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Author : Zhandong Zhong
Publisher :
ISBN 13 :
Total Pages : 518 pages
Book Rating : 4.:/5 (242 download)
Download or read book Reactions of Vinyl Platinum Complexes written by Zhandong Zhong and published by . This book was released on 1991 with total page 518 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Mark Harold Kowalski
Publisher :
ISBN 13 :
Total Pages : 386 pages
Book Rating : 4.:/5 (18 download)
Download or read book Formation and Reactions of Vinyl Platinum Triflate Complexes written by Mark Harold Kowalski and published by . This book was released on 1988 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Yan Wang
Publisher :
ISBN 13 :
Total Pages : 572 pages
Book Rating : 4.:/5 (89 download)
Download or read book Synthesis, Reactions and Mechanistic Studies of Rhenium-platinum Complexes written by Yan Wang and published by . This book was released on 1993 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : M.V. Twigg
Publisher : Springer Science & Business Media
ISBN 13 : 146153710X
Total Pages : 468 pages
Book Rating : 4.4/5 (615 download)
Download or read book Mechanisms of Inorganic and Organometallic Reactions Volume 7 written by M.V. Twigg and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 468 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of Mechanisms of Inorganic and Organometallic Reactions is to provide an ongoing critical review of the literature concerned with the mechanisms of reactions of inorganic and organometallic compounds. The main focus is on reactions in solution, although solid state and gas phase studies are included where they provide relevant mechanistic insight. Each volume covers an eighteen month literature period, and this, the seventh volume in the series, deals with papers published during July 1988 through December 1989. Where appropriate, there are references to earlier work, and also to specific sections in previous volumes. Coverage continues to span the whole area as comprehensively as possible in each volume, and although it is impossible be absolutely complete, every effort is made to include all the important for it to published work that is relevant to the elucidation of reaction mechanisms. Numerical data are reported in the units used by the original authors, and they are only converted to common units when making comparisons. The basic format of earlier volumes is retained to facilitate tracing progress over several years in a particular topic; this can now be done for more than a decade worth of research. In the last volume, ligand reactivity of both coordination and organometallic compounds were brought together in Chapter 12, and, in response to numerous positive comments from readers, this arrangement has been maintained. There have been some similar suggestions about oscillating reactions, and this topic may have a separate section in the next volume.
![Download Synthesis and Reactions of Palladium and Platinum Complexes of the Type [MF(PR3)3] [X] and [M2(OH)2(PR3)4] [X]2 PDF Online Free](https://books.google.com/books/content/images/frontcover/dyTlnQEACAAJ?fife=w200-h370)
Author : John James McFarland
Publisher :
ISBN 13 :
Total Pages : 116 pages
Book Rating : 4.:/5 (858 download)
Download or read book Synthesis and Reactions of Palladium and Platinum Complexes of the Type [MF(PR3)3] [X] and [M2(OH)2(PR3)4] [X]2 written by John James McFarland and published by . This book was released on 1974 with total page 116 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Alan R. Katritzky
Publisher : Elsevier
ISBN 13 : 9780080423227
Total Pages : 1452 pages
Book Rating : 4.4/5 (232 download)
Download or read book Comprehensive Organic Functional Group Transformations written by Alan R. Katritzky and published by Elsevier. This book was released on 1995 with total page 1452 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Volume covers the formation of carbon-carbon single-, double- and triple bonds by substitution and addition reactions as well as by various rearrangements. The formation of carbon-carbon multiple bonds by elimination and condensation procedures is fully documented. In addition the synthesis of carbon-hydrogen bonds principally by substitution and addition reactions is featured as is the preparation of a wide variety of carbon-centred anions, cations and radicals.
Author : Bogdan Marciniec
Publisher : Springer Nature
ISBN 13 : 3031459601
Total Pages : 332 pages
Book Rating : 4.0/5 (314 download)
Download or read book Perspectives of Hydrosilylation Reactions written by Bogdan Marciniec and published by Springer Nature. This book was released on 2023-12-01 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume describes the latest advances and perspectives in hydrosilylation, with a focus on new organometallic catalysts and their mechanistic aspects. Hydrosilylation is the reaction of ≡SiH with carbon-carbon, carbon-heteroatom or heteroatom-heteroatom bonds and is the most fundamental and elegant method for laboratory and industrial synthesis of organosilicon molecular and macromolecular compounds. Yet these reactions do require a catalyst, for which initially homogeneous noble metal catalyst, mainly platinum, rhodium, iridium or ruthenium were used. However the high prices, metallic residues of these valuable catalysts as well as issues with product purification, did increase the interest in developing new catalysts. Noteworthy in this regard are the recently developed hydrosilylation reactions using catalysts based on earth-abundant transition metals (for example Mn, Fe, Co, Ni) and heterogeneous catalysts presented here. This volume of Topics in Organometallic Chemistry is written for scientists interested in silicon chemistry and its catalytic aspects, but can also be used as valuable handbook for postgraduate and advanced undergraduate students working with organometallic chemistry, catalysis as well as synthesis of fine chemicals.
Author : Shawn Michael Robinson
Publisher :
ISBN 13 :
Total Pages : 168 pages
Book Rating : 4.:/5 (16 download)
Download or read book Reactions of Platinum Complexes with Dimethylamine-borane written by Shawn Michael Robinson and published by . This book was released on 2012 with total page 168 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis describes a study of the reactions of platinum complexes with dimethylamine-borane (DMAB) as models for alkane activation. It is concluded that sigmaborane complexes of platinum(II) or platinum(IV) will be difficult to synthesize or even to detect as intermediates in hydride transfer from boranes to platinum. The complex [PtMe(O2CCF3)(bpy)] reacts with DMAB to form an intermediate [PtMeH(bpy)] complex, which undergoes reductive elimination of methane with further degradation to give platinum(0) and free 2,2'-bipyridine. The addition of methyl acrylate to the reaction allowed the trapping of the platinum-hydride, producing [PtCl(CHMeCO2Me)(bpy)] and [Pt(CHMeCO2Me)2(bpy)]. Oxidative addition of methyl iodide produced the complex [PtMe(CHMeCO2Me)Cl(I)(bpy)]. As well, the reaction of [Pt(O2CCF3)2(dppe)] with DMAB afforded the [Pt( -H)(dppe)]2[O2CCF3]2 complex. These complexes are characterized by NMR spectroscopy, with additional structural information obtained from the crystal structure of [PtMe(CHMeCO2Me)Cl(I)(bpy)]. Complexes [PtMe3(OTf)(bpy)] and [PtMe3(OTf)(bu2bpy)] react with DMAB to afford [PtMe3(Me2NH)(bpy)]+, [Pt2Me6( -H)(bpy)2]+, [PtMe3(Me2NH)(bu2bpy)]+, and [Pt2Me6( -H)(bu2bpy)2]+. The addition of dibenzoyl peroxide to [PtMe2(bpy)] yielded [PtMe2(OBn)2(bpy)]. The reaction of [PtMe3(OTf)(dmpe)] with DMAB afforded the [PtMe4(dmpe)] complex. These complexes are characterized by NMR spectroscopy.
Author : Bruce Wayne Flint
Publisher :
ISBN 13 :
Total Pages : 184 pages
Book Rating : 4.:/5 (52 download)
Download or read book Exploring the Bonding and Reaction Chemistry of Gold and Platinum Complexes written by Bruce Wayne Flint and published by . This book was released on 2001 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt: Platinum complexes have been synthesized and characterized. Relative Pt-X Bond Dissociation Energies (BDE's) for these complexes have been calculated from experimentally measured equilibrium and organic BDE's. Changes in relative BDE's are noted when ligands for the complexes are exchanged. Oxygen atom transfer reactions by a new platinum hydroxo catalyst have been studied. This catalyst is generated by the reaction of a platinum oxo complex with water and catalytically activates the reaction of the this complex with ethylene. The kinetics of this reaction have been studied and a reaction pathway has been proposed. The synthesis and characterization of a series of heteroatom substituted gold imido complexes have been reported. It has been demonstrated that the stability of gold imido complexes has a linear free energy relationship with the donor strength of the adjacent phosphine ligand. The decomposition of the complex involves the release of a free nitrene. Larger phosphine ligands retard the decomposition, and the decomposition is blocked by alkylation of the hydrazido ligand.
Author : H. Azizian-Balaneji
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (597 download)
Download or read book Reactions of Organosilicon and Organotin Compounds with Platinum and Palladium Complexes written by H. Azizian-Balaneji and published by . This book was released on 1980 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
![Download Synthesis and Reactions of Palladium and Platinum Complexes of the Type [M2X2(PR3)4][BF4]2 PDF Online Free](https://books.google.com/books/content/images/frontcover/v0kIngEACAAJ?fife=w200-h370)
Author : David John Hawke
Publisher :
ISBN 13 :
Total Pages : 198 pages
Book Rating : 4.:/5 (858 download)
Download or read book Synthesis and Reactions of Palladium and Platinum Complexes of the Type [M2X2(PR3)4][BF4]2 written by David John Hawke and published by . This book was released on 1971 with total page 198 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Martin Oestreich
Publisher : John Wiley & Sons
ISBN 13 : 9780470716069
Total Pages : 608 pages
Book Rating : 4.7/5 (16 download)
Download or read book The Mizoroki-Heck Reaction written by Martin Oestreich and published by John Wiley & Sons. This book was released on 2009-02-11 with total page 608 pages. Available in PDF, EPUB and Kindle. Book excerpt: Exploring the importance of Richard F. Heck’s carbon coupling reaction, this book highlights the subject of the 2010 Nobel Prize in Chemistry for palladium-catalyzed cross couplings in organic synthesis, and includes a foreword from Nobel Prize winner Richard F. Heck. The Mizoroki-Heck reaction is a palladium-catalyzed carbon–carbon bond forming process which is widely used in organic and organometallic synthesis. It has seen increasing use in the past decade as chemists look for strategies enabling the controlled construction of complex carbon skeletons. The Mizoroki-Heck Reaction is the first dedicated volume on this important reaction, including topics on: mechanisms of the Mizoroki-Heck reaction intermolecular Mizoroki-Heck reactions focus on regioselectivity and product outcome in organic synthesis waste-minimized Mizoroki-Heck reactions intramolecular Mizoroki-Heck reactions formation of heterocycles chelation-controlled Mizoroki-Heck reactions the Mizoroki-Heck reaction in domino processes oxidative heck-type reactions (Fujiwara-Moritani reactions) Mizoroki-Heck reactions with metals other than palladium ligand design for intermolecular asymmetric Mizoroki-Heck reactions intramolecular enantioselective Mizoroki-Heck reactions desymmetrizing Mizoroki-Heck reactions applications in combinatorial and solid phase syntheses, and the development of modern solvent systems and reaction techniques the asymmetric intramolecular Mizoroki-Heck reaction in natural product total synthesis Several chapters are devoted to asymmetric Heck reactions with particular focus on the construction of otherwise difficult-to-obtain sterically congested tertiary and quaternary carbons. Industrial and academic applications are highlighted in the final section. The Mizoroki-Heck Reaction will find a place on the bookshelves of any organic or organometallic chemist. “I am convinced that this book will rapidly become the most important reference text for research chemists in academia and industry who seek orientation in the rapidly growing and – for the layman – confusing field described as the “’Mizoroki–Heck reaction’.” (Synthesis, March 2010)
Author : Susan Milena Thompson
Publisher :
ISBN 13 :
Total Pages : 284 pages
Book Rating : 4.:/5 (633 download)
Download or read book “The” Reactivity of Platinum Complexes in Dehydrogenative Coupling Reactions with Stannanes and Silanes written by Susan Milena Thompson and published by . This book was released on 2002 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Han Shen
Publisher :
ISBN 13 :
Total Pages : 278 pages
Book Rating : 4.:/5 (622 download)
Download or read book Reactions of Vinyl Chloride with Transition Metal Complexes written by Han Shen and published by . This book was released on 2003 with total page 278 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Florian P. Pruchnik
Publisher : Springer Science & Business Media
ISBN 13 : 9780306431920
Total Pages : 784 pages
Book Rating : 4.4/5 (319 download)
Download or read book Organometallic Chemistry of the Transition Elements written by Florian P. Pruchnik and published by Springer Science & Business Media. This book was released on 1990-09-30 with total page 784 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry belongs to the most rapidly developing area of chemistry today. This is due to the fact that research dealing with the structure of compounds and chemical bonding has been greatly intensified in recent years. Additionally, organometallic compounds have been widely utilized in catalysis, organic synthesis, electronics, etc. This book is based on my lectures concerning basic organometallic chemistry for fourth and fifth year chemistry students and on my lectures concerning advanced organometallic chemistry and homogeneous catalysis for Ph.D. graduate students. Many recent developments in the area of organometallic chemistry as weIl as homogeneous catalysis are presented. Essential research results dealing with a given class of organometallic compounds are discussed briefly. Results of physicochemical research methods of various organometallic compounds as weIl as their synthesis, properties, structures, reactivities, and applications are discussed more thoroughly. The selection of tabulated data is arbitrary because, often, it has been impossible to avoid omissions. Nevertheless, these data can be very helpful in understanding properties of organometaIlic compounds and their reactivities. All physical data are given in SI units; the interatomic distances are given in pm units in figures and tables. I am indebted to Professor S. A. Duraj for translating and editing this book. His remarks, discussions, and suggestions are greatly appreciated. I also express gratitude to Virginia E. Duraj for editing and proofreading.
Author : Johannes Karl Fink
Publisher : William Andrew
ISBN 13 : 0128145102
Total Pages : 714 pages
Book Rating : 4.1/5 (281 download)
Download or read book Reactive Polymers: Fundamentals and Applications written by Johannes Karl Fink and published by William Andrew. This book was released on 2017-10-24 with total page 714 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactive Polymers: Fundamentals and Applications: A Concise Guide to Industrial Polymers, Third Edition introduces engineers and scientists to a range of reactive polymers and then details their applications and performance benefits. Basic principles and industrial processes are described for each class of reactive resin (thermoset), as well as additives, the curing process, applications and uses. The initial chapters are devoted to individual resin types (e.g., epoxides, cyanacrylates), followed by more general chapters on topics such as reactive extrusion and dental applications. Injection molding of reactive polymers, radiation curing, thermosetting elastomers, and reactive extrusion equipment are covered as well. The use of reactive polymers enables manufacturers to make chemical changes at a late stage in the production process, which, in turn, cause changes in performance and properties. Material selection and control of the reaction are essential to achieve optimal performance. Material new to this edition includes the most recent developments, applications and commercial products for each chemical class of thermosets, as well as sections on fabrication methods, reactive biopolymers, recycling of reactive polymers and case studies. Covers the basics and most recent developments, including reactive biopolymers, recycling of reactive polymers, nanocomposites and fluorosilicones Offers an indispensable guide for engineers and advanced students alike Provides extensive literature and patent review Reflects a thorough review of all literature published in this area since 2014 Features revised and updated chapters to reflect the latest research in reactive polymers
Download or read book Substitution Reactions Platinum Complexes written by and published by . This book was released on 1972 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
