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Performance Of In Situ Chemical Oxidation Field Demonstrations At Doe Sites
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Book Synopsis Performance of in Situ Chemical Oxidation Field Demonstrations at DOE Sites by :
Download or read book Performance of in Situ Chemical Oxidation Field Demonstrations at DOE Sites written by and published by . This book was released on 1997 with total page 10 pages. Available in PDF, EPUB and Kindle. Book excerpt: Researchers at the Oak Ridge National Laboratory (ORNL) have been investigating the use of in situ chemical oxidation to remediate organic contaminants (VOCs, SVOCs, and PCBs) in soils and groundwater at the laboratory and field scales. Field scale design parameters (e.g., oxidant loading rates and oxidant delivery techniques) are often dictated by site conditions (e.g., soil properties and initial contaminant concentrations). Chemical destruction of organic compounds can be accomplished using a variety of oxidants. Recent research has involved field scale in situ chemical oxidation demonstrations using H2O2 and KMnO4 in conjunction with soil mixing as the oxidant delivery mechanism. A description of some of these fields activities and future field-scale work is presented here.
Book Synopsis In Situ Chemical Oxidation for Groundwater Remediation by : Robert L. Siegrist
Download or read book In Situ Chemical Oxidation for Groundwater Remediation written by Robert L. Siegrist and published by Springer Science & Business Media. This book was released on 2011-02-25 with total page 715 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume provides comprehensive up-to-date descriptions of the principles and practices of in situ chemical oxidation (ISCO) for groundwater remediation based on a decade of intensive research, development, and demonstrations, and lessons learned from commercial field applications.
Book Synopsis A Full-scale Demonstration of in Situ Chemical Oxidation Through Recirculation at the X-701B Site by :
Download or read book A Full-scale Demonstration of in Situ Chemical Oxidation Through Recirculation at the X-701B Site written by and published by . This book was released on 1997 with total page 110 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1996, researchers at Oak Ridge National Laboratory (ORNL) proposed an oxidant delivery technique involving injection and recirculation of the oxidant solution into a contaminated aquifer through multiple horizontal and vertical wells. This technique would be applicable to saturated, hydraulically conductive formations. In the spring of 1997, the Department of Energy (DOE) at the Portsmouth Gaseous Diffusion Plant (PORTS) agreed to collaborate with the DOE's Subsurface Contaminants Focus Area to conduct a field-scale treatability study using in situ chemical oxidation through recirculation (ISCOR). PORTS agreed to support the demonstration at the X-701B site where the technology can potentially be used to remediate TCE-contaminated groundwater and sediments. The ISCOR field demonstration took advantage of existing infrastructure and extensive site characterization data generated from previous field demonstrations at X-701B. The field test was implemented using a pair of previously installed horizontal wells that transect an area of DNAPL contamination. Groundwater was extracted from one horizontal well, pumped to an existing pump and treat facility, dosed with KMnO4, and re-injected into a parallel horizontal well approximately 90 ft away. The field demonstration lasted approximately one month. Treatment effectiveness was determined by comparing contaminant levels in pre-treatment, during, and post-treatment groundwater samples and pre- and post-treatment soil samples.
Book Synopsis Field Applications of In Situ Remediation Technologies by :
Download or read book Field Applications of In Situ Remediation Technologies written by and published by . This book was released on 1998 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt: Approximately 85% of the hazardous waste sites in the United States have contaminated ground water. The conventional approach for remediating contaminated ground water has been to extract the contaminated water, treat it above ground, and reinject or discharge the clean water ("pump- and-treat"). The recovered contaminants must be disposed of separately. It is becoming increasingly apparent that pump-and-treat technologies require considerable investment over extended period of time, and often times do not actually clean up the source of the contamination. Current policies and law stress "permanent" remedies over containment. Consequently, there is considerable interest and effort being expended on alternative, innovative treatment technologies for contaminated ground water. This report is one in a series that document recent pilot demonstrations and full-scale applications that either treat soil and ground water in place or increase the solubility and mobility of contaminants to improve their removal by other remediation technologies. It is hoped that this information will allow more regular consideration of new, less costly, and more effective technologies to address the problems associated with hazardous waste sites and petroleum.
Book Synopsis The Office of Environmental Management Technical Reports: A Bibliography by :
Download or read book The Office of Environmental Management Technical Reports: A Bibliography written by and published by DIANE Publishing. This book was released on 2001 with total page 245 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Office of Environmental Management's (EM) technical reports bibliography is an annual publication that contains information on scientific and technical reports sponsored by the Office of Environmental Management added to the Energy Science and Technology Database from July 1, 1994 through June 30, 1995. This information is divided into the following categories: Focus Areas, Cross-Cutting Programs, and Support Programs. In addition, a category for general information is included. EM's Office of Science and Technology sponsors this bibliography.
Book Synopsis Abiotic in Situ Technologies for Groundwater Remediation Conference by :
Download or read book Abiotic in Situ Technologies for Groundwater Remediation Conference written by and published by . This book was released on 2000 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Delivery and Mixing in the Subsurface by : Peter K. Kitanidis
Download or read book Delivery and Mixing in the Subsurface written by Peter K. Kitanidis and published by Springer Science & Business Media. This book was released on 2012-04-23 with total page 351 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is meant to provide the practitioner with information on the natural mixing processes occurring in aquifers as well as to describe basic strategies that can be implemented to enhance mixing in particular cases. For example, when it comes to mixing miscible liquids, one can speed up mixing in the formation by manipulating the flow such as through the use of recirculation wells. Furthermore, much of the mixing can be achieved partially within recirculation wells themselves, where contaminated water is admixed with additives, volatile products may be removed through a vapor mass exchanger, etc. Thus, adding mixing wells can significantly increase the performance of the delivery and mixing system and speed up the process of remediation.
Book Synopsis Laboratory Evaluation of In Situ Chemical Oxidation for Groundwater Remediation, Test Area North, Operable Unit 1-07B, Idaho National Engineering and Environmental Laboratory, Volume One - Main Text and Appendices A and B. by :
Download or read book Laboratory Evaluation of In Situ Chemical Oxidation for Groundwater Remediation, Test Area North, Operable Unit 1-07B, Idaho National Engineering and Environmental Laboratory, Volume One - Main Text and Appendices A and B. written by and published by . This book was released on 1999 with total page 200 pages. Available in PDF, EPUB and Kindle. Book excerpt: The laboratory investigation was performed to evaluate the feasibility of utilizing in situ chemical oxidation for remediating the secondary source of groundwater contaminants at the Idaho National Engineering and Environmental Laboratory (INEEL) Test Area North (TAN) Site. The study involved trichloroethene (TCE) contaminated media (groundwater, soil, and sludge) from TAN. The effectiveness of the selected oxidant, potassium permanganate (KMn0(sub4)), was evaluated at multiple oxidant and contaminant concentrations. Experiments were performed to determine the oxidant demand of each medium and the rate of TCE oxidation. The experiments were performed under highly controlled conditions (gas-tight reactors, constant 12C temperature). Multiple parameter were monitored over time including MN04 and TCE concentrations and pH.
Author :United States. Department of Energy. Office of Technology Development Publisher : ISBN 13 : Total Pages :232 pages Book Rating :4.0/5 ( download)
Book Synopsis FY 1993 Program Summary, Office of Research and Development, Office of Demonstration, Testing and Evaluation by : United States. Department of Energy. Office of Technology Development
Download or read book FY 1993 Program Summary, Office of Research and Development, Office of Demonstration, Testing and Evaluation written by United States. Department of Energy. Office of Technology Development and published by . This book was released on 1994 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Principles and Practices of in Situ Chemical Oxidation Using Permanganate by : Robert L. Siegrist
Download or read book Principles and Practices of in Situ Chemical Oxidation Using Permanganate written by Robert L. Siegrist and published by . This book was released on 2001 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt: - Chapter 1: An overview of chemical oxidation including its development and application for in situ treatment of contaminated sites. The oxidation chemistry of Fenton's reagent, permanganate, and ozone are highlighted along with optional methods of oxidant delivery for in situ application. The results of lab-and field-scale applications are summarized.- Chapter 2: A description of the principles and processes of chemical oxidation using potassium or sodium permanganate for organic chemical degradation, including reaction stoichiometry, equilibria, and kinetics, as well as the effects of environmental factors.- Chapter 3: Information provided on the effects of permanganate on the behavior of metals.- Chapter 4: A discussion of the potential for permeability loss and other secondary effects during in situ oxidation using permanganate.- Chapter 5: A description of optional methods of oxidant delivery for in situ remediation.- Chapter 6: A description of a process for evaluation, design, and implementation of permanganate systems.- Chapter 7: A detailed description of five different applications of an in situ chemical oxidation using potassium or sodium permanganate.- Chapter 8: Highlights of the current status and future directions of this remediation technology.
Book Synopsis Characterization of Subsurface Petroleum Contaminants and Their Chemical and Biological Remediation with Redox Manipulation by : Guibo Xie
Download or read book Characterization of Subsurface Petroleum Contaminants and Their Chemical and Biological Remediation with Redox Manipulation written by Guibo Xie and published by . This book was released on 2001 with total page 418 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis EPA ETV International Forum Meeting Summary July 1314, 2005 Washington, DC by :
Download or read book EPA ETV International Forum Meeting Summary July 1314, 2005 Washington, DC written by and published by DIANE Publishing. This book was released on with total page 103 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Wiley's Remediation Technologies Handbook by : Jay H. Lehr
Download or read book Wiley's Remediation Technologies Handbook written by Jay H. Lehr and published by John Wiley & Sons. This book was released on 2004-07-22 with total page 1283 pages. Available in PDF, EPUB and Kindle. Book excerpt: Wiley's Remediation Technologies Handbook: Major Contaminant Chemicals and Chemical Groups, extracted from the Enviroglobe database, consists of 368 chemicals and chemical groups. This book lists in alphabetical order these chemical and chemical groups along with the numerous technologies, many of which are patented, or trademarked techniques, to remediate them. A short description of each of these technologies is provided along with appropriate references. Wiley's Remediation Technologies Handbook: Major Contaminant Chemicals and Chemical Groups: Covers the most important chemical and chemical groups that are found to pollute the environment, and the ways to remediate them. Gives succinct abstract describing the numerous technologies used to clean-up a wide range of pollutants. Provides the uses and limitations of each technique. Note: CD-ROM/DVD and other supplementary materials are not included as part of eBook file.
Book Synopsis In Situ Chemical Oxidation Through Lance Permeation at the Portsmouth Gaseous Diffusion Plant (PORTS). by :
Download or read book In Situ Chemical Oxidation Through Lance Permeation at the Portsmouth Gaseous Diffusion Plant (PORTS). written by and published by . This book was released on 2003 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: In situ chemical oxidation through lance permeation (ISCO-LP) is an emerging remediation technology in which chemical oxidants (such as potassium or sodium permanganate) are delivered to the subsurface using vertical lance-like injectors. It is applicable to sites with oxidizable contaminants such as chlorinated solvents and fuel hydrocarbons. Because vertical lance injections can be deployed at relatively close spacing, ISCO-LP potentially can be used to clean-up contamination in low-permeability media. This document provides information that can help potential users determine whether ISCO-LP would apply to a particular environmental management problem. It contains a general description of the technology (Section 2), performance data from a field demonstration (Section 3), an assessment of technology applicability (Section 4), a summary of cost elements (Section 5), and a list of regulatory, environmental safety and health issues (Section 6). It is patterned after the Innovative Technology Summary Reports (ITSR) published by the Department of Energy's (DOE) Office of Science and Technology under the Subsurface Contaminants Focus Area (SCFA). As in the previously published ITSRs, the technology described in this report was developed through funding from SCFA. Most of the information contained in this report was obtained from a field demonstration of ISCO-LP conducted in July-August 2000 at DOE's Portsmouth Gaseous Diffusion Plant (PORTS). The field test was not completed due to an accident that caused a field worker serious injuries. Although performance assessment data are very limited, the field test highlighted important health and safety issues that must be considered by site managers and technology vendors interested in implementing ISCO-LP.
Book Synopsis Push-pull Tests to Support in Situ Chemical Oxidation System Design by : Ashley Mathai
Download or read book Push-pull Tests to Support in Situ Chemical Oxidation System Design written by Ashley Mathai and published by . This book was released on 2011 with total page 90 pages. Available in PDF, EPUB and Kindle. Book excerpt: The problems associated with the contamination of groundwater environments by non-aqueous phase liquids (NAPLs) such as chlorinated solvents, gasoline and manufacturing gas plant (MGP) residuals, including their distribution and persistence, are well accepted. The treatment of groundwater by in situ chemical oxidation (ISCO) relies on the oxidation potential of chemical reagents to destroy harmful organic compounds. The interaction of these oxidants with target and non-target compounds in the subsurface will help determine effectiveness and efficiency of an ISCO treatment system. Push-pull tests (PPTs) have the utility to estimate key properties in situ and allow for sampling a larger volume of aquifer to yield more representative estimates as compared to conventional bench-scale tests. The scale and cost-effectiveness of a PPT make it an ideal tool to collect valuable information on subsurface system behaviour so that uncertainties can be minimized. The use of PPTs to provide insight into treatment expectations or to support the design of an ISCO system requires a suitable interpretation tool. A multi-species numerical model ('PPT-ISCO') in a radial coordinate system was developed to simulate a PPT with the injection of a conservative tracer and oxidant (persulfate or permanganate) into the saturated zone of a porous medium environment. The pore space may contain variable amounts of immobile, multicomponent, residual NAPL. The aquifer material contains a natural organic matter (NOM) fraction and/or other oxidizable aquifer material (OAM) species. The model is capable of simulating mass transport for an arbitrary number of conservative and reactive tracers and NAPL constituents subjected to chemical reactions. The ability of PPTs to capture the in situ natural oxidant interaction (NOI) was tested with PPTISCO. Breakthrough curve (BTC) data collected from permanganate and persulfate PPTs conducted in the field were compared to simulated BTCs by assigning the same field operational parameters to the model and applying NOI kinetic information obtained from batch tests. These tests confirmed the usability of the model and PPTs to obtain the NOI kinetics from PPT BTCs. The sensitivity of PPT BTCs to variations in the field operating and NOI parameters were investigated. The results of varying the field operating parameters indicated that the oxidant BTCs could be scaled to match varying injection and extraction flow rates. Variations in NOI parameters revealed that the permanganate BTC is primarily controlled by the permanganate fast reaction rate coefficient and the quantity of OAM present in the aquifer. The spatial profiles of OAM across the test zone revealed that the majority of the OAM consumption is from the fast fraction and occurs in the vicinity of the well where the permanganate concentration is greatest. An estimate of the permanganate fast reaction rate coefficient can be obtained from a permanganate PPT BTC by employing the model to simulate the PPT with the operational parameters (used in the field) and literature estimates of the remaining NOI parameters. Calibration between the simulated and observed BTCs can be undertaken to adjust the permanganate fast reaction rate coefficient to fit the permanganate PPT BTC. Persulfate NOI sensitivity investigations revealed that persulfate PPT BTCs can be characterized by a concentration plateau at early times as a result of the increased ionic strength in the area around the injection well. The ionic strength is primarily controlled by the injected persulfate concentration, and as persulfate degrades into sulphate and acid, the ionic strength is enhanced. Graphical analysis of the BTC revealed that an underestimated value of the persulfate degradation rate coefficient can be obtained from the PPT BTC. A more representative estimate of the persulfate degradation rate coefficient can be achieved after fitting the field BTC to the simulated results, applying the underestimated value as a starting point. PPTs investigating ISCO treatability have the ability to provide insight into the effect of the NOI on the oxidation of target compounds, site-specific oxidant dosage requirements and NAPL treatment expectations. NAPL component BTCs from treatability PPTs are primarily controlled by the mass in the fast region, and the fast region mass transfer rate coefficient. Oxidation estimates extracted from NAPL component BTCs were shown to accurately approximate the mass of each NAPL component oxidized when compared to model calculations. The mass of NAPL oxidized for each of the components yields a site-specific oxidant dosage. This estimate exceeds what is prescribed by the stoichiometry between permanganate and the contaminant of concern due to the effect of the NOI. The utility of PPTs to study and quantify the interaction between injected oxidants and the aquifer material has been demonstrated with PPT-ISCO. In addition, PPT-ISCO has revealed that treatability PPTs can be tailored to investigate the dosage requirements and treatment expectations of residual NAPLs. Results from this effort will be used to support ongoing field research exploring the use of PPTs to assist in understanding the competing subsurface processes affecting ISCO applications.
Download or read book Remediation Case Studies written by and published by . This book was released on 1997 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Groundwater and Soil Cleanup by : National Research Council
Download or read book Groundwater and Soil Cleanup written by National Research Council and published by National Academies Press. This book was released on 1999-11-21 with total page 301 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a comprehensive, up-to-date review of technologies for cleaning up contaminants in groundwater and soil. It provides a special focus on three classes of contaminants that have proven very difficult to treat once released to the subsurface: metals, radionuclides, and dense nonaqueous-phase liquids such as chlorinated solvents. Groundwater and Soil Cleanup was commissioned by the Department of Energy (DOE) as part of its program to clean up contamination in the nuclear weapons production complex. In addition to a review of remediation technologies, the book describes new trends in regulation of contaminated sites and assesses DOE's program for developing new subsurface cleanup technologies.
