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Preparation Properties And Reactions Of Rhodium Iridium And Osmium Complexes With Group Via Donor Atoms And Other Pi Acid Ligands
Download Preparation Properties And Reactions Of Rhodium Iridium And Osmium Complexes With Group Via Donor Atoms And Other Pi Acid Ligands full books in PDF, epub, and Kindle. Read online Preparation Properties And Reactions Of Rhodium Iridium And Osmium Complexes With Group Via Donor Atoms And Other Pi Acid Ligands ebook anywhere anytime directly on your device. Fast Download speed and no annoying ads. We cannot guarantee that every ebooks is available!
Book Synopsis Preparation, Properties and Reactions of Rhodium, Iridium and Osmium Complexes with Group Via Donor Atoms and Other PI Acid Ligands by : Robert H. Ballan
Download or read book Preparation, Properties and Reactions of Rhodium, Iridium and Osmium Complexes with Group Via Donor Atoms and Other PI Acid Ligands written by Robert H. Ballan and published by . This book was released on 1978 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactions of Complexes of Rhodium and Iridium Having Chelating N,O-donor Ligands by : Namadzavho Enos Sitabule
Download or read book Synthesis and Reactions of Complexes of Rhodium and Iridium Having Chelating N,O-donor Ligands written by Namadzavho Enos Sitabule and published by . This book was released on 2000 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Modern Oxidation Methods by : Jan-Erling Bäckvall
Download or read book Modern Oxidation Methods written by Jan-Erling Bäckvall and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: At the very latest, with the award of the 2001 Nobel Prize for work on asymmetric oxidation, there has been a need for a comprehensive book on such methods. Edited by J.-E. Backvall, one of the world's leaders in the field, this book fills that gap by covering the topic, from classical to green chemistry methods. He has put together a plethora of well-established authors from all over the world who cover every important aspect in high-quality contributions -- whether aerobic oxidation or transition metal-catalyzed epoxidation of alkenes. By providing an overview of this huge topic, this book represents an unparalleled aid for any chemist working in the field. Chapters include: Recent Developments in the Osmium-Catalyzed Dihydroxylation of Olefins Transition Metal-Catalyzed Epoxidation of Alkenes Organocatalytic Oxidation - Ketone-Catalyzed Asymmetric Epoxidation of Olefins Modern Oxidation of Alcohols using environmentally Benign Oxidants Aerobic Oxidations and Related Reactions Catalyzed by N-Hydroxyphthalimide Ruthenium-Catalyzed Oxidation of Alkenes, Alcohols, Amines, Amides, b-Lactams, Phenols, and Hydrocarbons Selective Oxidations of Sulfides and Amines Liquid Phase Oxidation Reactions Catalyzed by Polyoxometalates Oxidation of Carbonyl Compounds Mn-catalysed Oxidation with Hydrogen Peroxide
Book Synopsis Synthesis and Characterization of Some Rhodium and Iridium Alkyl Complexes by : Matthew Albert Kulzick
Download or read book Synthesis and Characterization of Some Rhodium and Iridium Alkyl Complexes written by Matthew Albert Kulzick and published by . This book was released on 1984 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Index to Theses with Abstracts Accepted for Higher Degrees by the Universities of Great Britain and Ireland and the Council for National Academic Awards by :
Download or read book Index to Theses with Abstracts Accepted for Higher Degrees by the Universities of Great Britain and Ireland and the Council for National Academic Awards written by and published by . This book was released on 1988 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Iridium Complexes in Organic Synthesis by : Luis A. Oro
Download or read book Iridium Complexes in Organic Synthesis written by Luis A. Oro and published by John Wiley & Sons. This book was released on 2008-12-03 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ranging from hydrogenation to hydroamination, cycloadditions and nanoparticles, this first handbook to comprehensively cover the topic of iridium in synthesis discusses the important advances in iridium-catalyzed reactions, namely the use of iridium complexes in enantioselective catalysis. A must for organic, complex and catalytic chemists, as well as those working with/on organometallics.
Book Synopsis Studies of Osmium and Ruthenium Complexes, with Ligands Featuring Group 14 and 15 Donor Atoms by : Scott Darren Woodgate
Download or read book Studies of Osmium and Ruthenium Complexes, with Ligands Featuring Group 14 and 15 Donor Atoms written by Scott Darren Woodgate and published by . This book was released on 1998 with total page 996 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Part I. The Synthesis of Metal-metal Bonds Via Iridium and Rhodium Carbonyl Anions ; Part II. The Synthesis and Properties of Acyl Isocyanate Complexes of Iridium and Rhodium by : Frederick Davidson Vastine
Download or read book Part I. The Synthesis of Metal-metal Bonds Via Iridium and Rhodium Carbonyl Anions ; Part II. The Synthesis and Properties of Acyl Isocyanate Complexes of Iridium and Rhodium written by Frederick Davidson Vastine and published by . This book was released on 1967 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactivity of Rhodium and Iridium Silyl and Silylene Complexes Supported by PNP Pincer Ligands by : Elisa E. Calimano
Download or read book Synthesis and Reactivity of Rhodium and Iridium Silyl and Silylene Complexes Supported by PNP Pincer Ligands written by Elisa E. Calimano and published by . This book was released on 2009 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Organometallic Chemistry of Rhodium and Iridium Complexes of Macrocyclic PCP and POCOP Pincer Ligands by : Baptiste Leforestier
Download or read book Synthesis and Organometallic Chemistry of Rhodium and Iridium Complexes of Macrocyclic PCP and POCOP Pincer Ligands written by Baptiste Leforestier and published by . This book was released on 2020 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Kinetic Studies on Oxygen-carrying Iridium Complexes ; Preparation, Properties and Addition Reactions of New D8 Complexes of Cobalt, Rhodium and Iridium with Polydentate Tertiary Phosphines and Arsines by : Loomis Shu-jan Chen
Download or read book Kinetic Studies on Oxygen-carrying Iridium Complexes ; Preparation, Properties and Addition Reactions of New D8 Complexes of Cobalt, Rhodium and Iridium with Polydentate Tertiary Phosphines and Arsines written by Loomis Shu-jan Chen and published by . This book was released on 1973 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactivity of Rhodium and Iridium Complexes Supported by New Silyl Pincer Ligands by : MacLean Darren F.
Download or read book Synthesis and Reactivity of Rhodium and Iridium Complexes Supported by New Silyl Pincer Ligands written by MacLean Darren F. and published by . This book was released on 2008 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Characterization and Catalytic Performance of Rhodium and Iridium Complexes Supported in Dealuminated HY Zeolite by : Claudia Martinez Macias
Download or read book Synthesis, Characterization and Catalytic Performance of Rhodium and Iridium Complexes Supported in Dealuminated HY Zeolite written by Claudia Martinez Macias and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Essentially molecular supported catalysts were synthesized by using organometallic complexes as precursors, such as Rh(CO)2(acac), Rh(C2H4)2(acac), Ir(CO)2(acac), and Ir(C2H4)2(acac) (where acac is acetylacetonate) and HY zeolite as a support. A goal was to obtain highly uniform solid catalysts with well-defined structures. Characterization by X-ray absorption (XAS) and infrared (IR) spectroscopies confirmed the anchoring of the metal to the support with a high degree of uniformity. IR and 29Si and 27Al nuclear magnetic resonance (NMR) spectra characterize the presence of amorphous regions in the zeolite, and scanning transmission electron microscopy (STEM) identifies these amorphous regions, where iridium is more susceptible to aggregation than in the crystalline regions. Treatment of Ir(CO)2/HY zeolite with C2H4 and H2 at room temperature led to a family of species which includes Ir(CO)2, Ir(CO)(C2H4), Ir(CO)(C2H4)2, Ir(CO)(C2H5) and, tentatively, Ir(CO)(H). The identification of the species is based on XAS and IR spectra (including spectra of samples made with isotopically labeled ligands, 13CO and D2O) and density functional theory (DFT) calculations. The catalytic performance of isostructural rhodium and iridium species incorporating CO as a ligand was measured for the ethylene conversion; the CO not only acts as an inhibitor but it also as a probe molecule providing information about the electronic properties of the metal and of the species present during reaction. When isostructural rhodium and iridium diethylene species are bonded near each other on HY zeolite, the iridium complexes alter the selectivity of rhodium by spilling over hydrogen that hinders the interaction between ethylene and the acidic sites of the zeolite that act in concert with the rhodium, causing it to favor ethylene hydrogenation over dimerization. All these results show how structurally simple solid catalysts can be used to facilitate fundamental understanding of catalysts and their performance.
Book Synopsis Rhodium and Iridium Pincer Complexes Supported by Bis(phosphino)silyl Ligation by : Erin Morgan
Download or read book Rhodium and Iridium Pincer Complexes Supported by Bis(phosphino)silyl Ligation written by Erin Morgan and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactions of Iridium(111) and Rhodium(111) Complexes Containing Terminal Difluoro- and Dichloro-phosphino Groups by : Neil Thomas McManus
Download or read book Synthesis and Reactions of Iridium(111) and Rhodium(111) Complexes Containing Terminal Difluoro- and Dichloro-phosphino Groups written by Neil Thomas McManus and published by . This book was released on 1982 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Development of Novel Rhodium and Iridium Complexes with a Fac-chelating Ligand for Electrophilic C-H Activation by : Jennifer Lee Rhinehart
Download or read book Development of Novel Rhodium and Iridium Complexes with a Fac-chelating Ligand for Electrophilic C-H Activation written by Jennifer Lee Rhinehart and published by . This book was released on 2011 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Several new bis-3,5(dimethylpyrazol-1-yl)acetate rhodium and iridium complexes were synthesized from MCl3?H2O. [Rh(bdmpza)Cl3]- was isolated with three different cations, lithium, sodium and tetraethylamonium, to obtain a full characterization profile. Analogously, [Ir(bdmpza)Cl3]- was isolated with two different cations, lithium and sodium, and characterized by 1H NMR, 13C NMR, elemental analysis and X-ray crystal structure determination. A neutral rhodium complex, [Rh(bdmpza)Cl2(py)], was also isolated as two isomers by addition of pyridine. Reaction of [Rh(bdmpza)Cl3]- and [Rh(bdmpza)Cl2(py)] with dimethylzinc afforded three new complexes, [Rh(bdmpza)Cl2(Me)]-, [Rh(bdmpza)Cl(Me)2]- and [Rh(bdmpza)Cl(Me)(py)]. Stoichiometric and catalytic C-H activation of benzene was investigated for these new rhodium methyl complexes. Novel rhodium and iridium precatalysts catalysts, [Rh(bdmpza)Cl3]- Na+, [Ir(bdmpza)Cl3]- Na+ and [Rh(bdmpza)Cl2(py)], were subjected to H/D exchange conditions with benzene and deuterated trifluoroacetic acid, acetic acid and methanol in the presence of a halide abstractor. Optimum conditions of silver triflate, deuterated trifuoroacetic acid, 100°C and 24 hours were identified to conduct arene H/D exchange studies. Most arenes investigated showed modest H/D exchange in the ring, while branched [beta]-sp3C-H bonds also showed affinity for H/D exchange. Mechanistic studies of [beta]-sp3C-H H/D exchange were carried out, including synthesis of [Rh(bdmpz)Cl3(py)], which does not contain the pendant acetate group"--Leaf vi.
Book Synopsis Synthesis and Organometallic Chemistry of Rhodium and Iridium Complexes of Macrocyclic PNP and PONOP Pincer Ligands by : Thomas M. Hood
Download or read book Synthesis and Organometallic Chemistry of Rhodium and Iridium Complexes of Macrocyclic PNP and PONOP Pincer Ligands written by Thomas M. Hood and published by . This book was released on 2020 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: