Modified Layered Double Hydroxides as PVC Heat Stabilisers

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Publisher :
ISBN 13 :
Total Pages : 284 pages
Book Rating : 4.:/5 (11 download)

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Book Synopsis Modified Layered Double Hydroxides as PVC Heat Stabilisers by : Mikhail David Royeppen

Download or read book Modified Layered Double Hydroxides as PVC Heat Stabilisers written by Mikhail David Royeppen and published by . This book was released on 2016 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrotalcite (HTC) was intercalated with different aromatic carboxylic acids via two synthesis methods: reconstruction and co-precipitation. The reconstruction method involves the rehydration of the products of LDH calcination. The co-precipitation method involves the addition of a base to solutions containing a mixture of the MII and MIII ions found in the metallic layers of an LDH. The intercalated compounds were then compounded with flexible grade PVC to see if these compounds had any effect on the heat stability of the PVC. Complete intercalation of these stabilisers did not occur; however layered double hydroxides did form for almost every synthesis. The organic acids that were to be intercalated were also present in every synthesised stabiliser. Neat hydrotalcite was the best overall stabiliser with an early stability time of 32.40 min and a final or long term stability time of 106.51 min. The best modified layered double hydroxide (LDH) in terms of early stability was 4-hydroxybenzoic acid + HTC synthesised with the reconstruction method. This stabiliser had an early stability time of 25.40 min. The best performing modified stabiliser in terms of late stability was salicylic acid + HTC synthesised with the co-precipitation method. This stabiliser had a late stability time of 71.32 min. The highly activating nature of the hydroxyl substituent group should make hydrotalcites intercalated with hydroxybenzoic acids good free radical scavengers. The substituent group positions that give the best PVC heat stability are the ortho and para positions. The pKa 2 value for an organic acid may be used as a selection parameter for intercalation into hydrotalcite. If a high pKa 2 value organic acid is intercalated into hydrotalcite, the resulting compound will have good PVC heat stabilisation properties.

Layered Double Hydroxides as PVC Thermal Stabilisers

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Publisher :
ISBN 13 :
Total Pages : 250 pages
Book Rating : 4.:/5 (979 download)

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Book Synopsis Layered Double Hydroxides as PVC Thermal Stabilisers by : Harry Charles Wright

Download or read book Layered Double Hydroxides as PVC Thermal Stabilisers written by Harry Charles Wright and published by . This book was released on 2016 with total page 250 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Magnesium Hydroxide Derivatives as Stabilisers and Flame Retardants for Plasticised Poly (vinyl Chloride

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Publisher :
ISBN 13 :
Total Pages : 280 pages
Book Rating : 4.:/5 (14 download)

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Book Synopsis Magnesium Hydroxide Derivatives as Stabilisers and Flame Retardants for Plasticised Poly (vinyl Chloride by : Daniel Matlhomola Molefe

Download or read book Magnesium Hydroxide Derivatives as Stabilisers and Flame Retardants for Plasticised Poly (vinyl Chloride written by Daniel Matlhomola Molefe and published by . This book was released on 2015 with total page 280 pages. Available in PDF, EPUB and Kindle. Book excerpt: The potential of magnesium hydroxide, hydromagnesite and layered double hydroxides (LDHs) as heat stabilisers and flame retardants for plasticised poly (vinylchloride) (PVC) was studied. These inorganic hydrated fillers feature flake-shaped particles with a strong tendency to agglomerate. Filler particles must be homogeneously distributed and individually dispersed in the polymer matrix in order to attain the best performance. For this reason the first step in the investigation was to explore the use of a stearic acid coating in order to improve the dispersability of these fillers in liquids. The platelet morphology-type flame retardants were coated with approximately a monolayer of stearic acid using a solvent technique. Compared to the uncoated powders, the BET surface area was lower, the powder packing density was improved, and the thickening effect on white oil was significantly reduced. The latter two observations were rationalised in terms of a reduction in the attractive interactions between the powder particles. The viscosity of white oil slurries containing 25 wt.% solids showed shear-thinning non-Newtonian behaviour. The coated powders showed significantly lower viscosities at low shear rates although the difference diminished at high shear rates. The lower viscosities shown by the coated powders indicate that the surface modification facilitated the break-up of agglomerates and aided the dispersion of individual particles in the fluid. The thermal decomposition of these hydrated fillers is central to their flame retardant action. At elevated temperatures they endothermically release inert gases. The latter dilute the atmosphere surrounding the burning sample while the endothermic decomposition cools the substrate. These two effects are responsible for the flame retardant action of these fillers. The detailed behaviour of the present samples was studied using thermogravimetric analysis and spectroscopic methods.

Layered Double Hydroxide Polymer Nanocomposites

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Publisher : Woodhead Publishing
ISBN 13 : 0081019041
Total Pages : 886 pages
Book Rating : 4.0/5 (81 download)

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Book Synopsis Layered Double Hydroxide Polymer Nanocomposites by : Sabu Thomas

Download or read book Layered Double Hydroxide Polymer Nanocomposites written by Sabu Thomas and published by Woodhead Publishing. This book was released on 2019-11-28 with total page 886 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanocomposites based on layered double hydroxides (LDHs) have recently become a formidable research area due to their amendable properties and potential applications. The distinct properties of LDH polymer nanocomposites include a wide range of chemical compositions, structural homogeneity, unique anion exchanging ability, easy synthesis, high bound water content, memory effect, non-toxicity and biocompatibility. This means that LDH polymer nanocomposites have the potential for new and innovative applications. Layered Double Hydroxide Polymer Nanocomposites presents a comprehensive overview of the recent innovative advances in the fabrication, characterization and applications of LDH polymer nanocomposites. As well as covering fundamental structural and chemical knowledge, this book also explores various properties and characterization techniques including microscopic, spectroscopic and mechanical behaviors. There is also a strong focus on the potential applications of LDH polymer nanocomposites, such as energy, electrical and electronic, electromagnetic shielding, biomedical, agricultural, food packaging and water purification functions. This book provides comprehensive coverage of cutting-edge research in the field of LDH polymer nanocomposites and their future applications. This book will be an essential read for all academics, researchers, engineers and students working in this area. Fundamental knowledge of LDH polymer nanocomposites, including chemical composition, structural features and fabrication techniques Provides an analytical overview of the different types of characterization techniques and technologies Extensive review on cutting-edge research for potential future applications, in a variety of industries

PVC Degradation and Stabilization

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Publisher : Elsevier
ISBN 13 : 1927885620
Total Pages : 521 pages
Book Rating : 4.9/5 (278 download)

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Book Synopsis PVC Degradation and Stabilization by : George Wypych

Download or read book PVC Degradation and Stabilization written by George Wypych and published by Elsevier. This book was released on 2020-03-11 with total page 521 pages. Available in PDF, EPUB and Kindle. Book excerpt: PVC Degradation and Stabilization, Fourth Edition, includes new developments in PVC production, new stabilization methods and mechanisms, new approaches to plasticization, methods of waste reprocessing, accelerated degradation due to electric breakdown, and much more. The book contains all the information necessary for the successful design of stabilization formulas in any PVC-based product. Other topics covered include degradation by thermal energy, UV, gamma and other forms of radiation, chemical degradation, and more. Analytical methods for studying degradative and stabilization processes aid readers in establishing a system for verifying results of stabilization with different stabilizing systems. Many new topics included in this edition are of particular interest today. These comprise new developments in PVC production yielding range of new grades, new stabilization methods and mechanisms (e.g. synergistic mixtures containing hydrotalcites and their synthetic equivalents, beta-diketones, functionalized fillers, Shiff bases), new approaches to plasticization, methods of waste reprocessing (life cycle assessment, reformulation, biodegradable materials, and energy recovery), accelerated degradation due to electric breakdown, and many more Revised to include cutting-edge research, patent updates and other information required to design successful stabilization in PVC-based products Covers chemical structure, PVC manufacturing technology, morphology, degradation by thermal energy, mechanodegradation, and more Includes a chapter on the analytical methods used in studying degradative and stabilization processes Discusses information on the effects of PVC and its additives on health, safety and the environment

Hybrid Polymer Composite Materials: Structure and Chemistry

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Publisher : Woodhead Publishing
ISBN 13 : 0081007922
Total Pages : 358 pages
Book Rating : 4.0/5 (81 download)

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Book Synopsis Hybrid Polymer Composite Materials: Structure and Chemistry by : Vijay Kumar Thakur

Download or read book Hybrid Polymer Composite Materials: Structure and Chemistry written by Vijay Kumar Thakur and published by Woodhead Publishing. This book was released on 2017-06-03 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hybrid Polymer Composite Materials: Volume 1: Structure and Chemistry presents the latest on these composite materials that can best be described as materials that are comprised of synthetic polymers and biological/inorganic/organic derived constituents. The combination of unique properties that emerge as a consequence of the particular arrangement and interactions between the different constituents provides immense opportunities for advanced material technologies. This series of four volumes brings an interdisciplinary effort to accomplish a more detailed understanding of the interplay between synthesis, structure, characterization, processing, applications, and performance of these advanced materials, with this volume focusing on their structure and chemistry. Provides a clear understanding of the present state-of-the-art and the growing utility of hybrid polymer composite materials Includes contributions from world renowned experts and discusses the combination of different kinds of materials procured from diverse resources Discusses their synthesis, chemistry, processing, fundamental properties, and applications Provides insights on the potential of hybrid polymer composite materials for advanced applications

Layered Double Hydroxides

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Publisher : Springer Science & Business Media
ISBN 13 : 9783540282792
Total Pages : 256 pages
Book Rating : 4.2/5 (827 download)

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Book Synopsis Layered Double Hydroxides by : Xue Duan

Download or read book Layered Double Hydroxides written by Xue Duan and published by Springer Science & Business Media. This book was released on 2006-01-12 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: D.G. Evans, R.C.T. Slade: Structural Aspects of Layered Double Hydroxides.- J. He, M. Wei, B. Li, Y. Kang, D.G. Evans, X. Duan: Preparation of Layered Double Hydroxides.- C. Taviot-Gueho, F. Leroux: In Situ Polymerization and Intercalation of Polymers in Layered Double Hydroxides.- G.R. Williams, A.I. Khan, D. O'Hare: Mechanistic and Kinetic Studies of Guest Ion Intercalation into Layered Double Hydroxides Using Time-Resolved, In-Situ X-Ray Powder Diffraction.- F. Li, X. Duan: Applications of Layered Double Hydroxides

Poly(Vinyl Chloride) Based Composites and Nanocomposites

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Publisher : Springer Nature
ISBN 13 : 3031453751
Total Pages : 360 pages
Book Rating : 4.0/5 (314 download)

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Book Synopsis Poly(Vinyl Chloride) Based Composites and Nanocomposites by : Akhina H

Download or read book Poly(Vinyl Chloride) Based Composites and Nanocomposites written by Akhina H and published by Springer Nature. This book was released on 2023-12-06 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers Poly(vinyl chloride) Fundamentals, Fabrication and characterization of PVC based composites and nanocomposites specifically natural fibre reinforced PVC composites, carbonaceous filler reinforced PVC composites , metal oxide fled PVC composites and nanocomposites etc. This book also covers the conducting PVC composites and recent advances in nanocomposites based on PVC .The rheological, mechanical, barrier, thermal, dielectric behaviour of PVC composites and nanocomposites are discussed in details.

Advances in Functionalized Polymer Nanocomposites

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Publisher : Elsevier
ISBN 13 : 0443188610
Total Pages : 1122 pages
Book Rating : 4.4/5 (431 download)

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Book Synopsis Advances in Functionalized Polymer Nanocomposites by : Gautam Patel

Download or read book Advances in Functionalized Polymer Nanocomposites written by Gautam Patel and published by Elsevier. This book was released on 2024-07-17 with total page 1122 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Functionalized Polymer Nanocomposites: From Synthesis to Applications presents a detailed review on the synthesis, fundamental chemistry, properties, and applications of these high-performance materials. The introductory chapter provides a brief overview of the various types of organic and inorganic nanofillers used for the synthesis of polymer nanocomposites. Emphasis is placed on their fundamental chemistry, processing methods, functionalization and/or surface modification strategies. The dispersion state and their specific interaction with polymer matrices is also discussed in detail, as well as characterization techniques for functionalized nanofillers and functionalized polymer nanocomposites, and their properties, and applications. The book will be a valuable reference source for scientists, engineers, and postgraduate students, working in the field of polymer science and technology, materials science and engineering, composites, and nanocomposites. Covers fabrication, processing, characterization, and properties of various functionalized polymer nanocomposites Explores usage in energy storage systems, biomedical fields, environmental remediation, catalysis, gas sensing, biosensing, and electromagnetic interference (EMI) shielding Provides information on lifecycle assessment and environmental and health impacts of these materials

Applications of Layered Double Hydroxides

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Publisher : Nova Science Publishers
ISBN 13 : 9781685073817
Total Pages : 407 pages
Book Rating : 4.0/5 (738 download)

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Book Synopsis Applications of Layered Double Hydroxides by : Rajib Lochan Goswamee

Download or read book Applications of Layered Double Hydroxides written by Rajib Lochan Goswamee and published by Nova Science Publishers. This book was released on 2021-11-29 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Currently, Layered Double Hydroxides (LDH) is a hot area of research on inorganic layered materials. The present book, Applications of Layered Double Hydroxides, edited by Dr. Rjib Lochan Goswamee and Dr. Pinky Saikia, is a collection of articles from various researchers from different parts of the world mainly on structure and property relationships of various types of LDH and their related application prospects. How these application prospects can be related to the most pressing problems of humanity like drug delivery, global warming, green catalysis, electrochemical energy storage and generation etc. are clearly discussed in the articles inside. The book provides a thorough up-to-date review of recent literature on applications of LDH available in the global scientific and technical media. For example, the book lucidly describes the behaviour of LDH nanocarriers in biological fluids, their low cytotoxicity and high levels of cellular internalization, and high drug loading capacity. Similarly, the book examines why hybrid nanocomposites of LDH-MOF are considered promising materials due to their diverse functionality, flexible properties and tailored end-use properties. Likewise, application of LDH in secondary batteries and electro-chemical supercapacitors with a thorough up-to-date review is included in the book. Also, basic research articles on structural properties and measurements of a special class of unique LDH Li-Al-LDHs are included. Editors also have written their own articles on their findings on the prospective application of dispersions of LDH nanocomposites on structured catalysts for green-house gas emission. Overall, the book gives a short glimpse of wonderful opportunities that LDH can provide in solving many global socio-economic problems of today"--

Ecological and Health Effects of Building Materials

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Publisher : Springer Nature
ISBN 13 : 3030760731
Total Pages : 590 pages
Book Rating : 4.0/5 (37 download)

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Book Synopsis Ecological and Health Effects of Building Materials by : Junaid Ahmad Malik

Download or read book Ecological and Health Effects of Building Materials written by Junaid Ahmad Malik and published by Springer Nature. This book was released on 2021-08-07 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with the present adverse effects of using precarious building materials on the ecology and human health. Also, the detailed discussions on the novel and greener construction materials and their utilization as an alternative to the conventional harmful existing methods and materials are also presented in the subsequent chapters. This book helps to fill the research gaps in the existing prior-art knowledge in the field of sustainable construction and green building materials and methods giving due importance to ecology and health, specifically to the fields of sustainable structural engineering, sustainable geotechnical engineering, sustainable road engineering, etc. This book helps in achieving a sustainable environment through possible adoption of innovative and ecological construction practices. Hence, this book acts as a practical workbook, mainly for the academicians and practicing engineers who are willing to work toward the consecrated building industry. It is a well-established fact that the constructions of the engineering structures consume more and more earth resources than any other human activities in the world. In addition, the construction-related activities will produce several million tons of greenhouse gases, toxic emissions, water pollutants, and solid wastes. This creates a huge impact on environment and causes severe health issues on humans and animals. It is thus important to create an eco-friendly construction environment which can satisfy the ecological and health requirements.

Hydrotalcite-based Materials: Synthesis, Characterization and Application

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Publisher : Bentham Science Publishers
ISBN 13 : 9815256122
Total Pages : 387 pages
Book Rating : 4.8/5 (152 download)

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Book Synopsis Hydrotalcite-based Materials: Synthesis, Characterization and Application by : Ravi Tomar

Download or read book Hydrotalcite-based Materials: Synthesis, Characterization and Application written by Ravi Tomar and published by Bentham Science Publishers. This book was released on 2024-08-09 with total page 387 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrotalcite-based materials, characterized by their unique composition are integral to diverse applications in heterogeneous catalysis and beyond. Renowned for their catalytic prowess, these compounds serve as versatile bases for organic reactions, support structures for metal catalysts, and facilitators in organic transformations and water treatment. This comprehensive book introduces readers to hydrotalcite-like compounds, with ten chapters exploring variations in metal ion ratios and interlayer anions, and their impact on properties crucial for industrial applications (ranging from industrial catalysis to medicine). Key Features • Detailed exploration of hydrotalcite and hydrotalcite-like compounds • Recent trends and applications in industrial catalysis, organic synthesis, and environmental remediation • Hydrotalcite synthesis including methods like coprecipitation, sol-gel processing, and advanced techniques • Contributions from leading researchers in the field with references • Comprehensive overview for each topic suitable for both academics and industry professionals With its exhaustive coverage of hydrotalcite-based materials and their multifaceted applications, this book promises to be an indispensable resource for anyone who wants to understand the utilization of hydrotalcites for advanced catalytic processes.

Lignin Chemistry and Applications

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Publisher : Elsevier
ISBN 13 : 0128139633
Total Pages : 276 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Lignin Chemistry and Applications by : Jin Huang

Download or read book Lignin Chemistry and Applications written by Jin Huang and published by Elsevier. This book was released on 2019-02-07 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lignin Chemistry and Application systematically discusses the structure, physical and chemical modification of lignin, along with its application in the field of chemicals and materials. It presents the history of lignin chemistry and lignin-modified materials, describes recent progresses, applications and studies, and prospects the development direction of high value applications of lignin in the field of material science. In addition to covering the basic theories and technologies relating to the research and application of lignin in polymer chemistry and materials science, the book also summarizes the latest applications in rubber, engineering plastics, adhesives, films and hydrogels. Systematically discusses the structure, physical and chemical modification of lignin and its application in materials Presents the latest research results in the field of lignin Indicates the development direction of high value applications of lignin in a range of fields, including petrochemicals, household applications, medicine, agriculture, and more

Poly(vinyl chloride)-based Blends, Interpenetrating Polymer Networks (IPNs), and Gels

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Publisher : Elsevier
ISBN 13 : 032399475X
Total Pages : 646 pages
Book Rating : 4.3/5 (239 download)

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Book Synopsis Poly(vinyl chloride)-based Blends, Interpenetrating Polymer Networks (IPNs), and Gels by : Sabu Thomas

Download or read book Poly(vinyl chloride)-based Blends, Interpenetrating Polymer Networks (IPNs), and Gels written by Sabu Thomas and published by Elsevier. This book was released on 2024-04-12 with total page 646 pages. Available in PDF, EPUB and Kindle. Book excerpt: Poly(vinyl chloride)-Based Blends, IPNs, and Gels brings together the latest research on the blending of PVC, covering processing, materials, properties, and applications. This book addresses these challenges and highlights the state-of-the-art in the field, such as the development of eco-friendly micro and nanostructured functional materials based on PVC and advances in experimental and theoretical studies of PVC based-polymer blends. This is a valuable resource for researchers and advanced students in polymer science, chemistry, composite science, and materials science and engineering, as well as R&D professionals, engineers, and scientists working with advanced PVC-based materials across a range of industries. Offers methodical, in-depth coverage of PVC-based blends, IPNs and gels with each polymer type Explains advanced methods for PVC-based materials with improved properties for a range of novel applications Provides avenues for improved sustainability, discussing PVC from biomass, lifecycle, recycling, and other environmental considerations

Chemical Abstracts

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Publisher :
ISBN 13 :
Total Pages : 2668 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Chemical Abstracts by :

Download or read book Chemical Abstracts written by and published by . This book was released on 2002 with total page 2668 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Clay-Polymer Nanocomposites

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Publisher : Elsevier
ISBN 13 : 0323461611
Total Pages : 548 pages
Book Rating : 4.3/5 (234 download)

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Book Synopsis Clay-Polymer Nanocomposites by : Khouloud Jlassi

Download or read book Clay-Polymer Nanocomposites written by Khouloud Jlassi and published by Elsevier. This book was released on 2017-07-26 with total page 548 pages. Available in PDF, EPUB and Kindle. Book excerpt: Clay–Polymer Nanocomposites is a complete summary of the existing knowledge on this topic, from the basic concepts of synthesis and design to their applications in timely topics such as high-performance composites, environment, and energy issues. This book covers many aspects of synthesis such as in- situ polymerization within the interlamellar spacing of the clays or by reaction of pristine or pre-modified clays with reactive polymers and prepolymers. Indeed, nanocomposites can be prepared at industrial scale by melt mixing. Regardless the synthesis method, much is said in this book about the importance of theclay pre-modification step, which is demonstrated to be effective, on many occasions, in obtaining exfoliated nanocomposites. Clay–Polymer Nanocomposites reports the background to numerous characterization methods including solid state NMR, neutron scattering, diffraction and vibrational techniques as well as surface analytical methods, namely XPS, inverse gas chromatography and nitrogen adsorption to probe surface composition, wetting and textural/structural properties. Although not described in dedicated chapters, numerous X-ray diffraction patterns of clay–polymer nanocomposites and reference materials are displayed to account for the effects of intercalation and exfoliations of layered aluminosilicates. Finally, multiscale molecular simulation protocols are presenting for predicting morphologies and properties of nanostructured polymer systems with industrial relevance. As far as applications are concerned, Clay–Polymer Nanocomposites examines structural composites such as clay–epoxy and clay–biopolymers, the use of clay–polymer nanocomposites as reactive nanocomposite fillers, catalytic clay-(conductive) polymers and similar nanocomposites for the uptake of hazardous compounds or for controlled drug release, antibacterial applications, energy storage, and more. The most comprehensive coverage of the state of the art in clay–polymer nanocomposites, from synthesis and design to opportunities and applications Covers the various methods of characterization of clay–polymer nanocomposites - including spectroscopy, thermal analyses, and X-ray diffraction Includes a discussion of a range of application areas, including biomedicine, energy storage, biofouling resistance, and more

Fundamentals, Properties, and Applications of Polymer Nanocomposites

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Publisher : Cambridge University Press
ISBN 13 : 1316094413
Total Pages : 719 pages
Book Rating : 4.3/5 (16 download)

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Book Synopsis Fundamentals, Properties, and Applications of Polymer Nanocomposites by : Joseph H. Koo

Download or read book Fundamentals, Properties, and Applications of Polymer Nanocomposites written by Joseph H. Koo and published by Cambridge University Press. This book was released on 2016-10-31 with total page 719 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is focused primarily on polymer nanocomposites, based on the author's research experience as well as open literature. The environmental health and safety aspects of nanomaterials and polymer nanocomposites, risk assessment and safety standards, and fire toxicity of polymer nanocomposites, are studied. In the final chapter, a brief overview of opportunities, trends, and challenges of polymer nanocomposites are included. Throughout the book, the theme is developed that polymer nanocomposites are a whole family of polymeric materials whose properties are capable of being tailored to meet specific applications. This volume serves as a general introduction to students and researchers just entering the field and to scholars from other subfields seeking information.