzene> ethyl-benzene> toluene> n-xylene> m-xylene>o-xylene. The order of reaction, according to substance being hydrogenated, for benzene and o-xylene, is a zero order; for the remaining investigated compounds it is close to zeroth order. For the first time it has been shown that the hydrogenation of benzene and its homologues takes place with insignificant displacement of potential. The small displacement of potential makes it possible to assume that the adsorption takes place on the catalyst, the surface of which is occupied by hydrogen. The alcohol displaces aromatic hydrocarbons from the surface of the catalyst, and the reaction does not take place. (Author).
Author : Shigeo Nishimura
Publisher : Wiley-Interscience
ISBN 13 :
Total Pages : 728 pages
Book Rating : 4.3/5 (91 download)
Download or read book Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis written by Shigeo Nishimura and published by Wiley-Interscience. This book was released on 2001-04-17 with total page 728 pages. Available in PDF, EPUB and Kindle. Book excerpt: A complete guide to the most important reduction method in organic synthesis The most comprehensive reference in the field, Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis provides synthetic chemists and chemical engineers in fine chemicals and pharmaceuticals with detailed experimental guidelines for heterogeneous catalytic hydrogenation. Organized by functional groups for ready reference and featuring detailed examples of hundreds of reactions, this handbook covers hydrogenations of alkenes, alkynes, aldehydes and ketones, nitriles, imines, nitro and nitroso compounds, carboxylic acids and esters, and aromatic and heterocyclic compounds. In addition, coverage includes the preparation of amines by reductive alkylation and the hydrogenolysis of a variety of compounds. Examples of hydrogenation of functional groups and reaction pathways are illustrated with numerous equations and schemes. Practitioners will appreciate the plenitude of experimental details given for most of the reactions selected, including amounts of reagents and catalysts, reaction temperatures, hydrogen pressures, and reaction times. They will also find helpful the more than one hundred tables included throughout the book detailing the effects of key factors governing rate and selectivity, such as compound structure, the nature of catalysts and supports, and the nature of solvents. Researchers will benefit from the introductory chapters covering an array of hydrogenation catalysts, including nickel, cobalt, copper, iron, platinum group metals, rhenium, and other oxide and sulfide catalysts, as well as reactors and reaction conditions.
Author : Ruijun Hou
Publisher : Springer
ISBN 13 : 981100773X
Total Pages : 151 pages
Book Rating : 4.8/5 (11 download)
Download or read book Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene written by Ruijun Hou and published by Springer. This book was released on 2017-01-05 with total page 151 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.“/p>
Author : Shu-Li You
Publisher : John Wiley & Sons
ISBN 13 : 3527338519
Total Pages : 422 pages
Book Rating : 4.5/5 (273 download)
Download or read book Asymmetric Dearomatization Reactions written by Shu-Li You and published by John Wiley & Sons. This book was released on 2016-09-13 with total page 422 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first comprehensive account of the rapidly growing field of asymmetric dearomatization reactions with a focus on catalytic methods. It introduces the concept of dearomatization and describes recent progress in asymmetric reaction procedures with different catalyst systems, such as organocatalysts, transition metal catalysts, and enzymes. Chapters on dearomatizations of electron-deficient aromatic rings, dearomatization reactions via transition metal-catalyzed cross-couplings as well as dearomatization strategies in the synthesis of complex natural products are also included. Written by pioneers in the field, this is a highly valuable source of information not only for professional synthetic chemists in academia and industry but also for all those are interested in asymmetric methodologies and organic synthesis in general.
Author : P.A. Chaloner
Publisher : Springer Science & Business Media
ISBN 13 : 9401717915
Total Pages : 293 pages
Book Rating : 4.4/5 (17 download)
Download or read book Homogeneous Hydrogenation written by P.A. Chaloner and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous hydrogenation is one of the most thoroughly studied fields of homogeneous catalysis. The results of these studies have proved to be most important for an understanding of the underlying principles of the activation of small molecules by transition metal complexes. During the past three decades homogeneous hydrogenation has found widespread application in organic chemistry, including the production of important pharmaceuticals, especially where a sophisticated degree of selectivity is required. This volume presents a general account of the main principles and applications of homogeneous hydrogenation by transition metal complexes. Special attention is devoted to the mechanisms by which these processes occur, and the role of the recently discovered complexes of molecular hydrogen is described. Sources of hydrogen, other than H2, are also considered (transfer hydrogenation). The latest achievements in highly stereoselective hydrogenations have made possible many new applications in organic synthesis. These applications are documented by giving details of the reduction of important unsaturated substrates (alkenes, alkynes, aldehydes and ketones, nitrocompounds, etc.). Hydrogenation in biphasic and phase transfer catalyzed systems is also described. Finally, a discussion of the biochemical routes of H2 activation highlights the similarities and differences in performing hydrogenation in both natural and synthetic systems. For researchers working in the fields of homogeneous catalysis, especially in areas such as pharmaceuticals, plastics and fine chemicals.
Author : Robert L. Augustine
Publisher : CRC Press
ISBN 13 : 1000105008
Total Pages : 668 pages
Book Rating : 4.0/5 (1 download)
Download or read book Heterogeneous Catalysis for the Synthetic Chemist written by Robert L. Augustine and published by CRC Press. This book was released on 2020-08-11 with total page 668 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work delineates the effect of different reaction variables on the outcome of heterogeneously catalyzed reactions, and explains how to optimize the product yield of specific compounds. Metal catalysis, simple and complex oxides, zeolites and clays are discussed, both as catalysts and as potential supports for catalytically active metals.
Author : 刘仲毅
Publisher :
ISBN 13 : 9787030602558
Total Pages : 359 pages
Book Rating : 4.6/5 (25 download)
Download or read book Catalytic Technology for Selective Hydrogenation of Benzene to Cyclohexene written by 刘仲毅 and published by . This book was released on 2019 with total page 359 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Marc Dominique Langan
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (631 download)
Download or read book Rhodium Cluster Ultradispersed Catalysts of High and Low Activity: A Study of the Benzene Hydrogenation Activity of Adsorbed Or Slurried Supported Rhodium Catalysts written by Marc Dominique Langan and published by . This book was released on 1980 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Carmen Claver
Publisher : Springer
ISBN 13 : 3319666657
Total Pages : 291 pages
Book Rating : 4.3/5 (196 download)
Download or read book Rhodium Catalysis written by Carmen Claver and published by Springer. This book was released on 2017-12-15 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbrev iated as Top Organomet Chem and cited as a journal.
Author : Johannes G. de Vries
Publisher :
ISBN 13 :
Total Pages : 552 pages
Book Rating : 4.3/5 (91 download)
Download or read book The Handbook of Homogeneous Hydrogenation written by Johannes G. de Vries and published by . This book was released on 2007 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : R. Ugo
Publisher : Springer Science & Business Media
ISBN 13 : 9401033412
Total Pages : 279 pages
Book Rating : 4.4/5 (1 download)
Download or read book Aspects of Homogeneous Catalysis written by R. Ugo and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 279 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Piet W.N.M. van Leeuwen
Publisher : Springer Science & Business Media
ISBN 13 : 9781402004216
Total Pages : 304 pages
Book Rating : 4.0/5 (42 download)
Download or read book Rhodium Catalyzed Hydroformylation written by Piet W.N.M. van Leeuwen and published by Springer Science & Business Media. This book was released on 2002-03-31 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last decade there have been numerous advances in the area of rhodium-catalyzed hydroformylation, such as highly selective catalysts of industrial importance, new insights into mechanisms of the reaction, very selective asymmetric catalysts, in situ characterization and application to organic synthesis. The views on hydroformylation which still prevail in the current textbooks have become obsolete in several respects. Therefore, it was felt timely to collect these advances in a book. The book contains a series of chapters discussing several rhodium systems arranged according to ligand type, including asymmetric ligands, a chapter on applications in organic chemistry, a chapter on modern processes and separations, and a chapter on catalyst preparation and laboratory techniques. This book concentrates on highlights, rather than a concise review mentioning all articles in just one line. The book aims at an audience of advanced students, experts in the field, and scientists from related fields. The didactic approach also makes it useful as a guide for an advanced course.
Author : Philip Karl Welty
Publisher :
ISBN 13 :
Total Pages : 262 pages
Book Rating : 4.3/5 (129 download)
Download or read book Mineral-bound Rhodium Hydrogenation Catalysts written by Philip Karl Welty and published by . This book was released on 1974 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt:
