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Microfluidics For Fuel Cell Applications
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Book Synopsis Microfluidic Fuel Cells and Batteries by : Erik Kjeang
Download or read book Microfluidic Fuel Cells and Batteries written by Erik Kjeang and published by Springer. This book was released on 2014-06-14 with total page 81 pages. Available in PDF, EPUB and Kindle. Book excerpt: Microfluidic fuel cells and batteries represent a special type of electrochemical power generators that can be miniaturized and integrated in a microfluidic chip. Summarizing the initial ten years of research and development in this emerging field, this SpringerBrief is the first book dedicated to microfluidic fuel cell and battery technology for electrochemical energy conversion and storage. Written at a critical juncture, where strategically applied research is urgently required to seize impending technology opportunities for commercial, analytical, and educational utility, the intention is for this book to be a ‘one-stop shop’ for current and prospective researchers in the general area of membraneless, microfluidic electrochemical energy conversion. As the overall goal of the book is to provide a comprehensive resource for both research and technology development, it features extensive descriptions of the underlying fundamental theory, fabrication methods, and cell design principles, as well as a thorough review of previous contributions in this field and a future outlook with recommendations for further work. It is hoped that the content will entice and enable new research groups and engineers to rapidly gain traction in their own laboratories towards the development of next generation microfluidic electrochemical cells.
Book Synopsis Microfluidics for Fuel Cell Applications by : Ian Stewart
Download or read book Microfluidics for Fuel Cell Applications written by Ian Stewart and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In this work, a microfluidics approach is applied to two fuel cell related projects; the study of deformation and contact angle hysteresis on water invasion in porous media and the introduction of bubble fuel cells. This work was carried out as collaboration between the microfluidics and CFCE groups in the Department of Mechanical Engineering at the University of Victoria. Understanding water transport in the porous media of Polymer Electrolyte Membrane fuel cells is crucial to improve performance. One popular technique for both numeric simulations and experimental micromodels is pore network modeling, which predicts flow behavior as a function of capillary number and relative viscosity. An open question is the validity of pore network modeling for the small highly non-wetting pores in fuel cell porous media. In particular, current pore network models do not account for deformable media or contact angle hysteresis. We developed and tested a deformable microfluidic network with an average hydraulic diameter of 5?m, the smallest sizes to date. At a capillary number and relative viscosity for which conventional theory would predict strong capillary fingering behavior, we report almost complete saturation. This work represents the first experimental pore network model to demonstrate the combined effects of material deformation and contact angle hysteresis. Microfluidic fuel cells are small scale energy conversion devices that take advantage of microscale transport phenomena to reduce size, complexity and cost. They are particularly attractive for portable electronic devices, due to their potentially high energy density. The current state of the art microfluidic fuel cell uses the laminar flow of liquid fuel and oxidant as a membrane. Their performance is plagued by a number of factors including mixing, concentration polarization, ohmic polarization and low fuel utilization. In this work, a new type of microfluidic fuel cell is conceptualized and developed that uses bubbles to transport fuel and oxidant within an electrolyte. Bubbles offer a phase boundary to prevent mixing, higher rates of diffusion, and independent electrolyte selection. One particular bubble fuel cell design produces alternating current. This work presents, to our knowledge, the first microfluidic chip to produce bubbles of alternating composition in a single channel, class of fuel cells that use bubbles to transport fuel and oxidant and fuel cell capable of generating alternating current.
Book Synopsis Advances in Microfluidics by : Xiao-Ying Yu
Download or read book Advances in Microfluidics written by Xiao-Ying Yu and published by BoD – Books on Demand. This book was released on 2016-11-23 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: Increasing innovations and applications make microfluidics a versatile choice for researchers in many disciplines. This book consists of multiple review chapters that aim to cover recent advances and new applications of microfluidics in biology, electronics, energy, and materials sciences. It provides comprehensive views of various aspects of microfluidics ranging from fundamentals of fabrication, flow control, and droplet manipulation to the most recent exploration in emerging areas such as material synthesis, imaging and novel spectroscopy, and marriage with electronics. The chapters have many illustrations showcasing exciting results. This book should be useful for those who are eager to learn more about microfluidics as well as researchers who want to pick up new concepts and developments in this fast-growing field.
Book Synopsis Advances in Sustainable Polymers by : Vimal Katiyar
Download or read book Advances in Sustainable Polymers written by Vimal Katiyar and published by Springer Nature. This book was released on 2019-11-05 with total page 483 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a systematic overview of the processing and applications of sustainable polymers. The volume covers recent advances in biomedical, food packaging, fuel cell, membrane, and other emerging applications. The book begins by addressing different sections of biomedical application including use of carbohydrate-based therapeutics, nanohybrids, nanohydrogels, bioresorbable polymers and their composites, polymer-grafted nanobiomaterials for biomedical devices and implants, nanofibres, and others. The second part of this book discusses various processing and packaging materials for food packaging applications. The last section discusses other emerging applications, including using microbial fuel cells for waste water treatment, microfluidic fuel cells for low power applications, among others. This volume will be relevant to researchers working to improve the properties of bio-based materials for their advanced application and wide commercialization.
Book Synopsis Fabrication of Microfluidic Devices with Application to Membraneless Fuel Cells by : Jon McKechnie
Download or read book Fabrication of Microfluidic Devices with Application to Membraneless Fuel Cells written by Jon McKechnie and published by . This book was released on 2006 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis is part of an ongoing collaborative research project focused on the development of microstructured enzymatic fuel cells. Both enzymatic fuel cells and co-laminar fuel cells are, more generally, varieties of microfluidic membraneless fuel cells. A primary goal of this particular work is the establishment of microfabrication capabilities to develop these technologies. Rapid prototyping soft lithography capabilities are established in-house and protocols specific to the lab equipment are developed. These prototyping methods are then adapted for the fabrication of microfluidic membraneless fuel cells. Fabrication techniques using polymeric stencils and photoresist-based channel structures are developed to enable electrode patterning and current collection in the enzymatic and co-laminar fuel cells of interest. A variety of electrode patterning methods are developed. Gold electrode patterning by etching and lift-off techniques are investigated for the patterning of base electrode layers. An in-situ gold electrode patterning methodology is designed and tested, eliminating the need for precision alignment during device assembly. Carbon electrode patterning methods are developed for use in a vanadium-based colaminar fuel cell. Thin-film carbon electrodes are fabricated using a mixture of carbon microparticles and a polymeric binder. Alternatively, graphite rods are investigated for use as electrodes due to their high conductivity and chemical stability. The integration of channel structure and electrode fabrication methods is investigated to establish compatibilities and facilitate the assembly of functional devices. In addition to the development of these methods, the application of co-laminar streaming to microfabrication is explored through the development of a dynamic microfluidic photomasking device.
Book Synopsis PEM Fuel Cell Modeling and Simulation Using Matlab by : Colleen Spiegel
Download or read book PEM Fuel Cell Modeling and Simulation Using Matlab written by Colleen Spiegel and published by Elsevier. This book was released on 2011-08-29 with total page 454 pages. Available in PDF, EPUB and Kindle. Book excerpt: Although, the basic concept of a fuel cell is quite simple, creating new designs and optimizing their performance takes serious work and a mastery of several technical areas. PEM Fuel Cell Modeling and Simulation Using Matlab, provides design engineers and researchers with a valuable tool for understanding and overcoming barriers to designing and building the next generation of PEM Fuel Cells. With this book, engineers can test components and verify designs in the development phase, saving both time and money. Easy to read and understand, this book provides design and modelling tips for fuel cell components such as: modelling proton exchange structure, catalyst layers, gas diffusion, fuel distribution structures, fuel cell stacks and fuel cell plant. This book includes design advice and MATLAB and FEMLAB codes for Fuel Cell types such as: polymer electrolyte, direct methanol and solid oxide fuel cells. This book also includes types for one, two and three dimensional modeling and two-phase flow phenomena and microfluidics. *Modeling and design validation techniques *Covers most types of Fuel Cell including SOFC *MATLAB and FEMLAB modelling codes *Translates basic phenomena into mathematical equations
Book Synopsis Fabrication of Microfluidic Devices with Application to Membraneless Fuel Cells by : Jon McKechnie
Download or read book Fabrication of Microfluidic Devices with Application to Membraneless Fuel Cells written by Jon McKechnie and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis is part of an ongoing collaborative research project focused on the development of microstructured enzymatic fuel cells. Both enzymatic fuel cells and co-laminar fuel cells are, more generally, varieties of microfluidic membraneless fuel cells. A primary goal of this particular work is the establishment of microfabrication capabilities to develop these technologies. Rapid prototyping soft lithography capabilities are established in-house and protocols specific to the lab equipment are developed. These prototyping methods are then adapted for the fabrication of microfluidic membraneless fuel cells. Fabrication techniques using polymeric stencils and photoresist-based channel structures are developed to enable electrode patterning and current collection in the enzymatic and co-laminar fuel cells of interest. A variety of electrode patterning methods are developed. Gold electrode patterning by etching and lift-off techniques are investigated for the patterning of base electrode layers. An in-situ gold electrode patterning methodology is designed and tested, eliminating the need for precision alignment during device assembly. Carbon electrode patterning methods are developed for use in a vanadium-based colaminar fuel cell. Thin-film carbon electrodes are fabricated using a mixture of carbon microparticles and a polymeric binder. Alternatively, graphite rods are investigated for use as electrodes due to their high conductivity and chemical stability. The integration of channel structure and electrode fabrication methods is investigated to establish compatibilities and facilitate the assembly of functional devices. In addition to the development of these methods, the application of co-laminar streaming to microfabrication is explored through the development of a dynamic microfluidic photomasking device.
Author :Marco Aurelio Dos Santos Bernardes Publisher :BoD – Books on Demand ISBN 13 :9533074809 Total Pages :746 pages Book Rating :4.5/5 (33 download)
Book Synopsis Biofuel's Engineering Process Technology by : Marco Aurelio Dos Santos Bernardes
Download or read book Biofuel's Engineering Process Technology written by Marco Aurelio Dos Santos Bernardes and published by BoD – Books on Demand. This book was released on 2011-08-01 with total page 746 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book aspires to be a comprehensive summary of current biofuels issues and thereby contribute to the understanding of this important topic. Readers will find themes including biofuels development efforts, their implications for the food industry, current and future biofuels crops, the successful Brazilian ethanol program, insights of the first, second, third and fourth biofuel generations, advanced biofuel production techniques, related waste treatment, emissions and environmental impacts, water consumption, produced allergens and toxins. Additionally, the biofuel policy discussion is expected to be continuing in the foreseeable future and the reading of the biofuels features dealt with in this book, are recommended for anyone interested in understanding this diverse and developing theme.
Book Synopsis Microfluidics and Nanofluidics Handbook by : Sushanta K. Mitra
Download or read book Microfluidics and Nanofluidics Handbook written by Sushanta K. Mitra and published by CRC Press. This book was released on 2011-09-20 with total page 1103 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive handbook presents fundamental aspects, fabrication techniques, introductory materials on microbiology and chemistry, measurement techniques, and applications of microfluidics and nanofluidics. The first volume of the handbook focuses on physics and transport phenomena along with life sciences and related applications. It provides newcomers with the fundamental science background required for the study of microfluidics and nanofluidics. In addition, the advanced techniques and concepts described in the text will benefit experienced researchers and professionals.
Download or read book Micro Fuel Cells written by Tim Zhao and published by Academic Press. This book was released on 2009-07-07 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Today's consumers of portable electronics consumers are demanding devices not only deliver more power but also work healthy for the environment. This fact alone has lead major corporations like Intel, BIC, Duracell and Microsoft to believe that Microfuel Cells could be the next-generation power source for electronic products. Compact and readable, Microfuels Principles and Applications, offers engineers and product designers a reference unsurpassed by any other in the market. The book starts with a clear and rigorous exposition of the fundamentals engineering principles governing energy conversion for small electronic devices, followed by self-contained chapters concerning applications. The authors provide original points of view on all types of commercially available micro fuel cells types, including micro proton exchange membrane fuel cells, micro direct methanol fuel cells, micro solid oxide fuel cells and micro bio-fuel cells. The book also contains a detailed introduction to the fabrication of the components and the assembly of the system, making it a valuable reference both in terms of its application to product design and understanding micro engineering principles. An overview of the micro fuel cell systems and applications A detailed introduction to the fabrication of the components and the assembly of the system Original points of view on prospects of micro fuel cells
Book Synopsis Bioelectrochemical Systems by : Korneel Rabaey
Download or read book Bioelectrochemical Systems written by Korneel Rabaey and published by IWA Publishing. This book was released on 2009-12-01 with total page 525 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the context of wastewater treatment, Bioelectrochemical Systems (BESs) have gained considerable interest in the past few years, and several BES processes are on the brink of application to this area. This book, written by a large number of world experts in the different sub-topics, describes the different aspects and processes relevant to their development. Bioelectrochemical Systems (BESs) use micro-organisms to catalyze an oxidation and/or reduction reaction at an anodic and cathodic electrode respectively. Briefly, at an anode oxidation of organic and inorganic electron donors can occur. Prime examples of such electron donors are waste organics and sulfides. At the cathode, an electron acceptor such as oxygen or nitrate can be reduced. The anode and the cathode are connected through an electrical circuit. If electrical power is harvested from this circuit, the system is called a Microbial Fuel Cell; if electrical power is invested, the system is called a Microbial Electrolysis Cell. The overall framework of bio-energy and bio-fuels is discussed. A number of chapters discuss the basics – microbiology, microbial ecology, electrochemistry, technology and materials development. The book continues by highlighting the plurality of processes based on BES technology already in existence, going from wastewater based reactors to sediment based bio-batteries. The integration of BESs into existing water or process lines is discussed. Finally, an outlook is provided of how BES will fit within the emerging biorefinery area.
Book Synopsis Microfluidics and Nanofluidics Handbook by : Sushanta K. Mitra
Download or read book Microfluidics and Nanofluidics Handbook written by Sushanta K. Mitra and published by CRC Press. This book was released on 2016-04-19 with total page 644 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive handbook presents fundamental aspects, fabrication techniques, introductory materials on microbiology and chemistry, measurement techniques, and applications of microfluidics and nanofluidics. The second volume focuses on topics related to experimental and numerical methods. It also covers fabrication and applications in a variety of areas, from aerospace to biological systems. Reflecting the inherent nature of microfluidics and nanofluidics, the book includes as much interdisciplinary knowledge as possible. It provides the fundamental science background for newcomers and advanced techniques and concepts for experienced researchers and professionals.
Book Synopsis Microfluidic Platforms for the Investigation of Fuel Cell Catalysts and Electrodes by : Fikile R. Brushett
Download or read book Microfluidic Platforms for the Investigation of Fuel Cell Catalysts and Electrodes written by Fikile R. Brushett and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A clear need exists for novel approaches to producing and utilizing energy in more efficient ways, in light of society0́9s ever increasing demand as well as growing concerns with respect to climate change related to CO2 emissions. The development of low temperature fuel cell technologies will continue to play an important role in many alternative energy conversion strategies, especially for portable electronics and automotive applications. However, widespread commercialization of fuel cell technologies has yet to be achieved due to a combination of high costs, poor durability and, system performance limitations (Chapter 1). Developing a better understanding of the complex interplay of electrochemical, transport, and degradation processes that govern the performance and durability of novel fuel cell components, particularly catalysts and electrodes, within operating fuel cells is critical to designing robust, inexpensive configurations that are required for commercial introduction. Such detailed in-situ investigations of individual electrode processes are complicated by other factors such as water management, uneven performance across electrodes, and temperature gradients. Indeed, too many processes are interdependent on the same few variable parameters, necessitating the development of novel analytical platforms with more degrees of freedom. Previously, membraneless microfluidic fuel cells have been developed to address some of the aforementioned fuel cell challenges (Chapter 2). At the microscale, the laminar nature of fluid flow eliminates the need for a physical barrier, such as a stationary membrane, while still allowing ionic transport between electrodes. This enables the development of many unique and innovative fuel cell designs. In addition to addressing water management and fuel crossover issues, these laminar flow-based systems allow for the independent specification of individual stream compositions (e.g., pH). Furthermore, the use of a liquid electrolyte enables the simple in-situ analysis of individual electrode performance using an off-the-shelf reference electrode. These advantages can be leveraged to develop microfluidic fuel cells as versatile electro-analytical platforms for the characterization and optimization of catalysts and electrodes for both membrane- and membraneless fuel cells applications. To this end, a microfluidic hydrogen-oxygen (H2/O2) fuel cell has been developed which utilizes a flowing liquid electrolyte instead of a stationary polymeric membrane. For analytical investigations, the flowing stream (i) enables autonomous control over electrolyte parameters (i.e., pH, composition) and consequently the local electrode environments, as well as (ii) allows for the independent in-situ analyses of catalyst and/or electrode performance and degradation characteristics via an external reference electrode (e.g., Ag/AgCl). Thus, this microfluidic analytical platform enables a high number of experimental degrees of freedom, previously limited to a three-electrode electrochemical cell, to be employed in the construct of working fuel cell. Using this microfluidic H2/O2 fuel cell as a versatile analytical platform, the focus of this work is to provide critical insight into the following research areas: 0́Ø Identify the key processes that govern the electrode performance and durability in alkaline fuel cells as a function of preparation methods and operating parameters (Chapter 3). 0́Ø Determine the suitability of a novel Pt-free oxygen reduction reaction catalyst embedded in gas diffusion electrodes for acidic and alkaline fuel cell applications (Chapter 4). 0́Ø Establish electrode structure-activity relationships by aligning in-situ electrochemical analyses with ex-situ microtomographic (MicroCT) structural analyses (Chapter 5). 0́Ø Investigate the feasibility and utility of a microfluidic-based vapor feed direct methanol fuel cell (VF-DMFC) configuration as a power source for portable applications (Chapter 6). In all these areas, the information garnered from these in-situ analytical platforms will advance the development of more robust and cost-effective electrode configurations and thus more durable and commercially-viable fuel cell systems (both membrane-based and membraneless).
Book Synopsis Microfluidics in Membraneless Fuel Cells by : Jesus A. Diaz-Real
Download or read book Microfluidics in Membraneless Fuel Cells written by Jesus A. Diaz-Real and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In the 1990s, the idea of developing miniaturized devices that integrate functions other than what normally are carried out at the laboratory level was conceived, and the so-called "lab-on-a-chip" (LOC) devices emerged as one of the most important research areas. LOC devices exhibit advantages related to the use of microfluidic channels such as small sample and reagent consumption, portability, low-power consumption, laminar flow, and higher surface area/volume ratio that enhances both thermal dissipation and electrochemical kinetics. Fuel cells are electrochemical devices that convert chemical energy to electrical energy. These are considered as one of the greener ways to generate electricity because typical fuel cells produce water and heat as the main reaction byproducts. The technical challenges to develop systems at the microscale and the advantages of microfluidics exhibited an important impact on fuel cells for several reasons, mainly related to avoid inherent problems of gaseous-based fuel cells. As a result, the birth of a new type of fuel cells as microfluidic fuel cells (MFCs) took place. The first microfluidic fuel cell was reported in 2002. This MFC was operated with liquid fuel/oxidant and had the advantage of the low laminar flow generated using a "Y" microfluidic channel to separate the anodic and cathodic streams, resulting in an energy conversion device that did not require a physical barrier to separate both streams. This electrochemical system originated a specific type of MFCs categorized as membraneless also called colaminar microfluidic fuel cells. Since that year, numerous works focused on the nature of fuels, oxidants and anodic/cathodic electrocatalysts, and cell designs have been reported. The limiting parameters of this kind of devices toward their use in portable applications are related to their low cell performances, small mass activity, and partial selectivity/durability of electrocatalysts. On the other hand, it has been observed that the cell design has a high effect on the cell performance due to internal cell resistances and the crossover effect. Furthermore, current technology is growing faster than last centuries and new microfabrication technologies are always emerging, allowing the development of smaller and more powerful microfluidic energy devices. In this chapter, the application of microfluidics in membraneless fuel cells is addressed in terms of evolution of cell designs of miniaturized microfluidic fuel cells as a result of new discoveries in microfabrication technology and the use of several fuels and electrocatalysts for specific and selective applications.
Book Synopsis Fabrication of Microfluidic Devices with Application to Membraneless Fuel Cells by :
Download or read book Fabrication of Microfluidic Devices with Application to Membraneless Fuel Cells written by and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis is part of an ongoing collaborative research project focused on the development of microstructured enzymatic fuel cells. Both enzymatic fuel cells and co-laminar fuel cells are, more generally, varieties of microfluidic membraneless fuel cells. A primary goal of this particular work is the establishment of microfabrication capabilities to develop these technologies. Rapid prototyping soft lithography capabilities are established in-house and protocols specific to the lab equipment are developed. These prototyping methods are then adapted for the fabrication of microfluidic membraneless fuel cells. Fabrication techniques using polymeric stencils and photoresist-based channel structures are developed to enable electrode patterning and current collection in the enzymatic and co-laminar fuel cells of interest. A variety of electrode patterning methods are developed. Gold electrode patterning by etching and lift-off techniques are investigated for the patterning of base electrode layers. An in-situ gold electrode patterning methodology is designed and tested, eliminating the need for precision alignment during device assembly. Carbon electrode patterning methods are developed for use in a vanadium-based colaminar fuel cell. Thin-film carbon electrodes are fabricated using a mixture of carbon microparticles and a polymeric binder. Alternatively, graphite rods are investigated for use as electrodes due to their high conductivity and chemical stability. The integration of channel structure and electrode fabrication methods is investigated to establish compatibilities and facilitate the assembly of functional devices. In addition to the development of these methods, the application of co-laminar streaming to microfabrication is explored through the development of a dynamic microfluidic photomasking device.
Book Synopsis Microfluidic Platforms and Fundamental Electrocatalysis Studies for Fuel Cell Applications by : Jamie Lee Cohen
Download or read book Microfluidic Platforms and Fundamental Electrocatalysis Studies for Fuel Cell Applications written by Jamie Lee Cohen and published by . This book was released on 2007 with total page 1178 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Biofilms in Bioelectrochemical Systems by : Haluk Beyenal
Download or read book Biofilms in Bioelectrochemical Systems written by Haluk Beyenal and published by John Wiley & Sons. This book was released on 2015-09-08 with total page 429 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book serves as a manual of research techniques for electrochemically active biofilm research. Using examples from real biofilm research to illustrate the techniques used for electrochemically active biofilms, this book is of most use to researchers and educators studying microbial fuel cell and bioelectrochemical systems. The book emphasizes the theoretical principles of bioelectrochemistry, experimental procedures and tools useful in quantifying electron transfer processes in biofilms, and mathematical modeling of electron transfer in biofilms. It is divided into three sections: Biofilms: Microbiology and microbioelectrochemistry - Focuses on the microbiologic aspect of electrochemically active biofilms and details the key points of biofilm preparation and electrochemical measurement Electrochemical techniques to study electron transfer processes - Focuses on electrochemical characterization and data interpretation, highlighting key factors in the experimental procedures that affect reproducibility Applications - Focuses on applications of electrochemically active biofilms and development of custom tools to study electrochemically active biofilms. Chapters detail how to build the reactors for applications and measure parameters
