New Fluorinating Agents In Organic Synthesis

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New Fluorinating Agents in Organic Synthesis

Author : L.A. Alekseeva
Publisher : Springer
ISBN 13 :
Total Pages : 306 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis New Fluorinating Agents in Organic Synthesis by : L.A. Alekseeva

Download or read book New Fluorinating Agents in Organic Synthesis written by L.A. Alekseeva and published by Springer. This book was released on 1989-11-02 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book summarizes and gives a critical analysis of the literature on the use of reactive covalent fluorides (organic and inorganic) for the synthesis of fluoroorganic compounds. New methods of using SF4 for the fluorination of complex polyfunctional organic compounds are described. The prospects are shown for the selective fluorinations of complex compounds with non-traditional fluorinating agents (halogen fluorides, XeF2, fluorosulphuranes, N-F- and O-F-containing compounds). The book gives recommendations for the practical use of these fluorides, and typical synthetic procedures. It introduces the beginner to modern methods of fluorination and helps qualified scientists and technologists to choose the optimal methods of synthesis. Using the fluorinating agents described in this book, it is possible to synthesize various fluorine-containing substances.

Advances in Organic Synthesis

Author : Atta-ur-Rahman
Publisher : Bentham Science Publishers
ISBN 13 : 1608051986
Total Pages : 594 pages
Book Rating : 4.6/5 (8 download)

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Book Synopsis Advances in Organic Synthesis by : Atta-ur-Rahman

Download or read book Advances in Organic Synthesis written by Atta-ur-Rahman and published by Bentham Science Publishers. This book was released on 2011-01-10 with total page 594 pages. Available in PDF, EPUB and Kindle. Book excerpt: "The volume focuses on recent advances in organofluorine chemistry directed towards selective fluorine introduction into various target molecules, employing both traditional and contemporary, electrophilic and nucleophilic, fluorinating agents. It brings t"

Aromatic Fluorination

Author : James H. Clark
Publisher : CRC Press
ISBN 13 : 1351086782
Total Pages : 198 pages
Book Rating : 4.3/5 (51 download)

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Book Synopsis Aromatic Fluorination by : James H. Clark

Download or read book Aromatic Fluorination written by James H. Clark and published by CRC Press. This book was released on 2018-01-10 with total page 198 pages. Available in PDF, EPUB and Kindle. Book excerpt: Academia and industry join forces in Aromatic Fluorination, as an expert from each domain contributes to this new text on fluorination of carbocyclic and heterocyclic rings. The book begins with a discussion of fluorine's unique combination of properties, including size, electronic effects, and hydrophobicity, as well as the historical development of its product applications. It explains methods for introducing fluorine into an aromatic ring, focusing on nucleophilic fluorine transfer reactions. The role of catalysts, solvents, and other variables are examined, and the scope and limitations of the methods are discussed. Of particular interest to those working in non-specialist laboratories, Aromatic Fluorination includes detailed descriptions of the new electrophilic routes to fluoroaromatics, in addition to traditional routes and alternative methods involving radical chemistry. Because one of the most important fluorine-containing substituent is CF3, the book explains routes to benzotrifluorides (ArCF3), including traditional industrial methods and modern alternatives employing C-1 halofluorocarbons and other fluoroaliphatics. An alternative to CF3 is CF3S, and several methods of synthesizing aromatic CF3S-containing molecules are described. Since the successful development and diverse applications of aromatic fluorine compounds have led to the search for new compounds and novel substituents, the incorporation of other substituents is also explored. Aromatic Fluorination concludes with discussion of the factors responsible for the successful development of pharmaceutical, agrochemical and liquid crystal applications and the potential for applications in high-performance polymers and other areas. This section also describes in detail important industrial aromatic fluorination processes and the relative merits of different process technologies and their costs.

Fluorine in Organic Chemistry

Author : Richard D. Chambers
Publisher : CRC Press
ISBN 13 : 9780849317903
Total Pages : 426 pages
Book Rating : 4.3/5 (179 download)

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Book Synopsis Fluorine in Organic Chemistry by : Richard D. Chambers

Download or read book Fluorine in Organic Chemistry written by Richard D. Chambers and published by CRC Press. This book was released on 2004 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: The introduction of carbon-fluorine bonds into organic compounds can profoundly influence their chemical and physical properties when compared to their non-fluorine-containing analogues, leading to a range of man-made materials with highly desirable properties. These molecules are of interest across the wide spectrum of industrial and academic organic chemistry, from pharmaceuticals, through fine and specialty chemicals to polymers. From Prozac to Teflon, many of the most important products of the chemical and life-science industries rely on organic fluorine chemistry for their useful properties. This book covers both the preparative methodologies and chemical properties of partially and highly fluorinated organic systems.

Fluorination

Author : Jinbo Hu
Publisher : Springer
ISBN 13 : 9789811038952
Total Pages : 0 pages
Book Rating : 4.0/5 (389 download)

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Book Synopsis Fluorination by : Jinbo Hu

Download or read book Fluorination written by Jinbo Hu and published by Springer. This book was released on 2020-08-12 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume reviews the recent advances in formation of C-F bonds and X-F bonds (X = heteroatom) to produce useful fluorinated molecules for pharmaceuticals, materials and more. Reactions and methods associated with fluorination, including monofluorination, difluorination, trifluorination and other polyfluorination that have emerged within the past few years are systematically discussed. With contributions from front-line researchers in this field from both academia and industry, this book provides a valuable resource for scholars, graduate students as well as professionals.

Synthetic Aspects of the Fluorination of Organic Compounds

Author : G. G. Furin
Publisher : Taylor & Francis US
ISBN 13 : 9783718651573
Total Pages : 158 pages
Book Rating : 4.6/5 (515 download)

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Book Synopsis Synthetic Aspects of the Fluorination of Organic Compounds by : G. G. Furin

Download or read book Synthetic Aspects of the Fluorination of Organic Compounds written by G. G. Furin and published by Taylor & Francis US. This book was released on 1991 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organic Fluorine Chemistry

Author : William Arthur Sheppard
Publisher :
ISBN 13 :
Total Pages : 636 pages
Book Rating : 4.:/5 (43 download)

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Book Synopsis Organic Fluorine Chemistry by : William Arthur Sheppard

Download or read book Organic Fluorine Chemistry written by William Arthur Sheppard and published by . This book was released on 1969 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Emerging Fluorinated Motifs

Author : Dominique Cahard
Publisher : John Wiley & Sons
ISBN 13 : 3527824324
Total Pages : 872 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Emerging Fluorinated Motifs by : Dominique Cahard

Download or read book Emerging Fluorinated Motifs written by Dominique Cahard and published by John Wiley & Sons. This book was released on 2020-04-03 with total page 872 pages. Available in PDF, EPUB and Kindle. Book excerpt: A must-have resource for all the researchers working in the organofluorine and related fields This timely two-volume set uniquely focuses on emerging fluorinated motifs beyond R-CF3 and R-F, like R-CF2H, R-OCF3, R-SCF3 and R-SF5. It also offers descriptions of the properties, synthesis, and applications of these emerging fluorinated motifs in order to help readers design new chemical entities, while providing new interest for researchers in organofluorine chemistry and new tools for those in other areas. Emerging Fluorinated Motifs: Synthesis, Properties and Applications begins with a description of carbon-linked fluorine-containing groups that include monofluoromethyl and difluoromethyl groups. It then details combinations of heteroatoms, Oxygen, Sulfur, Selenium, Nitrogen, and Phosphorus with fluorine-containing groups, outlining subsections of the most popular current motifs. Fluoroalkyl ethers, thioethers, and the recent blossoming of the SF5 unit is covered. Other chapters look at: selenium-linked fluorine-containing motifs; construction of N?CF2H, N?CF3, N?CH2CF3 motifs; and the synthesis and applications of P¿Rf-containing molecules. -Focuses on the synthesis, properties, and applications of emerging fluorinated motifs -Covers carbon-linked fluorine-containing motifs, oxygen-linked fluorine-containing motifs, sulfur-linked fluorine-containing motifs, and more -Appeals to academic and industrial researchers working in organic chemistry, medicinal chemistry, food chemistry, and materials science -Edited by world-renowned experts in organofluorine chemistry Emerging Fluorinated Motifs is intended for academic research institutes, university libraries, researchers, graduate students, postdoctors, and researchers in the chemical industry.

Emerging Fluorinated Motifs, 2 Volume Set

Author : Dominique Cahard
Publisher : John Wiley & Sons
ISBN 13 : 3527346813
Total Pages : 870 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Emerging Fluorinated Motifs, 2 Volume Set by : Dominique Cahard

Download or read book Emerging Fluorinated Motifs, 2 Volume Set written by Dominique Cahard and published by John Wiley & Sons. This book was released on 2020-07-13 with total page 870 pages. Available in PDF, EPUB and Kindle. Book excerpt: A must-have resource for all the researchers working in the organofluorine and related fields This timely two-volume set uniquely focuses on emerging fluorinated motifs beyond R-CF3 and R-F, like R-CF2H, R-OCF3, R-SCF3 and R-SF5. It also offers descriptions of the properties, synthesis, and applications of these emerging fluorinated motifs in order to help readers design new chemical entities, while providing new interest for researchers in organofluorine chemistry and new tools for those in other areas. Emerging Fluorinated Motifs: Synthesis, Properties and Applications begins with a description of carbon-linked fluorine-containing groups that include monofluoromethyl and difluoromethyl groups. It then details combinations of heteroatoms, Oxygen, Sulfur, Selenium, Nitrogen, and Phosphorus with fluorine-containing groups, outlining subsections of the most popular current motifs. Fluoroalkyl ethers, thioethers, and the recent blossoming of the SF5 unit is covered. Other chapters look at: selenium-linked fluorine-containing motifs; construction of N?CF2H, N?CF3, N?CH2CF3 motifs; and the synthesis and applications of P¿Rf-containing molecules. -Focuses on the synthesis, properties, and applications of emerging fluorinated motifs -Covers carbon-linked fluorine-containing motifs, oxygen-linked fluorine-containing motifs, sulfur-linked fluorine-containing motifs, and more -Appeals to academic and industrial researchers working in organic chemistry, medicinal chemistry, food chemistry, and materials science -Edited by world-renowned experts in organofluorine chemistry Emerging Fluorinated Motifs is intended for academic research institutes, university libraries, researchers, graduate students, postdoctors, and researchers in the chemical industry.

Experimental Methods in Organic Fluorine Chemistry

Author : Tomoya Kitazume
Publisher : Routledge
ISBN 13 : 1351449230
Total Pages : 278 pages
Book Rating : 4.3/5 (514 download)

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Book Synopsis Experimental Methods in Organic Fluorine Chemistry by : Tomoya Kitazume

Download or read book Experimental Methods in Organic Fluorine Chemistry written by Tomoya Kitazume and published by Routledge. This book was released on 2019-06-14 with total page 278 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the fields of biologically active materials and functional materials, fluorinated organic materials are becoming a focus of significant interest. Over the past decade synthetic methodologies and reagents in fluorine chemistry have been developed, especially stereocontrolled synthetic methods, enzymatic resolution to synthesize enantiomers, fluoromethylated reagents, and fluorination reagents. These methods have contributed to the opening of new pathways for fluorinated materials. However, few fluorinated materials have been put to commercial use. Furthermore, there remain problems to be solved, such as the handling of the materials, availability of reagents and selectivity (stereo-, regio-, and/or chemoselectivity). Research chemists, technical engineers, and graduate students in all branches of chemistry, pharmaceutics, and material science interested in fluorinated materials need to know detailed experimental procedures of how to synthesize the target fluorinated materials. This volume summarizes the chemical and microbial methods for obtaining functionalized fluorinated materials for use as building blocks; detailed experimental methods (reaction conditions, solvent, temperature, handling techniques, etc.); and the stereoview (possible absolute configuration) of the structures with spectral data. Mono-, di-, tri-, and polyfluorinated materials derived from fluorinating agents, fluoromethylated reagents and building blocks are summarized. A chemical name index, molecular formula index, and reagent index are also included. The publication of this monograph will provide access to the enormous possibilities in fluorine chemistry, biological material chemistry, and functionalized material chemistry.

Chemistry of Organic Fluorine Compounds

Author : Milos Hudlicky
Publisher : Wiley-VCH
ISBN 13 :
Total Pages : 1328 pages
Book Rating : 4.X/5 (2 download)

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Book Synopsis Chemistry of Organic Fluorine Compounds by : Milos Hudlicky

Download or read book Chemistry of Organic Fluorine Compounds written by Milos Hudlicky and published by Wiley-VCH. This book was released on 1995-08 with total page 1328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides complete coverage of the chemistry of organic fluorine compounds. Topics include fluorinating agents, fluorination processes, reactions of fluorinated compounds, modern analytical methods, and properties and applications of fluorinated compounds. Offers a critical review of the literature and provides over 4,500 references. Updates the 1976 volume Chemistry of Organic Fluorine Compounds.

Advances in Organic Synthesis

Author : Atta-ur-Rahman
Publisher :
ISBN 13 : 9781608056446
Total Pages : pages
Book Rating : 4.0/5 (564 download)

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Book Synopsis Advances in Organic Synthesis by : Atta-ur-Rahman

Download or read book Advances in Organic Synthesis written by Atta-ur-Rahman and published by . This book was released on 2011-01-10 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: "The volume focuses on recent advances in organofluorine chemistry directed towards selective fluorine introduction into various target molecules, employing both traditional and contemporary, electrophilic and nucleophilic, fluorinating agents. It brings t"

Efficient Preparations of Fluorine Compounds

Author : Herbert W. Roesky
Publisher : John Wiley & Sons
ISBN 13 : 1118409442
Total Pages : 490 pages
Book Rating : 4.1/5 (184 download)

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Book Synopsis Efficient Preparations of Fluorine Compounds by : Herbert W. Roesky

Download or read book Efficient Preparations of Fluorine Compounds written by Herbert W. Roesky and published by John Wiley & Sons. This book was released on 2012-10-11 with total page 490 pages. Available in PDF, EPUB and Kindle. Book excerpt: The definitive guide to creating fluorine-based compounds—and the materials of tomorrow Discovered as an element by the French chemist Henri Moissan in 1886, through electrolysis of potassium fluoride in anhydrous hydrogen fluoride—"le fluor," or fluorine, began its chemical history as a substance both elusive and dangerous. With a slight pale yellow hue, fluorine is at room temperature a poisonous diatomic gas. Resembling a spirit from a chemical netherworld, fluorine is highly reactive, difficult to handle, yet very versatile as a reagent—with the power to form compounds with almost any other element. Comprising 20% of pharmaceutical products and 30% of agrochemical compounds, as well as playing a key role in electric cars, electronic devices, and space technology, compounds containing fluorine have grown in importance across the globe. Learning how to safely handle fluorine in the preparation of innovative new materials—with valuable new properties—is of critical importance to chemists today. Bringing together the research and methods of leading scientists in the fluorine field, Efficient Preparations of Fluorine Compounds is the definitive manual to creating, and understanding the reaction mechanisms integral to a wide variety of fluorine compounds. With sixty-eight contributed chapters, the book's extensive coverage includes: Preparation of Elemental Fluorine Synthesis Methods for Exotic Inorganic Fluorides with Varied Applications Introduction of Fluorine into Compounds via Electrophilic and Nucleophilic Reactions Direct Fluorination of Organic Compounds with Elemental Fluorine Efficient Preparations of Bioorganic Fluorine Compounds Asymmetric Fluorocyclization Reactions Preparations of Rare Earth Fluorosulfides and Oxyfluorosulfides The book offers methods and results that can be reproduced by students involved in advanced studies, as well as practicing chemists, pharmaceutical scientists, biologists, and environmental researchers. The only chemical resource of its kind, Efficient Preparations of Fluorine Compounds—from its first experiment to its last—is a unique window into the centuries old science of fluorine and the limitless universe of fluorine-based compounds.

Guide to Fluorine NMR for Organic Chemists

Author : William R. Dolbier, Jr.
Publisher : John Wiley & Sons
ISBN 13 : 1118831098
Total Pages : 472 pages
Book Rating : 4.1/5 (188 download)

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Book Synopsis Guide to Fluorine NMR for Organic Chemists by : William R. Dolbier, Jr.

Download or read book Guide to Fluorine NMR for Organic Chemists written by William R. Dolbier, Jr. and published by John Wiley & Sons. This book was released on 2016-08-24 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: Following its well-received predecessor, this book offers an essential guide to chemists for understanding fluorine in spectroscopy. With over 1000 compounds and 100 spectra, the second edition adds new data – featuring fluorine effects on nitrogen NMR, chemical shifts, and coupling constants. • Explains how to successfully incorporate fluorine into target molecules and utilize fluorine substituents to structurally characterize organic compounds • Includes new data on nitrogen NMR, focusing on N-15, to portray the influence of fluorine upon nitrogen NMR chemical shifts and coupling constants • Expands on each chapter from the first edition with additional data and updated discussion from recent findings • "The flawless ordering of material covered in this stand-alone volume is such that information can be found very easily." – Angewandte Chemie review of the first edition, 2010

Modern Synthesis Processes and Reactivity of Fluorinated Compounds

Author : Henri Groult
Publisher : Elsevier
ISBN 13 : 0128037903
Total Pages : 760 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Modern Synthesis Processes and Reactivity of Fluorinated Compounds by : Henri Groult

Download or read book Modern Synthesis Processes and Reactivity of Fluorinated Compounds written by Henri Groult and published by Elsevier. This book was released on 2016-11-04 with total page 760 pages. Available in PDF, EPUB and Kindle. Book excerpt: Modern Synthesis Processes and Reactivity of Fluorinated Compounds focuses on the exceptional character of fluorine and fluorinated compounds. This comprehensive work explores examples taken from all classes of fluorine chemistry and illustrates the extreme reactivity of fluorinating media and the peculiar synthesis routes to fluorinated materials. The book provides advanced and updated information on the latest synthesis routes to fluorocompounds and the involved reaction mechanisms. Special attention is given to the unique reactivity of fluorine and fluorinated media, along with the correlation of those properties to valuable applications of fluorinated compounds. Contains quality content edited, and contributed, by leading scholars in the field Presents applied guidance on the preparation of original fluorinated compounds, potentially transferable from the lab scale to industrial applications Provides practical synthesis information for a wide audience interested in fluorine compounds in many branches of chemistry, materials science, and physics

The Curious World of Fluorinated Molecules

Author : Konrad Seppelt
Publisher : Elsevier
ISBN 13 : 0128198753
Total Pages : 456 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis The Curious World of Fluorinated Molecules by : Konrad Seppelt

Download or read book The Curious World of Fluorinated Molecules written by Konrad Seppelt and published by Elsevier. This book was released on 2020-10-30 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Curious World of Fluorinated Molecules: Molecules Containing Fluorine is the sixth volume in the Progress in Fluorine Science series and is edited by the world-renowned scientist Konrad Seppelt. Dr. Seppelt brings together a team of global experts to uncover the multifaceted nature of the most electronegative element in the Periodic Table. The book explores the fascinating world of unpredictable, fluorine-containing molecules through their discoveries, path to recognition, current state of the art, and impact on the broader fields of fluorinated materials development. This volume will inspire and energize researchers, future scientists, and educators working in fluorine chemistry. Highlights the current state of fundamental research of fluorinated molecules that either helped to rewrite the fundamental rules of chemistry or impacted modern material technologies Features contributions from a global team of leading experts in the field Provides a unique combination of the historical and current examples that explain the unique role that fluorine can play in advancing our understanding of the scientific method at large

Late-Stage Fluorination of Bioactive Molecules and Biologically-Relevant Substrates

Author : Al Postigo
Publisher : Elsevier
ISBN 13 : 9780128129586
Total Pages : 0 pages
Book Rating : 4.1/5 (295 download)

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Book Synopsis Late-Stage Fluorination of Bioactive Molecules and Biologically-Relevant Substrates by : Al Postigo

Download or read book Late-Stage Fluorination of Bioactive Molecules and Biologically-Relevant Substrates written by Al Postigo and published by Elsevier. This book was released on 2018-09-10 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Late-Stage Fluorination of Bioactive Molecules and Biologically-Relevant Substrates reviews how the use of these techniques on compounds with already known and relevant biological activity can provide new pharmaceutical leads with improved medicinal properties. The fluorination strategies discussed take into account both conventional and novel reagents, including nucleophilic, electrophilic, those of a radical nature, and diverse families of organic compounds, such as (hetero) aromatic rings and aliphatic substrates. Drawing on the authors' expert knowledge, this book provides researchers with a broad set of applicable methods to use in their work.