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Molecular Orbital Studies Of Metal Metal Bonding In Bimetallic Organoactinide Compounds
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Book Synopsis Molecular Orbital Studies of Metal-metal Bonding in Bimetallic Organoactinide Compounds by : Kevin J. Novo-Gradac
Download or read book Molecular Orbital Studies of Metal-metal Bonding in Bimetallic Organoactinide Compounds written by Kevin J. Novo-Gradac and published by . This book was released on 1989 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Metal-Metal Bonds and Clusters in Chemistry and Catalysis by : John P. Fackler Jr.
Download or read book Metal-Metal Bonds and Clusters in Chemistry and Catalysis written by John P. Fackler Jr. and published by Springer Science & Business Media. This book was released on 2013-11-22 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book contains a series of papers and abstracts from the 7th Industry-University Cooperative Chemistry Program symposium held in the spring of 1989 at Texas A&M University. The symposium was larger than previous IUCCP symposia since it also celebrated the 25 years that had elapsed since the initial discovery by F. A. Cotton and his co-workers of the existence of metal-metal quadruple bonds. Cotton's discovery demonstrated that multiple bonding in inorganic systems is not governed by the same constraints observed in organic chemistry regarding s and p orbital involvement. The d orbitals are involved in the multiple bonding description. The quadruple bond involves considerable d orbital overlap between adjacent metal centers. Part I of this series of papers focuses upon the impact of this discovery and describes further contributions to the development of the field. Multiple metal-metal bonding now is known to permeate broad areas of transition metal chemistry. The understanding of metal-metal bonding that developed as a result of the discovery of multiple metal-metal bonding awakened a new chemistry involving metal clusters. Clusters were defined by Cotton to be species containing metal-metal bonding. Clusters in catalysis therefore seemed a logical grouping of papers in this symposium. Clusters play an every increasing role in the control of chemical reactions. Part II of this book describes some of the interesting new developments in this field. In Part III the papers examine the role clusters play in describing and understanding solid state materials.
Book Synopsis Molecular Orbital Studies of the Electronic Structure, Bonding and Reactivities of Heterobimetallic Compounds by : Gene C. Hancock
Download or read book Molecular Orbital Studies of the Electronic Structure, Bonding and Reactivities of Heterobimetallic Compounds written by Gene C. Hancock and published by . This book was released on 1985 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Molecular Orbital Studies of Bonding and Reacitivity in Organometallic Transition Metal Complexes and Cluster Compounds by : Birgitte E. R. Schilling
Download or read book Molecular Orbital Studies of Bonding and Reacitivity in Organometallic Transition Metal Complexes and Cluster Compounds written by Birgitte E. R. Schilling and published by . This book was released on 1979 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Molecular Metal-Metal Bonds by : Stephen T. Liddle
Download or read book Molecular Metal-Metal Bonds written by Stephen T. Liddle and published by John Wiley & Sons. This book was released on 2016-03-16 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: Systematically covering all the latest developments in the field, this is a comprehensive and handy introduction to metal-metal bonding. The chapters follow a uniform, coherent structure for a clear overview, allowing readers easy access to the information. The text covers such topics as synthesis, properties, structures, notable features, reactivity and examples of applications of the most important compounds in each group with metal-metal bonding throughout the periodic table. With its general remarks at the beginning of each chapter, this is a must-have reference for all molecular inorganic chemists, including PhD students and postdocs, as well as more experienced researchers.
Book Synopsis Molecular Orbital Studies of Bonding, Structures, and Reactions of Organometallic and Inorganic Complexes of Transition Metals by : Nenad M. Kostić
Download or read book Molecular Orbital Studies of Bonding, Structures, and Reactions of Organometallic and Inorganic Complexes of Transition Metals written by Nenad M. Kostić and published by . This book was released on 1982 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Molecular Orbitals of Transition Metal Complexes by : Yves Jean
Download or read book Molecular Orbitals of Transition Metal Complexes written by Yves Jean and published by OUP Oxford. This book was released on 2005-03-24 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book starts with the most elementary ideas of molecular orbital theory and leads the reader progressively to an understanding of the electronic structure, geometry and, in some cases, reactivity of transition metal complexes. The qualitative orbital approach, based on simple notions such as symmetry, overlap and electronegativity, is the focus of the presentation and a substantial part of the book is associated with the mechanics of the assembly of molecular orbital diagrams. The first chapter recalls the basis for electron counting in transition metal complexes. The main ligand fields (octahedral, square planar, tetrahedral, etc.) are studied in the second chapter and the structure of the "d block" is used to trace the relationships between the electronic structure and the geometry of the complexes. The third chapter studies the change in analysis when the ligands have pi-type interactions with the metal. All these ideas are then used in the fourth chapter to study a series of selected applications of varying complexity (e.g. structure and reactivity). The fifth chapter deals with the "isolobal analogy" which points out the resemblance between the molecular orbitals of inorganic and organic species and provides a bridge between these two subfields of chemistry. The last chapter is devoted to a presentation of basic Group Theory with applications to some of the complexes studied in the earlier chapters.
Book Synopsis Relativistic Theory of Atoms and Molecules II by : Pekka Pyykkö
Download or read book Relativistic Theory of Atoms and Molecules II written by Pekka Pyykkö and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 486 pages. Available in PDF, EPUB and Kindle. Book excerpt: Relativistic effects are of major importance for understan- ding the properties of heavier atoms and molecules. This book is still the only comprehensive bibliography on related calculations. The material is organized by subject into ta- bles containing a concise characterization. Together with Volume I (Lecture Notes in Chemistry Vol. 41, ISBN 3-540-17167-3) the literature until 1992 is now covered and 6577 references, with titles, are given in the two books. The book will provide aconvenient reference for theoretical chemists and atomic and molecular physicists interested in the properties of heavier elements. Contents: Introduction - One-particle problems - Quantum electrodynamical effects - Multielectron atoms: methods - Multielectron atoms: results - Symmetry - Molecular calcula- tions - Solid-state theory - Relativistic effects and heavy- element chemistry - Corrections to Volume I - Some comments on notations and terminology - List of acronyms and symbols - Bibliography.
Book Synopsis Organometallic Bonding and Reactivity by : J.M. Brown
Download or read book Organometallic Bonding and Reactivity written by J.M. Brown and published by Springer. This book was released on 2003-07-01 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt: The making and breaking of carbon-metal bonds is fundamental to all the processes of organometallic chemistry and metal mediated homogeneous or heterogeneous catalysis. The ever expanding scope of highly specific stoichiometric and catalytic transformations or organic substrates involving metals requires a thorough physical and theoretical understanding of fundamental principles of organometallic structure and reactivity. Diffraction experiments form the basis of tailoring the molecular architecture of organometallic compounds for specific functions. Mass spectrometric techniques possess the power to provide direct information on the energetics of transient species generated in the gas-phase. Computational chemistry with ab initio or density functional methods make a reliable numerical assessment of structures and (relative) energies increasingly feasible. Embedding methods, combining quantum chemistry with force field of semiempirical MO treatments, quantum dynamic studies and the computational modelling of solvent effects extend the utility of the basic methods. This volume in the series Topics in Organometallic Chemistry presents a survey by renowned experts of important experimental and theoretical developments to elucidate basic aspects of bonding, energetics, reaction mechanisms, molecular geometries and solid-state structures of organometallic compounds. Written by authors with frontier research expertise in their fields, both experimental and quantum chemical techniques, methodologies, results and interpretations are detailed in a manner suitable for the non-specialist, who seeks state-of-the-art information in the respective field.
Book Synopsis Molecular Orbital Studies of the Bonding in Heavy Element Organometallics. Progress Report by :
Download or read book Molecular Orbital Studies of the Bonding in Heavy Element Organometallics. Progress Report written by and published by . This book was released on 1992 with total page 14 pages. Available in PDF, EPUB and Kindle. Book excerpt: The upgrade to the DECstation 3100 (and other workstations underway) has enabled the use of more sophisticated electronic structure methods. Research were done in the following fields: tris(cyclopentadienyl) actinide complexes; actinide-containing molecules with metal-metal bonds (U dimer, Th-Ru, Zr-Ru); and applications of fully relativistic DV-X[alpha] method to trivalent actinide chemistry (MCl3).
Book Synopsis Multiple Bonds between Metal Atoms by : F. Albert Cotton
Download or read book Multiple Bonds between Metal Atoms written by F. Albert Cotton and published by Springer Science & Business Media. This book was released on 2006-07-31 with total page 840 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides historical perspective as well as current data Abundantly illustrated with figures redrawn from literature data Covers all pertinent theory and physical chemistry Catalytic and chemotherapeutic applications are included
Download or read book Metal–Ligand Bonding written by E A Moore and published by Royal Society of Chemistry. This book was released on 2019-05-02 with total page 116 pages. Available in PDF, EPUB and Kindle. Book excerpt: To appreciate the chemistry and physical properties of complexes of the transition series, an understanding of metal-ligand interactions applied to complexes of the d-block is needed. Metal Ligand Bonding aims to provide this through an accessible, detailed, non-mathematical approach. Initial chapters detail the crystal-field model, using it to describe the use of magnetic measurements to distinguish complexes with different electronic configurations and geometries. Subsequent chapters look at the molecular orbital theory of transition metal complexes using a pictorial approach. Bonding in octahedral complexes is explored and electronic spectra and magnetic properties are given extensive coverage. The material addressed in this book forms the foundation of undergraduate lecture courses on d-block chemistry and facilitates learning through various key features, including: full colour diagrams; in-text questions with answers; revision exercises and clearly defined learning outcomes to encourage a reflective approach to study; an associated website; and experimental data and observations from everyday life. A basic knowledge of atomic and molecular orbitals as applied to main group elements is assumed.
Book Synopsis Molecular Orbital Studies of the Bonding in Heavy Element Organometallics by :
Download or read book Molecular Orbital Studies of the Bonding in Heavy Element Organometallics written by and published by . This book was released on 1992 with total page 14 pages. Available in PDF, EPUB and Kindle. Book excerpt: The upgrade to the DECstation 3100 (and other workstations underway) has enabled the use of more sophisticated electronic structure methods. Research were done in the following fields: tris(cyclopentadienyl) actinide complexes; actinide-containing molecules with metal-metal bonds (U dimer, Th-Ru, Zr-Ru); and applications of fully relativistic DV-X[alpha] method to trivalent actinide chemistry (MCl[sub 3]).
Book Synopsis Dissertation Abstracts International by :
Download or read book Dissertation Abstracts International written by and published by . This book was released on 1990 with total page 796 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis I. Fenske-Hall Molecular Orbital Studies of [CpM(CO)n]2 Complexes by : Gerald Peter Niccolai
Download or read book I. Fenske-Hall Molecular Orbital Studies of [CpM(CO)n]2 Complexes written by Gerald Peter Niccolai and published by . This book was released on 1992 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Metal-Ligand Interactions by : N. Russo
Download or read book Metal-Ligand Interactions written by N. Russo and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 557 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Ligand Interactions - Structure and Reactivity emphasizes the experimental determination of structure and dynamics, supported by the theoretical and computational approaches needed to establish the concepts and guide the experiments. Leading experts present masterly surveys of: clusters, inorganic complexes, surfaces, catalysis, ab initio theory, density functional theory,semiempirical methods, and dynamics. Besides the presentations of the fields of study themselves, the papers also bring out those aspects that impinge on, or could benefit from, progress in other disciplines. Refined in the fire of an interactive and stimulating conference, the papers presented here represent the state of the art of current research.
Book Synopsis Molecular Orbital and Natural Bond Orbital Studies of Sometransition Metal Polysulfides by : David Robert Kanis
Download or read book Molecular Orbital and Natural Bond Orbital Studies of Sometransition Metal Polysulfides written by David Robert Kanis and published by . This book was released on 1988 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: