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Kinetics And Selectivity Of Carbon Carbon Bond Forming Reactions On Oxidized And Reduced Metal Oxides
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Book Synopsis Kinetics and Selectivity of Carbon-carbon Bond Forming Reactions on Oxidized and Reduced Metal Oxides by : James Edward Rekoske
Download or read book Kinetics and Selectivity of Carbon-carbon Bond Forming Reactions on Oxidized and Reduced Metal Oxides written by James Edward Rekoske and published by . This book was released on 1998 with total page 1062 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Carbon-Carbon ?-Bond Formation by : Barry M. Trost
Download or read book Carbon-Carbon ?-Bond Formation written by Barry M. Trost and published by Pergamon. This book was released on 1991 with total page 1220 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 3 covers carbon-to-carbon single bond forming reactions involving sp3, sp2 and sp carbon centers, but only those which do not involve additions to C-X &pgr;-bonds. The volume first compares and contrasts the alkylation reactions of all types of sp3 carbon nucleophiles and also covers vinyl and alkynyl carbanions. Following on from Volume 2, a separate section covers Friedel-Crafts alkylation reactions, which is complemented by discussions of polyene cyclizations and electrophilic transannular cyclizations in synthesis. Coupling reactions leading to &agr;-bond formation, and involving all types of combinations ofsp3, sp2 and sp carbon centers are next covered, including those reactions based on pinacol, acyloin and phenol oxidative coupling reactions, and also the Kolbe reaction. Rearrangement reactions, leading to carbon-to-carbon &agr;-bond formation, are often used in a clever manner in synthesis. The volume includes all those rearrangement reactions based on intermediate carbonium ions and carbanions, and also includes the benzil-benzilic acid and the Wolff rearrangements. The volume closes with coverage of carbonylation reactions, and the use of carbene insertion reactions into the C-H bond in synthesis.
Book Synopsis Selectivity in Carbon-carbon Bond Forming Reactions by : E. Buncel
Download or read book Selectivity in Carbon-carbon Bond Forming Reactions written by E. Buncel and published by . This book was released on 1984 with total page 303 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Dissertation Abstracts International by :
Download or read book Dissertation Abstracts International written by and published by . This book was released on 2006 with total page 886 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Carbon-carbon Bond Formation by : Robert L. Augustine
Download or read book Carbon-carbon Bond Formation written by Robert L. Augustine and published by CRC Press. This book was released on 1979-04-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Selectivity in Carbon-Carbon bond forming reactions. - 1984. - VII, 303 S. by : Erwin Buncel
Download or read book Selectivity in Carbon-Carbon bond forming reactions. - 1984. - VII, 303 S. written by Erwin Buncel and published by . This book was released on 1984 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Strong Metal-support Interactions by : R. T. K. Baker
Download or read book Strong Metal-support Interactions written by R. T. K. Baker and published by . This book was released on 1986 with total page 258 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Metal Oxides in Heterogeneous Catalysis by : Jacques C. Vedrine
Download or read book Metal Oxides in Heterogeneous Catalysis written by Jacques C. Vedrine and published by Elsevier. This book was released on 2018-01-11 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Oxides in Heterogeneous Catalysis is an overview of the past, present and future of heterogeneous catalysis using metal oxides catalysts. The book presents the historical, theoretical, and practical aspects of metal oxide-based heterogeneous catalysis. Metal Oxides in Heterogeneous Catalysis deals with fundamental information on heterogeneous catalysis, including reaction mechanisms and kinetics approaches.There is also a focus on the classification of metal oxides used as catalysts, preparation methods and touches on zeolites, mesoporous materials and Metal-organic frameworks (MOFs) in catalysis. It will touch on acid or base-type reactions, selective (partial) and total oxidation reactions, and enzymatic type reactions The book also touches heavily on the biomass applications of metal oxide catalysts and environmentally related/depollution reactions such as COVs elimination, DeNOx, and DeSOx. Finally, the book also deals with future trends and prospects in metal oxide-based heterogeneous catalysis. - Presents case studies in each chapter that provide a focus on the industrial applications - Includes fundamentals, key theories and practical applications of metal oxide-based heterogeneous catalysis in one comprehensive resource - Edited, and contributed, by leading experts who provide perspectives on synthesis, characterization and applications
Book Synopsis Radicals in Organic Synthesis by : Bernd Giese
Download or read book Radicals in Organic Synthesis written by Bernd Giese and published by C R C Press Reprints. This book was released on 1986 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Chemical Looping Partial Oxidation by : Liang-Shih Fan
Download or read book Chemical Looping Partial Oxidation written by Liang-Shih Fan and published by Cambridge University Press. This book was released on 2017-10-12 with total page 497 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first comprehensive guide to chemical looping partial oxidation processes, covering key principles, techniques, and applications.
Book Synopsis Solid State Chemistry in Catalysis by : Robert K. Grasselli
Download or read book Solid State Chemistry in Catalysis written by Robert K. Grasselli and published by . This book was released on 1985 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt: Good,No Highlights,No Markup,all pages are intact, Slight Shelfwear,may have the corners slightly dented, may have slight color changes/slightly damaged spine.
Book Synopsis Development of Neutral Redox Carbon-carbon Bond Forming Reactions Via Transition Metal-catalyzed Transfer Hydrogenation by : Khoa Dang Nguyen (Ph. D.)
Download or read book Development of Neutral Redox Carbon-carbon Bond Forming Reactions Via Transition Metal-catalyzed Transfer Hydrogenation written by Khoa Dang Nguyen (Ph. D.) and published by . This book was released on 2017 with total page 1316 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since C-C bonds form the backbone of every organic molecule and reside at the heart of chemical science, the development of new efficient methods for promoting C-C bond formation is of great significance. Inspired and expanded from traditional Grignard reactions, the work presented in this dissertation focuses on metal catalyzed neutral redox-triggered carbonyl addition via transfer hydrogenation. Advancing the native reducing capability of alcohols, employment of catalytic transition metals enables the formation of nucleophile-electrophile pairs in situ, en route to the products of formal alcohol C-H functionalization. These redox-triggered reactions circumvent the stoichiometric metallated byproduct waste and streamline the construction of complex molecules from simple and/or readily available feedstocks. The research reported herein discloses new developed methodologies of ruthenium and iridium catalyzed coupling reactions of primary and secondary alcohols with various pi-unsaturates. These studies contribute to the growing body of redox-triggered alcohol C-C couplings - new carbonyl addition chemistry that extends beyond the use of premetalated reagents.
Book Synopsis Activation and Functionalization of C-H Bonds by : Karen I. Goldberg
Download or read book Activation and Functionalization of C-H Bonds written by Karen I. Goldberg and published by ACS Symposium. This book was released on 2004 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Activation and Functionalization of C-H Bonds explores recent developments in the reaction chemistry of solution-phase transition-metal based systems with simple hydrocarbons and with more complex organic molecules. More than 20 internationally leading research groups contributed to this volume, and their chapters cover such topics as fundamental theoretical and mechanistic studies of C-H bond activation by metal complexes, catalytic systems for alkane functionalization, and new applications in synthetic organic chemistry. An introductory chapter offers an overview of stoichiometric and catalytic reactions of C-H bonds with transition metal complexes. The C-H bond is the most widespread linkage in organic chemistry, present in virtually every organic molecule. Unfortunately, C-H bonds are famously resistant to selective chemical transformations. The development of methods for their selective transformations has enormous potential value in fields ranging from the chemistry of fuels (for example, the conversion of methane to methanol) to the synthesis of the most complex organic molecules.
Book Synopsis Novel Interpretations of Carbon Oxide Reduction Reactions. I. Over Metal Oxides by :
Download or read book Novel Interpretations of Carbon Oxide Reduction Reactions. I. Over Metal Oxides written by and published by . This book was released on 1978 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The mechanism of the Fischer-Tropsch synthesis and the role of the catalyst in that reaction have not yet been satisfactorily explained. It is proposed that the reaction proceeds via the chemisorption of carbon monoxide through the oxygen and that the relative strengths of the metal-oxygen bond will help predict catalyst behavior. It is also proposed that carbon dioxide is reduced in an analogous manner by chemisorption through its oxygens. Although the postulates presented constitute a great oversimplification, the calculations demonstrate a qualitative guideline for the behavior of catalysts in the reaction. (JSR).
Book Synopsis Mechanistic Insights Into Carbon-Carbon Bond Oxidative Reconstruction and Construction by : Zhong Han Richmond Lee
Download or read book Mechanistic Insights Into Carbon-Carbon Bond Oxidative Reconstruction and Construction written by Zhong Han Richmond Lee and published by . This book was released on 2016 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical manipulation of carbon-carbon bond is an expansive subject and overarching theme in chemistry. By all accounts, it takes a broad and concerted experimental and theoretical effort in order to fully comprehend the nature of this chemical bond that is virtually omnipresent in most important molecules. Developing a more intimate understanding and appreciation of the stability and reactivity of carbon-carbon bonds through quantum chemical calculations is therefore the main theme and driver of this thesis. In this thesis, computational quantum chemistry was employed as the tool to assist in the mechanistic investigation of C=C and C-C bond oxidation by environmental oxidants (O3 and O2) and the associated peroxyl ROO self-reaction chemistry, copper catalysed aerobic photo-oxidation of double, triple and single carbon-carbon bonds, the stereoselective and chemo-divergent construction of C-C bonds, and rhodium catalysed C-C(O) bond formation in Metal Organic Frameworks. It was also used to examine why C-C bonds were not formed during the termination process of radical polymerisation of polyacrylates and decomposition of RAFT-based polymers. The scope of this work is wide but is just the tip of the iceberg on carbon-carbon bond chemistry. This thesis consists of 11 written manuscripts, and is categorised into two parts. The first part focuses on carbon-carbon bond cleavage and oxidative transformation to C(O), so termed 'oxidative reconstruction', and the second part on carbon-carbon bond generation or construction in a stereo and chemo-specific manner. To achieve these research goals, extensive and appropiately benchmarked quantum chemical calculations were used to paint an insightful mechanistic picture of the reactions mentioned, which went beyond simply capturing knowledge of the reactivities and properties of carbon-carbon bonds, but also provided clarifications to experiments, and allowed one to make perceptive chemical predictions. This thesis highlights the important role of theory in allowing new scientific ideas to prosper, for instance updating reaction mechanisms that conform to new experimental observations, enabling better catalysts to be designed and strategies to preserve the durability of polymers. In hindsight, each work and chapter strives to take further steps toward bridging gaps in our knowledge of carbon-carbon bond chemistry.
Book Synopsis Metal Catalysed Carbon-Carbon Bond-Forming Reactions by : SM. Roberts
Download or read book Metal Catalysed Carbon-Carbon Bond-Forming Reactions written by SM. Roberts and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Olefin Polymerization by : Walter Kaminsky
Download or read book Olefin Polymerization written by Walter Kaminsky and published by Wiley-VCH. This book was released on 2006-08-18 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: With an enormous velocity, olefin polymerization has expanded to one of the most significant fields in polymers since the first industrial use about 50 years ago. In 2005, 100 million tons of polyolefins were produced - the biggest part was catalyzed by metallorganic compounds. The Hamburg Macromolecular Symposium 2005 with the title "Olefin Polymerization" involved topics such as new catalysts and cocatalysts, kinetics, mechanism and polymer reaction engineering, synthesis of special polymers, and characterization of polyolefins. The conference combined scientists from different disciplines to discuss latest research results of polymers and to offer each other the possibility of cooperation. This is reflected in this volume, which contains invited lectures and selected posters presented at the symposium.
