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Author : Jai Hoon Lee
Publisher :
ISBN 13 :
Total Pages : 206 pages
Book Rating : 4.:/5 (246 download)
Download or read book Gas Phase Kinetic Study of Some Simple Atom-molecule Reactions ... written by Jai Hoon Lee and published by . This book was released on 1976 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : A. Fontijn
Publisher : Elsevier
ISBN 13 : 1483291219
Total Pages : 711 pages
Book Rating : 4.4/5 (832 download)
Download or read book Gas Phase Metal Reactions written by A. Fontijn and published by Elsevier. This book was released on 2017-05-04 with total page 711 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book brings together, for the first time, all aspects of reactions of metallic species in the gas phase and gives an up-to-date overview of the field. Reactions covered include those of atomic, other free radical and transient neutral species, as well as ions. Experimental and theoretical work is reviewed and the efforts to establish a closer link between these approaches are discussed. The field is mainly approached from a fundamental point-of-view, but the applied problems which have helped stimulate the interest are pointed out and form the major subject of the final chapters. These emphasize the competition between purely gas-phase and gas-surface reactions.
Author : Peter Frederick Ambidge
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (421 download)
Download or read book Kinetic Studies of Atom-molecule Reactions in the Gas Phase written by Peter Frederick Ambidge and published by . This book was released on 1977 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : V.N. Kondratiev
Publisher : Springer Science & Business Media
ISBN 13 : 3642676081
Total Pages : 254 pages
Book Rating : 4.6/5 (426 download)
Download or read book Gas-Phase Reactions written by V.N. Kondratiev and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present monograph appears after the death of Professor V. N. Kondratiev, one of those scientists who have greatly contributed to the foundation of contem porary gas kinetics. The most fundamental idea of chemical kinetics, put for ward at the beginning of the twentieth century and connected with names such as W. Nernst, M. Bodenstein, N. N. Semenov, and C. N. Hinshelwood, was that the complex chemical reactions are in fact a manifestation of a set of simpler elementary reactions involving but a small number of species. V. N. Kondratiev was one of the first to adopt this idea and to start investigations on the elementary chemical reactions proper. These investigations revealed explicitly that every elementary reaction in turn consisted of many elementary events usually referred to as elementary processes. It took some time to realize that an elementary reaction, represented in a very simple way by a macroscopic kinetic equation, can be described on a microscopic level by a generalized Boltzmann equation. Neverheless, up to the middle of the twentieth century, gas kinetics was mainly concerned with the interpretation of complex chemical reactions via a set of elementary reactions. But later on, the situation changed drastically. First, the conditions for reducing microscopic cquations to macroscopic ones were clearly set up. These are essentially based on the fact that the small perturbations of the Maxwell-Boltzmann distribution are caused by the reaction proper.
Author : B. Levitt
Publisher : Springer Science & Business Media
ISBN 13 : 1468426850
Total Pages : 342 pages
Book Rating : 4.4/5 (684 download)
Download or read book Physical Chemistry of Fast Reactions written by B. Levitt and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chapters in this book are devoted to the elementary reactions of small molecules in the gas phase, with some emphasis on reactions important in combustion. The first three chapters cover experimental measurements made at high temperatures, mainly using shock waves and flames; the final chapter describes discharge flow methods near room temperature. The authors-all active in the fields they describe were asked to aim at a level intermediate between a textbook and a review, designed for readers not already familiar with this branch of chemical kinetics. We hope the book will prove especially useful to research workers in related subjects, to research students, and perhaps as source material for the preparation of lectures. The examples have been chosen to illustrate the theoretical basis of the topics rather than attempt a complete coverage. Professors Wagner and Troe describe the remarkable progress made in recent years in measuring dissociation rates for small molecules. Tests ofunimolecular reaction theories are usually made in the 'fall-off' region of pressure: the kinetics change from first order to second order as the pressure is reduced. For large molecules this region lies below atmospheric pressure and is relatively easily accessible. For molecules with four or less atoms, however, the fall-off region lies well above atmospheric pressure: it has been explored using the high pressure shock tube techniques developed by the authors.
Author : Michael T. Bowers
Publisher : Academic Press
ISBN 13 : 1483216497
Total Pages : 363 pages
Book Rating : 4.4/5 (832 download)
Download or read book Gas Phase Ion Chemistry written by Michael T. Bowers and published by Academic Press. This book was released on 2013-10-22 with total page 363 pages. Available in PDF, EPUB and Kindle. Book excerpt: Gas Phase Ion Chemistry, Volume 2 covers the advances in gas phase ion chemistry. The book discusses the stabilities of positive ions from equilibrium gas-phase basicity measurements; the experimental methods used to determine molecular electron affinities, specifically photoelectron spectroscopy, photodetachment spectroscopy, charge transfer, and collisional ionization; and the gas-phase acidity scale. The text also describes the basis of the technique of chemical ionization mass spectrometry; the energetics and mechanisms of unimolecular reactions of positive ions; and the photodissociation of gas-phase ions. The applications of molecular beam techniques to the study of ion-molecule collisions; as well as the variational treatment of charge transfer reactions are also encompassed. Chemists and biochemists will find the book invaluable.
Author : Leon F. Phillips
Publisher :
ISBN 13 :
Total Pages : 8 pages
Book Rating : 4.:/5 (227 download)
Download or read book Gas-Phase Reactions of Atoms, Ions and Simple Molecules Related to Upper Atmosphere Chemistry written by Leon F. Phillips and published by . This book was released on 1975 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt: The report very briefly covers the following: Atom-molecule and ion-molecule reactions in flow systems; 58.4 nm photolyses of small molecules and the fluorescence of excited molecular ions generated during such photolyses; phase-shift studies of excited atom reactions; and matrix isolation spectroscopy.
Author : Chiu-Nan Wei
Publisher :
ISBN 13 :
Total Pages : 174 pages
Book Rating : 4.:/5 (472 download)
Download or read book The Kinetic Study of Some Simple Atom-molecule Reactions Using Fast Flow Methods written by Chiu-Nan Wei and published by . This book was released on 1975 with total page 174 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Ian W. M. Smith
Publisher : Butterworth-Heinemann
ISBN 13 : 1483161994
Total Pages : 400 pages
Book Rating : 4.4/5 (831 download)
Download or read book Kinetics and Dynamics of Elementary Gas Reactions written by Ian W. M. Smith and published by Butterworth-Heinemann. This book was released on 2013-10-22 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Kinetics and Dynamics of Elementary Gas Reactions surveys the state of modern knowledge on elementary gas reactions to understand natural phenomena in terms of molecular behavior. Part 1 of this book describes the theoretical and conceptual background of elementary gas-phase reactions, emphasizing the assumptions and limitations of each theoretical approach, as well as its strengths. In Part 2, selected experimental results are considered to demonstrate the scope of present day techniques and illustrate the application of the theoretical ideas introduced in Part 1. This publication is intended primarily for working kineticists and chemists, but is also beneficial to graduate students.
Author : Keith J. Laidler
Publisher : Elsevier
ISBN 13 : 1483222411
Total Pages : 263 pages
Book Rating : 4.4/5 (832 download)
Download or read book Reaction Kinetics written by Keith J. Laidler and published by Elsevier. This book was released on 2013-10-22 with total page 263 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactions Kinetics: Volume I: Homogeneous Gas Reactions presents a general introduction to the subject of kinetics, including the basic laws of kinetics and the theoretical treatment of reaction rates. This four-chapter book deals mainly with homogeneous reactions in the gas phase. Chapter 1 presents the kinetic laws based on experimental results in terms of their simple concepts, with a special consideration of the way in which rates depend on concentration, while Chapter 2 deals with the interpretation of rates in terms of more fundamental theories. Chapter 3 covers the overall reactions that are believed to be elementary, such as the reaction between hydrogen and iodine, the reverse decomposition of hydrogen iodide, the corresponding reactions involving deuterium instead of hydrogen, and the dimerizations of butadiene and cyclopentadiene, as well as a few elementary termolecular reactions, all involving nitric oxide. This chapter also includes a general account of some of the elementary reactions that occur as steps in more complex mechanisms. Chapter 4 examines the reaction rates of numerous complex gas reactions. Undergraduate physical chemistry and chemical kinetics students, as well as advanced students in other fields, such as biology and physics, will find this book invaluable.
Author : Willhelm Jost
Publisher : Elsevier
ISBN 13 : 0323146562
Total Pages : 545 pages
Book Rating : 4.3/5 (231 download)
Download or read book Kinetics Of Gas Reaction VIB written by Willhelm Jost and published by Elsevier. This book was released on 2012-12-02 with total page 545 pages. Available in PDF, EPUB and Kindle. Book excerpt: Physical Chemistry: An Advanced Treatise: Kinetics of Gas Reactions, Volume VIB, is devoted to gas phase chemical reactions. The purpose of this treatise is to present a comprehensive treatment of physical chemistry for advanced students and investigators in a reasonably small number of volumes. An attempt has been made to include all important topics in physical chemistry together with borderline subjects which are of particular interest and importance. The book contains six chapters and begins with a study on the elastic and inelastic scattering of ions on molecules, including such topics as rainbow scattering, reactive scattering, and experimental procedures and results of high-resolution measurements. This is followed by separate chapters on collision processes and the theory of elastic scattering; and atom reactions, with a discussion of experimental techniques (static, flow, and pulse methods), among the selected examples being the reactions of H, O, C, and N atoms with alkanes, alkenes, acetylene, sulfur, and nitrogen compounds. Subsequent chapters deal with experimental methods and results obtained by several techniques of relaxation methods in gases; thermal unimolecular reactions; and the interactions between chemical reactions, transport processes, and flow phenomena.
Author : Michael T. Bowers
Publisher : Academic Press
ISBN 13 : 1483216489
Total Pages : 369 pages
Book Rating : 4.4/5 (832 download)
Download or read book Gas Phase Ion Chemistry written by Michael T. Bowers and published by Academic Press. This book was released on 2013-10-22 with total page 369 pages. Available in PDF, EPUB and Kindle. Book excerpt: Gas Phase Ion Chemistry, Volume 1 covers papers on the advances of gas phase ion chemistry. The book discusses the advances in flow tubes and the measurement of ion-molecule rate coefficients and product distributions; the ion chemistry of the earth's atmosphere; and the classical ion-molecule collision theory. The text also describes statistical methods in reaction dynamics; the state selection by photoion-photoelectron coincidence; and the effects of temperature and pressure in the kinetics of ion-molecule reactions. The energy distribution in the unimolecular decomposition of ions, as well as the rapidity of ion-molecule reactions are also encompassed. Chemists, physicists, and people working in aeronomy laboratory and involved in space research will find the book invaluable.
Author : Maria Ramos Martinez
Publisher :
ISBN 13 :
Total Pages : 334 pages
Book Rating : 4.3/5 (91 download)
Download or read book Automated Estimation of Kinetic Rate Parameters and Mechanism of Complex Gas-phase Chemical Reactions written by Maria Ramos Martinez and published by . This book was released on 1974 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: Automated computational techniques were developed and used to evaluate the specific kinetic properties of molecules and to define chemically reacting systems. The Arrhenius rate parameters were calculated for over 100 simple fission, atom transfer, and hot molecule reactions. These data have been used to model the thermal decomposition complex gas phase reactions of organic molecules. As many as 30 elementary reactions were used in the reaction simulation analyses. Concentration/rate time histories were computed for each species represented in the mechanism scheme. The effective rate coefficients and kinetic order of some of the reactions were also determined from the basic data. The data are interpreted and correlated in some detail with experimental findings. (Author).
Author : Harold S. Johnston
Publisher :
ISBN 13 :
Total Pages : 384 pages
Book Rating : 4.3/5 (91 download)
Download or read book Gas Phase Reaction Rate Theory written by Harold S. Johnston and published by . This book was released on 1966 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Keiji Morokuma
Publisher :
ISBN 13 :
Total Pages : 18 pages
Book Rating : 4.:/5 (455 download)
Download or read book Theoretical Studies of Gas Phase Elementary Reactions written by Keiji Morokuma and published by . This book was released on 1998 with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt: Understanding the mechanism, kinetics and dynamics of elementary gas phase reactions is one of the major goals of chemistry. Such understanding is also essential to predicting and understanding plasma dynamics and optical radiation associated with the spacecraft-atmosphere interactions. The objective of the present research was to provide, based on mainly the ab initio molecular orbital and some dynamics calculations, theoretical information concerning the potential energy surfaces that dictate the kinetics and dynamics of gas phase elementary reactions. The reactions studied include ion-molecule reactions, photochemical reactions and neutral elementary reactions. Many of the systems for which theoretical calculations were performed in the present research are relevant to atmospheric chemistry and chemical lasers. Many systems were chosen based on the experimental studies and in collaboration with scientists at Air Force Research Laboratory, in order to provide them with some new insight that is not easily available without theoretical studies.
Author : Shuying Liu
Publisher :
ISBN 13 :
Total Pages : 282 pages
Book Rating : 4.:/5 (88 download)
Download or read book Kinetics of Gas Phase Ion-molecule Association Reactions in Simple Systems written by Shuying Liu and published by . This book was released on 1985 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Carleton James Howard
Publisher :
ISBN 13 :
Total Pages : 336 pages
Book Rating : 4.:/5 (13 download)
Download or read book Kinetics of Some Gas Phase Ion-molecule Reactions Involving Water Vapor written by Carleton James Howard and published by . This book was released on 1971 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt:
