Reactivity In Confined Spaces

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Reactivity in Confined Spaces

Author : Gareth Lloyd
Publisher : Royal Society of Chemistry
ISBN 13 : 1788019717
Total Pages : 491 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Reactivity in Confined Spaces by : Gareth Lloyd

Download or read book Reactivity in Confined Spaces written by Gareth Lloyd and published by Royal Society of Chemistry. This book was released on 2021-08-16 with total page 491 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry that occurs within confined spaces is the product of a collection of forces, often beyond the molecule, and is not easily ascribed to singular factors. There is a breadth of material types that can define a confined space (e.g. macrocycles, interlocked molecules, porous and non-porous crystals, organic and inorganic/coordination cages) which are rarely discussed together. Studies of supramolecular entities in the solution and solid states are also not often compared in the same discussion, even though the concepts are often similar or can be easily transferred between the two. Chapters in this book combine classical host-guest chemistry with catalysis, reactivity, and modern supramolecular chemistry. They cover the many different technologies used to describe and understand reactivity in confined spaces in one accessible title. With contributions from leading experts, Reactivity in Confined Spaces will be relevant for graduate students and researchers working in supramolecular chemistry, both organic- and inorganic-based, homogeneous and heterogeneous catalysis, polymer chemistry, and materials science in general.

Reactivity in Confined Spaces

Author : Gareth O. Lloyd
Publisher : Royal Society of Chemistry
ISBN 13 : 1788017765
Total Pages : 491 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Reactivity in Confined Spaces by : Gareth O. Lloyd

Download or read book Reactivity in Confined Spaces written by Gareth O. Lloyd and published by Royal Society of Chemistry. This book was released on 2021-08-25 with total page 491 pages. Available in PDF, EPUB and Kindle. Book excerpt: This title combines classical host: guest chemistry with catalysis, reactivity and modern supramolecular chemistry

Chemical Reactivity in Confined Systems

Author : Pratim Kumar Chattaraj
Publisher : John Wiley & Sons
ISBN 13 : 1119684021
Total Pages : 451 pages
Book Rating : 4.1/5 (196 download)

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Book Synopsis Chemical Reactivity in Confined Systems by : Pratim Kumar Chattaraj

Download or read book Chemical Reactivity in Confined Systems written by Pratim Kumar Chattaraj and published by John Wiley & Sons. This book was released on 2021-08-23 with total page 451 pages. Available in PDF, EPUB and Kindle. Book excerpt: An insightful analysis of confined chemical systems for theoretical and experimental scientists Chemical Reactivity in Confined Systems: Theory and Applications presents a theoretical basis for the molecular phenomena observed in confined spaces. The book highlights state-of-the-art theoretical and computational approaches, with a focus on obtaining physically relevant clarification of the subject to enable the reader to build an appreciation of underlying chemical principles. The book includes real-world examples of confined systems that highlight how the reactivity of atoms and molecules change upon encapsulation. Chapters include discussions on recent developments related to several host-guest systems, including cucurbit[n]uril, ExBox+4, clathrate hydrates, octa acid cavitand, metal organic frameworks (MOFs), covalent organic frameworks (COFs), zeolites, fullerenes, and carbon nanotubes. Readers will learn how to carry out new calculations to understand the physicochemical behavior of confined quantum systems. Topics covered include: A thorough introduction to global reactivity descriptors, including electronegativity, hardness, and electrophilicity An exploration of the Fukui function, as well as dual descriptors, higher order derivatives, and reactivity through information theory A practical discussion of spin dependent reactivity and temperature dependent reactivity Concise treatments of population analysis, reaction force, electron localization functions, and the solvent effect on reactivity Perfect for academic researchers and graduate students in theoretical and computational chemistry and confined chemical systems, Chemical Reactivity in Confined Systems: Theory and Applications will also earn a place in the libraries of professionals working in the areas of catalysis, supramolecular chemistry, and porous materials.

Chemical Reactivity in Confined Systems

Author : Pratim Kumar Chattaraj
Publisher : John Wiley & Sons
ISBN 13 : 1119683238
Total Pages : 451 pages
Book Rating : 4.1/5 (196 download)

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Book Synopsis Chemical Reactivity in Confined Systems by : Pratim Kumar Chattaraj

Download or read book Chemical Reactivity in Confined Systems written by Pratim Kumar Chattaraj and published by John Wiley & Sons. This book was released on 2021-08-13 with total page 451 pages. Available in PDF, EPUB and Kindle. Book excerpt: An insightful analysis of confined chemical systems for theoretical and experimental scientists Chemical Reactivity in Confined Systems: Theory and Applications presents a theoretical basis for the molecular phenomena observed in confined spaces. The book highlights state-of-the-art theoretical and computational approaches, with a focus on obtaining physically relevant clarification of the subject to enable the reader to build an appreciation of underlying chemical principles. The book includes real-world examples of confined systems that highlight how the reactivity of atoms and molecules change upon encapsulation. Chapters include discussions on recent developments related to several host-guest systems, including cucurbit[n]uril, ExBox+4, clathrate hydrates, octa acid cavitand, metal organic frameworks (MOFs), covalent organic frameworks (COFs), zeolites, fullerenes, and carbon nanotubes. Readers will learn how to carry out new calculations to understand the physicochemical behavior of confined quantum systems. Topics covered include: A thorough introduction to global reactivity descriptors, including electronegativity, hardness, and electrophilicity An exploration of the Fukui function, as well as dual descriptors, higher order derivatives, and reactivity through information theory A practical discussion of spin dependent reactivity and temperature dependent reactivity Concise treatments of population analysis, reaction force, electron localization functions, and the solvent effect on reactivity Perfect for academic researchers and graduate students in theoretical and computational chemistry and confined chemical systems, Chemical Reactivity in Confined Systems: Theory and Applications will also earn a place in the libraries of professionals working in the areas of catalysis, supramolecular chemistry, and porous materials.

Modelling and Simulation in the Science of Micro- and Meso-Porous Materials

Author : C.Richard A. Catlow
Publisher : Elsevier
ISBN 13 : 0128050586
Total Pages : 370 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Modelling and Simulation in the Science of Micro- and Meso-Porous Materials by : C.Richard A. Catlow

Download or read book Modelling and Simulation in the Science of Micro- and Meso-Porous Materials written by C.Richard A. Catlow and published by Elsevier. This book was released on 2017-09-20 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: Modelling and Simulation in the Science of Micro- and Meso-Porous Materials addresses significant developments in the field of micro- and meso-porous science. The book includes sections on Structure Modeling and Prediction, Synthesis, Nucleation and Growth, Sorption and Separation processes, Reactivity and Catalysis, and Fundamental Developments in Methodology to give a complete overview of the techniques currently utilized in this rapidly advancing field. It thoroughly addresses the major challenges in the field of microporous materials, including the crystallization mechanism of porous materials and rational synthesis of porous materials with controllable porous structures and compositions. New applications in emerging areas are also covered, including biomass conversion, C1 chemistry, and CO2 capture. Authored and edited by experts in the field of micro- and meso-porous materials Includes introductory material and background both on the science of microporous materials and on the techniques employed in contemporary modeling studies Rigorous enough for scientists conducting related research, but also accessible to graduate students in chemistry, chemical engineering, and materials science

Chemical Energy Storage

Author : Robert Schlögl
Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 3110608596
Total Pages : 685 pages
Book Rating : 4.1/5 (16 download)

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Book Synopsis Chemical Energy Storage by : Robert Schlögl

Download or read book Chemical Energy Storage written by Robert Schlögl and published by Walter de Gruyter GmbH & Co KG. This book was released on 2022-01-19 with total page 685 pages. Available in PDF, EPUB and Kindle. Book excerpt: Energy – in the headlines, discussed controversially, vital. The use of regenerative energy in many primary forms leads to the necessity to store grid dimensions for maintaining continuous supply and enabling the replacement of fossil fuel systems. Chemical energy storage is one of the possibilities besides mechano-thermal and biological systems. This work starts with the more general aspects of chemical energy storage in the context of the geosphere and evolves to dealing with aspects of electrochemistry, catalysis, synthesis of catalysts, functional analysis of catalytic processes and with the interface between electrochemistry and heterogeneous catalysis. Top-notch experts provide a sound, practical, hands-on insight into the present status of energy conversion aimed primarily at the young emerging research front.

Zeolites and Zeolite-like Materials

Author : Bert Sels
Publisher : Elsevier
ISBN 13 : 0444635149
Total Pages : 474 pages
Book Rating : 4.4/5 (446 download)

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Book Synopsis Zeolites and Zeolite-like Materials by : Bert Sels

Download or read book Zeolites and Zeolite-like Materials written by Bert Sels and published by Elsevier. This book was released on 2016-07-29 with total page 474 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolites and Zeolite-like Materials offers a comprehensive and up-to-date review of the important areas of zeolite synthesis, characterization, and applications. Its chapters are written in an educational, easy-to-understand format for a generation of young zeolite chemists, especially those who are just starting research on the topic and need a reference that not only reflects the current state of zeolite research, but also identifies gaps and opportunities. The book demonstrates various applications of zeolites in heterogeneous catalysis and biomass conversion and identifies the endless possibilities that exist for this class of materials, their structures, functions, and future applications. In addition, it demonstrates that zeolite-like materials should be regarded as a living body developing towards new modern applications, thereby responding to the needs of modern technology challenges, including biomass conversion, medicine, laser techniques, and nanomaterial design, etc. The book will be of interest not only to zeolite-focused researchers, but also to a broad scientific and non-scientific audience. Provides a comprehensive review of the literature pertaining to zeolites and zeolite-like materials since 2000 Covers the chemistry of novel zeolite-like materials such as Metal-Organic Frameworks (MOFs), Covalent Organic Frameworks (COFs), hierarchical zeolite materials, new mesoporous and composite zeolite-like micro/mesoporous materials Presents essential information of the new zeolite-like structures, with a balanced coverage of the most important areas of the zeolite research (synthesis, characterization, adsorption, catalysis, new applications of zeolites and zeolite-like materials) Contains chapters prepared by known specialists who are members of the International Zeolite Association

Confined Space Entry and Emergency Response

Author : D. Alan Veasey
Publisher : John Wiley & Sons
ISBN 13 : 0471787655
Total Pages : 512 pages
Book Rating : 4.4/5 (717 download)

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Book Synopsis Confined Space Entry and Emergency Response by : D. Alan Veasey

Download or read book Confined Space Entry and Emergency Response written by D. Alan Veasey and published by John Wiley & Sons. This book was released on 2005-12-02 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: EVERY SECOND COUNTS WHEN YOU'RE RESPONDING TO AN EMERGENCYINVOLVINGCONFINED SPACE-HERE'S THE DEFINITIVE GUIDE TO PERFORMINGFLAWLESS RESCUES! Confined Space Entry and Emergency Response utilizes a realistic,scenario-based approach to teach you-and your staff-the right wayto respond to an incident involving a confined space. The authorsprovide intensive, step-by-step guidance through the challengingmaze of training regulations, equipment needs, and procedures tokeep your response team finely tuned and ready to go under anyconditions. You'll find expert, detailed coverage of complex-and oftenconfusing-topics such as: * The basic components of rescue * OSHA's regulations for confined space entry and rescue * Confined space entry permitting * Assessing confined space hazards * Hazardous atmospheres and how to protect entrants from them * Air monitoring in confined spaces * Selection and use of personal protective equipment * The use of ropes and rigging The CD-ROM includes the Instructor's Guide along with lesson plansand useful practice tools such as worksheets, exercise handouts,performance checklists, diagrams and equipment lists for fieldexercises, instructions for building field training simulators, andguidelines for identifying rescue trainers and evaluating theircompetency as well as that of outside rescue teams. Everything you need to effectively train those working in aconfined space can truly be found within these pages and on theCD-ROM.

Safety and Health in Confined Spaces

Author : Neil McManus
Publisher : Routledge
ISBN 13 : 1351417797
Total Pages : 1412 pages
Book Rating : 4.3/5 (514 download)

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Book Synopsis Safety and Health in Confined Spaces by : Neil McManus

Download or read book Safety and Health in Confined Spaces written by Neil McManus and published by Routledge. This book was released on 2018-12-18 with total page 1412 pages. Available in PDF, EPUB and Kindle. Book excerpt: Safety and Health in Confined Spaces goes beyond all other resources currently available. International in scope, the 15 chapters and 10 appendices cover every facet of this important subject. A significant addition to the literature, this book provides a confined space focus to other health and safety concepts. Confined spaces differ from other workspaces because their boundary surfaces amplify the consequences of hazardous conditions. The relationship between the individual, the boundary surface, and the hazardous condition is the critical factor in the onset, outcome, and severity of accidents in these workspaces. The author uses information about causative and other factors from analysis of fatal accidents to develop a hazard assessment and hazard management system. He provides a detailed, disciplined protocol, covering 36 hazardous conditions, that addresses all segments of work--the undisturbed space, entry preparation, work activity, and emergency preparedness and response--and illustrates how to use it. Safety and Health in Confined Spaces gives you the tools you need for preventing and responding to accidents.

Proceedings of the Conference on Atmospheric Contamination in Confined Spaces, 30 March-1 April 1965

Author :
Publisher :
ISBN 13 :
Total Pages : 344 pages
Book Rating : 4.:/5 ( download)

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Book Synopsis Proceedings of the Conference on Atmospheric Contamination in Confined Spaces, 30 March-1 April 1965 by :

Download or read book Proceedings of the Conference on Atmospheric Contamination in Confined Spaces, 30 March-1 April 1965 written by and published by . This book was released on 1965 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: "The report is a complete compilation of the papers presented and the proceedings of the Conference on Atmospheric Contamination in Confined Spaces, sponsored by the Aerospace Medical Research Laboratories and held in Dayton, Ohio on 30, 31 March and 1 April 1965. Major technical areas discussed by the invited speakers, panel members and conference attendees included continuous inhalation exposure techniques, statistical methods for evaluation and interpretation of exposure data, minimum criteria for continuous exposure studies and toxicological qualification of space cabin materials. The conference participants were provided the opportunity to tour the Toxic Hazards Research Unit at Wright-Patterson Air Force Base and to ask questions regarding its operation. A discussion of the Clean Air Act of 1963 was presented by a representative of the Federal Department of Health, Education and Welfare."--Abstract

Guidelines for Safe Storage and Handling of Reactive Materials

Author : CCPS (Center for Chemical Process Safety)
Publisher : John Wiley & Sons
ISBN 13 : 0470938005
Total Pages : 364 pages
Book Rating : 4.4/5 (79 download)

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Book Synopsis Guidelines for Safe Storage and Handling of Reactive Materials by : CCPS (Center for Chemical Process Safety)

Download or read book Guidelines for Safe Storage and Handling of Reactive Materials written by CCPS (Center for Chemical Process Safety) and published by John Wiley & Sons. This book was released on 2010-09-09 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt: With new and growing interest in dealing with the hazards of reactive chemicals, this book offers guidelines that can significantly reduce the risk or mitigate the severity of accidents associated with storing and handling reactive materials. Necessary elements of a reliable system to prevent equipment or human failures that might lead to a reactive chemical incident are sound and responsible management policies, together with a combination of superior siting, design, fabrication, erection, inspection, monitoring, maintenance, operations and maintenance of facilities. These Guidelines deal with all of these elements with emphasis on design considerations.

Synthesis and Reactivity of Donor-Acceptor Substituted Aminocyclopropanes and Aminocyclobutanes

Author : Florian de Nanteuil
Publisher : Springer
ISBN 13 : 3319230069
Total Pages : 315 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis Synthesis and Reactivity of Donor-Acceptor Substituted Aminocyclopropanes and Aminocyclobutanes by : Florian de Nanteuil

Download or read book Synthesis and Reactivity of Donor-Acceptor Substituted Aminocyclopropanes and Aminocyclobutanes written by Florian de Nanteuil and published by Springer. This book was released on 2015-09-26 with total page 315 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis presents a general approach to accessing nitrogen-substituted hetero- and carbocycles. In short, the annulation reactions developed in the thesis make it possible to access nitrogen-substituted four-, five- and six-membered rings, all essential building blocks for the synthesis of bioactive molecules. Many natural products display a saturated polycyclic core allowing a well-defined arrangement of functional groups in space. As such, they can interact with biological targets with a high degree of affinity and selectivity, surpassing many synthetic drugs. Nevertheless, the efficient synthesis of such complex ring systems poses a challenge for organic chemistry. Through careful tuning of the electronic properties of a nitrogen donor group and a diester acceptor group, the first [3+2] annulation reaction between aminocyclopropanes and enol ethers or carbonyl compounds is now possible. The reaction proceeded under mild catalytic conditions, and the building blocks obtained can be found at the core of bioactive alkaloids, drugs such as Ramipril and biomolecules such as DNA and RNA. Thanks to the dynamic kinetic asymmetric annulation of aminocyclopropanes with enol ethers and aldehydes, access to enantioenriched compounds is also now possible. Lastly, a synthesis of donor-acceptor aminocyclobutanes via [2+2] cycloaddition using a cheap iron catalyst was developed, allowing them to be used in [4+2] annulations to access cyclohexylamines.

Effects of Nanoconfinement on Catalysis

Author : Rinaldo Poli
Publisher : Springer
ISBN 13 : 3319502077
Total Pages : 266 pages
Book Rating : 4.3/5 (195 download)

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Book Synopsis Effects of Nanoconfinement on Catalysis by : Rinaldo Poli

Download or read book Effects of Nanoconfinement on Catalysis written by Rinaldo Poli and published by Springer. This book was released on 2017-01-24 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book highlights the recent advances and state of the art in the use of functionalized nanostructured environments on catalysis. Nanoconfinements considered include well-defined molecular cages, imprinted self-assembled supramolecules, polymers made by living or controlled polymerization, metallorganic frameworks, carbon nanotubes, mesoporous inorganic solids, and hybrids thereof. Advantages of nanoconfinement of catalysts discussed include higher activities, improved selectivities, catalyst stabilization, cooperativity effects, simplified protocols for cascade syntheses, better catalyst recovery, and recyclability. The multiple applications that these materials offer are revolutionizing industrial sectors such as energy, electronics, sensors, biomedicine, and separation technology.

Worker Deaths in Confined Spaces

Author : Thomas R. Bender
Publisher : DIANE Publishing
ISBN 13 : 9780788131837
Total Pages : 288 pages
Book Rating : 4.1/5 (318 download)

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Book Synopsis Worker Deaths in Confined Spaces by : Thomas R. Bender

Download or read book Worker Deaths in Confined Spaces written by Thomas R. Bender and published by DIANE Publishing. This book was released on 1996-07 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: Includes: overview of confined-space hazards; epidemiology of confined space-related fatalities; & prevention: elements of a confined-space program. Majority of report consists of summary data & investigative reports of fatal incidents involving workers who entered confined spaces. Involves: explosives, inert gases, oxygen deficient air, solvents, toxic gases, engulfment, falls, electrocution, & drowning. A resource & case study manual for safety & public health professionals, safety & health instructors, research & public safety personnel.

Worker Deaths in Confined Spaces

Author :
Publisher :
ISBN 13 :
Total Pages : 288 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Worker Deaths in Confined Spaces by :

Download or read book Worker Deaths in Confined Spaces written by and published by . This book was released on 1994 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organic Solid-State Reactions

Author : Fumio Toda
Publisher : Springer Science & Business Media
ISBN 13 : 9781402002274
Total Pages : 292 pages
Book Rating : 4.0/5 (22 download)

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Book Synopsis Organic Solid-State Reactions by : Fumio Toda

Download or read book Organic Solid-State Reactions written by Fumio Toda and published by Springer Science & Business Media. This book was released on 2002-04-30 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Most organic reactions have long been carried out in organic solvents without concern for their real necessity, reaction efficiency, and pollution problems. Very recently, we have found that most organic reactions can be carried out in the absence of a solvent, namely, in the solid state. In many cases, the solid-state reaction proceeds more easily and efficiently, and even more selectively than solution reaction. This shows that molecules move easily and selectively in the solid state. This finding changed the classical idea which suggests "molecules do not move and reactions do not occur in the solid state", and opened up a new research field for the study molecular dynamics in the solid state. The organic solid state reactions have many possibilities to be developed. For example, enantioselective reactions can easily be accomplished by carrying out the reaction in an inclusion complex crystal with an optically active host compound. Catalytic reactions also proceed in the solid state. Moreover, the solid-state reactions are more economical and ecologically sound. In the future, pollution-free synthetic procedures in the solid state will become increasingly important, not only in chemical industries but also in university laboratories.

Handbook of Industrial Toxicology and Hazardous Materials

Author : Nicholas P. Cheremisinoff
Publisher : CRC Press
ISBN 13 : 1482292955
Total Pages : 928 pages
Book Rating : 4.4/5 (822 download)

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Book Synopsis Handbook of Industrial Toxicology and Hazardous Materials by : Nicholas P. Cheremisinoff

Download or read book Handbook of Industrial Toxicology and Hazardous Materials written by Nicholas P. Cheremisinoff and published by CRC Press. This book was released on 1999-01-12 with total page 928 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing vital safety information on over 1000 commerical chemicals, this work explores up-to-date data on fire and chemical compatibility, response methods for incidents involving chemical spills and fires, and personnel and worksite safety monitoring and sampling. The book includes more than 700 illustrations, structures, equations and tables, a