Metal Metal Bonded Carbonyl Dimers And Clusters

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Metal-metal Bonded Carbonyl Dimers and Clusters

Author : Catherine E. Housecroft
Publisher :
ISBN 13 :
Total Pages : 108 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Metal-metal Bonded Carbonyl Dimers and Clusters by : Catherine E. Housecroft

Download or read book Metal-metal Bonded Carbonyl Dimers and Clusters written by Catherine E. Housecroft and published by . This book was released on 1996 with total page 108 pages. Available in PDF, EPUB and Kindle. Book excerpt: The potential commercial uses of some compounds as catalysts has generated much research interest. Metal-metal bonded dimers and clusters are an example of these. This concise basic approach to the subject covers among other topics: structure of metal-metal bonded dimers and clusters including both small and large clusters, synthesis of reprensentative dimers and clusters, and localized bonding schemes and their limitations. Highly illustrated, with a relatively basic text that includes problems, this addition to the Oxford Chemistry Primers series will be valuable to the advanced chemistry undergraduate.

Metal-Metal Bonds and Clusters in Chemistry and Catalysis

Author : John P. Fackler Jr.
Publisher : Springer Science & Business Media
ISBN 13 : 1489924922
Total Pages : 344 pages
Book Rating : 4.4/5 (899 download)

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Book Synopsis Metal-Metal Bonds and Clusters in Chemistry and Catalysis by : John P. Fackler Jr.

Download or read book Metal-Metal Bonds and Clusters in Chemistry and Catalysis written by John P. Fackler Jr. and published by Springer Science & Business Media. This book was released on 2013-11-22 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book contains a series of papers and abstracts from the 7th Industry-University Cooperative Chemistry Program symposium held in the spring of 1989 at Texas A&M University. The symposium was larger than previous IUCCP symposia since it also celebrated the 25 years that had elapsed since the initial discovery by F. A. Cotton and his co-workers of the existence of metal-metal quadruple bonds. Cotton's discovery demonstrated that multiple bonding in inorganic systems is not governed by the same constraints observed in organic chemistry regarding s and p orbital involvement. The d orbitals are involved in the multiple bonding description. The quadruple bond involves considerable d orbital overlap between adjacent metal centers. Part I of this series of papers focuses upon the impact of this discovery and describes further contributions to the development of the field. Multiple metal-metal bonding now is known to permeate broad areas of transition metal chemistry. The understanding of metal-metal bonding that developed as a result of the discovery of multiple metal-metal bonding awakened a new chemistry involving metal clusters. Clusters were defined by Cotton to be species containing metal-metal bonding. Clusters in catalysis therefore seemed a logical grouping of papers in this symposium. Clusters play an every increasing role in the control of chemical reactions. Part II of this book describes some of the interesting new developments in this field. In Part III the papers examine the role clusters play in describing and understanding solid state materials.

Transition Metal Carbonyl Cluster Chemistry

Author : Paul J. Dyson
Publisher : CRC Press
ISBN 13 : 1482283077
Total Pages : 179 pages
Book Rating : 4.4/5 (822 download)

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Book Synopsis Transition Metal Carbonyl Cluster Chemistry by : Paul J. Dyson

Download or read book Transition Metal Carbonyl Cluster Chemistry written by Paul J. Dyson and published by CRC Press. This book was released on 2018-10-03 with total page 179 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.

Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces

Author : Dennis R. Salahub
Publisher : Springer Science & Business Media
ISBN 13 : 9401128227
Total Pages : 428 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces by : Dennis R. Salahub

Download or read book Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces written by Dennis R. Salahub and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-ligand interactions are currently being studied in different fields, from a variety of points of view, and recent progress has been substantial. Whole new classes of compounds and reactions have been found; an arsenal of physical methods has been developed; mechanistic detail can be ascertained to an increasingly minute degree; and the theory is being developed to handle systems of ever-growing complexity. As usual, such multidisciplinarity leads to great opportunities, coupled with great problems of communication between specialists. It is in its promotion of interactions across these fields that Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces makes its timely contribution: the tools, both theoretical and experimental, are highly developed, and fundamental questions remain unanswered. The most fundamental of these concerns the nature of the microscopic interactions between metal atoms (clusters, surfaces) and ligands (atoms, molecules, absorbates, reagents, products) and the changes in these interactions during physical and chemical transformation. In Metal-Ligand Interactions, leading experts discuss the following, vital aspects: ab initio theory, semi-empirical theory, density functional theory, complexes and clusters, surfaces, and catalysis.

Multiple Bonds between Metal Atoms

Author : F. Albert Cotton
Publisher : Springer Science & Business Media
ISBN 13 : 9780387250847
Total Pages : 856 pages
Book Rating : 4.2/5 (58 download)

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Book Synopsis Multiple Bonds between Metal Atoms by : F. Albert Cotton

Download or read book Multiple Bonds between Metal Atoms written by F. Albert Cotton and published by Springer Science & Business Media. This book was released on 2005-06-28 with total page 856 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides historical perspective as well as current data Abundantly illustrated with figures redrawn from literature data Covers all pertinent theory and physical chemistry Catalytic and chemotherapeutic applications are included

Organometallic Chemistry

Author : Shay Beck
Publisher : Scientific e-Resources
ISBN 13 : 1839472022
Total Pages : 293 pages
Book Rating : 4.8/5 (394 download)

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Book Synopsis Organometallic Chemistry by : Shay Beck

Download or read book Organometallic Chemistry written by Shay Beck and published by Scientific e-Resources. This book was released on 2019-09-06 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic Chemistry is the study of chemical compounds containing bonds between carbon and metal. The term "e;Metal"e; is defined deliberately broadly in this context and may include elements, such as silicon or boron, which are not metallic but are considered to be metalloids. Almost all branches of chemistry and material science now interface with organometallic chemistry. Organometallics find practical uses in stoichiometric and catalytic processes, especially processes involving carbon monoxide and alkene-derived polymers. Organometallic (OM) chemistry is the study of compounds containing, and reactions involving, metal-carbon bonds. The metal-carbon bond may be transient or temporary, but if one exists during a reaction or in a compound of interest, we're squarely in the domain of organometallic chemistry. Despite the denotational importance of the M-C bond, bonds between metals and the other common elements of organic chemistry also appear in OM chemistry: metal-nitrogen, metal-oxygen, metal-halogen, and even metal-hydrogen bonds all play a role. Metals cover a vast swath of the periodic table and include the alkali metals (group 1), alkali earth metals (group 2), transition metals (groups 3-12), the main group metals (groups 13-15, "e;under the stairs"e;), and the lanthanides and actinides. The principal idea of this book is to offer a comprehensive coverage of unconventional and thought-provoking topics in organometallic chemistry. It also supplies practical information about reaction mechanisms, along with the descriptions of contemporary applications to organic synthesis, organized by mechanism and kinetic. It will serve as a valuable reference tool for students and professional of organic and post organic chemistry, who need to become better acquainted with the subject.

Landmarks in Organo-Transition Metal Chemistry

Author : Helmut Werner
Publisher : Springer Science & Business Media
ISBN 13 : 0387098488
Total Pages : 361 pages
Book Rating : 4.3/5 (87 download)

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Book Synopsis Landmarks in Organo-Transition Metal Chemistry by : Helmut Werner

Download or read book Landmarks in Organo-Transition Metal Chemistry written by Helmut Werner and published by Springer Science & Business Media. This book was released on 2008-12-16 with total page 361 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the discovery of ferrocene and the sandwich-type complexes, the development of organometallic chemistry took its course like an avalanche and became one of the scientific success stories of the second half of the twentieth century. Based on this development, the traditional boundaries between inorganic and organic chemistry gradually disappeared and a rebirth of the nowadays highly important field of homogeneous catalysis occurred. It is fair to say that despite the fact that the key discovery, which sparked it all off, was made more than 50 years ago, organometallic chemistry remains a young and lively discipline.

Molecular Metal-Metal Bonds

Author : Stephen T. Liddle
Publisher : John Wiley & Sons
ISBN 13 : 3527673385
Total Pages : 592 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Molecular Metal-Metal Bonds by : Stephen T. Liddle

Download or read book Molecular Metal-Metal Bonds written by Stephen T. Liddle and published by John Wiley & Sons. This book was released on 2016-03-16 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: Systematically covering all the latest developments in the field, this is a comprehensive and handy introduction to metal-metal bonding. The chapters follow a uniform, coherent structure for a clear overview, allowing readers easy access to the information. The text covers such topics as synthesis, properties, structures, notable features, reactivity and examples of applications of the most important compounds in each group with metal-metal bonding throughout the periodic table. With its general remarks at the beginning of each chapter, this is a must-have reference for all molecular inorganic chemists, including PhD students and postdocs, as well as more experienced researchers.

Kirk-Othmer Concise Encyclopedia of Chemical Technology, 2 Volume Set

Author : Kirk-Othmer
Publisher : John Wiley & Sons
ISBN 13 : 0470047488
Total Pages : 2762 pages
Book Rating : 4.4/5 (7 download)

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Book Synopsis Kirk-Othmer Concise Encyclopedia of Chemical Technology, 2 Volume Set by : Kirk-Othmer

Download or read book Kirk-Othmer Concise Encyclopedia of Chemical Technology, 2 Volume Set written by Kirk-Othmer and published by John Wiley & Sons. This book was released on 2007-07-16 with total page 2762 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is an easily-accessible two-volume encyclopedia summarizing all the articles in the main volumes Kirk-Othmer Encyclopedia of Chemical Technology, Fifth Edition organized alphabetically. Written by prominent scholars from industry, academia, and research institutions, the Encyclopedia presents a wide scope of articles on chemical substances, properties, manufacturing, and uses; on industrial processes, unit operations in chemical engineering; and on fundamentals and scientific subjects related to the field.

Organometallic Chemistry

Author : E W Abel
Publisher : Royal Society of Chemistry
ISBN 13 : 1847554105
Total Pages : 516 pages
Book Rating : 4.8/5 (475 download)

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Book Synopsis Organometallic Chemistry by : E W Abel

Download or read book Organometallic Chemistry written by E W Abel and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Inorganic and Bio-Inorganic Chemistry - Volume II

Author : Ivano Bertini
Publisher : EOLSS Publications
ISBN 13 : 1848262159
Total Pages : 502 pages
Book Rating : 4.8/5 (482 download)

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Book Synopsis Inorganic and Bio-Inorganic Chemistry - Volume II by : Ivano Bertini

Download or read book Inorganic and Bio-Inorganic Chemistry - Volume II written by Ivano Bertini and published by EOLSS Publications. This book was released on 2009-02-10 with total page 502 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inorganic and Bio-Inorganic Chemistry is the component of Encyclopedia of Chemical Sciences, Engineering and Technology Resources in the global Encyclopedia of Life Support Systems (EOLSS), which is an integrated compendium of twenty one Encyclopedias. The Theme on Inorganic and Bio-Inorganic Chemistry in the Encyclopedia of Chemical Sciences, Engineering and Technology Resources deals with the discipline which studies the chemistry of the elements of the periodic table. It covers the following topics: From simple to complex compounds; Chemistry of metals; Inorganic synthesis; Radicals reactions with metal complexes in aqueous solutions; Magnetic and optical properties; Inorganometallic chemistry; High temperature materials and solid state chemistry; Inorganic biochemistry; Inorganic reaction mechanisms;Homogeneous and heterogeneous catalysis; Cluster and polynuclear compounds; Structure and bonding in inorganic chemistry; Synthesis and spectroscopy of transition metal complexes; Nanosystems;Computational inorganic chemistry; Energy and inorganic chemistry. These two volumes are aimed at the following five major target audiences: University and College students Educators, Professional practitioners, Research personnel and Policy analysts, managers, and decision makers and NGOs

Core Carbonyl Chemistry

Author : John Jones
Publisher :
ISBN 13 : 0198559593
Total Pages : 99 pages
Book Rating : 4.1/5 (985 download)

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Book Synopsis Core Carbonyl Chemistry by : John Jones

Download or read book Core Carbonyl Chemistry written by John Jones and published by . This book was released on 1997 with total page 99 pages. Available in PDF, EPUB and Kindle. Book excerpt: This new primer offers a thorough understanding of the carbonyl group, knowledge essential for an understanding of organic chemistry. The Carbonyl groups appears in many classes of compounds, Core Carbonyl Chemistry covers the chemistry of these classes in a brisk style, and also embraces thereactivity of this group. Recent developments are dealt with where appropriate. The study of this material is a vital part of all university year and/or second year courses in chemistry or biochemistry, and this Primer will be useful to all students taking such courses.

Synthesis and Technique in Inorganic Chemistry

Author : Gregory S. Girolami
Publisher : University Science Books
ISBN 13 : 9780935702484
Total Pages : 292 pages
Book Rating : 4.7/5 (24 download)

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Book Synopsis Synthesis and Technique in Inorganic Chemistry by : Gregory S. Girolami

Download or read book Synthesis and Technique in Inorganic Chemistry written by Gregory S. Girolami and published by University Science Books. This book was released on 1999 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Previously by Angelici, this laboratory manual for an upper-level undergraduate or graduate course in inorganic synthesis has for many years been the standard in the field. In this newly revised third edition, the manual has been extensively updated to reflect new developments in inorganic chemistry. Twenty-three experiments are divided into five sections: solid state chemistry, main group chemistry, coordination chemistry, organometallic chemistry, and bioinorganic chemistry. The included experiments are safe, have been thoroughly tested to ensure reproducibility, are illustrative of modern issues in inorganic chemistry, and are capable of being performed in one or two laboratory periods of three or four hours. Because facilities vary from school to school, the authors have included a broad range of experiments to help provide a meaningful course in almost any academic setting. Each clearly written & illustrated experiment begins with an introduction that hig! hlights the theme of the experiment, often including a discussion of a particular characterization method that will be used, followed by the experimental procedure, a set of problems, a listing of suggested Independent Studies, and literature references.

Introduction to Modern Inorganic Chemistry, 6th edition

Author : R.A. Mackay
Publisher : CRC Press
ISBN 13 : 1351991108
Total Pages : 630 pages
Book Rating : 4.3/5 (519 download)

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Book Synopsis Introduction to Modern Inorganic Chemistry, 6th edition by : R.A. Mackay

Download or read book Introduction to Modern Inorganic Chemistry, 6th edition written by R.A. Mackay and published by CRC Press. This book was released on 2017-12-21 with total page 630 pages. Available in PDF, EPUB and Kindle. Book excerpt: This popular and comprehensive textbook provides all the basic information on inorganic chemistry that undergraduates need to know. For this sixth edition, the contents have undergone a complete revision to reflect progress in areas of research, new and modified techniques and their applications, and use of software packages. Introduction to Modern Inorganic Chemistry begins by explaining the electronic structure and properties of atoms, then describes the principles of bonding in diatomic and polyatomic covalent molecules, the solid state, and solution chemistry. Further on in the book, the general properties of the periodic table are studied along with specific elements and groups such as hydrogen, the 's' elements, the lanthanides, the actinides, the transition metals, and the "p" block. Simple and advanced examples are mixed throughout to increase the depth of students' understanding. This edition has a completely new layout including revised artwork, case study boxes, technical notes, and examples. All of the problems have been revised and extended and include notes to assist with approaches and solutions. It is an excellent tool to help students see how inorganic chemistry applies to medicine, the environment, and biological topics.

Inorganic and Organometallic Reaction Mechanisms

Author : Jim D. Atwood
Publisher : John Wiley & Sons
ISBN 13 : 0471188972
Total Pages : 327 pages
Book Rating : 4.4/5 (711 download)

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Book Synopsis Inorganic and Organometallic Reaction Mechanisms by : Jim D. Atwood

Download or read book Inorganic and Organometallic Reaction Mechanisms written by Jim D. Atwood and published by John Wiley & Sons. This book was released on 1997-02-18 with total page 327 pages. Available in PDF, EPUB and Kindle. Book excerpt: Jetzt in neuer Auflage: Das erfolgreiche Lehrwerk über Kinetik und Mechanismen anorganischer und organometallischer Reaktionen für fortgeschrittene Studenten! Hervorragend geeignet als Begleiter eines Vorlesungssemesters. Mit zahlreichen Übungsaufgaben; für eine bessere Übersicht sorgen Zusammenfassungen am Ende jedes Kapitels.

Organometallics and Catalysis

Author : Manfred Bochmann
Publisher : Oxford University Press, USA
ISBN 13 : 0199668213
Total Pages : 429 pages
Book Rating : 4.1/5 (996 download)

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Book Synopsis Organometallics and Catalysis by : Manfred Bochmann

Download or read book Organometallics and Catalysis written by Manfred Bochmann and published by Oxford University Press, USA. This book was released on 2015 with total page 429 pages. Available in PDF, EPUB and Kindle. Book excerpt: A succinct review of the essential concepts of organometallic chemistry, enriched throughout with examples that demonstrate how our understanding of organometallic chemistry has led to new applications in research and industry - not least in relation to catalysis.

Metal Clusters in Chemistry

Author : Luis A. Oro
Publisher : Wiley-VCH
ISBN 13 :
Total Pages : 660 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Metal Clusters in Chemistry by : Luis A. Oro

Download or read book Metal Clusters in Chemistry written by Luis A. Oro and published by Wiley-VCH. This book was released on 1999 with total page 660 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal cluster chemistry is at the cutting edge between molecular and solid-state chemistry and has therefore had a great impact on the researchers working on organic, coordination, and solid-state chemistry, catalysis, physics, and materials science. The development of new sophisticated synthetic techniques has led to enormous progress in the synthesis of this diverse class of compounds. The number of clusters is growing rapidly, since the possible variations in the metal and ligand sphere are numerous. Modern bonding theories, such as the isolobal principle, have allowed a better understanding of the structures and properties of metal clusters, and thus paved the way for the usage of these versatile materials. Catalysis and nanomaterials are just two of the very promising application-oriented fields. Seventy six contributions, written by world experts in this research field, provide extensive coverage of different aspects of cluster chemistry, ranging from synthesis, structure determination, and dynamics to applications. Up-to-date information, including an impressive collection of structural data and illustrations, extensive coverage of the most important publications of the last decade, and many more features make this three-volume set a complete single-source guide for all researchers working in the area of cluster chemistry.