Perspectives of Hydrosilylation Reactions

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Author :
Publisher : Springer Nature
ISBN 13 : 3031459601
Total Pages : 332 pages
Book Rating : 4.0/5 (314 download)

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Book Synopsis Perspectives of Hydrosilylation Reactions by : Bogdan Marciniec

Download or read book Perspectives of Hydrosilylation Reactions written by Bogdan Marciniec and published by Springer Nature. This book was released on 2023-12-01 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume describes the latest advances and perspectives in hydrosilylation, with a focus on new organometallic catalysts and their mechanistic aspects. Hydrosilylation is the reaction of ≡SiH with carbon-carbon, carbon-heteroatom or heteroatom-heteroatom bonds and is the most fundamental and elegant method for laboratory and industrial synthesis of organosilicon molecular and macromolecular compounds. Yet these reactions do require a catalyst, for which initially homogeneous noble metal catalyst, mainly platinum, rhodium, iridium or ruthenium were used. However the high prices, metallic residues of these valuable catalysts as well as issues with product purification, did increase the interest in developing new catalysts. Noteworthy in this regard are the recently developed hydrosilylation reactions using catalysts based on earth-abundant transition metals (for example Mn, Fe, Co, Ni) and heterogeneous catalysts presented here. This volume of Topics in Organometallic Chemistry is written for scientists interested in silicon chemistry and its catalytic aspects, but can also be used as valuable handbook for postgraduate and advanced undergraduate students working with organometallic chemistry, catalysis as well as synthesis of fine chemicals.

Comprehensive Handbook on Hydrosilylation

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Author :
Publisher : Elsevier
ISBN 13 : 0080912435
Total Pages : 767 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Comprehensive Handbook on Hydrosilylation by : B. Marciniec

Download or read book Comprehensive Handbook on Hydrosilylation written by B. Marciniec and published by Elsevier. This book was released on 2013-10-22 with total page 767 pages. Available in PDF, EPUB and Kindle. Book excerpt: This handbook provides an up-to-date account of hydrosilylation reactions and the directions in which synthetic and mechanistic studies as well as practical applications of these processes are proceeding. The book consists of two parts: the first is descriptive, presenting the catalytic, mechanistic, structural and synthetic aspects of hydrosilylation, as well as its application in organic and organosilicon chemistry. The second part, presented in tabular form sets out encyclopedic information concerning reaction conditions taken from more than 2000 papers and patents in the period 1965 - 1990.

Perspectives in Organometallic Chemistry

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Author :
Publisher : Royal Society of Chemistry
ISBN 13 : 9780854048762
Total Pages : 336 pages
Book Rating : 4.0/5 (487 download)

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Book Synopsis Perspectives in Organometallic Chemistry by : Constantinos G. Screttas

Download or read book Perspectives in Organometallic Chemistry written by Constantinos G. Screttas and published by Royal Society of Chemistry. This book was released on 2003 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is an area which touches on, and plays an active role in, all of the traditional divisions of chemistry: inorganic, organic, physical and theoretical. This timely book provides overviews of recent original developments in these areas, including: the synthesis of main group, transition metal and lanthanide organometallics; applications to homogeneous catalysis; structural and theoretical studies; and enantioselective processes. As these topics are currently part of a stream of exciting research with potentially important industrial applications, this title presents informed accounts of state-of-the-art research which will be of great interest to readers. Written by some of the foremost groups in the field and handsomely illustrated throughout, each chapter also provides an extensive bibliography. By introducing areas that are likely to play a prominent role in organometallic chemistry in the near future, Perspectives in Organometallic Chemistry provides an authoritative source of ideas, particularly for all those engaged in research.

Organometallic Chemistry Research Perspectives

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Author :
Publisher : Nova Publishers
ISBN 13 : 9781600217807
Total Pages : 324 pages
Book Rating : 4.2/5 (178 download)

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Book Synopsis Organometallic Chemistry Research Perspectives by : Richard P. Irwin

Download or read book Organometallic Chemistry Research Perspectives written by Richard P. Irwin and published by Nova Publishers. This book was released on 2007 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. This book presents research in this field.

Handbook of Reagents for Organic Synthesis

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 1119952298
Total Pages : 706 pages
Book Rating : 4.1/5 (199 download)

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Book Synopsis Handbook of Reagents for Organic Synthesis by : André B. Charette

Download or read book Handbook of Reagents for Organic Synthesis written by André B. Charette and published by John Wiley & Sons. This book was released on 2017-06-26 with total page 706 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook is a compilation of 99 articles on diverse reagents and catalysts that describe the synthesis of heteroarenes, the building blocks of a wide range of chemicals used in pharma and chemical industries. Articles are selected from the e-EROS database and edited to make sure that it includes only the material relevant to the topic of the book and focus on the synthetic aspects. This makes the articles very focused on the needs of readers wanting information on specific syntheses of specific heteroarenes. In addition, the chemistry of each parent heteroarene is also included to ensure that the reader rapidly finds important information. The Handbook is a part of the Handbook of Reagents for Organic Chemistry series, aiming at collecting articles on a particular theme that individual researchers in academia or industry can use on a daily basis.

Homogeneous Catalysis

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Publisher : John Wiley & Sons
ISBN 13 : 1118872517
Total Pages : 288 pages
Book Rating : 4.1/5 (188 download)

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Book Synopsis Homogeneous Catalysis by : Sumit Bhaduri

Download or read book Homogeneous Catalysis written by Sumit Bhaduri and published by John Wiley & Sons. This book was released on 2014-09-11 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last decade, the area of homogeneous catalysis withtransition metal has grown in great scientific interest andtechnological promise, with research in this area earning threeNobel Prizes and filing thousands of patents relating tometallocene and non-metallocene single site catalysts, asymmetriccatalysis, carbon-carbon bond forming metathesis and cross couplingreactions. This text explains these new developments in a unified, cogent, andcomprehensible manner while also detailing earlier discoveries andthe fundamentals of homogeneous catalysis. Serving as a self-studyguide for students and all chemists seeking to gain entry into thisfield, it can also be used by experienced researchers from bothacademia and industry for referring to leading state of the artreview articles and patents, and also as a quick self-study manualin an area that is outside their immediate expertise. The bookfeatures: • Topics including renewable feed stocks (biofuel,glycerol), carbon dioxide based processes (polycarbonates),fluorous solvents, ionic liquid, hydroformylation, polymerization,oxidation, asymmetric catalysis, and more • Basic principles of organometallic chemistry,homogeneous catalysis, and relevant technological issues • Problems and answers, industrial applications (casestudies), and examples from proven industrial processes with cleardiscussions on environmental and techno-commercial issues • Extensive references to cutting edge research withapplication potential and leading patents • Tables and illustrations to help explain difficultconcepts

Applied Homogeneous Catalysis with Organometallic Compounds

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 3527651764
Total Pages : 1872 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Applied Homogeneous Catalysis with Organometallic Compounds by : Boy Cornils

Download or read book Applied Homogeneous Catalysis with Organometallic Compounds written by Boy Cornils and published by John Wiley & Sons. This book was released on 2017-09-05 with total page 1872 pages. Available in PDF, EPUB and Kindle. Book excerpt: The completely revised third edition of this four-volume classic is fully updated and now includes such topics as as CH-activation and multicomponent reactions. It describes the most important reaction types, new methods and recent developments in catalysis. The internationally renowned editors and a plethora of international authors (including Nobel laureate R. Noyori) guarantee high quality content throughout the book. A "must read" for everyone in academia and industry working in this field.

Organosilicon Compounds

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Publisher : Academic Press
ISBN 13 : 0128142146
Total Pages : 410 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Organosilicon Compounds by : Vladimir Ya Lee

Download or read book Organosilicon Compounds written by Vladimir Ya Lee and published by Academic Press. This book was released on 2017-09-25 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organosilicon Compounds: Experiment (Physico-Chemical Studies) and Applications, volume 2, also contains two parts. In its first part, Experiment (Physico-Chemical Studies), the application of modern instrumental tools (such as X-ray crystallography, 29Si NMR spectroscopy, UV-Photoelectron Spectroscopy, and other methods) for assessing the structures of organosilicon compounds is described. The second part, Applications, reviews the current research in the field of material science, specifically the use of organosilicon compounds in synthetic chemistry directed towards the creation of new materials. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds’ structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. Features valuable contributions from prominent experts cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry Covers important breakthroughs in the field as well as with the historically significant achievements of the past Includes applied information for a wide range of specialists from junior and senior researchers (from both academia and industry), working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields such as polymer, material science, nanotechnology

Comprehensive Organic Synthesis

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Author :
Publisher : Newnes
ISBN 13 : 008097743X
Total Pages : 9815 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Comprehensive Organic Synthesis by :

Download or read book Comprehensive Organic Synthesis written by and published by Newnes. This book was released on 2014-02-14 with total page 9815 pages. Available in PDF, EPUB and Kindle. Book excerpt: The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition, Nine Volume Set an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively

Ionic Liquids in Catalysis

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Author :
Publisher : MDPI
ISBN 13 : 3036512462
Total Pages : 196 pages
Book Rating : 4.0/5 (365 download)

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Book Synopsis Ionic Liquids in Catalysis by : Hieronim Maciejewski

Download or read book Ionic Liquids in Catalysis written by Hieronim Maciejewski and published by MDPI. This book was released on 2021-08-30 with total page 196 pages. Available in PDF, EPUB and Kindle. Book excerpt: Due to their distinctive properties, ionic liquids have attracted the great and unflagging interest of researchers for over 30 years. This interest has been focused mainly on their use as a green alternative to volatile organic solvents. However, they often act not only as solvents but also as catalysts, catalyst immobilizers and initiators. Over 100 types of chemical reactions are known in which ionic liquids (ILs) were applied successfully. This Special Issue is aimed at showing the most recent advances and trends in the design, synthesis and characterization of catalysts based on ILs, as well as presenting their activity and application potential.

Iridium Catalysts for Organic Reactions

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Author :
Publisher : Springer Nature
ISBN 13 : 3030690830
Total Pages : 461 pages
Book Rating : 4.0/5 (36 download)

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Book Synopsis Iridium Catalysts for Organic Reactions by : Luis A. Oro

Download or read book Iridium Catalysts for Organic Reactions written by Luis A. Oro and published by Springer Nature. This book was released on 2021-03-29 with total page 461 pages. Available in PDF, EPUB and Kindle. Book excerpt: This new volume “Iridium Catalysts for Organic Reactions” in the series “Topics in Organometallic Chemistry” intends to update several representative well-known reactions and to introduce other less known or new reactions in particular covering sustainability aspects. Iridium complexes are efficient in many catalytic homogeneous transformations providing high efficiency in both results, activity and selectivity. The interest of the book lies in the presentation of the advances, new perspectives and application in a variety of representative iridium-catalysed reaction. All chapters in the volume are contributed by relevant international experts in the field. The book is aimed at researchers, graduate students and synthetic chemists at all levels in academia and industry.

Early Main Group Metal Catalysis

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Publisher : John Wiley & Sons
ISBN 13 : 3527344489
Total Pages : 400 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Early Main Group Metal Catalysis by : Sjoerd Harder

Download or read book Early Main Group Metal Catalysis written by Sjoerd Harder and published by John Wiley & Sons. This book was released on 2020-04-06 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.

Photoinitiators

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Publisher : John Wiley & Sons
ISBN 13 : 3527346090
Total Pages : 768 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Photoinitiators by : Jean-Pierre Fouassier

Download or read book Photoinitiators written by Jean-Pierre Fouassier and published by John Wiley & Sons. This book was released on 2021-06-08 with total page 768 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photoinitiators A comprehensive text that covers everything from the processes and mechanisms to the reactions and industrial applications of photoinitiators Photoinitiators offers a wide-ranging overview of existing photoinitiators and photoinitiating systems and their uses in ever-growing green technologies. The authors—noted experts on the topic—provide a concise review of the backgrounds in photopolymerization and photochemistry, explain the available structures, and examine the excited state properties, involved mechanisms, and structure, reactivity, and efficiency relationships. The text also contains information on the latest developments and trends in the design of novel tailor-made systems. The book explores the role of current systems in existing and emerging processes and applications. Comprehensive in scope, it covers polymerization of thick samples and in-shadow areas, polymerization under LEDs, NIR light induced thermal polymerization, photoinitiators for novel specific and improved properties, and much more. Written by an experienced and internationally renowned team of authors, this important book: Provides detailed information about excited state processes, mechanisms and design of efficient photoinitiator systems Discusses the performance of photoinitiators of polymerization by numerous examples of reactions and application Includes information on industrial applications Presents a review of current developments and challenges Offers an introduction to the background information necessary to understand thefield The role played by photoinitiators in a variety of different polymerization reactions Written for polymer chemists, photochemists, and materials scientists, Photoinitiators will also earn a place in the libraries of photochemists seeking an authoritative, one-stop guide to the processes, mechanisms, and industrial applications of photoinitiators.

Organic Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 3527819274
Total Pages : 2876 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Organic Chemistry by : Pierre Vogel

Download or read book Organic Chemistry written by Pierre Vogel and published by John Wiley & Sons. This book was released on 2019-08-08 with total page 2876 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides the background, tools, and models required to understand organic synthesis and plan chemical reactions more efficiently Knowledge of physical chemistry is essential for achieving successful chemical reactions in organic chemistry. Chemists must be competent in a range of areas to understand organic synthesis. Organic Chemistry provides the methods, models, and tools necessary to fully comprehend organic reactions. Written by two internationally recognized experts in the field, this much-needed textbook fills a gap in current literature on physical organic chemistry. Rigorous yet straightforward chapters first examine chemical equilibria, thermodynamics, reaction rates and mechanisms, and molecular orbital theory, providing readers with a strong foundation in physical organic chemistry. Subsequent chapters demonstrate various reactions involving organic, organometallic, and biochemical reactants and catalysts. Throughout the text, numerous questions and exercises, over 800 in total, help readers strengthen their comprehension of the subject and highlight key points of learning. The companion Organic Chemistry Workbook contains complete references and answers to every question in this text. A much-needed resource for students and working chemists alike, this text: -Presents models that establish if a reaction is possible, estimate how long it will take, and determine its properties -Describes reactions with broad practical value in synthesis and biology, such as C-C-coupling reactions, pericyclic reactions, and catalytic reactions -Enables readers to plan chemical reactions more efficiently -Features clear illustrations, figures, and tables -With a Foreword by Nobel Prize Laureate Robert H. Grubbs Organic Chemistry: Theory, Reactivity, and Mechanisms in Modern Synthesis is an ideal textbook for students and instructors of chemistry, and a valuable work of reference for organic chemists, physical chemists, and chemical engineers.

Pincer Compounds

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Author :
Publisher : Elsevier
ISBN 13 : 0128129328
Total Pages : 754 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Pincer Compounds by : David Morales-Morales

Download or read book Pincer Compounds written by David Morales-Morales and published by Elsevier. This book was released on 2018-04-11 with total page 754 pages. Available in PDF, EPUB and Kindle. Book excerpt: Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen’s The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. Describes the chemistry and applications of this important class of organometallic and coordination compounds Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry

Silicon and Silicones

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Author :
Publisher : Springer
ISBN 13 : 9783540175650
Total Pages : 180 pages
Book Rating : 4.1/5 (756 download)

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Book Synopsis Silicon and Silicones by : Eugene G. Rochow

Download or read book Silicon and Silicones written by Eugene G. Rochow and published by Springer. This book was released on 1987-05-27 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: An Overview for the General Reader The fact that silicone rubber boots made those footprints on the moon, and that other silicone polymers made possible the construc tion and functioning of space suits and space vehicles, has led to the general belief that silicones are very modem materials conjured up to meet the needs of space travel. Actually, though, silicone chemis try has deep roots in human history, dating from the dawn of the race and extending through all of geology, mineralogy, and the ancient ceramic arts. This little book seeks to put the development of silicone materials in perspective as part of the fascinating involvement of the element silicon in our daily lives, from the stuff the earth and the moon are made of to the modem use of ultra pure silicon in transistors and computers, and the use of ordi nary elementary silicon to make silicone rubber, silicone oil, sili cone resins, and silicon or silicone-containing polishes, drugs, and fragrances. Of course these are not our only connections with silicon. The natural compounds of silicon and oxygen (the silicates) are the starting materials for making bricks, tile, cement, glass, and a host of modem ceramic products. The widespread usefulness of silicon and its compounds comes about for two reasons: first, there is so much of it, and second, it is so versatile.

Dendrimer Chemistry

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Author :
Publisher : Royal Society of Chemistry
ISBN 13 : 1788011325
Total Pages : 327 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Dendrimer Chemistry by : Michael Malkoch

Download or read book Dendrimer Chemistry written by Michael Malkoch and published by Royal Society of Chemistry. This book was released on 2020 with total page 327 pages. Available in PDF, EPUB and Kindle. Book excerpt: An overview of the latest advances in the synthesis, characterization and applications of dendrimers and other complex dendritic architectures.