Group 2 Mediated Dehydrocoupling

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Group 2 Mediated Dehydrocoupling

Author : David J Liptrot
Publisher : Springer
ISBN 13 : 331921036X
Total Pages : 162 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis Group 2 Mediated Dehydrocoupling by : David J Liptrot

Download or read book Group 2 Mediated Dehydrocoupling written by David J Liptrot and published by Springer. This book was released on 2015-07-28 with total page 162 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents an in-depth study into the utility of σ-bond metathesis in Group 2 mediated reactivity. A comprehensive introduction defines the state of the art in both Group 2 mediated catalysis and dehydrocoupling. Structural investigations giving rise to a range of mixed s-block metal hydrides including a remarkable dodecabimetallic decahydride are then described. Subsequent extensive mechanistic work focussing on both silicon-nitrogen and boron-nitrogen dehydrocoupling gives insights into both congeneric effects down Group 2 and ligand effects centring upon magnesium. These studies show the striking effects of these factors, as well as the electronic nature of the hydridic coupling partner. Finally, the unprecedented introduction of single-electron transfer steps into Group 2 catalytic manifolds is described. The use of the stable radical TEMPO to induce single-electron transfer to substituents bound to Group 2 centres coupled with σ-bond metathesis allows a novel hydrogen release from silanes.

Comprehensive Inorganic Chemistry II

Author :
Publisher : Newnes
ISBN 13 : 0080965296
Total Pages : 7694 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Comprehensive Inorganic Chemistry II by :

Download or read book Comprehensive Inorganic Chemistry II written by and published by Newnes. This book was released on 2013-07-23 with total page 7694 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Inorganic Chemistry II, Nine Volume Set reviews and examines topics of relevance to today’s inorganic chemists. Covering more interdisciplinary and high impact areas, Comprehensive Inorganic Chemistry II includes biological inorganic chemistry, solid state chemistry, materials chemistry, and nanoscience. The work is designed to follow on, with a different viewpoint and format, from our 1973 work, Comprehensive Inorganic Chemistry, edited by Bailar, Emeléus, Nyholm, and Trotman-Dickenson, which has received over 2,000 citations. The new work will also complement other recent Elsevier works in this area, Comprehensive Coordination Chemistry and Comprehensive Organometallic Chemistry, to form a trio of works covering the whole of modern inorganic chemistry. Chapters are designed to provide a valuable, long-standing scientific resource for both advanced students new to an area and researchers who need further background or answers to a particular problem on the elements, their compounds, or applications. Chapters are written by teams of leading experts, under the guidance of the Volume Editors and the Editors-in-Chief. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource for information in the field. The chapters will not provide basic data on the elements, which is available from many sources (and the original work), but instead concentrate on applications of the elements and their compounds. Provides a comprehensive review which serves to put many advances in perspective and allows the reader to make connections to related fields, such as: biological inorganic chemistry, materials chemistry, solid state chemistry and nanoscience Inorganic chemistry is rapidly developing, which brings about the need for a reference resource such as this that summarise recent developments and simultaneously provide background information Forms the new definitive source for researchers interested in elements and their applications; completely replacing the highly cited first edition, which published in 1973

Early Main Group Metal Catalysis

Author : Sjoerd Harder
Publisher : John Wiley & Sons
ISBN 13 : 3527344489
Total Pages : 400 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Early Main Group Metal Catalysis by : Sjoerd Harder

Download or read book Early Main Group Metal Catalysis written by Sjoerd Harder and published by John Wiley & Sons. This book was released on 2020-04-06 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.

Reactivity of P-H Group of Phosphorus Based Compounds

Author : Kolio D. Troev
Publisher : Academic Press
ISBN 13 : 0128138351
Total Pages : 464 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Reactivity of P-H Group of Phosphorus Based Compounds by : Kolio D. Troev

Download or read book Reactivity of P-H Group of Phosphorus Based Compounds written by Kolio D. Troev and published by Academic Press. This book was released on 2017-09-06 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactivity of P-H Group of Phosphorus Based Compounds bridges the gap between inorganic and organic phosphorus compounds, providing a basis to explore the myriad possibilities for synthesis of novel low and high molecular phosphorus-containing compounds. It covers well-documented reactions in detail, including: tautomerization, oxidation, reduction, alkylation, oxidation coupling, addition reaction to: carbon-carbon multiple bonds, Schiff base, isocyanates, nitriles, epoxides; addition to carbonyl group, Kabachnik- Fields reaction, cross-coupling reaction and more. In an accessible style complete with synthetic routes and figures, the resource then covers the reactivity of multiple P-H group members: phosphines, phosphine oxides, hypophosphorus acid, H-phosphinic acids and polys(alkylene H-phosphonate). This valuable coverage supports the advancement of research and applications in this area for scientists solving a scientific problem or starting a variety of new projects, such as a new reaction for the synthesis of biologically active compounds, new methods of polymer synthesis or a new methodology for polymer modification. Describes the diverse reactivity of the phosphorus-hydrogen group, perhaps the most powerful in organic chemistry Includes practical information for the synthesis of catalysts, biologically active substances, flame retardants, advance materials and polymer materials Offers a visually-accessible guide to important reactions by an internationally recognized chemist

The Lightest Metals

Author : Timothy P. Hanusa
Publisher : John Wiley & Sons
ISBN 13 : 1118751434
Total Pages : 496 pages
Book Rating : 4.1/5 (187 download)

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Book Synopsis The Lightest Metals by : Timothy P. Hanusa

Download or read book The Lightest Metals written by Timothy P. Hanusa and published by John Wiley & Sons. This book was released on 2015-10-12 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first seven metals in the periodic table are lithium, beryllium, sodium, magnesium, aluminium, potassium and calcium, known collectively as the “lightest metals”. The growing uses of these seven elements are enmeshing them ever more firmly into critical areas of 21st century technology, including energy storage, catalysis, and various applications of nanoscience. This volume provides comprehensive coverage of the fundamentals and recent advances in the science and technology of the lightest metals. Opening chapters of the book describe major physical and chemical properties of the metals, their occurrence and issues of long-term availability. The book goes on to disucss a broad range of chemical features, including low oxidation state chemistry, organometallics, metal-centered NMR spectroscopy, and cation-π interactions. Current and emerging applications of the metals are presented, including lithium-ion battery technology, hydrogen storage chemistry, superconductor materials, transparent ceramics, nano-enhanced catalysis, and research into photosynthesis and photoelectrochemical cells. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc

Frontiers in Organometallic Chemistry

Author : Marin A. Cato
Publisher : Nova Publishers
ISBN 13 : 9781594548864
Total Pages : 336 pages
Book Rating : 4.5/5 (488 download)

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Book Synopsis Frontiers in Organometallic Chemistry by : Marin A. Cato

Download or read book Frontiers in Organometallic Chemistry written by Marin A. Cato and published by Nova Publishers. This book was released on 2006 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: A black hole is a point of extreme mass in space-time with a radius, or event horizon, inside of which all electromagnetic radiation (including light) is trapped by gravity. A black hole is an extremely compact object, collapsed by gravity which has overcome electric and nuclear forces. It is believed that stars appreciably larger than the Sun, once they have exhausted all their nuclear fuel, collapse to form black holes: they are "black" because no light escapes their intense gravity. Material attracted to a black hole, though, gains enormous energy and can radiate part of it before being swallowed up. Some astronomers believe that enormously massive black holes exist in the centre of our galaxy and of other galaxies. This book brings together leading research from throughout the world.

Trends in Organometallic Chemistry Research

Author : Marin A. Cato
Publisher : Nova Publishers
ISBN 13 : 9781594544941
Total Pages : 228 pages
Book Rating : 4.5/5 (449 download)

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Book Synopsis Trends in Organometallic Chemistry Research by : Marin A. Cato

Download or read book Trends in Organometallic Chemistry Research written by Marin A. Cato and published by Nova Publishers. This book was released on 2005 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. Research in organometallic chemistry is also conducted in the areas of cluster synthesis, main-group derivatives in unusual oxidation states, organometallic polymers, unstable organometallic compounds and intermediates in matrices, structure determination of organometallic compounds in the solid state [X-ray diffraction] and gaseous states [electron diffraction], and mechanisms of reactions of transient silylenes and related species. In addition to the traditional metals and semimetals, elements such as selenium, lithium and magnesium are considered to form organometallic compounds, e.g. organomagnesium compounds MeMgI, iodo(methyl)magnesium and diethylmagnesium which are Grignard reagents an organo-lithium compound BuLi butyllithium; Organometallic compounds often find practical use as catalysts, the processing of petroleum products and the production of organic polymers.

Alkaline-Earth Metal Compounds

Author : Sjoerd Harder
Publisher : Springer
ISBN 13 : 3642362702
Total Pages : 282 pages
Book Rating : 4.6/5 (423 download)

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Book Synopsis Alkaline-Earth Metal Compounds by : Sjoerd Harder

Download or read book Alkaline-Earth Metal Compounds written by Sjoerd Harder and published by Springer. This book was released on 2013-07-20 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Handbook of Chalcogen Chemistry

Author : Francesco Devillanova
Publisher : Royal Society of Chemistry
ISBN 13 : 1847557570
Total Pages : 884 pages
Book Rating : 4.8/5 (475 download)

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Book Synopsis Handbook of Chalcogen Chemistry by : Francesco Devillanova

Download or read book Handbook of Chalcogen Chemistry written by Francesco Devillanova and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 884 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook of Chalcogen Chemistry: New Perspectives in Sulfur, Selenium and Tellurium provides an overview of recent developments, particularly from the last decade, on the chemistry of the chalcogen group elements (S, Se and Te). While up to a few decades ago, chalcogen chemistry was mainly centred on sulphur, in recent years the research based on Se and Te has increased dramatically, and has created huge scope for the use of compounds based on this type of chemistry. This book is organised into two parts, the first of which deals systematically with the chemistry of chalcogens in relation to other group elements in the periodic table. It also includes an overview of metal-chalcogenides and metal-polychalcogenides. The second part reflects the interdisciplinary nature of chalcogen chemistry and focuses on biological, materials and supramolecular aspects of the field. This book gives a comprehensive overview on recent developments over the last decade and is ideal for researchers in the field.

Polar Organometallic Reagents

Author : Andrew E. H. Wheatley
Publisher : John Wiley & Sons
ISBN 13 : 1119448824
Total Pages : 420 pages
Book Rating : 4.1/5 (194 download)

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Book Synopsis Polar Organometallic Reagents by : Andrew E. H. Wheatley

Download or read book Polar Organometallic Reagents written by Andrew E. H. Wheatley and published by John Wiley & Sons. This book was released on 2022-03-14 with total page 420 pages. Available in PDF, EPUB and Kindle. Book excerpt: Outlines recent advances in the field of polar organometallic chemistry, particularly in the context of the emergent areas of synergic and cooperative species. Polar Organometallic Reagents provides a critical overview of developments in the field of modern polar organometallic chemistry. With a particular focus on the emergent area of synergic heterometallic reagents, this timely volume describes our attempts to understand recently developed polar organometallics and their application in a range of new directions. Contributions from leading researchers present new synthetic work and discuss recent advances in characterization techniques, synthetic applications, and mechanistic understanding of heterometallic complexes. In-depth chapters provide detailed information on fundamental, structural, and theoretical aspects of polar organometallic chemistry while articulating the need and rationale for the advent of new reagents. Topics include alkali and alkaline earth organometallics, synergy and cooperativity, cationic p-block clusters and other developments in main group catalysis, synthetic trends in alkenyl copper, ate complex and borylmetal chemistry, non-traditional reaction environments, and trends in developing greener processes. Designed to keep readers updated with the latest progress in the field, this much-needed book: Includes an introductory chapter outlining the development of synergic bases and the logic behind their creation Highlights the role of solid-state structural work in elucidating the bonding and reactivity displayed by modern polar organometallics Examines the use of calculations in catalyst design and plotting more sustainable reaction pathways Discusses modern trends in solution techniques that have achieved new insights into the structures of active species Presents striking advances in the ease of handling of polar organometallics and the emergence of main group catalysis Polar Organometallic Reagents is essential reading for researchers in chemical disciplines including synthetic inorganic and coordination chemistry, main group chemistry, organometallic chemistry, organic synthesis and catalysis.

Metal-Metal Bonding

Author : Gerard Parkin
Publisher : Springer Science & Business Media
ISBN 13 : 3642052428
Total Pages : 316 pages
Book Rating : 4.6/5 (42 download)

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Book Synopsis Metal-Metal Bonding by : Gerard Parkin

Download or read book Metal-Metal Bonding written by Gerard Parkin and published by Springer Science & Business Media. This book was released on 2010-03-04 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: None

Advances in Heterocyclic Chemistry

Author : Alan R. Katritzky
Publisher : Academic Press
ISBN 13 : 0124046436
Total Pages : 313 pages
Book Rating : 4.1/5 (24 download)

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Book Synopsis Advances in Heterocyclic Chemistry by : Alan R. Katritzky

Download or read book Advances in Heterocyclic Chemistry written by Alan R. Katritzky and published by Academic Press. This book was released on 2012-12-25 with total page 313 pages. Available in PDF, EPUB and Kindle. Book excerpt: Established in 1960, Advances in Heterocyclic Chemistry is the definitive serial in the area—one of great importance to organic chemists, polymer chemists and many biological scientists. Written by established authorities in the field, the comprehensive reviews combine descriptive chemistry and mechanistic insight and yield an understanding of how the chemistry drives the properties. Provides up-to-date material on a fast-growing and highly topical subject area Contains the latest research covering a wide variety of heterocyclic topics Written by leading authorities and designed as a handbook for students and industry and academic researchers

The Synthesis and Characterization of Novel Polysilanes

Author : John Patrick Banovetz
Publisher :
ISBN 13 :
Total Pages : 390 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis The Synthesis and Characterization of Novel Polysilanes by : John Patrick Banovetz

Download or read book The Synthesis and Characterization of Novel Polysilanes written by John Patrick Banovetz and published by . This book was released on 1993 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Hydrogen Storage

Author : Thomas Zell
Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 3110536420
Total Pages : 391 pages
Book Rating : 4.1/5 (15 download)

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Book Synopsis Hydrogen Storage by : Thomas Zell

Download or read book Hydrogen Storage written by Thomas Zell and published by Walter de Gruyter GmbH & Co KG. This book was released on 2019-01-14 with total page 391 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrogen is believed to be the energy source of the future, enabling zero-emission and efficient production of power. This comprehensive publication presents a broad spectrum of various chemical aspects of hydrogen storage. The authors also address global climate change issues, carbon dioxide sequestration problems and CO2-based hydrogen storage.

The Synthesis of Electrophilic Lanthanide and Hafnium Complexes and Their Reactivity Towards S-bond Metathesis

Author : Ivan Castillo
Publisher :
ISBN 13 :
Total Pages : 566 pages
Book Rating : 4.:/5 (34 download)

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Book Synopsis The Synthesis of Electrophilic Lanthanide and Hafnium Complexes and Their Reactivity Towards S-bond Metathesis by : Ivan Castillo

Download or read book The Synthesis of Electrophilic Lanthanide and Hafnium Complexes and Their Reactivity Towards S-bond Metathesis written by Ivan Castillo and published by . This book was released on 2001 with total page 566 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organophosphorus Chemistry

Author : David Loakes
Publisher : Royal Society of Chemistry
ISBN 13 : 1849732817
Total Pages : 398 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Organophosphorus Chemistry by : David Loakes

Download or read book Organophosphorus Chemistry written by David Loakes and published by Royal Society of Chemistry. This book was released on 2011-04-27 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organophosphorus Chemistry provides a comprehensive and critical review of the recent literature. Coverage includes phosphines and their chalcogenides, phosphonium salts, low coordination number phosphorus compounds, penta- and hexa- coordinated compounds, quiquevalent phosphorus acids, nucleotides and nucleic aicds, ylides and related compounds, phosphazenes and the application of physical methods in the study of organophosphorus compounds. This is the 40th in a series of volumes which first appeared in 1970 under the editorship of Stuart Trippett and which covered the literature of organophosphorus chemistry published in the period from January 1968 to June 1969, citing some 1370 publications. The present volume covers the literature from January 2009 to January 2010, citing more than 2200 publications, continuing our efforts to provide an up to date survey of progress in an area of chemistry that has expanded significantly over the past 40 years.

Advances in Organometallic Chemistry

Author :
Publisher : Academic Press
ISBN 13 : 0080580432
Total Pages : 432 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Advances in Organometallic Chemistry by :

Download or read book Advances in Organometallic Chemistry written by and published by Academic Press. This book was released on 1998-03-30 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: This widely-acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry. In basic research, organometallics have contributed inter alia to: * Metal cluster chemistry * Surface chemistry * The stabilization of highly reactive species by metal coordination * Chiral synthesis * The formulation of multiple bonds between carbon and the other elements and between the elements themselves This book is an essential reference work for the academic and industrial chemist and will provide up-to-date material at the cutting edge of chemistry research. In basic research, organometallics have contributed inter alia to: Metal cluster chemistry Surface chemistry The stabilization of highly reactive species by metal coordination Chiral synthesis The formulation of multiple bonds between carbon and the other elements and between the elements themselves