Modern Coordination Chemistry

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Publisher : Royal Society of Chemistry
ISBN 13 : 1847551483
Total Pages : 416 pages
Book Rating : 4.8/5 (475 download)

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Book Synopsis Modern Coordination Chemistry by : Jeff Leigh

Download or read book Modern Coordination Chemistry written by Jeff Leigh and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: Coordination chemistry, as we know it today, has been shaped by major figures from the past, one of whom was Joseph Chatt. Beginning with a description of Chatt's career presented by co-workers, contemporaries and students, this fascinating book then goes on to show how many of today's leading practitioners in the field, working in such diverse areas as phosphines, hydrogen complexes, transition metal complexes and nitrogen fixation, have been influenced by Chatt. The reader is then brought right up-to-date with the inclusion of some of the latest research on these topics, all of which serves to underline Chatt's continuing legacy. Intended as a permanent record of Chatt's life, work and influence, this book will be of interest to lecturers, graduate students, researchers and science historians.

The Chemistry of the Catalyzed Hydrogenation of Carbon Monoxide

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Publisher : Springer Science & Business Media
ISBN 13 : 3642696627
Total Pages : 239 pages
Book Rating : 4.6/5 (426 download)

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Book Synopsis The Chemistry of the Catalyzed Hydrogenation of Carbon Monoxide by : G. Henrici-Olive

Download or read book The Chemistry of the Catalyzed Hydrogenation of Carbon Monoxide written by G. Henrici-Olive and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 239 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the oil embargo, in the winter 1973174, parts of Western Europe present ed an almost war-like aspect on Saturdays and Sundays: no traffic on the high ways, no crowds at ski resorts and other weekend entertainment places, no gaso line at the pumps. Living and teaching then in that part of the world, and discussing the situa tion with our students, we came to the conclusion that it would be timely to col lect the fine chemistry already known at the time in the field of conversion of coal to gasoline and other chemicals, and by this way help to draw the attention to this important alternative to crude oil. The idea of this book was born. The energy shock of the early seventies has been healthy and of great conse quences in chemistry. Large amounts of research money have been put to work since, and our knowledge of the possibilities and limitations of coal-based chemistry has increased enormously. During several years it appeared inap propriate to write a monograph about a topic which was in the midst of such an impetuous development. Nevertheless, we collected, and critically selected, the upcoming work as it appeared in the literature, and also tried to provide some modest input ourselves. Now, ten years later, the situation seems to be settled to a certain degree.

A Textbook of Inorganic Chemistry – Volume 1

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Author :
Publisher : Dalal Institute
ISBN 13 : 8193872002
Total Pages : 482 pages
Book Rating : 4.1/5 (938 download)

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Book Synopsis A Textbook of Inorganic Chemistry – Volume 1 by : Mandeep Dalal

Download or read book A Textbook of Inorganic Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.

Organometallic Chemistry and Catalysis

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Publisher : Springer Science & Business Media
ISBN 13 : 3540461280
Total Pages : 598 pages
Book Rating : 4.5/5 (44 download)

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Book Synopsis Organometallic Chemistry and Catalysis by : Didier Astruc

Download or read book Organometallic Chemistry and Catalysis written by Didier Astruc and published by Springer Science & Business Media. This book was released on 2007-08-02 with total page 598 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the book. Beginners in inorganic, organic and organometallic chemistry, as well as advanced scholars and chemists from academia and industry will find much value in this title.

Cluster Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 3642859267
Total Pages : 310 pages
Book Rating : 4.6/5 (428 download)

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Book Synopsis Cluster Chemistry by : Guillermo Gonzalez-Moraga

Download or read book Cluster Chemistry written by Guillermo Gonzalez-Moraga and published by Springer Science & Business Media. This book was released on 2013-11-09 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.

Palladacycles

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Publisher : John Wiley & Sons
ISBN 13 : 3527317813
Total Pages : 433 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Palladacycles by : Jairton Dupont

Download or read book Palladacycles written by Jairton Dupont and published by John Wiley & Sons. This book was released on 2008-10-13 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: From synthesis to applications in catalysis, material science and biology this much-needed book is the first to comprehensively present everything you need to know about palladacycles. Renowned international authors guarantee high-quality content, making this a must-have for everyone working in the field.

Understanding Organometallic Reaction Mechanisms and Catalysis

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Publisher : John Wiley & Sons
ISBN 13 : 3527678220
Total Pages : 483 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Understanding Organometallic Reaction Mechanisms and Catalysis by : Valentin P. Ananikov

Download or read book Understanding Organometallic Reaction Mechanisms and Catalysis written by Valentin P. Ananikov and published by John Wiley & Sons. This book was released on 2014-08-29 with total page 483 pages. Available in PDF, EPUB and Kindle. Book excerpt: Exploring and highlighting the new horizons in the studies of reaction mechanisms that open joint application of experimental studies and theoretical calculations is the goal of this book. The latest insights and developments in the mechanistic studies of organometallic reactions and catalytic processes are presented and reviewed. The book adopts a unique approach, exemplifying how to use experiments, spectroscopy measurements, and computational methods to reveal reaction pathways and molecular structures of catalysts, rather than concentrating solely on one discipline. The result is a deeper understanding of the underlying reaction mechanism and correlation between molecular structure and reactivity. The contributions represent a wealth of first-hand information from renowned experts working in these disciplines, covering such topics as activation of small molecules, C-C and C-Heteroatom bonds formation, cross-coupling reactions, carbon dioxide converison, homogeneous and heterogeneous transition metal catalysis and metal-graphene systems. With the knowledge gained, the reader will be able to improve existing reaction protocols and rationally design more efficient catalysts or selective reactions. An indispensable source of information for synthetic, analytical, and theoretical chemists in academia and industry.

Hydrosilylation

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Publisher : Springer Science & Business Media
ISBN 13 : 1402081723
Total Pages : 424 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Hydrosilylation by : Bogdan Marciniec

Download or read book Hydrosilylation written by Bogdan Marciniec and published by Springer Science & Business Media. This book was released on 2008-11-09 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: For fifty years, Hydrosilylation has been one of the most fundamental and elegant methods for the laboratory and industrial synthesis of organosilicon and silicon related compounds. Despite the intensive research and continued interest generated by organosilicon compounds, no comprehensive book incorporating its various aspects has been published this century. The aim of this book is to comprehensively review the advances of hydrosilylation processes since 1990. The survey of the literature published over the last two decades enables the authors to discuss the most recent aspects of hydrosilylation advances (catalytic and synthetic) and to elucidate the reaction mechanism for the given catalyst used and the reaction utilization. New catalytic pathways under optimum conditions necessary for efficient synthesis of organosilicon compounds are presented. This monograph shows the extensive development in the application of hydrosilylation in organic and asymmetric syntheses and in polymer and material science.

Science Data Booklet

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Author :
Publisher : Manjunath.R
ISBN 13 :
Total Pages : 1221 pages
Book Rating : 4./5 ( download)

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Book Synopsis Science Data Booklet by : Manjunath.R

Download or read book Science Data Booklet written by Manjunath.R and published by Manjunath.R. This book was released on 2020-07-11 with total page 1221 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Scientific Compendium: A Comprehensive Reference for Data and Formulas The "Science Data Booklet" is an essential companion for students, researchers, and science enthusiasts alike, providing a comprehensive collection of key scientific data and information. This meticulously curated reference book serves as a treasure trove of facts, equations, and formulas from various scientific disciplines, designed to empower readers with the tools they need to excel in their scientific pursuits. Inside this invaluable compendium, readers will discover a wealth of information spanning the realms of physics, chemistry, biology, astronomy, and more. From fundamental constants to conversion factors, this book offers a concise and easily accessible compilation of scientific knowledge that is essential for scientific investigations, experiments, and calculations. Whether you are a student preparing for exams, a researcher seeking quick access to vital data, or a science enthusiast eager to delve deeper into the world of scientific knowledge, this book is your indispensable companion. With the help of this book, you can access a plethora of scientific knowledge at your fingertips, anytime and anywhere. In a world increasingly driven by scientific advancements, the "Science Data Booklet" serves as an invaluable resource for anyone seeking to navigate the complexities of scientific data. This book is not only a reference guide but also a catalyst for curiosity, inspiring readers to explore the wonders of the natural world and embark on their own scientific journeys. Unlock the power of scientific knowledge with the "Science Data Booklet" and embark on a fascinating voyage of discovery, innovation, and understanding.

Reaction Mechanisms in Carbon Dioxide Conversion

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Publisher : Springer
ISBN 13 : 366246831X
Total Pages : 423 pages
Book Rating : 4.6/5 (624 download)

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Book Synopsis Reaction Mechanisms in Carbon Dioxide Conversion by : Michele Aresta

Download or read book Reaction Mechanisms in Carbon Dioxide Conversion written by Michele Aresta and published by Springer. This book was released on 2015-11-07 with total page 423 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an analysis of the reaction mechanisms relevant to a number of processes in which CO2 is converted into valuable products. Several different processes are considered that convert CO2 either in specialty chemicals or in bulk products or fuels. For each reaction, the mechanism is discussed and the assessed steps besides the dark sites of the reaction pathway are highlighted. From the insertion of CO2 into E-X bonds to the reduction of CO2 to CO or other C1 molecules or else to C2 or Cn molecules, the reactions are analysed in order to highlight the known and obscure reaction steps. Besides well known reaction mechanisms and energy profiles, several lesser known situations are discussed. Advancing knowledge of the latter would help to develop efficient routes for the conversion of CO2 into valuable products useful either in the chemical or in the energy industry. The content of this book is quite different from other books reporting the use of CO2. On account of its clear presentation, “Reaction Mechanisms in Carbon Dioxide Conversion” targets in particular researchers, teachers and PhD students.

Organometallic Chemistry and Catalysis

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Publisher : Springer Science & Business Media
ISBN 13 : 9783211835999
Total Pages : 184 pages
Book Rating : 4.8/5 (359 download)

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Book Synopsis Organometallic Chemistry and Catalysis by : Karl Kirchner

Download or read book Organometallic Chemistry and Catalysis written by Karl Kirchner and published by Springer Science & Business Media. This book was released on 2001-02-01 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt: From the beginning of chemistry as an exact (natural) science - almost 200 years ago - there was a more or less distinct differentiation between its various branches such as organic, inorganic, physical, analytical, or biochemistry. With the increasing insight into the connections and governing laws it soon became obvious, however, that such a clear separation could be regarded as more or less obsolete; within almost any field of chemical research one has to deal with most of the branches mentioned. Especially organic and inorganic chemistry are significant examples for this statement, overlapping considerably within the important field of organome tallic chemistry. This regime of chemistry started its advance with the discovery of dimethylzinc 150 years ago, had a highlight with the introduction of Grignard reagents around 1900, developed further with the start of lithium organyls in 1925 and literally exploded after the discovery of the first transition metal cyclopenta dienyl complex ferrocene half a century ago. The chronological sequence of the important steps, i. e. 1850 (Zn) - 1900 (Mg) - 1925 (Li) - 1950 (Fe), seems rather remarkable. The increasing group of metallocenes is not only of high theoretical and, due to the potential chirality of its members, stereochemical interest, but offers also a wide variety of extremely useful catalysts, especially for stereoselective reactions. The Austrian Chemical Society took this development into account by organizing the Twelfth International Conference on Organometallic Chemistry held in Vienna in 1985.

Handbook of Environmental Analysis

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Publisher : CRC Press
ISBN 13 : 1498745628
Total Pages : 661 pages
Book Rating : 4.4/5 (987 download)

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Book Synopsis Handbook of Environmental Analysis by : Pradyot Patnaik

Download or read book Handbook of Environmental Analysis written by Pradyot Patnaik and published by CRC Press. This book was released on 2017-08-23 with total page 661 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook will cover all aspects of environmental analysis and will examine the emergence of many new classes of pollutants in recent years. It will provide information on an array of topics from instrumentation, analytical techniques, and sample preparations to statistical calculations, chemical structures, and equations. It will present the tools and techniques required to measure a wide range of toxic pollutants in our environment. It will be fully revised throughout, and will add four new chapters (Microbial Analysis, Chlorophyll, Chlorine, Chloramines and Chlorine Dioxide, and Derivatization Reactions in Environmental Analysis).

Biomedical Applications of Metals

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Publisher : Springer
ISBN 13 : 3319748149
Total Pages : 332 pages
Book Rating : 4.3/5 (197 download)

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Book Synopsis Biomedical Applications of Metals by : Mahendra Rai

Download or read book Biomedical Applications of Metals written by Mahendra Rai and published by Springer. This book was released on 2018-02-24 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: Focused more specifically on the recent advances in applications of various metals and their complexes used in biomedicine, particularly in the diagnosis and treatment of chronic diseases. The editors give equal importance to other key aspects such as toxicological issues and safety concerns. The application of metals in the biomedical field is highly interdisciplinary and has a broad appeal across all biomedical specialties. Biomedical Applications of Metals is particularly focused on covering the role of metals in medicine and the development of novel therapeutic products and solutions in the form of alternative medicines, and some topics on Indian traditional medicine i.e., “Ayurveda”. In Section I, the book discusses the role of metals in medicines and include chapters on nanoparticles, noble metals, medical devices, copper. selenium, silver, and microbial pathogens; while Section II includes topics on metals toxicity including heavy metals, carcinogens, cancer therapy, Bhasma’s and chelating agents used in Ayurveda, and biochemical and molecular targets including actions of metals. These new and emerging concepts of applications of metals in medicine, their crucial role in management of microbial resistance, and their use in the treatment of various chronic diseases is essential information for toxicologists, and clinical and biomedical researchers.

Inorganic and Organometallic Reaction Mechanisms

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Publisher : John Wiley & Sons
ISBN 13 : 0471188972
Total Pages : 327 pages
Book Rating : 4.4/5 (711 download)

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Book Synopsis Inorganic and Organometallic Reaction Mechanisms by : Jim D. Atwood

Download or read book Inorganic and Organometallic Reaction Mechanisms written by Jim D. Atwood and published by John Wiley & Sons. This book was released on 1997-02-18 with total page 327 pages. Available in PDF, EPUB and Kindle. Book excerpt: Jetzt in neuer Auflage: Das erfolgreiche Lehrwerk über Kinetik und Mechanismen anorganischer und organometallischer Reaktionen für fortgeschrittene Studenten! Hervorragend geeignet als Begleiter eines Vorlesungssemesters. Mit zahlreichen Übungsaufgaben; für eine bessere Übersicht sorgen Zusammenfassungen am Ende jedes Kapitels.

Clusters and Colloids

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Publisher : John Wiley & Sons
ISBN 13 : 3527616063
Total Pages : 570 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Clusters and Colloids by : Günter Schmid

Download or read book Clusters and Colloids written by Günter Schmid and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive overview of the rapidly developing field of cluster science. In an interdisciplinary approach, basic concepts as well as recent developments in research and practical applications are authoritatively discussed by leading authors. Topics covered include 'naked' metal clusters, clusters stabilized by ligands, clusters in solids, and colloids. The reader will find answers to questions like: * How many metal atoms must a particle have to exhibit metallic properties? * How can the large specific surface of clusters and colloids be employed in catalysts? * How can metal clusters be introduced into solid hosts? * Which effects are responsible for the transition from isolated to condensed clusters? The editor has succeeded in bringing the contributions of various authors together into a homogeneous, readable book, which will be useful for the academic and industrial reader alike.

Fine Chemicals through Heterogeneous Catalysis

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Publisher : John Wiley & Sons
ISBN 13 : 3527612971
Total Pages : 636 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Fine Chemicals through Heterogeneous Catalysis by : R. A. Sheldon

Download or read book Fine Chemicals through Heterogeneous Catalysis written by R. A. Sheldon and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nowadays, the chemical industry is under increased pressure to develop cleaner production processes and technologies. Much effort is devoted to the development of heterogeneous catalysts and their application in industrial-scale organic synthesis. This handbook concentrates on current attempts, focusing on fine chemical production. With contributions from an impressive array of international experts, this is essential reading for everyone interested in the advances in this field.

Advanced Heterogeneous Catalysts, Volume 1

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Publisher : ACS Symposium
ISBN 13 : 9780841298804
Total Pages : 608 pages
Book Rating : 4.2/5 (988 download)

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Book Synopsis Advanced Heterogeneous Catalysts, Volume 1 by : Sudarsanam Putla

Download or read book Advanced Heterogeneous Catalysts, Volume 1 written by Sudarsanam Putla and published by ACS Symposium. This book was released on 2021-05-07 with total page 608 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances and applications of nanosized catalysts Over the last five years, tremendous advances have been made in heterogeneous catalysis. In particular, catalysts' design from the bulk to nano-scale (1-100 nm), with desirable active sites, has received great attention in current catalysis research with the aim to fill the gap between homogeneous and heterogeneous catalysis. This volume focuses on applications of nanosized catalysts. Articles describe characterization, synthesis, and applications in biomass conversion, auto-exhaust purification, selective oxidation/hydrogenation, syngas conversion, and other important reactions. Readers will find examples of catalysts designed to be tunable for specific outcomes, inspiring their research. Scientists and engineers in chemistry, materials science, nanotechnology, and chemical engineering will find this volume useful.