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Author : Mary E. Pulling
Publisher :
ISBN 13 :
Total Pages : 268 pages
Book Rating : 4.:/5 (69 download)
Download or read book Hydrogen Atom Transfer from Transition-metal Hydrides written by Mary E. Pulling and published by . This book was released on 2009 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Graham Abramo
Publisher :
ISBN 13 :
Total Pages : 292 pages
Book Rating : 4.:/5 (457 download)
Download or read book Kinetics, Mechanism, and Applications of Hydrogen Atom Transfer from Transition-metal Hydrides written by Graham Abramo and published by . This book was released on 2000 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Alain Dedieu
Publisher :
ISBN 13 :
Total Pages : 424 pages
Book Rating : 4.F/5 ( download)
Download or read book Transition Metal Hydrides written by Alain Dedieu and published by . This book was released on 1992 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Chengbo Yao
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (131 download)
Download or read book First Row Transition Metal Hydrides Catalyzed Hydrogen Atom Transfer written by Chengbo Yao and published by . This book was released on 2022 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: By combining this reaction with the H• transfer, metalloradicals can often catalyze the formation of radicals from H2. Over the years, the Norton group has studied several transition metal hydride systems and demonstrated their applications in different scenarios. The kinetics and thermodynamics of these systems have been studies in detail, and they are shown be competent hydrogen atom donors to unsaturated organic substrates and to organic radicals. Some of these metal hydrides can be made catalytic under hydrogen pressure, thus providing an atom-economical way to effect radical reactions. Specifically, the thermodynamic properties of the chromium hydride HCpCr(CO)3 have been carefully studied. Based on this information, I developed a Ti/Cr cooperative catalytic system featuring multiple interactions between the two metal systems. Herein are described three applications of this Ti/Cr catalytic system: anti-Markovnikov hydrogenation of epoxides (Chapter 2), reductive cyclization of epoxy enones under H2 (Chapter 3), and aziridine isomerization to allyl amines (Chapter 4).
Author : Jongwook Choi
Publisher :
ISBN 13 :
Total Pages : 254 pages
Book Rating : 4.:/5 (213 download)
Download or read book Thermodynamics and Kinetics of Hydrogen Atom Transfer from Transition-metal Hydrides written by Jongwook Choi and published by . This book was released on 2007 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Anne Erwin Moody
Publisher :
ISBN 13 :
Total Pages : 212 pages
Book Rating : 4.:/5 (228 download)
Download or read book Thermodynamic Acidities and Hydrogen Atom Transfer Rates of Transition Metal Hydrides written by Anne Erwin Moody and published by . This book was released on 1989 with total page 212 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Maurizio Peruzzini
Publisher : Elsevier
ISBN 13 : 0080540333
Total Pages : 577 pages
Book Rating : 4.0/5 (85 download)
Download or read book Recent Advances in Hydride Chemistry written by Maurizio Peruzzini and published by Elsevier. This book was released on 2002-01-30 with total page 577 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book has been conceived to collect the most important recent advances in all areas of hydride chemistry research, including chemical reactivity, instrumental investigation, theory, and applications in the areas of catalysis, biochemistry and materials science. Many of the chapters have been written by the plenary lecturers of the EURO-Hydrides 2000 conference, but other leading scientists in this field have also been invited to contribute. The first part of the book focuses on the chemistry and catalysis of transition metal hydrides. Another block of chapters illustrates the most recent advances in the application of instrumental techniques to the study of the properties and reactivity of hydride compounds. The final part of the book illustrates the relevance of metal-hydrogen bonds in biochemistry and materials science. All of the chapters of this book have been evaluated by independent reviewers.
Download or read book Transition Metal Hydrides that Mediate Catalytic Hydrogen Atom Transfers written by and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: I have attempted to regenerate these vanadium hydrides by a sequential reduction then protonation of the metalloradical. With HV(CO)4dppe this only produced hydrogen gas, presumably by one electron reduction of HV(CO)4dppe. However, with HV(CO)4dppf this does not readily occur and this hydride could potentially be a catalyst for radical cyclizations. Many radical cyclizations involve vinyl (sp2) radicals. I have shown that both the CpCr(CO)3H and the Co(dmgBF2)2(H2O)2 systems can catalytically perform metal to alkyne hydrogen atom transfers (MAHAT's) and that these reactions can be used to perform radical cyclizations very efficiently.
Author : Justine Pilar Roth
Publisher :
ISBN 13 :
Total Pages : 370 pages
Book Rating : 4.:/5 (466 download)
Download or read book Intrinsic and Thermodynamic Influences on Hydrogen Atom Transfer Reactions Involving Transition Metal Complexes written by Justine Pilar Roth and published by . This book was released on 2000 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Ian Anderson Kieffer
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (13 download)
Download or read book Investigation and Manipulation of Proton, Hydride, and Hydrogen Atom Transfer with Main Group Compounds written by Ian Anderson Kieffer and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : John F. Hartwig
Publisher :
ISBN 13 :
Total Pages : 1172 pages
Book Rating : 4.:/5 (318 download)
Download or read book Organotransition Metal Chemistry: From Bonding to Catalysis written by John F. Hartwig and published by . This book was released on 2010-02-10 with total page 1172 pages. Available in PDF, EPUB and Kindle. Book excerpt: Based on Collman et al.'s best-selling classic book, Principles and Applications of Organotransition Metal Chemistry, Hartwig's text consists of new or thoroughly updated and restructured chapters and provides an in-depth view into mechanism, reaction scope, and applications. It covers the most important developments in the field over the last twenty years with great clarity with a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the elementary reactions of these complexes, and many catalytic processes occurring through organometallic intermediates, making this the Organotransition Metal Chemistry text for a new generation of scientists.
Author : Hans-Joachim Knoelker
Publisher : Springer Science & Business Media
ISBN 13 : 3642255280
Total Pages : 268 pages
Book Rating : 4.6/5 (422 download)
Download or read book Alkaloid Synthesis written by Hans-Joachim Knoelker and published by Springer Science & Business Media. This book was released on 2012-01-13 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lycopodium Alkaloids: Isolation and Asymmetric Synthesis, by Mariko Kitajima and Hiromitsu Takayama.- Synthesis of Morphine Alkaloids and Derivatives, by Uwe Rinner and Tomas Hudlicky.- Indole Prenylation in Alkaloid Synthesis, by Thomas Lindel, Nils Marsch and Santosh Kumar Adla.- Marine Pyrroloiminoquinone Alkaloids, by Yasuyuki Kita and Hiromichi Fujioka.- Synthetic Studies on Amaryllidaceae and Other Terrestrially Derived Alkaloids, by Martin G. Banwell, Nadia Yuqian Gao, Brett D. Schwartz and Lorenzo V. White.- Synthesis of Pyrrole and Carbazole Alkaloids, by Ingmar Bauer and Hans-Joachim Knölker.-
Author : Gabriela Guillena
Publisher : Springer
ISBN 13 : 3319430513
Total Pages : 393 pages
Book Rating : 4.3/5 (194 download)
Download or read book Hydrogen Transfer Reactions written by Gabriela Guillena and published by Springer. This book was released on 2016-09-27 with total page 393 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
Author : Elizabeth Papish
Publisher :
ISBN 13 :
Total Pages : 312 pages
Book Rating : 4.:/5 (522 download)
Download or read book Kinetics and Thermodynamics of Proton and Hydrogen Atom Transfer from Transistion Metal Hydrides written by Elizabeth Papish and published by . This book was released on 2002 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Jonathan Lan Kuo
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (11 download)
Download or read book Using First Row Transition Metal Hydrides as Hydrogen Atom Donors written by Jonathan Lan Kuo and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: I have therefore reevaluated the reactivity of [CpV(CO)3H]–, and found that although the 18 electron anionic hydride is not a good hydrogen atom donor, the oxidized 17-electron neutral CpV(CO)3H is an extremely potent one. I have made the reactions with [CpV(CO)3H]– catalytic under H2 (now the reactions are done with an added base). The catalytic reactions that use [CpV(CO)3H]– can enact the exact same transformations that tin does, so I have developed a true catalytic replacement for Bu3SnH.
Author : L. Cervený
Publisher : Elsevier
ISBN 13 : 0080960618
Total Pages : 705 pages
Book Rating : 4.0/5 (89 download)
Download or read book Catalytic Hydrogenation written by L. Cervený and published by Elsevier. This book was released on 1986-08-01 with total page 705 pages. Available in PDF, EPUB and Kindle. Book excerpt: The collection of contributions in this volume presents the most up-to-date findings in catalytic hydrogenation. The individual chapters have been written by 36 top specialists each of whom has achieved a remarkable depth of coverage when dealing with his particular topic. In addition to detailed treatment of the most recent problems connected with catalytic hydrogenations, the book also contains a number of previously unpublished results obtained either by the authors themselves or within the organizations to which they are affiliated.Because of its topical and original character, the book provides a wealth of information which will be invaluable not only to researchers and technicians dealing with hydrogenation, but also to all those concerned with homogeneous and heterogeneous catalysis, organic technology, petrochemistry and chemical engineering.
Author : Gust Bambakidis
Publisher : Springer
ISBN 13 :
Total Pages : 408 pages
Book Rating : 4.:/5 (44 download)
Download or read book Metal Hydrides written by Gust Bambakidis and published by Springer. This book was released on 1981-12-31 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last five years, the study of metal hydrides has ex panded enormously due to the potential technological importance of this class of materials in hydrogen based energy conversion schemes. The scope of this activity has been worldwide among the industrially advanced nations. There has been a consensus among researchers in both fundamental and applied areas that a more basic understanding of the properties of metal/hydrogen syster;,s is required in order to provide a rational basis for the selection of materials for specific applications. The current worldwide need for and interest in research in metal hydrides indicated the timeliness of an Advanced Study Insti tute to provide an in-depth view of the field for those active in its various aspects. The inclusion of speakers from non-NATO coun tries provided the opportunity for cross-fertilization of ideas for future research. While the emphasis of the Institute was on basic properties, there was a conscious effort to stimulate interest in the application of metal hydrides to solar/hydrogen energy conver sion schemes in land areas where solar energy has promise as a primary energy source. In addition to the lectures, several seminars were given which treated topics of special interest in greater detail.
