Author :
Publisher :
ISBN 13 :
Total Pages : 9 pages
Book Rating : 4.:/5 (16 download)
Book Synopsis Investigation of Combined SO2/NO3 Removal by Ceria Sorbents. Quarterly Technical Progress Report by :
Download or read book Investigation of Combined SO2/NO3 Removal by Ceria Sorbents. Quarterly Technical Progress Report written by and published by . This book was released on 1995 with total page 9 pages. Available in PDF, EPUB and Kindle. Book excerpt: Simultaneous removal of SO2 and NOx using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO2 and NOx removal operations. Recent studies at PETC considered cerium oxide as an alternate sorbent to CuO. The present study aims to determine the effects of ammonia on the sulfation of the sorbent and to obtain a rate expression for the regeneration of alumina-supported Ce2 sorbents. The sulfation experiments indicated that 100% conversion of ceria can be attained. Activation energy for the sulfation reaction was found to be 19 KJ/mol. The rate of sulfation reaction is first order with respect to SO2 and solid reactant concentrations. For regeneration with hydrogen, the activation energy and the reaction order with respect to hydrogen was found to be 114 KJ/mol and 0.56, respectively. The ceria sorbent preserved its activity and structural stability after 6 cycles. In the last quarter regeneration with methane was studied. Since regeneration with methane is more complicated than regeneration with hydrogen, the evaluation of data needs the development of new methods. The information obtained from these studies will be used to develop models for reactor-regenerator configurations. Subsequently, the SO2/NOx removal facility will be integrated into the power production process using a commercial process simulation software.