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Preparation And Characterization Of Zro2 Stabilized With Ruiv And Laiii
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Book Synopsis Preparation and Characterization of ZrO2 Stabilized with Ru(IV) and La(III). by : Y-C. Long
Download or read book Preparation and Characterization of ZrO2 Stabilized with Ru(IV) and La(III). written by Y-C. Long and published by . This book was released on 1988 with total page 9 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ruthenium oxide, dispersed on oxide supports such as TiO2, SiO2, and ZrO2, are known to shown Fischer-Tropsch activity. Little is known about the catalyst-support interactions which must play an important role in the catalytic activity of dispersed ruthenium oxide. The strength of catalytic support interaction may be directly related to the stability of the dispersed catalyst towards reduction. Hence, solid solutions of Ru(IV)/ZrO2 have been prepared, and the resulting stability of Ru(IV) toward reduction with hydrogen was measured and compared with that of bulk RuO2. The observed increase in stability toward reduction was related to interaction between RuO2 and ZrO2. The introduction of a small amount of La2O3 with the ZrO2 produced further stabilization of the Ru(IV) toward reduction.
Book Synopsis Preparation and Characterization of Cubic ZrO2 Stabilized by Fe(III) and Fe(II). by : S. Davison
Download or read book Preparation and Characterization of Cubic ZrO2 Stabilized by Fe(III) and Fe(II). written by S. Davison and published by . This book was released on 1987 with total page 17 pages. Available in PDF, EPUB and Kindle. Book excerpt: Samples of cubic zirconium oxide contained 2.5at% - 40af% ferric iron were prepared by codecomposition of the nitrates. X-ray powder diffraction analysis and magnetic measurements indicated that alpha iron nitrate and ZRO2 form a solid solution up to 25at% Fe/Zr in the product. At this point, the solubility limit of alpha-Fe2O3 in ZrO2 is exceeded. The reduction of cubic zirconia samples containing 2.5at% - 20at% Fe(III) leads to the stabilization of iron (II) in the zirconia lattice. Reduction to metallic iron occurs at much higher temperatures than the reduction of bulk alpha-Fe2O3. (Reprints).
Book Synopsis Stabilization of Cubic ZrO2 with Rh(III) And/or La(III). by : Y-C. Zhang
Download or read book Stabilization of Cubic ZrO2 with Rh(III) And/or La(III). written by Y-C. Zhang and published by . This book was released on 1987 with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt: Samples of stabilized cubic zirconium oxide were prepared containing rhodium(III), lanthanum(III) and both La(III) and Rh(III). The properties of these compounds were studied by x-ray analysis and temperature programmed reduction. These studies indicated that the cubic phase becomes stabilized with the incorporation of La(III) or Rh(III) into the ZrO2 structure.
Book Synopsis Preparation and Properties of Cubic ZrO2 Stabilized with Ni(II). by : K. E. Smith
Download or read book Preparation and Properties of Cubic ZrO2 Stabilized with Ni(II). written by K. E. Smith and published by . This book was released on 1987 with total page 10 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Fischer-Tropsch activity of the nickel-zirconia system has been investigated and preparations of the catalyst involving coprecipitation gave a significantly more active catalyst than did preparations involving impregnation. Stabilization towards reduction has been observed when certain transition metal ions such as Rh(III) are inserted into the fluorite ZrO2 structure. Recent investigations using the NiO/ZrO2 system have concluded that NiO does not interact with zirconium oxide, but the materials were prepared by incipient wetness. It was the purpose of this study to investigate the formation of cubic ZrO2 stabilized with Ni(II) and to relate the structural properties of the catalyst with its observed stability in reducing atmospheres. These properties were then compared to those of catalysts prepared by incipient wetness. Changes in the structure of ZrO and in the temperatures at which reduction of Ni(II) to Ni metal occurred were then related to the relative strengths of the catalyst-support interaction.
Download or read book Physics Briefs written by and published by . This book was released on 1988-07 with total page 1418 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Chemical Bond in Inorganic Chemistry by : Ian David Brown
Download or read book The Chemical Bond in Inorganic Chemistry written by Ian David Brown and published by . This book was released on 2002 with total page 289 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes the bond valence model, a description of acid-base bonding which is becoming increasingly popular particularly in fields such as materials science and mineralogy where solid state inorganic chemistry is important. Recent improvements in crystal structure determination have allowed the model to become more quantitative. Unlike other models of inorganic chemical bonding, the bond valence model is simple, intuitive, and predictive, and can be used for analysing crystal structures and the conceptual modelling of local as well as extended structures. This is the first book to explore in depth the theoretical basis of the model and to show how it can be applied to synthetic and solution chemistry. It emphasizes the separate roles of the constraints of chemistry and of three-dimensional space by analysing the chemistry of solids. Many applications of the model in physics, materials science, chemistry, mineralogy, soil science, surface science, and molecular biology are reviewed. The final chapter describes how the bond valence model relates to and represents a simplification of other models of inorganic chemical bonding.
Book Synopsis Materials Fundamentals of Gate Dielectrics by : Alexander A. Demkov
Download or read book Materials Fundamentals of Gate Dielectrics written by Alexander A. Demkov and published by Springer. This book was released on 2011-02-03 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the fundamentals of novel gate dielectrics that are being introduced into semiconductor manufacturing to ensure the continuous scaling of CMOS devices. As this is a rapidly evolving field of research we choose to focus on the materials that determine the performance of device applications. Most of these materials are transition metal oxides. Ironically, the d-orbitals responsible for the high dielectric constant cause severe integration difficulties, thus intrinsically limiting high-k dielectrics. Though new in the electronics industry many of these materials are well-known in the field of ceramics, and we describe this unique connection. The complexity of the structure-property relations in TM oxides requires the use of state-of-the-art first-principles calculations. Several chapters give a detailed description of the modern theory of polarization, and heterojunction band discontinuity within the framework of the density functional theory. Experimental methods include oxide melt solution calorimetry and differential scanning calorimetry, Raman scattering and other optical characterization techniques, transmission electron microscopy, and X-ray photoelectron spectroscopy. Many of the problems encountered in the world of CMOS are also relevant for other semiconductors such as GaAs. A comprehensive review of recent developments in this field is thus also given.
Book Synopsis Hydrogen and Syngas Production and Purification Technologies by : Ke Liu
Download or read book Hydrogen and Syngas Production and Purification Technologies written by Ke Liu and published by John Wiley & Sons. This book was released on 2010-01-07 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covers the timely topic of fuel cells and hydrogen-based energy from its fundamentals to practical applications Serves as a resource for practicing researchers and as a text in graduate-level programs Tackles crucial aspects in light of the new directions in the energy industry, in particular how to integrate fuel processing into contemporary systems like nuclear and gas power plants Includes homework-style problems
Book Synopsis Properties and Applications of Polymer Nanocomposites by : Deba Kumar Tripathy
Download or read book Properties and Applications of Polymer Nanocomposites written by Deba Kumar Tripathy and published by Springer. This book was released on 2017-05-07 with total page 229 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of the present edited book is to furnish scientific information about manufacturing, properties, and application of clay and carbon based polymer nanocomposites. It can be used as handbook for undergraduate and post graduate courses (for example material science and engineering, polymer science and engineering, rubber technology, manufacturing engineering, etc.) as well as as reference book for research fellows and professionals. Polymer nanocomposites have received outstanding importance in the present decade because of their broad range of high-performance applications in various areas of engineering and technology due to their special material properties. A great interest is dedicated to nanofiller based polymeric materials, which exhibit excellent enhancement in macroscopic material properties (mechanical, thermal, dynamic mechanical, electrical and many more) at very low filler contents and can therefore be used for the development of next-generation composite materials.
Download or read book Natural Polymers written by Maya J John and published by Royal Society of Chemistry. This book was released on 2012-08-31 with total page 369 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the search for sustainable materials, natural polymers present an attractive alternative for many applications compared to their synthetic counterparts derived from petrochemicals. The two volume set, Natural Polymers, covers the synthesis, characterisation and applications of key natural polymeric systems including their morphology, structure, dynamics and properties. Volume one focuses on natural polymer composites, including both natural and protein fibres, and volume two on natural polymer nanocomposites. The first volume examines the characterization, life cycle assessment and new sources of natural fibres and their potential as a replacement for synthetic fibres in industrial applications. It then explores the important advancements in the field of wool, silk, spidersilk and mussel byssus fibres. The second volume looks at the properties and characterization of cellulose, chitosan, furanic, starch, wool and silk nanocomposites and the potential industrial applications of natural polymer nanocomposites. With contributions from leading researchers in natural polymers from around the globe, Natural Polymers provides a valuable reference for material scientists, polymer chemists and polymer engineers.
Book Synopsis Luminescence of Lanthanide Ions in Coordination Compounds and Nanomaterials by : Ana de Bettencourt-Dias
Download or read book Luminescence of Lanthanide Ions in Coordination Compounds and Nanomaterials written by Ana de Bettencourt-Dias and published by John Wiley & Sons. This book was released on 2014-09-08 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive book presents the theoretical principles, current applications and latest research developments in the field of luminescent lanthanide complexes; a rapidly developing area of research which is attracting increasing interest amongst the scientific community. Luminescence of Lanthanide Ions in Coordination Compounds and Nanomaterials begins with an introduction to the basic theoretical and practical aspects of lanthanide ion luminescence, and the spectroscopic techniques used to evaluate the efficiency of luminescence. Subsequent chapters introduce a variety of different applications including: • Circularly polarized luminescence • Luminescence bioimaging with lanthanide complexes • Two-photon absorption of lanthanide complexes • Chemosensors • Upconversion luminescence • Excitation spectroscopy • Heterometallic complexes containing lanthanides Each chapter presents a detailed introduction to the application, followed by a description of experimental techniques specific to the area and an extensive review of recent literature. This book is a valuable introduction to the literature for scientists new to the field, as well as providing the more experienced researcher with a comprehensive resource covering the most relevant information in the field; a ‘one stop shop’ for all key references.
Book Synopsis Dean's Analytical Chemistry Handbook by : Pradyot Patnaik
Download or read book Dean's Analytical Chemistry Handbook written by Pradyot Patnaik and published by McGraw Hill Professional. This book was released on 2004-06-14 with total page 1193 pages. Available in PDF, EPUB and Kindle. Book excerpt: This essential on-the-job resource for the analytical chemist has been revised and updated with 40% new material. Readers will find all the conventional wet and instrumental techniques in one exhaustive reference along with all the critical data needed to apply them. Worked examples, troubleshooting tips, and numerous tables and charts are provided for easy access to the data. * The most up-to-date and complete guide to analytical chemistry available today * NEW: 3 major chapters on Analysis of Indoor Air, Analysis of Pesticides, Analysis of Trace Metals
Book Synopsis Oxide Nanostructures by : Avanish Kumar Srivastava
Download or read book Oxide Nanostructures written by Avanish Kumar Srivastava and published by CRC Press. This book was released on 2014-04-09 with total page 418 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanomaterials, their synthesis, and property studies have been an obsession with modern current physicists, chemist, and materials scientists for their vast array of technological implications and the remarkable way their properties are modified or enhanced when the size dimensions are reduced to the realm of nanometers. Although nanomaterials, for
Book Synopsis Self-healing Materials by : Martin D. Hager
Download or read book Self-healing Materials written by Martin D. Hager and published by Springer. This book was released on 2016-07-06 with total page 418 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science. The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics. Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist. Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned. Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students
Book Synopsis Imperfections in Crystals by : Hendrik Gerard Bueren
Download or read book Imperfections in Crystals written by Hendrik Gerard Bueren and published by . This book was released on 1960 with total page 748 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Advanced Research in Nanosciences for Water Technology by : Ram Prasad
Download or read book Advanced Research in Nanosciences for Water Technology written by Ram Prasad and published by Springer. This book was released on 2019-02-04 with total page 457 pages. Available in PDF, EPUB and Kindle. Book excerpt: The establishment of clean, safe water is one of the major challenges facing societies around the globe. The continued urbanization of human populations, the increasing manipulation of natural resources, and the resulting pollution are driving remarkable burden on water resources. Increasing demands for food, energy, and natural resources are expected to continue to accelerate in the near future in response to the demands of these changing human populations. In addition, the complexity of human activities is leading to a diversity of new chemical contaminants in the environment that represent a major concern for water managers. This will create increased pressure on both water quantity and quality, making it increasingly difficult to provide a sustainable supply of water for human welfare and activities. Although protection of water resources is the best long-term solution, we will also need innovative novel approaches and technologies to water treatment to ensure an adequate superior quality resource to meet these needs. Solving tomorrow’s water issues will require unique approaches that incorporate emerging new technologies. Great advances have been made in the area of nanotechnology. Due to their unique physical and chemical properties, nanomaterials are extensively used in antibacterial medical products, membrane filters, electronics, catalysts, and biosensors. Nanoparticles can have distinctly different properties from their bulk counterparts, creating the opportunity for new materials with a diversity of applications. Recent developments related to water treatment include the potential use of carbon nanotubes, nanocompositae, nanospheres, nanofibers, and nanowires for the removal of a diversity of chemical pollutants. By exploiting the assets and structure of these new materials, such as increased surface area, high reactivity, and photocatalytic action, it will be possible to create technologies that can be very efficient at removing and degrading environmental pollutants. Understanding and using these unique properties should lead to innovative, cost-effective applications for addressing the complexities of emerging needs for water treatment and protection. Although still in the early stages, research into the application of nanotechnology shows great promise for solving some of these major global water issues. This comprehensive text describes the latest research and application methods in this rapidly advancing field.
Book Synopsis Lanthanide Metal-Organic Frameworks by : Peng Cheng
Download or read book Lanthanide Metal-Organic Frameworks written by Peng Cheng and published by Springer. This book was released on 2015-01-19 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Structure and Bonding publishes critical reviews on topics of research concerned with chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors. Readership: research scientists at universities or in industry, graduate students.
