Scale-up of Reactive Processes in Heterogeneous Media

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ISBN 13 :
Total Pages : 438 pages
Book Rating : 4.:/5 (93 download)

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Book Synopsis Scale-up of Reactive Processes in Heterogeneous Media by : Harpreet Singh

Download or read book Scale-up of Reactive Processes in Heterogeneous Media written by Harpreet Singh and published by . This book was released on 2014 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: Physical and chemical heterogeneities cause the porous media transport parameters to vary with scale, and between these two types of heterogeneities geological heterogeneity is considered to be the most important source of scale-dependence of transport parameters. Subsurface processes associated with chemical alterations result in changing reservoir properties with interlinked spatial and temporal scale, and there is uncertainty in the evolution of those properties and the chemical processes. This dissertation provides a framework and procedures to quantify the spatiotemporal scaling characteristics of reservoir attributes and transport processes in heterogeneous media accounting for chemical alterations in the reservoir. Conventional flow scaling groups were used to assess their applicability in scaling of recovery and Mixing Zone Length (MZL) in presence of chemical reactivity and permeability heterogeneity through numerical simulations of CO2 injection. It was found out that these scaling groups are not adequate enough to capture the scaling of recovery and transport parameters in the combined presence of chemical reactivity and physical heterogeneity. In this illustrative example, MZL was investigated as a function of spatial scale, temporal scale, multi-scale heterogeneity, and chemical reactivity; key conclusions are that 1) the scaling characteristics of MZL distinctly differ for low permeability and high permeability media, 2) heterogeneous media with spatial arrangements of both high and low permeability regions exhibit scaling characteristics of both high and low permeability media, 3) reactions affect scaling characteristics of MZL in heterogeneous media, 4) a simple rescaling can combine various MZL curves by merging them into a single MZL curve irrespective of the correlation length of heterogeneity, and 5) estimates of MZL (and consequently predictions of oil recovery) will fluctuate corresponding to displacements in a permeable medium whose lateral length is smaller than the correlation length of geological formation. We illustrate and extend the procedure of estimating Representative Elementary Volume (REV) to include temporal scale by coupling it with spatial scale. The current practice is to perform spatial averaging of attributes and account for residual variability by calibration and history matching. This results in poor predictions of future reservoir performance. The proposed semi-analytical technique to scale-up in both space and time provides guidance for selection of spatial and temporal discretizations that takes into account the uncertainties due to sub-processes. Finally, a probabilistic particle tracking (PT) approach is proposed to scale-up flow and transport of diffusion-reaction (DR) processes while addressing multi-scale and multi-physics nature of DR mechanisms and also maintaining consistent reservoir heterogeneity at different levels of scales. This multi-scale modeling uses a hierarchical approach which is based on passing the macroscopic subsurface heterogeneity down to the finer scales and then returning more accurate reactive flow response. This PT method can quantify the impact of reservoir heterogeneity and its uncertainties on statistical properties such as reaction surface area and MZL, at various scales.

Upscaling Multiphase Flow in Porous Media

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Publisher : Springer Science & Business Media
ISBN 13 : 9781402035135
Total Pages : 276 pages
Book Rating : 4.0/5 (351 download)

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Book Synopsis Upscaling Multiphase Flow in Porous Media by : D.B. Das

Download or read book Upscaling Multiphase Flow in Porous Media written by D.B. Das and published by Springer Science & Business Media. This book was released on 2005-06-10 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides concise, up-to-date and easy-to-follow information on certain aspects of an ever important research area: multiphase flow in porous media. This flow type is of great significance in many petroleum and environmental engineering problems, such as in secondary and tertiary oil recovery, subsurface remediation and CO2 sequestration. This book contains a collection of selected papers (all refereed) from a number of well-known experts on multiphase flow. The papers describe both recent and state-of-the-art modeling and experimental techniques for study of multiphase flow phenomena in porous media. Specifically, the book analyses three advanced topics: upscaling, pore-scale modeling, and dynamic effects in multiphase flow in porous media. This will be an invaluable reference for the development of new theories and computer-based modeling techniques for solving realistic multiphase flow problems. Part of this book has already been published in a journal. Audience This book will be of interest to academics, researchers and consultants working in the area of flow in porous media.

Heterogeneous Photocatalysis

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ISBN 13 :
Total Pages : 218 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Heterogeneous Photocatalysis by : M. Schiavello

Download or read book Heterogeneous Photocatalysis written by M. Schiavello and published by . This book was released on 1997-10-09 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photocatalysis is a reaction which is accelerated by light while a heterogeneous reaction consists of two phases ( a solid and a liquid for example). Heterogeneous Photocatalysis is a fast developing science which to date has not been fully detailed in a monograph. This title discusses the basic principles of heterogeneous photocatalysis and describes the bulk and surface properties of semiconductors. Applications of various types of photoreactions are described and the problems related to the modeling and design of photoreactors are covered.

Pore Scale Geochemical Processes

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Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 1501502077
Total Pages : 496 pages
Book Rating : 4.5/5 (15 download)

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Book Synopsis Pore Scale Geochemical Processes by : Carl Steefel

Download or read book Pore Scale Geochemical Processes written by Carl Steefel and published by Walter de Gruyter GmbH & Co KG. This book was released on 2015-09-25 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: This RiMG (Reviews in Mineralogy & Geochemistry) volume includes contributions that review experimental, characterization, and modeling advances in our understanding of pore-scale geochemical processes. The volume had its origins in a special theme session at the 2015 Goldschmidt Conference in Prague. From a diversity of pore-scale topics that ranged from multi-scale characterization to modeling, this work summarizes the state-of-the-science in this subject. Topics include: modification of thermodynamics and kinetics in small pores. chemo-mechanical processes and how they affect porosity evolution in geological media. small angle neutron scattering (SANS) techniques. how isotopic gradients across fluid–mineral boundaries can develop and how these provide insight into pore-scale processes. Information on an important class of models referred to as "pore network" and much more. The material in this book is accessible for graduate students, researchers, and professionals in the earth, material, environmental, hydrological, and biological sciences. The pore scale is readily recognizable to geochemists, and yet in the past it has not received a great deal of attention as a distinct scale or environment that is associated with its own set of questions and challenges. Is the pore scale merely an environment in which smaller scale (molecular) processes aggregate, or are there emergent phenomena unique to this scale? Is it simply a finer-grained version of the "continuum" scale that is addressed in larger-scale models and interpretations? The scale is important because it accounts for the pore architecture within which such diverse processes as multi-mineral reaction networks, microbial community interaction, and transport play out, giving rise to new geochemical behavior that might not be understood or predicted by considering smaller or larger scales alone.

Reactive Transport in Natural and Engineered Systems

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Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 1501512005
Total Pages : 514 pages
Book Rating : 4.5/5 (15 download)

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Book Synopsis Reactive Transport in Natural and Engineered Systems by : Jennifer Druhan

Download or read book Reactive Transport in Natural and Engineered Systems written by Jennifer Druhan and published by Walter de Gruyter GmbH & Co KG. This book was released on 2020-03-04 with total page 514 pages. Available in PDF, EPUB and Kindle. Book excerpt: Open system behavior is predicated on a fundamental relationship between the timescale over which mass is transported and the timescale over which it is chemically transformed. This relationship describes the basis for the multidisciplinary field of reactive transport (RT). In the 20 years since publication of Review in Mineralogy and Geochemistry volume 34: Reactive Transport in Porous Media, RT principles have expanded beyond early applications largely based in contaminant hydrology to become broadly utilized throughout the Earth Sciences. RT is now employed to address a wide variety of natural and engineered systems across diverse spatial and temporal scales, in tandem with advances in computational capability, quantitative imaging and reactive interface characterization techniques. The present volume reviews the diversity of reactive transport applications developed over the past 20 years, ranging from the understanding of basic processes at the nano- to micrometer scale to the prediction of Earth global cycling processes at the watershed scale. Key areas of RT development are highlighted to continue advancing our capabilities to predict mass and energy transfer in natural and engineered systems.

Modeling and Simulation of Heterogeneous Catalytic Processes

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Publisher : Academic Press
ISBN 13 : 012800455X
Total Pages : 312 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Modeling and Simulation of Heterogeneous Catalytic Processes by :

Download or read book Modeling and Simulation of Heterogeneous Catalytic Processes written by and published by Academic Press. This book was released on 2014-09-22 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous catalysis and mathematical modeling are essential components of the continuing search for better utilization of raw materials and energy, with reduced impact on the environment. Numerical modeling of chemical systems has progressed rapidly due to increases in computer power, and is used extensively for analysis, design and development of catalytic reactors and processes. This book presents reviews of the state-of-the-art in modeling of heterogeneous catalytic reactors and processes. Reviews by leading authorities in the respective areas Up-to-date reviews of latest techniques in modeling of catalytic processes Mix of US and European authors, as well as academic/industrial/research institute perspectives Connections between computation and experimental methods in some of the chapters

Upscaling Mixing-limited Chemical Reactions from Pore to Continuum Scale Using the Dispersive Lamella Concept

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ISBN 13 :
Total Pages : 116 pages
Book Rating : 4.:/5 (115 download)

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Book Synopsis Upscaling Mixing-limited Chemical Reactions from Pore to Continuum Scale Using the Dispersive Lamella Concept by : Lazaro J. Perez Fonseca

Download or read book Upscaling Mixing-limited Chemical Reactions from Pore to Continuum Scale Using the Dispersive Lamella Concept written by Lazaro J. Perez Fonseca and published by . This book was released on 2020 with total page 116 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactive transport modeling is an important tool for the analysis of coupled physical, chemical, and biological processes in Earth systems. Observed reactive transport in heterogeneous porous media shows a different behavior than the established transport laws for homogeneous media. Natural aquifers exhibit physical and chemical heterogeneities at all scales, which leads to reaction and transport dynamics that cannot be explained by traditional reactive models based on the advection-dispersion-reaction equation (ADRE). In particular, the discrepancy is traced back to the nonuniform nature of flow velocity fields, complex spatial concentration distributions, and the degree of mixing between reactants. The role and contribution of these factors is key to provide accurate predictions of reactions. The complexity of the task lies in the enormous range of spatial and temporal scales that reactants find in natural porous media. Hence, the complete characterization of the fate of chemical reactions requires that models accounts for the basic mechanisms that govern the mixing and reaction dynamics. In this thesis, we present a novel methodology for the simulation of homogeneous chemical reactions. The proposed methodology is a random walk particle tracking approach (RWPT) coupled with reactions that simulates bimolecular chemical reactions, and is equivalent to the ADRE. Reactions among particles are determined by a reaction probability given in terms of the reaction rate coefficient, the total number of particles, and an interaction radius that describes a well-mixed support volume at which all particles have the same probability to react. The method is meshless and free of numerical dispersion. The RWPT approach is validated against analytical solutions for different flow scenarios under slow and fast reaction kinetics. We focus on the impact of the mixing degree between chemical species and its role in the global reaction behavior. We first consider a reactive displacement in a Poiseuille flow through a pore channel, this system allow us to quantify the impact of the interaction of interface deformation and diffusion on mixing and reactive transport. We observe overestimation of the global reaction efficiency by the use of the Taylor dispersion coefficient at preasymptotic times, when the system is characterized by incomplete mixing. Next, we observe features of incomplete mixing in a synthetic porous medium. Results show that macroscopic predictions using the hydrodynamic dispersion coefficient overestimates the amount of reaction. In addition, we analize the bimolecular reactive transport in a laboratory experiment, where we find that the amount of reaction is affected by the amount of mixing due to difusion, the amount of mixing due to spreading and the degree of heterogeneity of the flow field. The contributions of these factors induces that ADRE estimation of the total reaction product fails. In order to characterize incomplete mixing and provide an explicit relation between fluid deformation and its impact on the temporal evolution of the chemical reactivity, we develop the dispersive lamella approach based on the concept of effective dispersion which accurately predicts the full evolution of the product mass. Specifically, the approach captures the impact of interface deformation and diffusive coalescence. Using this methodology, we quantify the impact of flow heterogeneities on the amount of fluid mixing in a pore channel, where we observe three temporal regimes based on the production rate of the product mass. In addition, the dispersive lamella predictions capture the kinetics of the reaction in a synthetic porous medium. Results reveal that reaction behavior is controlled by the interface front between the two reactants. In the pore-scale experimental visualization, the dispersive lamella show that reaction is controlled by the deformed mixing interface at early times, and for fingering coalescence at late times.

Reactive Transport in Porous Media

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Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 1501509799
Total Pages : 452 pages
Book Rating : 4.5/5 (15 download)

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Book Synopsis Reactive Transport in Porous Media by : Peter C. Lichtner

Download or read book Reactive Transport in Porous Media written by Peter C. Lichtner and published by Walter de Gruyter GmbH & Co KG. This book was released on 2018-12-17 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 34 of Reviews in Mineralogy focuses on methods to describe the extent and consequences of reactive flow and transport in natural subsurface systems. Since the field of reactive transport within the Earth Sciences is a highly multidisciplinary area of research, including geochemistry, geology, physics, chemistry, hydrology, and engineering, this book is an attempt to some extent bridge the gap between these different disciplines. This volume contains the contributions presented at a short course held in Golden, Colorado, October 25-27, 1996 in conjunction with the Mineralogical Society of America's (MSA) Annual Meeting with the Geological Society of America in Denver, Colorado.

Salt Crystallization in Porous Media

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Publisher : John Wiley & Sons
ISBN 13 : 1789451140
Total Pages : 276 pages
Book Rating : 4.7/5 (894 download)

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Book Synopsis Salt Crystallization in Porous Media by : Hannelore Derluyn

Download or read book Salt Crystallization in Porous Media written by Hannelore Derluyn and published by John Wiley & Sons. This book was released on 2024-09-24 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt: The crystallization of one or multiple salts in porous media (rocks, soils, building materials, etc.) is a subject of major interest in connection with numerous issues such as soil salinization, evaporation, CO2 injection into saline aquifers, the durability of building materials and the preservation of our cultural heritage. Salt Crystallization in Porous Media provides an interdisciplinary review of the key scientific knowledge required to understand this field of research, and illustrates the issues involved through a series of concrete examples. This book has been written for students completing their Master’s level degree or higher in the field, as well as researchers and engineers interested in this research. It may also be of interest to a wider readership, as certain sections can be used to illustrate basic concepts, reaching beyond the subject of salt crystallization itself.

Re-Engineering the Chemical Processing Plant

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Publisher : CRC Press
ISBN 13 : 9780203913291
Total Pages : 556 pages
Book Rating : 4.9/5 (132 download)

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Book Synopsis Re-Engineering the Chemical Processing Plant by : Andrzej Stankiewicz

Download or read book Re-Engineering the Chemical Processing Plant written by Andrzej Stankiewicz and published by CRC Press. This book was released on 2018-12-14 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first guide to compile current research and frontline developments in the science of process intensification (PI), Re-Engineering the Chemical Processing Plant illustrates the design, integration, and application of PI principles and structures for the development and optimization of chemical and industrial plants. This volume updates professionals on emerging PI equipment and methodologies to promote technological advances and operational efficacy in chemical, biochemical, and engineering environments and presents clear examples illustrating the implementation and application of specific process-intensifying equipment and methods in various commercial arenas.

Stochastic Subsurface Hydrology

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Publisher : Prentice Hall
ISBN 13 :
Total Pages : 408 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Stochastic Subsurface Hydrology by : L. W. Gelhar

Download or read book Stochastic Subsurface Hydrology written by L. W. Gelhar and published by Prentice Hall. This book was released on 1993 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume describes new stochastic subsurface hydrology techniques and results and examines the basic stochastic methods used to treat flow and contaminant transport in naturally heterogeneous permeable earth materials.

Modeling Phenomena of Flow and Transport in Porous Media

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Publisher : Springer
ISBN 13 : 3319728261
Total Pages : 761 pages
Book Rating : 4.3/5 (197 download)

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Book Synopsis Modeling Phenomena of Flow and Transport in Porous Media by : Jacob Bear

Download or read book Modeling Phenomena of Flow and Transport in Porous Media written by Jacob Bear and published by Springer. This book was released on 2018-01-25 with total page 761 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents and discusses the construction of mathematical models that describe phenomena of flow and transport in porous media as encountered in civil and environmental engineering, petroleum and agricultural engineering, as well as chemical and geothermal engineering. The phenomena of transport of extensive quantities, like mass of fluid phases, mass of chemical species dissolved in fluid phases, momentum and energy of the solid matrix and of fluid phases occupying the void space of porous medium domains are encountered in all these disciplines. The book, which can also serve as a text for courses on modeling in these disciplines, starts from first principles and focuses on the construction of well-posed mathematical models that describe all these transport phenomena.

Chemical Reactor Modeling

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Publisher : Springer Science & Business Media
ISBN 13 : 3319050923
Total Pages : 1589 pages
Book Rating : 4.3/5 (19 download)

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Book Synopsis Chemical Reactor Modeling by : Hugo A. Jakobsen

Download or read book Chemical Reactor Modeling written by Hugo A. Jakobsen and published by Springer Science & Business Media. This book was released on 2014-04-02 with total page 1589 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical Reactor Modeling closes the gap between Chemical Reaction Engineering and Fluid Mechanics. The second edition consists of two volumes: Volume 1: Fundamentals. Volume 2: Chemical Engineering Applications In volume 1 most of the fundamental theory is presented. A few numerical model simulation application examples are given to elucidate the link between theory and applications. In volume 2 the chemical reactor equipment to be modeled are described. Several engineering models are introduced and discussed. A survey of the frequently used numerical methods, algorithms and schemes is provided. A few practical engineering applications of the modeling tools are presented and discussed. The working principles of several experimental techniques employed in order to get data for model validation are outlined. The monograph is based on lectures regularly taught in the fourth and fifth years graduate courses in transport phenomena and chemical reactor modeling and in a post graduate course in modern reactor modeling at the Norwegian University of Science and Technology, Department of Chemical Engineering, Trondheim, Norway. The objective of the book is to present the fundamentals of the single-fluid and multi-fluid models for the analysis of single and multiphase reactive flows in chemical reactors with a chemical reactor engineering rather than mathematical bias. Organized into 13 chapters, it combines theoretical aspects and practical applications and covers some of the recent research in several areas of chemical reactor engineering. This book contains a survey of the modern literature in the field of chemical reactor modeling.

Process Intensification in Chemical Engineering

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Publisher : Springer
ISBN 13 : 3319283928
Total Pages : 341 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis Process Intensification in Chemical Engineering by : Juan Gabriel Segovia-Hernández

Download or read book Process Intensification in Chemical Engineering written by Juan Gabriel Segovia-Hernández and published by Springer. This book was released on 2016-04-02 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book will provide researchers and graduate students with an overview of the recent developments and applications of process intensification in chemical engineering. It will also allow the readers to apply the available intensification techniques to their processes and specific problems. The content of this book can be readily adopted as part of special courses on process control, design, optimization and modelling aimed at senior undergraduate and graduate students. This book will be a useful resource for researchers in process system engineering as well as for practitioners interested in applying process intensification approaches to real-life problems in chemical engineering and related areas.

Handbook for Chemical Process Research and Development, Second Edition

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Publisher : CRC Press
ISBN 13 : 1000859053
Total Pages : 938 pages
Book Rating : 4.0/5 (8 download)

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Book Synopsis Handbook for Chemical Process Research and Development, Second Edition by : Wenyi Zhao

Download or read book Handbook for Chemical Process Research and Development, Second Edition written by Wenyi Zhao and published by CRC Press. This book was released on 2023-03-21 with total page 938 pages. Available in PDF, EPUB and Kindle. Book excerpt: This fully updated second edition reflects the significant changes in process chemistry since the first edition and includes more common process issues such as safety, cost, robustness, and environmental impact. Some areas have made notable progress such as process safety, stereochemistry, new reagents and reagent surrogates. Forty years ago there were few process research and development activities in the pharmaceutical industry, partly due to the simplicity of drug molecules. With increasing structural complexity especially the introduction of chiral centers into drug molecules and stricter regulations, process R&D has become one of the critical departments for pharmaceutical companies. Features: This unique volume now in its second edition is designed to provide readers with an unprecedented strategy and approach which will help chemists and graduate students develop chemical processes in an efficient manner. Promotes an industrial mindset concerning safety and commercial viability when developing methods. The author discusses development strategies with case studies and experimental procedures. Focuses on mechanism-guided process development which provides readers with practical strategies and approaches. Addresses more common process issues such as safety, cost, robustness, and environmental impact. This book provides a new direction for scientists, researchers, and students in materials science and polymer chemistry who seek to better understand the chemistry behind conducting polymers and improve their performance for use in advanced energy applications.

Handbook of Engineering Hydrology (Three-Volume Set)

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Publisher : CRC Press
ISBN 13 : 1466552360
Total Pages : 1920 pages
Book Rating : 4.4/5 (665 download)

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Book Synopsis Handbook of Engineering Hydrology (Three-Volume Set) by : Saeid Eslamian

Download or read book Handbook of Engineering Hydrology (Three-Volume Set) written by Saeid Eslamian and published by CRC Press. This book was released on 2018-10-03 with total page 1920 pages. Available in PDF, EPUB and Kindle. Book excerpt: While most books examine only the classical aspects of hydrology, this three-volume set covers multiple aspects of hydrology, and includes contributions from experts from more than 30 countries. It examines new approaches, addresses growing concerns about hydrological and ecological connectivity, and considers the worldwide impact of climate change

Gas Transport in Porous Media

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Publisher : Springer Science & Business Media
ISBN 13 : 140203962X
Total Pages : 442 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Gas Transport in Porous Media by : Clifford K. Ho

Download or read book Gas Transport in Porous Media written by Clifford K. Ho and published by Springer Science & Business Media. This book was released on 2006-10-07 with total page 442 pages. Available in PDF, EPUB and Kindle. Book excerpt: CLIFFORD K. HOAND STEPHEN W. WEBB Sandia National Laboratories, P. O. Box 5800, Albuquerque, NM 87185, USA Gas and vapor transport in porous media occur in a number of important applications includingdryingofindustrialandfoodproducts,oilandgasexploration,environm- tal remediation of contaminated sites, and carbon sequestration. Understanding the fundamental mechanisms and processes of gas and vapor transport in porous media allows models to be used to evaluate and optimize the performance and design of these systems. In this book, gas and vapor are distinguished by their available states at stan- ? dard temperature and pressure (20 C, 101 kPa). If the gas-phase constituent can also exist as a liquid phase at standard temperature and pressure (e. g. , water, ethanol, toluene, trichlorothylene), it is considered a vapor. If the gas-phase constituent is non-condensable at standard temperature and pressure (e. g. , oxygen, carbon di- ide, helium, hydrogen, propane), it is considered a gas. The distinction is important because different processes affect the transport and behavior of gases and vapors in porous media. For example, mechanisms specific to vapors include vapor-pressure lowering and enhanced vapor diffusion, which are caused by the presence of a g- phase constituent interacting with its liquid phase in an unsaturated porous media. In addition, the “heat-pipe” exploits isothermal latent heat exchange during evaporation and condensation to effectively transfer heat in designed and natural systems.