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High Efficiency Syngas Generation
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Book Synopsis HIGH EFFICIENCY SYNGAS GENERATION. by :
Download or read book HIGH EFFICIENCY SYNGAS GENERATION. written by and published by . This book was released on 2005 with total page 30 pages. Available in PDF, EPUB and Kindle. Book excerpt: This project investigated an efficient and low cost method of auto-thermally reforming natural gas to hydrogen and carbon monoxide. Reforming is the highest cost step in producing products such as methanol and Fisher Tropsch liquids (i.e., gas to liquids); and reducing the cost of reforming is the key to reducing the cost of these products. Steam reforming is expensive because of the high cost of the high nickel alloy reforming tubes (i.e., indirectly fired reforming tubes). Conventional auto-thermal or Partial Oxidation (POX) reforming minimizes the size and cost of the reformers and provides a near optimum mixture of CO and hydrogen. However POX requires pure oxygen, which consumes power and significantly increases the cost to reforming. Our high efficiency process extracts oxygen from low-pressure air with novel oxygen sorbent and transfers the oxygen to a nickel-catalyzed reformer. The syngas is generated at process pressure (typically 20 to 40 bar) without nitrogen dilution and has a 1CO to 2H2 ratio that is near optimum for the subsequent production of Fisher-Tropsch liquid to liquids and other chemicals (i.e., Gas to Liquids, GTL). Our high process efficiency comes from the way we transfer the oxygen into the reformer. All of the components of the process, except for the oxygen sorbent, are commonly used in commercial practice. A process based on a longlived, regenerable, oxygen transfer sorbent could substantially reduce the cost of natural gas reforming to syngas. Lower cost syngas (CO + 2H2) that is the feedstock for GTL would reduce the cost of GTL and for other commercial applications (e.g., methanol, other organic chemicals). The vast gas resources of Alaska's North Slope (ANS) offer more than 22 Tcf of gas and GTL production in this application alone, and could account for as much as 300,000 to 700,000 bpd for 20 to 30+ years. We developed a new sorbent, which is an essential part of the High Efficiency Oxygen Process (HOP). We tested the sorbent and observed that it has both a good oxygen capacity and operates as a highly effective reforming catalyst. We conducted a long duration tests of the sorbent (1,500 hours of continuous operation in the HOP cycle). Although the sorbent lost some oxygen capacity with cycling, the sorbent oxygen capacity stabilized after 1,000 hours and remained constant to the end of the test, 1,500 hour. The activity of the catalyst to reform methane to a hydrogen and carbon monoxide mixture was unchanged through the oxidation/reduction cycling. Our cost and performance analyses indicated a significant reduction in the cost of GTL production when using the HOP process integrated into a GTL plant.
Book Synopsis Natural Gas Conversion V by : A. Parmaliana
Download or read book Natural Gas Conversion V written by A. Parmaliana and published by Elsevier. This book was released on 1998-09-17 with total page 1005 pages. Available in PDF, EPUB and Kindle. Book excerpt: On January 1988, the ascertained and economically accessible reserves of Natural Gas (NG) amounted to over 144,000 billion cubic meters worldwide, corresponding to 124 billion tons of oil equivalents (comparable with the liquid oil reserves, which are estimated to be 138 billion TOE). It is hypothesized that the volume of NG reserve will continue to grow at the same rate of the last decade. Forecasts on production indicate a potential increase from about 2,000 billion cubic meters in 1990 to not more than 3,300 billion cubic meters in 2010, even in a high economic development scenario. NG consumption represents only one half of oil: 1.9 billion TOE/y as compared to 3.5 of oil. Consequently, in the future gas will exceed oil as a carbon atom source. In the future the potential for getting energetic vectors or petrochemicals from NG will continue to grow. The topics covered in Natural Gas Conversion V reflect the large global R&D effort to look for new and economic ways of NG exploitation. These range from the direct conversion of methane and light paraffins to the indirect conversion through synthesis gas to fuels and chemicals. Particularly underlined and visible are the technologies already commercially viable. These proceedings prove that mature and technologically feasible processes for natural gas conversion are already available and that new and improved catalytic approaches are currently developing, the validity and feasibility of which will soon be documented. This is an exciting area of modern catalysis, which will certainly open novel and rewarding perspectives for the chemical, energy and petrochemical industries.
Book Synopsis Hydrogen and Syngas Production and Purification Technologies by : Ke Liu
Download or read book Hydrogen and Syngas Production and Purification Technologies written by Ke Liu and published by John Wiley & Sons. This book was released on 2010-01-07 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covers the timely topic of fuel cells and hydrogen-based energy from its fundamentals to practical applications Serves as a resource for practicing researchers and as a text in graduate-level programs Tackles crucial aspects in light of the new directions in the energy industry, in particular how to integrate fuel processing into contemporary systems like nuclear and gas power plants Includes homework-style problems
Book Synopsis Sustainable Alternative Syngas Fuel by : Chaouki Ghenai
Download or read book Sustainable Alternative Syngas Fuel written by Chaouki Ghenai and published by BoD – Books on Demand. This book was released on 2019-11-27 with total page 105 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development and use of sustainable and alternative fuels (syngas, biogas, biodiesel, bio-oil, hydrogen) derived from sources other than petroleum is needed due to the limited fossil fuel resources, the need for reduction of atmospheric greenhouse gas emissions, energy security, and to meet the future high energy demand due to population growth. New alternative fuels that can be produced locally and derived from renewable sources will be more sustainable compared to fossil fuels. Alternative and renewable fuels can be produced using different thermochemical and bio-chemical processes. Gasification is a thermochemical process used to produce syngas fuel (mainly hydrogen and carbon dioxide) from renewable (biomass) and conventional (coal) sources. The syngas fuels produced from the gasification process can be used for different applications: power generation (combustion of syngas fuel in gas turbine engines), heating, and transportation (internal combustion engines). This book intends to provide the reader with an overview of the current technologies, methods, and strategies of syngas fuel production, characterization, and application.
Book Synopsis Polygeneration Systems by : Francesco Calise
Download or read book Polygeneration Systems written by Francesco Calise and published by Academic Press. This book was released on 2021-09-22 with total page 453 pages. Available in PDF, EPUB and Kindle. Book excerpt: The support for polygeneration lies in the possibility of integrating different technologies into a single energy system, to maximize the utilization of both fossil and renewable fuels. A system that delivers multiple forms of energy to users, maximizing the overall efficiency makes polygeneration an emerging and viable option for energy consuming industries. Polygeneration Systems: Design, Processes and Technologies provides simple and advanced calculation techniques to evaluate energy, environmental and economic performance of polygeneration systems under analysis. With specific design guidelines for each type of polygeneration system and experimental performance data, referred both to single components and overall systems, this title covers all aspects of polygeneration from design to operation, optimization and practical implementation. Giving different aspects of both fossil and non-fossil fuel based polygeneration and the wider area of polygeneration processes, this book helps readers learn general principles to specific system design and development through analysis of case studies, examples, simulation characteristics and thermodynamic and economic data. Detailed economic data for technology to assist developing feasibility studies regarding the possible application of polygeneration technologies Offers a comprehensive list of all current numerical and experimental results of polygeneration available Includes simulation models, cost figures, demonstration projects and test standards for designers and researchers to validate their own models and/or to test the reliability of their results
Book Synopsis Sustainable Strategies for the Upgrading of Natural Gas: Fundamentals, Challenges, and Opportunities by : E.G. Derouane
Download or read book Sustainable Strategies for the Upgrading of Natural Gas: Fundamentals, Challenges, and Opportunities written by E.G. Derouane and published by Springer Science & Business Media. This book was released on 2005-06-01 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt: Energy and feedstock materials for the chemical industry are in increasing demand and, with constraints related to the availability and use of oil, the energy and chemical industry is undergoing considerable changes. In recent years, major restructuring has occurred in the oil, petrochemical, and chemical industry, with increasing attention devoted to the use of natural gas, methane in particular, as a chemical feedstock rather than just as a fuel. The conversion of remote natural gas into liquid fuels or other transportable chemicals is a challenge to industrial catalysis. Few processes exist so far with the major ones involving the conversion of natural gas to synthesis gas by steam reforming, CO2 reforming, or partial oxidation, followed by the syntheses of methanol, hydrocarbons (Fischer-Tropsch synthesis), or ammonia. In this book, a comprehensive overview of the field of processing natural gas is given, through a series of chapters written by leading scientists and engineers in the field. New developments are discussed and current work relevant to the area is shown by a series of recent works by researchers working in this and related fields.
Download or read book Biofuels written by Krzysztof Biernat and published by BoD – Books on Demand. This book was released on 2018-07-11 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers the current state of knowledge in the field of biofuels, presented by selected research centers from around the world. Biogas from waste production process and areas of application of biomethane were characterized. Also, possibilities of applications of wastes from fruit bunch of oil palm tree and high biomass/bagasse from sorghum and Bermuda grass for second-generation bioethanol were presented. Processes and mechanisms of biodiesel production, including the review of catalytic transesterification process, and careful analysis of kinetics, including bioreactor system for algae breeding, were widely analyzed. Problem of emissivity of NOx from engines fueled by B20 fuel was characterized. The closing chapters deal with the assessment of the potential of biofuels in Turkey, the components of refinery systems for production of biodegradable plastics from biomass. Also, a chapter concerning the environmental conditions of synthesis gas production as a universal raw material for the production of alternative fuels was also added.
Book Synopsis Syngas from Waste by : Luis Puigjaner
Download or read book Syngas from Waste written by Luis Puigjaner and published by Springer Science & Business Media. This book was released on 2011-07-15 with total page 329 pages. Available in PDF, EPUB and Kindle. Book excerpt: Syngas from Waste presents the most recent concepts, methods and techniques for the preliminary design of a promising emerging technology: production of clean syngas from waste materials. An in-depth account is given of the steps necessary to achieve the optimum design and up-to-date tools are presented to support the designer’s decision-making tasks: modelling, simulation and optimization. Numerous illustrations and tables are included to facilitate the reader’s understanding, as well as suggestions for further reading. The text is complemented with practical examples and industrial applications ranging from clean power generation to complex combined heat and power systems and high purity hydrogen for use in fuel cells. Syngas from Waste contains high-quality contributions from leading experts in the field. It is intended for academics at MSc or PhD level, researchers and industry practitioners in syngas production and applications, who are involved in the design, retrofit design and evaluation activities of alternative scenarios. It contains valuable teaching material for lecturers and provides industry professionals with the know-how to evaluate and improve existing installations or even to design a new one.
Book Synopsis Natural Gas Conversion VI by : T.H. Fleisch
Download or read book Natural Gas Conversion VI written by T.H. Fleisch and published by Elsevier. This book was released on 2001-06-01 with total page 577 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains peer-reviewed manuscripts describing the scientific and technological advances presented at the 6th Natural Gas Conversion Sumposium held in Alaska in June 2001. This symposium continues the tradition of excellence and the status as the premier technical meeting in this area established by previous meetings. The 6th Natural Gas Conversion Symposium is conducted under the overall direction of the Organizing Committee. The Program Committee was responsible for the review, selection, editing of most of the manuscripts included in this volum. A standing International Advisory Board has ensured the effective long-term planning and the continuity and technical excellence of these meetings.
Book Synopsis Integrated Gasification Combined Cycle (IGCC) Technologies by : Ting Wang
Download or read book Integrated Gasification Combined Cycle (IGCC) Technologies written by Ting Wang and published by Woodhead Publishing. This book was released on 2016-11-26 with total page 929 pages. Available in PDF, EPUB and Kindle. Book excerpt: Integrated Gasification Combined Cycle (IGCC) Technologies discusses this innovative power generation technology that combines modern coal gasification technology with both gas turbine and steam turbine power generation, an important emerging technology which has the potential to significantly improve the efficiencies and emissions of coal power plants. The advantages of this technology over conventional pulverized coal power plants include fuel flexibility, greater efficiencies, and very low pollutant emissions. The book reviews the current status and future developments of key technologies involved in IGCC plants and how they can be integrated to maximize efficiency and reduce the cost of electricity generation in a carbon-constrained world. The first part of this book introduces the principles of IGCC systems and the fuel types for use in IGCC systems. The second part covers syngas production within IGCC systems. The third part looks at syngas cleaning, the separation of CO2 and hydrogen enrichment, with final sections describing the gas turbine combined cycle and presenting several case studies of existing IGCC plants. Provides an in-depth, multi-contributor overview of integrated gasification combined cycle technologies Reviews the current status and future developments of key technologies involved in IGCC plants Provides several case studies of existing IGCC plants around the world
Book Synopsis Syngas Generation from Hydrocarbons and Oxygenates with Structured Catalysts by : Vladislav Sadykov
Download or read book Syngas Generation from Hydrocarbons and Oxygenates with Structured Catalysts written by Vladislav Sadykov and published by Nova Science Publishers. This book was released on 2012 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Syngas generation by oxidative or steam reforming of hydrocarbons and oxygenates now attracts a lot of attention of researchers in the fields of heterogeneous catalysis and chemical engineering due to its tremendous importance for energy generation and synfuels production. This book reviews results of the long-term research of the international team of scientists aimed at development of efficient processes of syngas generation in structured catalytic reactors. Multiscale integrated optimisation approach is applied throughout of this work including design of nanocomposite active components stable to coking and sintering; developing heat-conducting monolithic substrates comprised of refractory alloys and cermets (honeycomb and microchannel structures, gauzes etc) and procedures of their loading with active components; design and manufacturing of several types of pilot-scale reactors (with the radial or the axial flow direction) equipped with unique liquid fuel evaporation and mixing units and internal heat exchangers. Extended tests of these reactors fed by fuels from C1 to gasoline, mineral and sunflower oil have been carried out with a broad variation of experimental parameters including stability tests up to 1000 h. Performance analysis has been made with a due regard for equilibrium restrictions on the operational parameters. Transient behaviour of the monolith reactor during start-up (ignition) of the methane partial oxidation to synthesis gas was studied and analysed via mathematical modelling based upon detailed elementary step mechanism. This provides required bases for theoretical optimisation of the catalyst bed configuration and process parameters.
Book Synopsis Advanced Nanomaterials for Catalysis and Energy by : Vladislav A. Sadykov
Download or read book Advanced Nanomaterials for Catalysis and Energy written by Vladislav A. Sadykov and published by Elsevier. This book was released on 2018-08-27 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Nanomaterials for Catalysis and Energy: Synthesis, Characterization and Applications outlines new approaches to the synthesis of nanomaterials (synthesis in flow conditions, laser electrodispersion of single metals or alloys on carbon or oxide supports, mechanochemistry, sol-gel routes, etc.) to provide systems with a narrow particle size distribution, controlled metal-support interaction and nanocomposites with uniform spatial distribution of domains of different phases, even in dense sintered materials. Methods for characterization of real structure and surface properties of nanomaterials are discussed, including synchrotron radiation diffraction and X-ray photoelectron spectroscopy studies, neutronography, transmission/scanning electron microscopy with elemental analysis, and more. The book covers the effect of nanosystems' composition, bulk and surface properties, metal-support interaction, particle size and morphology, deposition density, etc. on their functional properties (transport features, catalytic activity and reaction mechanism). Finally, it includes examples of various developed nanostructured solid electrolytes and mixed ionic-electronic conductors as materials in solid oxide fuel cells and asymmetric supported membranes for oxygen and hydrogen separation. Outlines synthetic and characterization methods for nanocatalysts Relates nanocatalysts' properties to their specific applications Proposes optimization methods aiming at specific applications
Book Synopsis Hydrogen Production Technologies by : Mehmet Sankir
Download or read book Hydrogen Production Technologies written by Mehmet Sankir and published by John Wiley & Sons. This book was released on 2017-03-20 with total page 653 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a comprehensive practical review of the new technologies used to obtain hydrogen more efficiently via catalytic, electrochemical, bio- and photohydrogen production. Hydrogen has been gaining more attention in both transportation and stationary power applications. Fuel cell-powered cars are on the roads and the automotive industry is demanding feasible and efficient technologies to produce hydrogen. The principles and methods described herein lead to reasonable mitigation of the great majority of problems associated with hydrogen production technologies. The chapters in this book are written by distinguished authors who have extensive experience in their fields, and readers will have a chance to compare the fundamental production techniques and learn about the pros and cons of these technologies. The book is organized into three parts. Part I shows the catalytic and electrochemical principles involved in hydrogen production technologies. Part II addresses hydrogen production from electrochemically active bacteria (EAB) by decomposing organic compound into hydrogen in microbial electrolysis cells (MECs). The final part of the book is concerned with photohydrogen generation. Recent developments in the area of semiconductor-based nanomaterials, specifically semiconductor oxides, nitrides and metal free semiconductor-based nanomaterials for photocatalytic hydrogen production are extensively discussed.
Book Synopsis Integrated Energy Systems for Multigeneration by : Ibrahim Dincer
Download or read book Integrated Energy Systems for Multigeneration written by Ibrahim Dincer and published by Elsevier. This book was released on 2019-09-13 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt: Integrated Energy Systems for Multigeneration looks at how measures implemented to limit greenhouse gas emissions must consider smart utilization of available limited resources and employ renewable resources through integrated energy systems and the utilization of waste energy streams. This reference considers the main concepts of thermal and conventional energy systems through detailed systems description, analyses of methodologies, performance assessment and optimization, and illustrative examples and case studies. The book examines producing power and heat with cooling, freshwater, green fuels and other useful commodities designed to tackle rising greenhouse gas emissions in the atmosphere. With worldwide energy demand increasing, and the consequences of meeting supply with current dependency on fossil fuels, investigating and developing sustainable alternatives to the conventional energy systems is a growing concern for global stakeholders. Analyzes the links between clean energy technologies and achieving sustainable development Illustrates several examples of design and analysis of integrated energy systems Discusses performance assessment and optimization Uses illustrative examples and global case studies to explain methodologies and concepts
Book Synopsis Synthetic Natural Gas by : Tilman J. Schildhauer
Download or read book Synthetic Natural Gas written by Tilman J. Schildhauer and published by John Wiley & Sons. This book was released on 2016-07-05 with total page 325 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides an overview of the different pathways to produce Synthetic Natural Gas Covers technological, and economic aspects of this Synthetic Natural Gas Details the most popular technologies and state-of-the-art of SNG technologies while also covering recent and future research trends Covers the main process steps during conversion of coal and dry biomass to SNG: gasification, gas cleaning, methanation and gas upgrading Describes a number of novel processes for the production of SNG with their specific combination of process steps as well as the boundary conditions Covers important technical aspects of Power-to-Gas processes
Book Synopsis Catalysts for Syngas Production by : Javier Ereña Loizaga
Download or read book Catalysts for Syngas Production written by Javier Ereña Loizaga and published by MDPI. This book was released on 2020-12-10 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Special Issue on “Catalysts for Syngas Production”, included in the Catalysts open access journal, shows new research about the development of catalysts and catalytic routes for syngas production, and the optimization of the reaction conditions for the process. This issue includes ten articles about the different innovative processes for syngas production. Synthesis gas (or syngas) is a mixture of hydrogen and carbon monoxide, with different chemical composition and H2/CO molar ratios, depending on the feedstock and production technology used. Syngas may be obtained from alternative sources to oil, such as natural gas, coal, biomass, organic wastes, etc. Syngas is a very good intermediate for the production of high value compounds at the industrial scale, such as hydrogen, methanol, liquid fuels, and a wide range of chemicals. Accordingly, efforts should be made on the co-feeding of CO2 with syngas, as an alternative for reducing greenhouse gas emissions. In addition, more syngas will be required in the near future, in order to satisfy the demand for synfuels and high value chemicals.
Book Synopsis Biomass Volume Estimation and Valorization for Energy by : Jaya Shankar Tumuluru
Download or read book Biomass Volume Estimation and Valorization for Energy written by Jaya Shankar Tumuluru and published by BoD – Books on Demand. This book was released on 2017-02-22 with total page 518 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is the outcome of contributions by many experts in the field from different disciplines, various backgrounds, and diverse expertise. This book provides information on biomass volume calculation methods and biomass valorization for energy production. The chapters presented in this book include original research and review articles. I hope the research presented in this book will help to advance the use of biomass for bioenergy production and valorization. The key features of the book are: Providing information on biomass volume estimation using direct, nondestructive and remote sensing methods Biomass valorization for energy using thermochemical (gasification and pyrolysis) and biochemical (fermentation) conversion processes.
